Description
Book SynopsisThis book provides a fresh approach to the subjects, integrating classical thermodynamics and statistical mechanics to give students a solid understanding of the fundamentals and how macroscopic and microscopic ideas interweave. Includes numerous worked examples, and well over 400 guided, often multi-step, end-of-chapter problems that address conceptual, fundamental, and applied skill sets.
Trade Review'This textbook presents an accessible (but still rigorous) treatment of the material at a beginning-graduate level, including many worked examples. By making the concept of entropy central to the book, Professor Shell provides an organizing principle that makes it easier for the students to achieve mastery of this important area.' Athanassios Z. Panagiotopoulos, Princeton University
'Other integrated treatments of thermodynamics and statistical mechanics exist, but this one stands out as remarkably thoughtful and clear in its selection and illumination of key concepts needed for understanding and modeling materials and processes.' Thomas Truskett, University of Texas, Austin
'This text provides a long-awaited and modern approach that integrates statistical mechanics with classical thermodynamics, rather than the traditional sequential approach, in which teaching of the molecular origins of thermodynamic laws and models only follows later, after classical thermodynamics. The author clearly shows how classical thermodynamic concepts result from the underlying behavior of the molecules themselves.' Keith E. Gubbins, North Carolina State University
Table of Contents1. Introduction and guide to this text; 2. Equilibrium and entropy; 3. Energy and how the microscopic world works; 4. Entropy and how the macroscopic world works; 5. The fundamental equation; 6. The first law and reversibility; 7. Legendre transforms and other potentials; 8. Maxwell relations and measurable quantities; 9. Gases; 10. Phase equilibrium; 11. Stability; 12. Solutions - fundamentals; 13. Solutions - advanced and special cases; 14. Solids; 15. The third law; 16. The canonical partition function; 17. Fluctuations; 18. Statistical mechanics of classical systems; 19. Other ensembles; 20. Reaction equilibrium; 21. Reaction coordinates and rates; 22. Molecular simulation methods.
