Description

Book Synopsis
The metal-catalyzed amination of aryl and alkenyl electrophiles has developed into a widely used methodology for the synthesis of natural products, active pharmaceutical ingredients, agricultural chemicals, and materials for molecular electronics. Copper catalysts promote the coupling of a wide range of nitrogen nucleophiles, including amines, amides, and heteroaromatic nitrogen compounds with aryl and alkenyl halides. The reactivity profile of copper catalysts is complementary to that of palladium catalysts in many cases. Copper catalysts are highly effective with less nucleophilic nitrogen nucleophiles, such as amides and azoles, whereas palladium catalysts are more effective with more nucleophilic amine nucleophiles. Copper is an attractive alternative to palladium due to its significantly lower cost. In addition, high activity palladium catalysts require expensive and often air-sensitive ligands, whereas the modern copper systems use relatively stable and inexpensive diamine or

Table of Contents
Foreword vii

Preface ix

Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles 1
Kevin H. Shaughnessy, Engelbert Ciganek, and Rebecca B. DeVasher

Index 675

CopperCatalyzed Amination of Aryl and Alkenyl

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    A Paperback / softback by Kevin H. Shaughnessy, Engelbert Ciganek, Rebecca B. DeVasher

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      Book details

      Publisher John Wiley & Sons Inc
      Published 7 March 2017
      ISBN-13 9781119345985
      978-1119345985
      ISBN-10 1119345987
      Also in:
      Chemistry Quantum and theoretical chemistry

      Description

      Book Synopsis
      The metal-catalyzed amination of aryl and alkenyl electrophiles has developed into a widely used methodology for the synthesis of natural products, active pharmaceutical ingredients, agricultural chemicals, and materials for molecular electronics. Copper catalysts promote the coupling of a wide range of nitrogen nucleophiles, including amines, amides, and heteroaromatic nitrogen compounds with aryl and alkenyl halides. The reactivity profile of copper catalysts is complementary to that of palladium catalysts in many cases. Copper catalysts are highly effective with less nucleophilic nitrogen nucleophiles, such as amides and azoles, whereas palladium catalysts are more effective with more nucleophilic amine nucleophiles. Copper is an attractive alternative to palladium due to its significantly lower cost. In addition, high activity palladium catalysts require expensive and often air-sensitive ligands, whereas the modern copper systems use relatively stable and inexpensive diamine or

      Table of Contents
      Foreword vii

      Preface ix

      Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles 1
      Kevin H. Shaughnessy, Engelbert Ciganek, and Rebecca B. DeVasher

      Index 675

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