Description

Book Synopsis
In this monograph, investigations of the electronic structures of the transition-metal oxides MnO, CoO, and NiO with spin-polarized electron energy-loss spectroscopy are presented and compared with other experimental and theoretical results. After a review of the present knowledge of the electronic structure of the monoxides, the spectroscopic method applied and its special advantages are described. The knowledge and use of the different spin, angle, and primary-energy dependences of the various relevant inelastic electron-scattering mechanisms provide new insights into the excitation processes of the optically forbidden transitions between the crystal-field-split 3d states of the bulk and of the surface.

Table of Contents
Electronic Structure of MnO, CoO, and NiO.- Electron Energy-Loss Spectroscopy — Inelastic Electron Scattering.- Experiment.- SPEELS of Transition-Metal Oxides — Results and Discussion.- Summary.

d-d Excitations in Transition-Metal Oxides: A Spin-Polarized Electron Energy-Loss Spectroscopy (SPEELS) Study

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    A Paperback by Bärbel Fromme

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      Book details

      Publisher Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
      Published 20 November 2013
      ISBN-13 9783662146859
      978-3662146859
      ISBN-10 3662146851
      Also in:
      Condensed matter physics Physical chemistry Materials science

      Description

      Book Synopsis
      In this monograph, investigations of the electronic structures of the transition-metal oxides MnO, CoO, and NiO with spin-polarized electron energy-loss spectroscopy are presented and compared with other experimental and theoretical results. After a review of the present knowledge of the electronic structure of the monoxides, the spectroscopic method applied and its special advantages are described. The knowledge and use of the different spin, angle, and primary-energy dependences of the various relevant inelastic electron-scattering mechanisms provide new insights into the excitation processes of the optically forbidden transitions between the crystal-field-split 3d states of the bulk and of the surface.

      Table of Contents
      Electronic Structure of MnO, CoO, and NiO.- Electron Energy-Loss Spectroscopy — Inelastic Electron Scattering.- Experiment.- SPEELS of Transition-Metal Oxides — Results and Discussion.- Summary.

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