Description
Book SynopsisCumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of click reactions.
Table of ContentsPreface Acknowledgements
1 General Introduction
References
2 1-Carbon Cumulenes
2.1 Sulfines, R2C SO
2.2 Sulfenes, R2C S(O)O
2.3 Other 1-Carbon Cumulenes
3 2-Carbon Cumulenes
3.1 Carbon Oxides, O C O, :CO
3.2 Carbon Sulfides, S C S, S CO
3.3 Carbon Nitrides
3.4 Center Carbon Phosphorallenes, P C P
4 1,2-Dicarbon Cumulenes
4.1 Ketenes, R2C C O
4.2 Thioketenes, R2C C S
4.3 Ketenimines, R2C C NR
4.4 1-Silaallenes, R2C C Si
4.5 1-Phosphaallenes, R2C C P
4.6 Other Metal Allenes
5 1,3-Dicarbon Cumulenes
5.1 Thiocarbonyl S-ylides, R2C S CH2
5.2 2-Azaallenium Salts, R(Ce)C N+ C(Ce)R
5.3 1-Oxa-3-azoniabutatriene Salts, R2C N+ C O
5.4 1-Thia-3-azabutatriene Salts, R2C N+ C S
5.5 Phosphorus Ylides
6 1,2,3-Tricarbon Cumulenes
6.1 Allenes, R2C CR2
6.2 [3] Cumulenes, R2C C C CR2
6.3 [4] Cumulenes, R2C C C C CR2
6.4 [5] Cumulenes, R2C C C C C CR2
7 Noncarbon Cumulenes
7.1 Azides, RN N N
7.2 Triazaallenium Salts, RN N+ NR
7.3 Sulfur Oxides
7.4 Sulfur Nitrides
7.5 Cationic Boron Cumulenes, R2N B NR
Index
