Organic chemistry Books
Cambridge University Press Introduction to Phosphorous Chemistry
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£45.59
Cambridge University Press Surface Analysis of Polymers by XPS and Static Sims
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£118.75
Cambridge University Press The Chemistry of Macrocyclic Ligand Complexes
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Cambridge University Press Half a Century of Free Radical Chemistry
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£35.14
Cambridge University Press Bound Carbohydrates in Nature
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£48.44
Cambridge University Press Understanding Organic Reaction Mechanisms
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£69.34
Cambridge University Press Practical Polyphenolics
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Cambridge University Press Modern Methods of Organic Synthesis
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£75.99
Cambridge University Press Amines Synthesis Properties and Applications
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£194.75
Cambridge University Press Rubberlike Elasticity
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£102.00
Cambridge University Press Crystallization of Polymers
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£126.00
Pearson Education (US) Organic Chemistry
Book SynopsisTable of ContentsPART 1: AN INTRODUCTION TO THE STUDY OF ORGANIC CHEMISTRY 1. Remembering General Chemistry: Electronic Structure and Bonding 2. Acids and Bases: Central to Understanding Organic Chemistry TUTORIAL: Acids and Bases 3. An Introduction to Organic Compounds: Nomenclature, Physical Properties, and Structure PART 2: ELECTROPHILIC ADDITION REACTIONS, STEREOCHEMISTRY, AND ELECTRON DELOCALIZATION TUTORIAL: Using Molecular Models 4. Isomers: The Arrangement of Atoms in Space TUTORIAL: Interconverting Structural Representations 5. Alkenes: Structure, Nomenclature, and an Introduction to Reactivity • Thermodynamics and Kinetics TUTORIAL: Drawing Curved Arrows 6. The Reactions of Alkenes • The Stereochemistry of Addition Reactions 7. The Reactions of Alkynes • An Introduction to Multistep Synthesis 8. Delocalized Electrons: Their Effect on Stability, pKa, and the Products of a Reaction • Aromaticity and Electronic Effects: An Introduction the Reactions of Benzene TUTORIAL: Drawing Resonance Contributors PART 3: SUBSTITUTION AND ELIMINATION REACTIONS 9. Substitution and Elimination Reactions of Alkyl Halides 10. Reactions of Alcohols, Ethers, Epoxides, Amines, and Sulfur-Containing Compounds 11. Organometallic Compounds 12. Radicals TUTORIAL: Drawing Curved Arrows in Radical Systems PART 4: IDENTIFICATION OF ORGANIC COMPOUNDS 13. Mass Spectrometry; Infrared Spectroscopy; and UV/Vis Spectroscopy 14. NMR Spectroscopy PART 5: CARBONYL COMPOUNDS 15. Reactions of Carboxylic Acids and Carboxylic Acid Derivatives 16. Reactions of Aldehydes and Ketones • More Reactions of Carboxylic Acid Derivatives 17. Reactions at the α-Carbon TUTORIAL: Synthesis and Retrosynthetic Analysis PART 6: AROMATIC COMPOUNDS 18. Reactions of Benzene And Substituted Benzenes 19. More About Amines • Reactions of Heterocyclic Compounds PART 7: BIOORGANIC COMPOUNDS 20. The Organic Chemistry Of Carbohydrates 21. Amino Acids, Peptides, and Proteins 22. Catalysis in Organic Reactions and in Enzymatic Reactions 23. The Organic Chemistry of the Coenzymes, Compounds Derived from Vitamins 24. The Organic Chemistry of the Metabolic Pathways 25. The Organic Chemistry of Lipids 26. The Chemistry of the Nucleic Acids PART 8: SPECIAL TOPICS IN ORGANIC CHEMISTRY 27. Synthetic Polymers 28. Pericyclic Reactions Appendices I. pKa Values II. Kinetics III. Summary of Methods Used to Synthesize a Particular Functional Group IV. Summary of Methods Employed to Form Carbon-Carbon Bonds V. Spectroscopy Tables VI. Physical Properties of Organic Compounds VII. Answers to Selected Problems
£243.94
Oxford University Press Aromatic Heterocyclic Chemistry
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£999.99
Mariner Books Full Spectrum
Book SynopsisInformative and entertaining...Rogers is a seasoned raconteur, unreeling an eons-spanning tale with skill. —Wall Street JournalA lively account of our age-old quest for brighter colors, which changed the way we see the world, with a new afterword by the author From kelly green to millennial pink, our world is graced with a richness of colors. But our human-made colors haven’t always matched nature’s kaleidoscopic array. To reach those brightest heights required millennia of remarkable innovation and a fascinating exchange of ideas between science and craft that’s allowed for the most luminous manifestations of our built and adorned world.In Full Spectrum, Rogers takes us on that globe-trotting journey, tracing an arc from the earliest humans to our digitized, synthesized present and future. We meet our ancestors mashing charcoal in caves, Silk Road merchants competing for the best ceramics, and textile artists cracking the centuries-old mystery of how colors mix, before shooting to the modern era for high-stakes corporate espionage and the digital revolution that’s rewriting the rules of color forever. In prose as vibrant as its subject, Rogers opens the door to Oz, sharing the liveliest events of an expansive human quest—to make a brighter, more beautiful world—and along the way, proving why he’s “one of the best science writers around.”* *National Geographic
£16.14
WW Norton & Co Symphony in C
Book SynopsisA Science News Favorite Book of 2019 An earth scientist reveals the dynamic biography of the most resonant—and most necessary—chemical element on Earth.Trade Review"A fascinating read." -- Science News"A valuable and welcome explanation of why we would do well to pay more attention to the sixth element?and of how much more remains to be discovered about its planetary role through time." -- Ted Nield - Nature"A symphonic masterpiece that reveals how the primitive life that began on our planet four billion years ago has evolved into Darwin’s ‘endless forms most beautiful.’" -- David W. Deamer, author of Assembling Life"Hazen’s enthusiasm, the string of shareable facts presented, and the introduction of so many interesting scientists… make this book such a fascinating read.… Hazen brings a distinct and intentionally personal perspective to this topic.… Throughout Symphony in C, science is presented as a living and very human endeavor." -- Nicola Pohl - Science"Hazen sets the record straight in this thoughtful love letter to [carbon]." -- Gemma Tarlach - Discover"[A] lively, expert overview.… Hazen [is] a smooth stylist.… A skillful account of the central element in our lives." -- Kirkus Reviews"Hazen brings the process of scientific investigation to life.… [He] conveys the delight he finds in the process of understanding the world around him.… [This] enthusiastic survey also shows the limits of existing knowledge and the potential for future discoveries in an exciting field." -- Publishers Weekly"Probing.… Science that burrows into issues of profound interest." -- Booklist"From the Big Bang to coal, carbohydrates, and ultra-strong high-tech nanofibers, Robert M. Hazen provides an illuminating and enjoyable guide to the remarkable odyssey of carbon, the element of life. Enjoy the trip!" -- Andrew Knoll, Fisher Professor of Natural History, Harvard University"Robert M. Hazen’s virtuoso performance captures the wonder of the sixth element?from volcanic gases to al dente pasta to life’s very beginnings?while telling the wonderful stories about the people behind the discoveries." -- Terry Plank, Arthur D. Storke Memorial Professor of Geochemistry, Columbia University
£13.29
WW Norton & Co Symphony in C
Book SynopsisA Science News Favorite Book of 2019 An enchanting biography of the most resonant—and most necessary—chemical element on Earth.Trade Review"Covering topics from carbon’s ancient origins to the threats that carbon compounds pose to our future climate, Hazen’s book is a fascinating read. Symphony in C chronicles cutting-edge science that’s helping researchers make better sense of the carbon-rich world around us." -- Science News"From the Big Bang to coal, carbohydrates, and ultra-strong high-tech nanofibers, Robert M. Hazen provides an illuminating and enjoyable guide to the remarkable odyssey of carbon, the element of life. Enjoy the trip!" -- Andrew Knoll, Fisher Professor of Natural History, Harvard University"A valuable and welcome explanation of why we would do well to pay more attention to the sixth element—and of how much more remains to be discovered about its planetary role through time." -- Nature"C is the element carbon. C is a musical note. Scientist-musician Hazen uses the element and the note to compose a symphonic masterpiece that reveals how the primitive life that began on our planet four billion years ago has evolved into Darwin’s ‘endless forms most beautiful.’" -- David W. Deamer, author of Assembling Life"Hazen’s virtuoso performance captures the wonder of the sixth element—from volcanic gases to al dente pasta to life’s very beginnings—while telling the wonderful stories about the people behind the discoveries." -- Terry Plank, Arthur D. Storke Memorial Professor of Geochemistry, Columbia University"This book is an incredibly rich story of carbon and its role in of life. Hazen has outdone himself in delivering an engaging, edifying, great read. If you don’t know why carbon is important in your life, or even if you think you do, you should put down whatever you’re reading and get this book." -- Paul G. Falkowski, author of Life’s Engines
£19.94
W. W. Norton & Company Organic Chemistry
Book Synopsis
£152.80
WW Norton & Co Study Guide and Solutions Manual For Organic
Book Synopsis
£95.00
John Wiley & Sons Inc Dendrimers
Book SynopsisThis book will be mainly focussed on the properties and uses of dendrimers and dendrons. The aim of this book is to be the reference book about dendrimers applications. It will not describe all details, but it will give the reader a unique overview of what has currently been done with dendrimers, with numerous references and illustrations. It will be divided in four main parts: Part 1) Generalities, syntheses, characterizations and properties; Part 2) Applications in catalysis; Part 3) Applications for the elaboration or modification of materials; and Part 4) Applications in biology/medicine. The role of the nanometric size and the multiple functions of dendrimers on the properties will be emphasized.Trade Review “The book is of high quality and recommended reading for anyone working with dendrimers or wanting to have a good reference book; rich in information, clearly organized and thoroughly referenced with topical primary publications.” (Angewandte Chemie, 2012) Table of ContentsPreface xv Part 1 Generalities, Syntheses, Characterizations, and Physicochemical Properties 1 1 Syntheses of Dendrimers and Dendrons 3 Anne-Marie Caminade 1.1 Introduction: What Are Dendrimers and Dendrons? 3 1.2 Syntheses of Poly(propyleneimine) Dendrimers (PPI) 5 1.3 Synthesis of Poly(amidoamine) Dendrimers (PAMAM) 5 1.4 Syntheses of Poly(ether) Dendrimers 7 1.5 Syntheses of Poly(ester) Dendrimers 10 1.6 Synthesis of Poly(lysine) Dendrimers 14 1.7 Syntheses of Silicon-Containing Dendrimers 15 1.8 Syntheses of Phosphorus-Containing Dendrimers 16 1.9 Syntheses of Carbon-Based Dendrimers 17 1.10 Syntheses of Dendrimers Constituted of Nitrogen Heterocycles 19 1.11 Syntheses by Self-Assembly 21 1.12 Accelerated Syntheses 26 1.13 Conclusion 30 References 30 2 Methods of Characterization of Dendrimers 35 Anne-Marie Caminade 2.1 Introduction 35 2.2 Spectroscopy and Spectrometry 36 2.2.1 Nuclear Magnetic Resonance (NMR) 36 2.2.2 Mass Spectrometry 40 2.2.3 X-ray Diffraction 41 2.2.4 Infrared (IR) and Raman Spectroscopy 42 2.2.5 Ultraviolet–Visible (UV–vis) Spectroscopy 43 2.2.6 Fluorescence 44 2.2.7 Chirality, Optical Rotation, and Circular Dichroism (CD) 45 2.2.8 Electron Paramagnetic Resonance (EPR) 45 2.2.9 Electrochemistry 46 2.2.10 Magnetometry 46 2.2.11 Mössbauer Spectroscopy 46 2.2.12 X-ray Spectroscopies 47 2.3 Scattering Techniques 47 2.3.1 Laser Light Scattering (LLS) 47 2.3.2 Small-Angle Neutron Scattering (SANS) 47 2.3.3 Small-Angle X-ray Scattering (SAXS) and Wide-Angle X-ray Scattering (WAXS) 48 2.4 Microscopy 48 2.4.1 Transmission Electron Microscopy (TEM) 49 2.4.2 Atomic Force Microscopy (AFM) 49 2.4.3 Polarizing Optical Microscopy (POM) 50 2.5 Rheology and Physical Characterizations 50 2.5.1 Intrinsic Viscosity 50 2.5.2 Differential Scanning Calorimetry (DSC) 50 2.5.3 Dielectric Spectroscopy (DS) 51 2.5.4 Dipole Moments 51 2.6 Separation Techniques 52 2.6.1 Size Exclusion Chromatography 52 2.6.2 Electrophoresis 53 2.7 Conclusion 53 References 54 3 Luminescent Dendrimers 67 Anne-Marie Caminade 3.1 Introduction 67 3.2 Dendrimers with Fluorescent Terminal Groups 68 3.2.1 Fully Substituted Dendrimers 68 3.2.2 Partially Substituted Dendrimers 69 3.3 Luminescent Group at the Core of Dendrimers and Energy/Light-Harvesting Properties 74 3.3.1 Organic Fluorophores as Cores 74 3.3.2 Porphyrins and Phthalocyanines as Cores 77 3.3.3 Metallic Cores 78 3.4 Fluorescent Groups inside the Structure of Dendrimers 79 3.5 Intrinsically Fluorescent Dendrimers 81 3.5.1 Fluorescent Groups throughout the Dendrimeric Structure 81 3.5.2 Fluorescence of Dendrimers without Known Fluorophores 86 3.6 Two-Photon-Excited Fluorescence of Dendrimers 86 3.7 Conclusion 89 References 90 4 Stimuli-Responsive Dendrimers 99 Anne-Marie Caminade 4.1 Introduction 99 4.2 Photoresponsive Dendrimeric Structures 100 4.2.1 Azobenzene-Containing Dendrimers and Dendrons 101 4.2.2 Other Types of Photoresponsive Dendrimers 108 4.3 Thermoresponsive Dendrimeric Structures 110 4.3.1 Thermoresponsive Properties of Dendrimers 110 4.3.2 Thermoresponsive Properties of Dendrons and Dendronized Polymers 112 4.4 Dendrimers Responsive to Solution Media Changes 114 4.4.1 pH-Responsive Dendrimers 114 4.4.2 Dendrimers Disassembly 115 4.5 Conclusion 117 References 118 5 Liquid Crystalline Dendrimers 125 Anne-Marie Caminade 5.1 Introduction 125 5.2 Mesogenic Groups as Terminal Functions of Dendrons 126 5.3 Mesogenic Groups as Terminal Functions of Dendrimers 131 5.4 Mesogenic Groups as Branches of Dendrimers 134 5.5 Conclusion 135 References 136 6 Dendrimers and Nanoparticles 141 Cédric-Olivier Turrin and Anne-Marie Caminade 6.1 Introduction 141 6.2 Dendrimers or Dendrons for Coating Nanoparticles 142 6.2.1 Dendronization of Nanoparticles by Ligand Exchange 142 6.2.2 Direct Synthesis of Dendronized Nanoparticles 147 6.2.3 Dendrimer Coated Nanoparticles 149 6.2.4 Nanocomposites with Interdendrimer Nanoparticles 151 6.3 Dendrimers as Templates for the Synthesis of Dendrimer-Encapsulated Nanoparticles (DENs) 152 6.3.1 Catalysis with Dendrimer-Encapsulated Nanoparticles 153 6.3.2 Other Uses of Dendrimer-Encapsulated Nanoparticles 154 6.4 Conclusion and Perspectives 154 References 155 Part 2 Applications in Catalysis 163 7 Terminal Groups of Dendrimers as Catalysts for Homogeneous Catalysis 165 Armelle Ouali and Anne-Marie Caminade 7.1 General Introduction 165 7.1.1 The “Dendrimer Effect” 165 7.1.2 Recycling the Catalysts 166 7.2 Catalytic Organometallic Sites as Catalysts for Homogeneous Catalysis 167 7.2.1 Formation of C–X Bonds (X = C, N, O) 167 7.2.2 Addition Reactions on a C=X Double Bond (X = C, O) 175 7.2.3 Oxidation Reactions 177 7.3 Organocatalysis with Dendrimers 178 7.4 Conclusion 178 References 179 8 Catalytic Sites inside the Dendrimeric Structure for Homogeneous Catalysis 183 Armelle Ouali and Anne-Marie Caminade 8.1 Introduction 183 8.2 Catalytic Sites as the Core of Dendrimers 184 8.2.1 Dendrimers Bearing a Transition-Metal-Based Complex at the Core 184 8.2.2 Dendrimers Bearing an Organocatalyst at the Core 188 8.3 Catalytic Sites inside the Branches of Dendrimers 191 8.3.1 Formation of C–X Bonds (X = C, N, O) 191 8.3.2 Addition Reactions on a C=C Double Bond: Olefi n Hydrogenation 192 8.4 Conclusion 192 References 193 9 Dendrimers as Homogeneous Enantioselective Catalysts 197 Armelle Ouali and Anne-Marie Caminade 9.1 Introduction 197 9.2 Catalytic Organometallic Sites as Catalysts for Homogeneous Catalysis 198 9.2.1 Formation of C–X Bonds (X = C, N, O) 198 9.2.2 Addition Reactions on a C=X Double Bond (X = C, O) 204 9.3 Organocatalysis with Dendrimers 209 9.3.1 Aldolizations 209 9.3.2 Aza–Morita–Baylis–Hillmann Reactions 209 9.3.3 Transaminations 210 9.4 Conclusion 210 References 210 10 Catalysis with Dendrimers in Particular Media 215 Régis Laurent and Anne-Marie Caminade 10.1 Introduction 215 10.2 Two-Phase (Liquid–Liquid) Media 216 10.3 Catalysis in Ionic Liquids 219 10.4 Catalysis in Supercritical Media 220 10.5 Catalysis in Aqueous Media 221 10.6 Conclusion 234 References 234 11 Heterogeneous Catalysis with Dendrimers 239 Régis Laurent and Anne-Marie Caminade 11.1 Introduction 239 11.2 Catalysis with Dendrons Synthesized from a Solid Material 240 11.2.1 Silica as an Inorganic Support 240 11.2.2 Polymers and Resins as Organic Supports 248 11.3 Catalysis with Dendrons or Dendrimers Grafted on to a Solid Surface 254 11.4 Catalysis with Insoluble Dendrimers 257 11.5 Conclusion 260 References 261 Part 3 Applications for the Elaboration or Modification of Materials 267 12 Dendrimers inside Materials 269 Régis Laurent and Anne-Marie Caminade 12.1 Introduction 269 12.2 Dendrimers for the Elaboration of Gels 270 12.2.1 Dendrimers for the Elaboration of Supramolecular Hygrogels 270 12.2.2 Dendrimers for the Elaboration of Polymer-Type Hygrogels 273 12.2.3 Dendrimers for the Elaboration of Organogels 276 12.3 Dendrimers inside Silica Gels 280 12.4 Dendrimers inside Other Types of Materials 285 12.5 Dendrimers for the Elaboration of OLEDs 288 12.5.1 Fluorescent Dendrimers for the Elaboration of OLEDs 290 12.5.2 Phosphorescent Dendrimers for the Elaboration of OLEDs 295 12.6 Conclusion 298 References 299 13 Self-Assembly of Dendrimers in Layers 313 Béatrice Delavaux-Nicot and Anne-Marie Caminade 13.1 Introduction 313 13.2 Langmuir–Blodgett Films of Dendrons and Dendrimers 314 13.2.1 Poly(benzyl ether) Derivatives 316 13.2.2. Poly(amidoamine) and Poly(propyleneimine) Derivatives 319 13.2.3 Azobenzene Derivatives 320 13.2.4 Poly(carbosilane) Dendrimer Derivatives 321 13.2.5 Fullerene C60 Derivatives 322 13.2.6 Other Examples 325 13.3 Assemblies of Dendrons and Dendrimers on Solid Surfaces 326 13.3.1 Assembly of Dendrons and Dendrimers on Gold Surfaces 327 13.3.2 Assembly of Dendrons and Dendrimers on Silicon Substrates or Related Substrates 330 13.4 Several Routes for the Formation of Dendron or Dendrimer Multilayers 334 13.5 Nanoimprinting with Dendrons and Dendrimers on Solid Surfaces 342 13.5.1 Dendrimer-Based Self-Assembled Monolayers as Resists for Scanning Probe Lithography 342 13.5.2 Microprinting, Transfer Printing, and Dip-Pen Nanolithography with Dendrimers 344 13.6 Conclusion 350 References 351 14 Dendrimers as Chemical Sensors 361 Anne-Marie Caminade 14.1 Introduction 361 14.2 Dendrimers as Chemical Sensors in Solution 362 14.2.1 Porphyrins and Other Macrocyclic Derivatives as the Core or Branches of Dendrimeric Sensors 362 14.2.2 Terminal Groups of Dendrimers as Sensors in Solution 363 14.3 Dendrimers as Electrochemical Sensors 365 14.4 Dendrimers on Modifi ed Surfaces as Chemical Sensors 367 14.4.1 Dendrimers on Surfaces at the Interface with a Solution 367 14.4.2 Dendrimers on Surfaces at the Interface with a Vapor 368 14.5 Conclusion 370 References 370 15 Dendrimers as Biological Sensors 375 Anne-Marie Caminade 15.1 Introduction 375 15.2 Dendrimers as Sensors in Solutions of Biological Media 375 15.3 Detection by Electrochemical Methods 378 15.4 Dendrimers or Dendrons for DNA Microarrays 380 15.5 Dendrimers for Other Types of Biomicroarrays 383 15.6 Dendrimers on Other Types of Support 384 15.7 Dendrimers as Multiply Labeled Entities Connected to the Target 385 15.8 Conclusion 386 References 387 Part 4 Applications in Biology/Medicine 393 16 Dendrimers for Imaging 395 Cédric-Olivier Turrin and Anne-Marie Caminade 16.1 Introduction 395 16.2 Magnetic Resonance Imaging with Dendrimers 395 16.2.1 Paramagnetic Dendrimer-Based Contrast Agents 398 16.2.2 PARACEST Dendrimer-Based Contrast Agents 402 16.2.3 Superparamagnetic Dendrimer-Based Contrast Agents 402 16.2.4 Dendrimer-Based 129Xe HYPER-CEST MRI Contrast Agents 403 16.2.5 19F Dendrimer-Based MRI Contrast Agents 403 16.3 Other Types of Imaging with Dendrimers 403 16.3.1 Dendrimers for Optical Imaging 403 16.3.2 Dendrimers for Nuclear Medicine (NM) Imaging and Computed Tomography X-Ray Imaging (CT) 405 16.4 Conclusion and Perspectives 407 References 407 17 Dendrimers as Transfection Agents 413 Cédric-Olivier Turrin and Anne-Marie Caminade 17.1 Introduction 413 17.2 Gene Transfection with PAMAM Dendrimers 415 17.2.1 Pioneering Results 415 17.2.2 Gene Transfection with Surface-Modifi ed PAMAM 416 17.2.3 Gene Transfection with Core-Modifi ed PAMAM 418 17.2.4 Gene Transfection with PAMAM-Functionalized Nanoparticles 419 17.2.5 Gene Transfection with PAMAM-Like Hyperbranched Polymers 420 17.3 Gene Transfection with Other Dendrimers 421 17.3.1 Gene Transfection with PPI Dendrimers 421 17.3.2 Gene Transfection with Peptide-Based Dendrimers 422 17.3.3 Gene Transfection with Phosphorus-Based Dendrimers 423 17.3.4 Gene Transfection with Silane-Based Dendrimers 424 17.4 Conclusion and Perspective 426 References 426 18 Dendrimer Conjugates for Drug Delivery 437 Cédric-Olivier Turrin and Anne-Marie Caminade 18.1 Introduction 437 18.2 Improving Bioavailability with Dendrimers 438 18.3 Passive Targeting in Tumors with Dendrimer–Drug Conjugates 440 18.3.1 Dendrimer–Drug Bioconjugates and the EPR Effect 440 18.3.2 PEGylated Dendrimeric Scaffolds 442 18.4 Active Targeting with Site-Specifi c Dendrimer–Drug Conjugates 446 18.4.1 Addressing with Folic Acid (FA) 446 18.4.2 Addressing with Tumor-Homing Peptides 448 18.4.3 Addressing with Monoclonal Antibodies 449 18.5 Dendrimers for Photodynamic Therapy (PDT) 449 18.6 Dendrimers for Boron Neutron Capture Therapy (BNCT) 451 18.7 Conclusion and Perspectives 452 References 453 19 Encapsulation of Drugs inside Dendrimers 463 Cédric-Olivier Turrin and Anne-Marie Caminade 19.1 Introduction 463 19.2 From Dendritic Boxes to Dendrimer-Based Formulations 464 19.3 Improving Bioavailability with Dendrimers? 464 19.4 Toxicological Issues 465 19.5 Dendrimer-Based Formulations for Drug Delivery 466 19.5.1 Nontargeted Formulations 466 19.5.2 Supramolecular Assemblies Involving Surface Ionic Interactions 473 19.5.3 Targeted Formulations 475 19.6 Conclusion and Perspectives 477 References 477 20 Unexpected Biological Applications of Dendrimers and Specifi c Multivalency Activities 485 Cédric-Olivier Turrin and Anne-Marie Caminade 20.1 Introduction 485 20.2 Dendrimers and Multivalency 486 20.2.1 Multivalent Effects and Dendrimeric Effects 486 20.2.2 Glycodendrimers 487 20.3 Antimicrobial Dendrimers 488 20.3.1 Polycationic Dendrimers 489 20.3.2 Polyanionic Dendrimers 491 20.4 From Immunomodulation to Regenerative Medicine 494 20.4.1 Immunomodulation and Anti-Inflammation 494 20.4.2 Dendrimers and Regenerative Medicine 498 20.5 Conclusion and Perspectives 501 References 502 21 General Conclusions and Perspectives 511 Anne-Marie Caminade Index 515
£137.70
John Wiley & Sons Inc Inorganic Syntheses Volume 31
Book SynopsisThe volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preperation of important inorganic solidsd, sutheses used in the development of pharamacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains calcuable information on transition organometallic compunds, including species with meta-metal cluster molecules. All syntheses presented here have been tested.Table of ContentsChapter One MAIN GROUP COMPOUNDS. 1. Volatile-² Diketonate Complexes of Calcium(II), Strontium(II), and Barium(II). 2. Bis(1,1,1,3,3,3-hexamethyldisilazanato) bis(tetrahydrofuran)-barium. 3. Ammonium and Barium Salts of the Tris- [1,2-benzenediolate(2-)-O,O']titanium(IV) Dianion. 4. N-Donor Adducts of Dimethylzinc. 5. Arene Chalcogenolato Complexes of Zinc and Cadmium. 6. Arene Thiolato, Selenolato, and Tellurolato Complexes of Mercury. 7. Electronic Grade Alkyls of Group 12 and 13 Elements. 8. Trimethylindium and Trimethylgallium. 9. (N,N-dimethylethanamine) trihydridoafuminum. 10. Tertiary Amine and Phosphine Adducts of Gallium Trihydride. 11. trans-1,1-Di-tert-butyl-2,3-dimethylsilane and 2,2-Di-tert-butyl 1,1,1-triethyldisilane. 12. Tin(II) Sulfide and Tin(II) Selenide. 13. Tin(IV) Fluoride (Tetrafluorostannane). 14. N,N,N'-Tris(trimethylsilyl) Amidines. 15. Homoleptic Bismuth Amides. 16. Cyclo-tetrasulfur(2+) Bis[hexafluoroarsenate(1-)], Cyclo-tetrasulfur(2+)Bis[undecafluorodiantimonate(1-)], Cyclo-tetraselenium(2+)Bis[hexafluroarsenate(1-)] and Cyclo-tetraselenium(2+) Bis[undecafluorodiantimonate(1-)]. 17. Fe2(S2)(CO)6, and Fe3Te2(CO)9,10. Chapter Two LIGANDS AND REAGENTS. 18. 5,10,15,20-Tetrakis (2,6-dihydroxyphenyl) -21H,23H-porphine. 19. Tribenzocycline (TBC) and Tetrabenzocyclyne (QBC). 20. (Chloromethylene)bis[trimethylsilane] [Bis(trimethylsilyl)chloromethane]. 21. S,S-Chiraphos [(S,S)-(-)-(1,2-Dimethyl-1,2-ethandiyl) bis-(diphenylphosphine)]. 22. ²-Ketophosphines: Ligands of Catalytic Relevance. 23. N,N-Diisobutyl-2-(octylphenylphosphinyl) acetamide (CMPO). 24. Aresenic(III) Chloride. 25. Tris(trimethylsilyl)arsine and Lithium Bis(trimethylsilyl)arsenide. 26. Sterically Hindered Arene Chalcogenols. 27. Tris(trimethylsilyl)silyl Lithium Tris(tetrahydrofuran), Lithium Tris(trimethylsilyl)silyltellurolate Bis(tetrahydrofuran), and Tris(trimethylsilyl)silyltellurol. 28. Metal Complexes of the Lacunary Heteropolytungstates [B-±-PW9O34]9- and [±-P2W15O56]12-. 29. Polyoxoanion-Supported, Atomically Dispersed Iridium(I) and Rhodium(I). Chapter Three ORGANOMETALLIC COMPOUNDS. 30. One-Pot Synthesis of Dicarbonyltris(phosphine)iron(0) Complexes from Pentacarbonyliron. 31. Tricarbonylbis(phosphine)iron(0) Complexes. 32. (·5-Pentamethylcyclopentadienyl) (·5-cyclopentadienyl)iron [1,2,3,4,5-pentamethylferrocene]. 33. Pyrazolate-Bridged Ruthenium(I) Carbonyl Complexes. 34. Main Group-Transition Metal Carbonyl Complexes. 35. MnII4(1/44-O)[(CO)9Co3(1/43-CCO2)]6, M = Co, Zn. 36. 1,2,3,4-Tetramethyl-5-(trifluoromethyl)cyclopentadiene (Cp+ H) and Di-1/4-Chlorodichlorobis [·5-tetramethyl- (Trifluoromethyl)Cyclopentadienyl] Dirhodium(III). 37. Acetonitrile-Substituted Derivatives of Rh6(CO)16: Rh6(CO)16-x(NCMe)x(x = 1, 2). 38. Tetraphenylarsonium Carbonyltrichloroplatinate(II). Chapter Four TRANSITION METAL, LANTHANIDE, AND ACTINIDE COMPLEXES. 39. Dichlordioxobis(dimethyl sulphoxide)molybdenum(VI). 40. Metal-Catalyzed Synthesis of cis-[Re(CO)4,LI] [L = P(OMe)3, PMe2Ph, PPh3]. 41. Tris(l,2-bis(dimethylphosphino) ethane)rhenium(1) Trifluoromethanesulfonate, [Re(DMPE)3[CF3SO3]. 42. Tetrahalo Oxorhenate Anions. 43. A Rhenium(I) Dinitrogen Complex Containing a Tertiary Phosphine. 44. Bis(2,4-pentanedionato)iron(II) [Iron(II)Bis(acetylacetonate)]. 45. Synthesis of trans-Tetraammined.ichlorocobalt(III)Chloride. 46. [[3,3'-(1,3-Propanediyldiimino) bis[3-methy-2-butanone]- dioximatel(1-)-N,N',N'',N''']nickel(II), Nioyl. 47. Platinum Complexes Suitable as Precursors for Synthesis in Nonaqueous Solvents. 48. Tetrakis(propanenitrile)platinum(II)Trifluoromethanesulfonate as a Suitable Intermediate in Synthetic Pt(II) Chemistry. 49. [(1,2,5,6-·)-1,5-Cyclooctadiene]dimethylplatinum(II). 50. Bis(2,2,6,6-tetramethyl-3,5 -heptanedionato)copper. 51. Lewis Base Adducts of 1,1,1,5,5,5 -Hexafluoro-2,4-pentadionato -Copper(I) Compounds. 52. Copper(II) Alkoxides. 53. Pyrazolato Copper(I) Complexes. 54. Tris(2,2,6,6-tetramethyl -3,5-heptanedionato) Yttrium. 55. Lewis Base Adducts of Uranium Triiodide and Tris[bis(trimethylsilyl)amido] uranium. Contributor Index. Subject Index. Formula Index. Chemical Abstracts Service Registry Number Index.
£204.20
John Wiley & Sons Inc Heterocyclic Chemistry
Book SynopsisDeals with the fundamental chemistry of fully saturated and unsaturated 4-, 5- and 6- membered heterocycles. This title introduces a selection of important heterocyclic compounds and the vital role that they play in life, medicine and industry.Trade Review"Although primarily an undergraduate text, the main principles that govern heterocyclic chemistry as a whole are addressed in this book, providing a sure foundation for those wishing to widen their interest in heterocyclic chemistry in later years." (The Chemist, Summer 2003) "...this is a useful and straightforward little text that could be recommended to students who seriously want to get to grips with the basics of heterocyclic chemistry." (Biochemistry and Molecular Education, Jan/Feb 2002)Table of ContentsIntroduction to Heterocyclic Chemistry. Pyridine. Benzopyridines. Pyrylium Salts, Pyrans and Pyrones. Benzopyrylium Salts, Coumarins, Chromones, Flavonoids and Related Compounds. Five-membered Heterocycles containing One Heteroatom: Pyrrole, Furan and Thiophene. Benzo[b]pyrrole, Benzo[b]furan and Benzo[b]thiophene. Four-membered Heterocycles containing a Single Nitrogen, Oxygen or Sulfur Atom. Answers to Problems. Subject Index.
£52.95
Scion Publishing Techniques and Experiments For Organic Chemistry
Book Synopsis
£114.72
John Wiley & Sons Inc Natural Products Analysis
Book SynopsisThis book highlights analytical chemistry instrumentation and practices applied to the analysis of natural products and their complex mixtures, describing techniques for isolating and characterizing natural products. Applies analytical techniques to natural products research an area of critical importance to drug discovery Offers a one-stop shop for most analytical methods: x-ray diffraction, NMR analysis, mass spectrometry, and chemical genetics Includes coverage of natural products basics and highlights antibacterial research, particularly important as efforts to combat drug resistance gain prominence Covers instrumental techniques with enough detail for both current practitioners and beginning researchersTrade Review“Every chapter, even those that depart somewhat from the declared remit, is packed with information most of it, as I said at the beginning, representing the cutting edge of the subject. I cannot recommend it too highly.” (Chromatographia, 1 May 2015) Table of ContentsPreface ix Contributors xi 1. Natural Products Analysis: Instrumentation, Methods, and Applications 1 Vladimír Havlíèek and Jaroslav Spí?ek 2. The Need for New Antifungal and Antimalarial Compounds 9 Jaroslav Spí?ek and Arnold L. Demain 3. Emerging Instrumental Methods for Antimicrobial Resistance and Virulence Testing 25 Plamen A. Demirev 4. Plant and Marine Sources: Biological Activity of Natural Products and Therapeutic Use 43 Amedeo Amedei and Elena Niccolai 5. Emerging Trends for Stimulating the Discovery of Natural Products 115 Navid Adnani, Gregory A. Ellis, Thomas P. Wyche, Tim S. Bugni, Jason C. Kwan, and Eric W. Schmidt 6. Advances and Challenges in Optical Molecular Spectroscopy Including Surface Plasmon Resonance-Based Methods for Bioanalysis 163 Pavel Matìjka, Blanka Vlèková, Lucie Bednárová, and Petr Malon 7. Advanced Techniques for NMR Analysis of Complex Biological Mixtures—From Simple NMR to Hyphenated Techniques 239 Helena Pelantová, Simona Bártová, and Marek Kuzma 8. Advances in X-Ray Diffraction: Implications to the Pharmaceutical Industry 285 Alexandr Jegorov and Michal Hušák 9. Laser Ablation Inductively Coupled Plasma Mass Spectrometry as a Tool in Biological Sciences 313 Michaela Vašinová Galiová, Jan Havliš, and Viktor Kanický 10. Imaging Mass Spectrometry, Metabolism, and New Views of the Microbial World 349 B. Christopher Hoefler and Paul D. Straight 11. Structural Separations for Natural Product Characterization by Ion Mobility–Mass Spectrometry: Fundamental Theory to Emerging Applications 397 Sarah M. Stow, Nichole M. Lareau, Kelly M. Hines, C. Ruth McNees, Cody R. Goodwin, Brian O. Bachmann, and John A. McLean 12. High-Resolution Tandem Mass Spectrometry for Nonribosomal Peptide and Polyketide Analysis 433 Rebecca H. Wills, Manuela Tosin, and Peter B. O’Connor 13. Natural Product Drug Discovery and Analysis Using Mass Spectrometry and Affinity-Based Technologies 475 Evelyn H. Wang and Kevin A. Schug 14. Glycosylated Ribosomally Synthesized Peptide Toxins: Discovery, Characterization, and Applications 507 Gillian E. Norris and Mark L. Patchett 15. Using Ultrahigh-Resolution Mass Spectrometry to Unravel the Chemical Space of Complex Natural Product Mixtures 545 Constanze Müller, Mourad Harir, Norbert Hertkorn, Basem Kanawati, Dimitrios Tziotis, and Philippe Schmitt-Kopplin 16. Functional Amyloid Fibrils: Lessons from Microbes 571 Sally L. Gras and Dennis Claessen Index 601
£128.20
John Wiley & Sons Inc Environmental Organic Chemistry
Book SynopsisExamines in a pedagogical way all pertinent molecular and macroscopic processes that govern the distribution and fate of organic chemicals in the environment and provides simple modeling tools to quantitatively describe these processes and their interplay in a given environmental system Treats fundamental aspects of chemistry, physics, and mathematical modeling as applied to environmentally relevant problems, and gives a state of the art account of the field Teaches the reader how to relate the structure of a given chemical to its physical chemical properties and intrinsic reactivities Provides a holistic and teachable treatment of phase partitioning and transformation processes, as well as a more focused and tailor-made presentation of physical, mathematical, and modeling aspects that apply to environmental situations of concern Includes a large number of questions and problems allowing teachers to explore the depth of understanding of tTable of ContentsPreface xiii About the Companion Website xvii 1 General Topic and Overview 1 1.1 Introduction 2 1.2 Assessing Organic Chemicals in the Environment 4 1.3 What is This Book All About? 7 1.4 Bibliography 14 Part I Background Knowledge 17 2 Background Knowledge on Organic Chemicals 19 2.1 The Makeup of Organic Compounds 20 2.2 Intermolecular Forces Between Uncharged Molecules 37 2.3 Questions and Problems 40 2.4 Bibliography 43 3 The Amazing World of Anthropogenic Organic Chemicals 45 3.1 Introduction 47 3.2 A Lasting Global Problem: Persistent Organic Pollutants (POPs) 47 3.3 Natural but Nevertheless Problematic: Petroleum Hydrocarbons 48 3.4 Notorious Air and Groundwater Pollutants: Organic Solvents 53 3.5 Safety First: Flame Retardants All Around Us 56 3.6 How to Make Materials “Repellent”: Polyfluorinated Chemicals (PFCs) 58 3.7 From Washing Machines to Surface Waters: Complexing Agents, Surfactants, Whitening Agents, and Corrosion Inhibitors 60 3.8 Health, Well-Being, and Water Pollution: Pharmaceuticals and Personal Care Products 63 3.9 Fighting Pests: Herbicides, Insecticides, and Fungicides 65 3.10 Our Companion Compounds: Representative Model Chemicals 69 3.11 Questions 72 3.12 Bibliography 73 4 Background Thermodynamics, Equilibrium Partitioning and Acidity Constants 81 4.1 Important Thermodynamic Functions 83 4.2 Using Thermodynamic Functions to Quantify Equilibrium Partitioning 89 4.3 Organic Acids and Bases I: Acidity Constant and Speciation in Natural Waters 98 4.4 Organic Acids and Bases II: Chemical Structure and Acidity Constant 107 4.5 Questions and Problems 116 4.6 Bibliography 119 5 Earth Systems and ComPartments 121 5.1 Introduction 123 5.2 The Atmosphere 125 5.3 Surface Waters and Sediments 131 5.4 Soil and Groundwater 148 5.5 Biota 154 5.6 Questions 155 5.7 Bibliography 158 6 Environmental Systems: Physical Processes and Mathematical Modeling 165 6.1 Systems and Models 167 6.2 Box Models: A Concept for a Simple World 174 6.3 When Space Matters: Transport Processes 191 6.4 Models in Space and Time 196 6.5 Questions and Problems 203 6.6 Bibliography 211 Part II Equilibrium Partitioning in Well-Defined Systems 213 7 Partitioning Between Bulk Phases: General Aspects and Modeling Approaches 215 7.1 Introduction 216 7.2 Molecular Interactions Governing Bulk Phase Partitioning of Organic Chemicals 217 7.3 Quantitative Approaches to Estimate Bulk Phase Partition Constants/Coefficients: Linear Free Energy Relationships (LFERs) 225 7.4 Questions 232 7.5 Bibliography 234 8 Vapor Pressure (pi∗) 237 8.1 Introduction and Theoretical Background 238 8.2 Molecular Interactions Governing Vapor Pressure and Vapor Pressure Estimation Methods 246 8.3 Questions and Problems 253 8.4 Bibliography 257 9 Solubility (Csatiw ) and Activity Coefficient (𝜸satiw ) in Water; Air–Water Partition Constant (Kiaw) 259 9.1 Introduction and Thermodynamic Considerations 261 9.2 Molecular Interactions Governing the Aqueous Activity Coefficient and the Air–Water Partition Constant 267 9.3 LFERs for Estimating Air–Water Partition Constants and Aqueous Activity Coefficients/Aqueous Solubilities 270 9.4 Effect of Temperature, Dissolved Salts, and pH on the Aqueous Activity Coefficient/Aqueous Solubility and on the Air–Water Partition Constant 272 9.5 Questions and Problems 282 9.6 Bibliography 285 10 Organic Liquid–Air and Organic Liquid–Water Partitioning 289 10.1 Introduction 291 10.2 Thermodynamic Considerations and Comparisons of Different Organic Solvents 291 10.3 The Octanol–Water System: The Atom/Fragment Contribution Method for Estimation of the Octanol–Water Partition Constant 298 10.4 Partitioning Involving Organic Solvent–Water Mixtures 301 10.5 Evaporation and Dissolution of Organic Compounds from Organic Liquid Mixtures–Equilibrium Considerations 307 10.6 Questions and Problems 311 10.7 Bibliography 317 11 Partitioning of Nonionic Organic Compounds Between Well-Defined Surfaces and Air or Water 321 11.1 Introduction 322 11.2 Adsorption from Air to Well-Defined Surfaces 322 11.3 Adsorption from Water to Inorganic Surfaces 335 11.4 Questions and Problems 342 11.5 Bibliography 345 Part III Equilibrium Partitioning in Environmental Systems 349 12 General Introduction to Sorption Processes 351 12.1 Introduction 352 12.2 Sorption Isotherms and the Solid–Water Equilibrium Distribution Coefficient (Kid) 354 12.3 Speciation (Sorbed versus Dissolved or Gaseous), Retardation, and Sedimentation 360 12.4 Questions and Problems 366 12.5 Bibliography 368 13 Sorption from Water to Natural Organic Matter (NOM) 369 13.1 The Structural Diversity of Natural Organic Matter Present in Aquatic and Terrestrial Environments 371 13.2 Quantifying Natural Organic Matter–Water Partitioning of Neutral Organic Compounds 376 13.3 Sorption of Organic Acids and Bases to Natural Organic Matter 388 13.4 Questions and Problems 392 13.5 Bibliography 397 14 Sorption of Ionic Organic Compounds to Charged Surfaces 405 14.1 Introduction 407 14.2 Cation and Anion Exchange Capacities of Solids in Water 408 14.3 Ion Exchange: Nonspecific Adsorption of Ionized Organic Chemicals from Aqueous Solutions to Charged Surfaces 414 14.4 Surface Complexation: Specific Bonding of Organic Compounds with Solid Phases in Water 426 14.5 Questions and Problems 432 14.6 Bibliography 436 15 Aerosol–Air Partitioning: Dry andWet Deposition of Organic Pollutants 441 15.1 Origins and Properties of Atmospheric Aerosols 442 15.2 Assessing Aerosol–Air Partition Coefficients (KiPMa) 445 15.3 Dry and Wet Deposition 453 15.4 Questions and Problems 459 15.5 Bibliography 464 16 Equilibrium Partitioning From Water and Air to Biota 469 16.1 Introduction 471 16.2 Predicting Biota–Water and Biota–Air Equilibrium Partitioning 471 16.3 Bioaccumulation and Biomagnification in Aquatic Systems 485 16.4 Bioaccumulation and Biomagnification in Terrestrial Systems 498 16.5 Baseline Toxicity (Narcosis) 503 16.6 Questions and Problems 507 16.7 Bibliography 514 Part IV Mass Transfer Processes in Environmental Systems 523 17 Random Motion, Molecular and Turbulent Diffusivity 525 17.1 Random Motion 526 17.2 Molecular Diffusion 534 17.3 Other Random Transport Processes in the Environment 545 17.4 Questions and Problems 550 17.5 Bibliography 557 18 Transport at Boundaries 559 18.1 The Role of Boundaries in the Environment 560 18.2 Bottleneck Boundaries 562 18.3 Wall Boundaries 567 18.4 Hybrid Boundaries 572 18.5 Questions and Problems 577 18.6 Bibliography 580 19 Air–Water Exchange 581 19.1 The Air–Water Interface 583 19.2 Air–Water Exchange Models 585 19.3 Measurement of Air–Water Exchange Velocities 592 19.4 Air–Water Exchange in Flowing Waters 599 19.5 Questions and Problems 604 19.6 Bibliography 613 20 Interfaces Involving Solids 617 20.1 The Sediment–Water Interface 618 20.2 Transport in Unsaturated Soil 626 20.3 Questions and Problems 630 20.4 Bibliography 634 Part V Transformation Processes 635 21 Background Knowledge on Transformation Reactions of Organic Pollutants 637 21.1 Identifying Reactive Sites Within Organic Molecules 638 21.2 Thermodynamics of Transformation Reactions 643 21.3 Kinetics of Transformation Reactions 650 21.4 Questions and Problems 657 21.5 Bibliography 661 22 Hydrolysis And ReactionsWith Other Nucleophiles 663 22.1 Nucleophilic Substitution and Elimination Reactions Involving Primarily Saturated Carbon Atoms 665 22.2 Hydrolytic Reactions of Carboxylic and Carbonic Acid Derivatives 680 22.3 Enzyme-Catalyzed Hydrolysis Reactions: Hydrolases 695 22.4 Questions and Problems 701 22.5 Bibliography 710 23 Redox Reactions 715 23.1 Introduction 716 23.2 Evaluating the Thermodynamics of Redox Reactions 719 23.3 Examples of Chemical Redox Reactions in Natural Systems 730 23.4 Examples of Enzyme-Catalyzed Redox Reactions 747 23.5 Questions and Problems 756 23.6 Bibliography 765 24 Direct Photolysis in Aquatic Systems 773 24.1 Introduction 775 24.2 Some Basic Principles of Photochemistry 776 24.3 Light Absorption by Organic Compounds in Natural Waters 788 24.4 Quantum Yield and Rate of Direct Photolysis 800 24.5 Effects of Solid Sorbents (Particles, Soil Surfaces, Ice) on Direct Photolysis 803 24.6 Questions and Problems 804 24.7 Bibliography 811 25 Indirect Photolysis: Reactions with Photooxidants in Natural Waters and in the Atmosphere 815 25.1 Introduction 816 25.2 Indirect Photolysis in Surface Waters 817 25.3 Indirect Photolysis in the Atmosphere (Troposphere): Reaction with Hydroxyl Radical (HO∙) 829 25.4 Questions and Problems 833 25.5 Bibliography 838 26 Biotransformations 845 26.1 Introduction 847 26.2 Some Important Concepts about Microorganisms Relevant to Biotransformations 848 26.3 Initial Biotransformation Strategies 858 26.4 Rates of Biotransformations 864 26.5 Questions and Problems 882 26.6 Bibliography 889 27 Assessing Transformation Processes Using Compound-Specific Isotope Analysis (CSIA) 897 27.1 Introduction, Methodology, and Theoretical Background 898 27.2 Using CSIA for Assessing Organic Compound Transformations in Laboratory and Field Systems 914 27.3 Questions and Problems 930 27.4 Bibliography 936 Part VI Putting Everything Together 945 28 Exposure Assessment of Organic Pollutants Using Simple Modeling Approaches 947 28.1 One-Box Model: The Universal Tool for Process Integration 948 28.2 Assessing Equilibrium Partitioning in Simple Multimedia Systems 952 28.3 Simple Dynamic Systems 956 28.4 Systems Driven by Advection 960 28.5 Bibliography 974 Appendix 977 Index 995
£126.95
John Wiley & Sons Inc Graphene Chemistry
Book SynopsisWhat are the chemical aspects of graphene as a novel 2D material and how do they relate to the molecular structure? This book addresses these important questions from a theoretical and computational standpoint.Table of ContentsList of Contributors xv Preface xix Acknowledgements xxi 1 Introduction 1 De-en Jiang and Zhongfang Chen 2 Intrinsic Magnetism in Edge-Reconstructed Zigzag Graphene Nanoribbons 9 Zexing Qu and Chungen Liu 2.1 Methodology 10 2.1.1 Effective Valence Bond Model 10 2.1.2 Density Matrix Renormalization Group Method 11 2.1.3 Density Functional Theory Calculations 12 2.2 Polyacene 12 2.3 Polyazulene 14 2.4 Edge-Reconstructed Graphene 17 2.4.1 Energy Gap 17 2.4.2 Frontier Molecular Orbitals 18 2.4.3 Projected Density of States 19 2.4.4 Spin Density in the Triplet State 20 2.5 Conclusion 22 Acknowledgments 23 References 23 3 Understanding Aromaticity of Graphene and Graphene Nanoribbons by the Clar Sextet Rule 29 Dihua Wu, Xingfa Gao, Zhen Zhou, and Zhongfang Chen 3.1 Introduction 29 3.1.1 Aromaticity and Clar Theory 30 3.1.2 Previous Studies of Carbon Nanotubes 33 3.2 Armchair Graphene Nanoribbons 34 3.2.1 The Clar Structure of Armchair Graphene Nanoribbons 34 3.2.2 Aromaticity of Armchair Graphene Nanoribbons and Band Gap Periodicity 37 3.3 Zigzag Graphene Nanoribbons 40 3.3.1 Clar Formulas of Zigzag Graphene Nanoribbons 40 3.3.2 Reactivity of Zigzag Graphene Nanoribbons 40 3.4 Aromaticity of Graphene 42 3.5 Perspectives 44 Acknowledgements 45 References 45 4 Physical Properties of Graphene Nanoribbons: Insights from First-Principles Studies 51 Dana Krepel and Oded Hod 4.1 Introduction 51 4.2 Electronic Properties of Graphene Nanoribbons 53 4.2.1 Zigzag Graphene Nanoribbons 53 4.2.2 Armchair Graphene Nanoribbons 56 4.2.3 Graphene Nanoribbons with Finite Length 58 4.2.4 Surface Chemical Adsorption 60 4.3 Mechanical and Electromechanical Properties of GNRs 63 4.4 Summary 66 Acknowledgements 66 References 66 5 Cutting Graphitic Materials: A Promising Way to Prepare Graphene Nanoribbons 79 Wenhua Zhang and Zhenyu Li 5.1 Introduction 79 5.2 Oxidative Cutting of Graphene Sheets 80 5.2.1 Cutting Mechanisms 80 5.2.2 Controllable Cutting 83 5.3 Unzipping Carbon Nanotubes 85 5.3.1 Unzipping Mechanisms Based on Atomic Oxygen 86 5.3.2 Unzipping Mechanisms Based on Oxygen Pairs 88 5.4 Beyond Oxidative Cutting 91 5.4.1 Metal Nanoparticle Catalyzed Cutting 92 5.4.2 Cutting by Fluorination 95 5.5 Summary 96 References 96 6 Properties of Nanographenes 101 Michael R. Philpott 6.1 Introduction 101 6.2 Synthesis 103 6.3 Computation 103 6.4 Geometry of Zigzag-Edged Hexangulenes 104 6.5 Geometry of Armchair-Edged Hexangulenes 107 6.6 Geometry of Zigzag-Edged Triangulenes 110 6.7 Magnetism of Zigzag-Edged Hexangulenes 112 6.8 Magnetism of Zigzag-Edged Triangulenes 114 6.9 Chimeric Magnetism 115 6.10 Magnetism of Oligocenes, Bisanthene-Homologs, Squares and Rectangles 117 6.10.1 Oligocene Series: C4m+2H2m+4 (na=1; m=2, 3, 4 . . .) 117 6.10.2 Bisanthene Series: C8m+4H2m+8 (na 3; m=2, 3, 4 . . .) 119 6.10.3 Square and Rectangular Nano-Graphenes: C8m+4H2m+8 (m=2, 3, 4 . . .) 122 6.11 Concluding Remarks 122 Acknowledgment 123 References 124 7 Porous Graphene and Nanomeshes 129 Yan Jiao, Marlies Hankel, Aijun Du, and Sean C. Smith 7.1 Introduction 129 7.1.1 Graphene-Based Nanomeshes 130 7.1.2 Graphene-Like Polymers 130 7.1.3 Other Relevant Subjects 131 7.1.3.1 Isotope Separation 131 7.1.3.2 Van der Waals Correction for Density Functional Theory 132 7.1.3.3 Potential Energy Surfaces for Hindered Molecular Motions Within the Narrow Pores 133 7.2 Transition State Theory 134 7.2.1 A Brief Introduction of the Idea 134 7.2.2 Evaluating Partition Functions: The Well-Separated “Reactant” State 136 7.2.3 Evaluating Partition Functions: The Fully Coupled 4D TS Calculation 137 7.2.4 Evaluating Partition Functions: Harmonic Approximation for the TS Derived Directly from Density Functional Theory Calculations 138 7.3 Gas and Isotope Separation 139 7.3.1 Gas Separation and Storage by Porous Graphene 139 7.3.1.1 Porous Graphene for Hydrogen Purification and Storage 139 7.3.1.2 Porous Graphene for Isotope Separation 140 7.3.2 Nitrogen Functionalized Porous Graphene for Hydrogen Purification/Storage and Isotope Separation 140 7.3.2.1 Introduction 140 7.3.2.2 NPG and its Asymmetrically Doped Version for D2/H2 Separation – A Case Study 141 7.3.3 Graphdiyne for Hydrogen Purification 144 7.4 Conclusion and Perspectives 147 Acknowledgement 147 References 147 8 Graphene-Based Architecture and Assemblies 153 Hongyan Guo, Rui Liu, Xiao Cheng Zeng, and Xiaojun Wu 8.1 Introduction 153 8.2 Fullerene Polymers 154 8.3 Carbon Nanotube Superarchitecture 156 8.4 Graphene Superarchitectures 160 8.5 C60/Carbon Nanotube/Graphene Hybrid Superarchitectures 163 8.5.1 Nanopeapods 163 8.5.2 Carbon Nanobuds 165 8.5.3 Graphene Nanobuds 168 8.5.4 Nanosieves and Nanofunnels 169 8.6 Boron-Nitride Nanotubes and Monolayer Superarchitectures 171 8.7 Conclusion 173 Acknowledgments 173 References 174 9 Doped Graphene: Theory, Synthesis, Characterization, and Applications 183 Florentino López-Urías, Ruitao Lv, Humberto Terrones, and Mauricio Terrones 9.1 Introduction 183 9.2 Substitutional Doping of Graphene Sheets 184 9.3 Substitutional Doping of Graphene Nanoribbons 194 9.4 Synthesis and Characterization Techniques of Doped Graphene 196 9.5 Applications of Doped Graphene Sheets and Nanoribbons 200 9.6 Future Work 201 Acknowledgments 202 References 202 10 Adsorption of Molecules on Graphene 209 O. Leenaerts, B. Partoens, and F. M. Peeters 10.1 Introduction 209 10.2 Physisorption versus Chemisorption 210 10.3 General Aspects of Adsorption of Molecules on Graphene 212 10.4 Various Ways of Doping Graphene with Molecules 215 10.4.1 Open-Shell Adsorbates 215 10.4.2 Inert Adsorbates 217 10.4.3 Electrochemical Surface Transfer Doping 220 10.5 Enhancing the Graphene-Molecule Interaction 221 10.5.1 Substitutional Doping 221 10.5.2 Adatoms and Adlayers 222 10.5.3 Edges and Defects 224 10.5.4 External Electric Fields 224 10.5.5 Surface Bending 225 10.6 Conclusion 226 References 226 11 Surface Functionalization of Graphene 233 Maria Peressi 11.1 Introduction 233 11.2 Functionalized Graphene: Properties and Challenges 236 11.3 Theoretical Approach 237 11.4 Interaction of Graphene with Specific Atoms and Functional Groups 238 11.4.1 Interaction with Hydrogen 238 11.4.2 Interaction with Oxygen 240 11.4.3 Interaction with Hydroxyl Groups 241 11.4.4 Interaction with Other Atoms, Molecules, and Functional Groups 245 11.5 Surface Functionalization of Graphene Nanoribbons 247 11.6 Conclusions 248 References 249 12 Mechanisms of Graphene Chemical Vapor Deposition (CVD) Growth 255 Xiuyun Zhang, Qinghong Yuan, Haibo Shu, and Feng Ding 12.1 Background 255 12.1.1 Graphene and Defects in Graphene 255 12.1.2 Comparison of Methods of Graphene Synthesis 257 12.1.3 Graphene Chemical Vapor Deposition (CVD) Growth 257 12.1.3.1 The Status of Graphene CVD Growth 257 12.1.3.2 Phenomenological Mechanism 260 12.1.3.3 Challenges in Graphene CVD Growth 260 12.2 The Initial Nucleation Stage of Graphene CVD Growth 261 12.2.1 C Precursors on Catalyst Surfaces 262 12.2.2 The sp C Chain on Catalyst Surfaces 262 12.2.3 The sp2 Graphene Islands 263 12.2.4 The Magic Sized sp2 Carbon Clusters 264 12.2.5 Nucleation of Graphene on Terrace versus Near Step 266 12.3 Continuous Growth of Graphene 271 12.3.1 The Upright Standing Graphene Formation on Catalyst Surfaces 271 12.3.2 Edge Reconstructions on Metal Surfaces 273 12.3.3 Growth Rate of Graphene and Shape Determination 275 12.3.4 Nonlinear Growth of Graphene on Ru and Ir Surfaces 276 12.4 Graphene Orientation Determination in CVD Growth 278 12.5 Summary and Perspectives 280 References 282 13 From Graphene to Graphene Oxide and Back 291 Xingfa Gao, Yuliang Zhao, and Zhongfang Chen 13.1 Introduction 291 13.2 From Graphene to Graphene Oxide 292 13.2.1 Modeling Using Cluster Models 292 13.2.1.1 Oxidative Etching of Armchair Edges 292 13.2.1.2 Oxidative Etching of Zigzag Edges 293 13.2.1.3 Linear Oxidative Unzipping 294 13.2.1.4 Spins upon Linear Oxidative Unzipping 296 13.3 Modeling Using PBC Models 297 13.3.1 Oxidative Creation of Vacancy Defects 297 13.3.2 Oxidative Etching of Vacancy Defects 298 13.3.3 Linear Oxidative Unzipping 299 13.3.4 Linear Oxidative Cutting 300 13.4 From Graphene Oxide back to Graphene 302 13.4.1 Modeling Using Cluster Models 302 13.4.1.1 Cluster Models for Graphene Oxide 302 13.4.1.2 Hydrazine De-Epoxidation 302 13.4.1.3 Thermal De-Hydroxylation 307 13.4.1.4 Thermal De-Carbonylation and De-Carboxylation 308 13.4.1.5 Temperature Effect on De-Epoxidation and De-Hydroxylation 309 13.4.1.6 Residual Groups of Graphene Oxide Reduced by Hydrazine and Heat 311 13.4.2 Modeling Using Periodic Boundary Conditions 312 13.4.2.1 Hydrazine De-Epoxidation 312 13.4.2.2 Thermal De-Epoxidation 313 13.5 Concluding Remarks 314 Acknowledgement 314 References 314 14 Electronic Transport in Graphitic Carbon Nanoribbons 319 Eduardo Costa Girão, Liangbo Liang, Jonathan Owens, Eduardo Cruz-Silva, Bobby G. Sumpter, and Vincent Meunier 14.1 Introduction 319 14.2 Theoretical Background 320 14.2.1 Electronic Structure 320 14.2.1.1 Density Functional Theory 320 14.2.1.2 Semi-Empirical Methods 320 14.2.2 Electronic Transport at the Nanoscale 322 14.3 From Graphene to Ribbons 324 14.3.1 Graphene 324 14.3.2 Graphene Nanoribbons 325 14.4 Graphene Nanoribbon Synthesis and Processing 329 14.5 Tailoring GNR’s Electronic Properties 330 14.5.1 Defect-Based Modifications of the Electronic Properties 331 14.5.1.1 Non-Hexagonal Rings 331 14.5.1.2 Edge and Bulk Disorder 332 14.5.2 Electronic Properties of Chemically Doped Graphene Nanoribbons 332 14.5.2.1 Substitutional Doping of Graphene Nanoribbons 332 14.5.2.2 Chemical Functionalization of Graphene Nanoribbons 333 14.5.3 GNR Assemblies 334 14.5.3.1 Nanowiggles 334 14.5.3.2 Antidots and Junctions 335 14.5.3.3 GNR Rings 335 14.5.3.4 GNR Stacking 336 14.6 Thermoelectric Properties of Graphene-Based Materials 336 14.6.1 Thermoelectricity 336 14.6.2 Thermoelectricity in Carbon 336 14.7 Conclusions 338 Acknowledgements 339 References 339 15 Graphene-Based Materials as Nanocatalysts 347 Fengyu Li and Zhongfang Chen 15.1 Introduction 347 15.2 Electrocatalysts 347 15.2.1 N-Graphene 348 15.2.2 N-Graphene-NP Nanocomposites 350 15.2.3 Non-Pt Metal on the Porphyrin-Like Subunits in Graphene 351 15.2.4 Graphyne 352 15.3 Photocatalysts 353 15.3.1 TiO2-Graphene Nanocomposite 353 15.3.2 Graphitic Carbon Nitrides (g-C3N4) 355 15.4 CO Oxidation 356 15.4.1 Metal-Embedded Graphene 357 15.4.2 Metal-Graphene Oxide 358 15.4.3 Metal-Graphene under Mechanical Strain 359 15.4.4 Metal-Embedded Graphene under an External Electric Field 360 15.4.5 Porphyrin-Like Fe/N/C Nanomaterials 361 15.4.6 Si-Embedded Graphene 361 15.4.7 Experimental Aspects 361 15.5 Others 362 15.5.1 Propene Epoxidation 362 15.5.2 Nitromethane Combustion 362 15.6 Conclusion 363 Acknowledgements 364 References 364 16 Hydrogen Storage in Graphene 371 Yafei Li and Zhongfang Chen 16.1 Introduction 371 16.2 Hydrogen Storage in Molecule Form 373 16.2.1 Hydrogen Storage in Graphene Sheets 373 16.2.2 Hydrogen Storage in Metal Decorated Graphene 374 16.2.2.1 Lithium Decorated Graphene 375 16.2.2.2 Calcium Decorated Graphene 376 16.2.2.3 Transition Metal Decorated Graphene 377 16.2.3 Hydrogen Storage in Graphene Networks 377 16.2.3.1 Covalently Bonded Graphene 378 16.2.4 Notes to Computational Methods 381 16.3 Hydrogen Storage in Atomic Form 382 16.3.1 Graphane 382 16.3.2 Chemical Storage of Hydrogen by Spillover 383 16.4 Conclusion 386 Acknowledgements 386 References 386 17 Linking Theory to Reactivity and Properties of Nanographenes 393 Qun Ye, Zhe Sun, Chunyan Chi, and Jishan Wu 17.1 Introduction 393 17.2 Nanographenes with Only Armchair Edges 394 17.3 Nanographenes with Both Armchair and Zigzag Edges 397 17.3.1 Structure of Rylenes 398 17.3.2 Chemistry at the Armchair Edges of Rylenes 398 17.3.3 Anthenes and Periacenes 402 17.4 Nanographene with Only Zigzag Edges 405 17.4.1 Phenalenyl-Based Open-Shell Systems 406 17.5 Quinoidal Nanographenes 411 17.5.1 Bis(Phenalenyls) 412 17.5.2 Zethrenes 414 17.5.3 Indenofluorenes 417 17.6 Conclusion 417 References 418 18 Graphene Moiré Supported Metal Clusters for Model Catalytic Studies 425 Bradley F. Habenicht, Ye Xu, and Li Liu 18.1 Introduction 425 18.2 Graphene Moiré on Ru(0001) 426 18.3 Metal Cluster Formation on g/Ru(0001) 430 18.4 Two-dimensional Au Islands on g/Ru(0001) and its Catalytic Activity 434 18.5 Summary 440 Acknowledgments 441 References 441 Index 447
£128.20
McGraw-Hill Companies Loose Leaf for General Organic and Biochemistry
Book Synopsis
£182.50
ISTE Ltd and John Wiley & Sons Inc Activation Methods: Sonochemistry and High
Book SynopsisActivation Methods examines recent improvements in the utilization of ultrasonic waves and pressurized gases to generate reactions. A straightforward method to use, sonochemistry allows chemical reactions to be carried out under ultrasound without the need for external heat, reagents or catalysts leading to high yields and the production of a minimum amount of waste. This book presents an overview of the main applications of sonochemistry in green organic chemistry, with an emphasis on texts published within the last few years. High-pressure chemical reactions offer innovative solutions to problems relating to synthesis. They allow access to new products and a further understanding of reaction mechanisms. This book presents the characteristics of hyperbaric activation, which allow the integration of an arsenal of tools for green chemistry, such as the lowering of energy costs and of by-products, as well as the possibility of using substrates that are sterically congested and generally inert.Table of ContentsChapter 1. Organic Sonochemistry: Ultrasound in Green Organic Synthesis 1Micheline DRAYE, Julien ESTAGER and Nathalie KARDOS 1.1. Introduction: history of ultrasound, organic sonochemistry and early work 2 1.1.1. The history of ultrasound and organic sonochemistry 2 1.1.2. Pioneering work in organic sonochemistry 4 1.2. Some elements of ultrasound theory 14 1.2.1. Bubble dynamics 17 1.2.2. Factors affecting cavitation 21 1.2.3. Estimation of ultrasonic parameters 23 1.3. Laboratory and industrial equipment 28 1.3.1. Ultrasonic bath 29 1.3.2. Ultrasonic probes 31 1.3.3. High frequency reactors 32 1.3.4. Cup-horn reactors 32 1.3.5. Continuous reactors 33 1.4. Green organic sonochemistry 34 1.4.1. True and false sonochemistry 34 1.4.2. Synthesis in a homogeneous and heterogeneous system 35 1.4.3. Synthesis in a heterogeneous system 37 1.5. Sonochemistry in unconventional environments 53 1.5.1. Physical activator 53 1.5.2. Solvent-free chemistry 54 1.5.3. Ionic liquids and ultrasound 55 1.5.4. Sonochemistry in water 60 1.5.5. Sonochemistry in glycerol 64 1.5.6. Enzymatic chemistry under ultrasound 66 1.5.7. Sonoelectrosynthesis 74 1.6. Conclusion 74 1.7. References 76 Chapter 2. High-Pressure Synthesis: An Eco-friendly Chemistry 95Isabelle CHATAIGNER and Jacques MADDALUNO 2.1. High pressures in synthetic chemistry 95 2.2. Important concepts 97 2.2.1. Physicochemistry of high pressures 97 2.2.2. Activation volume 101 2.2.3. Effect of high pressures on the solvent 104 2.3. Instrumentation 105 2.3.1. How can we generate high pressures? 105 2.3.2. Choice of equipment 108 2.3.3. Safety of the installations 112 2.4. Applications 114 2.4.1. Cycloaddition and annulation reactions 114 2.4.2. Nucleophilic addition reactions 125 2.4.3. Substitution reactions 136 2.4.4. Metallocatalyzed reactions 138 2.5. Conclusion 139 2.6. References 140 List of Authors 151 Index 153
£132.00
ISTE Ltd and John Wiley & Sons Inc Oxydative Ageing of Polymers
Book SynopsisThis book aims to rehabilitate kinetic modeling in the domain of polymer ageing, where it has been almost abandoned by the research community. Kinetic modeling is a key step for lifetime prediction, a crucial problem in many industrial domains in which needs cannot be satisfied by the common empirical methods.The book proposes a renewed approach of lifetime prediction in polymer oxidative ageing. This approach is based on kinetic models built from relatively simple mechanistic schemes but integrating physical processes (oxygen diffusion and stabilizer transport), and use property (for instance mechanical failure) changes. An important chapter is dedicated to radiation-induced oxidation and its most important applications: radiochemical ageing at low dose rates and photo-chemical ageing under solar radiation. There is also a chapter devoted to the problem of ageing under coupled oxidation and mechanical loading.Table of ContentsAcknowledgements xi General Introduction xiii Chapter 1. Methodological Aspects 1 1.1. Definitions 1 1.2. Empirical and semi-empirical models 4 1.3. Towards a non-empirical method of lifetime prediction 8 1.4. Arguments against kinetic modeling 11 1.5. Principles of model elaboration 15 Chapter 2. Aspects Common to all Oxidation Processes 17 2.1. Oxidation: a radical chain mechanism 17 2.2. Propagation 20 2.3. Termination 25 2.4. Initiation 30 2.5. Thermodynamic aspects 41 Chapter 3. Basic Kinetic Schemes 45 3.1. Simplifying hypotheses 45 3.2. The ASEC scheme 50 3.3. The ASCTL scheme 54 3.4. The BESC scheme 57 3.5. The BASC scheme 66 3.6. Other schemes 74 3.7. General problems of kinetic analysis of polymer oxidation. The outlines of a new approach 85 Chapter 4. Oxidation and Oxygen Diffusion 93 4.1. Properties of oxygen transport in polymers 93 4.2. The reaction/diffusion equation 101 Chapter 5. Stabilization 111 5.1. Principles of stabilization 111 5.2. Action on hydroperoxide decomposition 113 5.3. Stabilization by capture of P° radicals 117 5.4. Stabilization by capture of POO° radicals 119 5.5. Synergistic mixtures HD + CBA 125 5.6. Polyfunctional stabilizers 126 5.7. Hindered amines 127 5.8. Other stabilizing mechanisms 131 5.9. Physical aspects of stabilization by additives 131 Chapter 6. Molecular Mobility and Reactivity 145 6.1. The issue . 145 6.2. The chemical way . . 149 6.3. The physical way . . 154 6.4. Control by diffusion of macromolecular reactive species and heterogeneity 158 6.5. The paradox of thermostability in glassy polymers 161 Chapter 7. Structural Changes Caused by Oxidation 163 7.1. On the molecular scale 163 7.2. On the macromolecular scale 175 7.3. On the morphological scale 192 Chapter 8. Effects of Oxidation on Physical and Mechanical Properties 203 8.1. Introduction 203 8.2. Weight changes 204 8.3. Changes in density and volume 207 8.4. Optical properties 210 8.5. Electrical properties 215 8.6. Glass transition and melting 218 8.7. Mechanical properties at low strains 223 8.8. Fracture properties in the case of homogeneous degradation. 230 8.9. Fracture properties in the case of homogeneous crosslinking 243 Chapter 9. Couplings 249 9.1. Introduction 249 9.2. “Spontaneous” cracking 250 9.3. Coupling between cracking and oxidation 252 9.4. Lifetime under static strain and oxidation 254 9.5. Physical ageing and oxidation 264 9.6. Oxidation during processing – degradation and recycling 266 Chapter 10. Oxidation Under Irradiation 277 10.1. Definitions. General aspects 277 10.2. Radiochemical initiation 283 10.3. A perculiarity of radiochemical ageing 288 10.4. Photochemical initiation 291 10.5. Photostabilization 300 10.6. Ageing under natural sunlight 308 Bibliography 321 Appendix 347 Index 353
£152.90
University Science Books Student Solutions Manual for Modern Physical
Book Synopsis
£65.87
University Science Books,U.S. Organic Chemistry, second edition
Book SynopsisThe second edition of Organic Chemistry maintains all the innovative features of the first edition in a sleeker, slimmer, and easier-to-navigate design. Hailed by J Chem Ed as “the new wave” in organic textbooks, this book’s mechanistic approach constructs organic chemistry from the ground up. By focusing on the points of reactivities in organic, this text allows students to approach more and more complex molecules with enhanced understanding. Also noteworthy are the biochemical examples for their variety, substance, and depth. Despite its unique emphasis on reactivity, the book facilitates easy adoption by covering organic compound classes in the traditional order. Hundreds of worked examples and student exercises combine with clear writing and sound pedagogy to make this text an exceptional choice. What's New in this Edition? a sleeker, slimmer volume improved organization designed for ease of use more examples and solved exercises fewer specialized topics the first chapter on nucleophilic substitution has been expanded and divided into two chapters, allowing alkyl halides and alcohol substitution reactions to be treated separately oxidation reactions of alcohols have been removed from the chapter on elimination reactions, and a separate chapter on reduction and oxidation reactions has been created (Chapter 11), which also includes discussions about the reduction and oxidation reactions of alkenes the chemistry of dienes, including the Diels-Alder reaction, have been collected in a chapter separate from the one devoted to the addition reactions of simple alkenes the order of topics in the chapters presenting spectroscopic methods has been reversed, so nuclear magnetic resonance spectroscopy is now covered first the chapter that introduces synthetic methods has been largely preserved from the first edition, but it is followed directly by the chapter on enantioselective synthesis the discussion of enantioselective reactions has been completely rewritten, and its emphasis has been changed to encourage students to think about designing enantioselective syntheses without having to memorize a lot of details about specific reagents and conditions the topic of aromatic compounds – benzene and its derivatives – has been moved, and the presentations about diazonium compounds and nucleophilic aromatic substitution reactions, have been incorporated into new Chapter 17 the chapter about about aldehydes, ketones, and carbohydrates has been divided into two chapters in the current edition, with the division made according to the reaction mechanisms involved, not according to the functional groups that are undergoing the reactions the chapter on nitrogen-containing compounds has been parceled in this edition among several chapters in the new edition in contrast, the discussions of polymer chemistry, which were interspersed throughout the book in the first edition, have been collected to form Chapter 26 in this edition Table of Contents1. The Structures of Organic Molecules 2. Bonding in Organic Molecules 3. The Conformations of Organic Molecules 4. The Stereochemistry of Organic Molecules 5. Chemical Reactions and Mechanisms 6. Substitution Reactions of Alkyl Halides 7. Substitution Reactions of Alcohols and Related Compounds 8. Elimination Reactions of Alkyl Halides, Alcohols and Related Compounds 9. Addition Reactions of Alkenes and Alkynes 10. Addition Reactions of Conjugated Dienes 11. Oxidation and Reduction Reactions 12. Free Radicals: Substitution and Addition Reactions 13. Proton and Carbon Nuclear Magnetic Resonance Spectroscopy 14. Determining the Structures of Organic Molecules 15. Organometallic Reagents and Chemical Synthesis 16. Asymmetric Reactions and Synthesis 17. The Chemistry of Benzene and Its Derivativesa 18. Nucleophilic Addition Reactions of Aldehydes and Ketones 19. Addition-Substitution Reactions of Aldehydes and Ketones; The Chemistry of Carbohydrates 20. Addition-Elimination Reactions of Aldehydes and Ketones 21. Addition-Elimination Reactions of Carboxylic Acids and Derivatives 22. The Acid-Base Chemistry of Carbonyl Compounds 23. The Nucleophilic Addition Reactions of Enolate Ions 24. Conjugate Addition Reactions of Unsaturated Carbonyl Compounds 25. The Chemistry of Polycyclic and Heterocyclic Arenes 26. Polymers and Polymerization 27. Amino acids, Peptides, and Proteins 28. Nucleic acids and Molecular Recognition
£118.87
University Science Books Student Solutions Manual for Organic Chemistry
Book SynopsisTo accompany Thomas Sorrellâs Organic Chemistry, Second Edition textbook, this manual includes solutions for every one of the textbookâs exercises.
£45.04
