Description
Book SynopsisThis book is based on the 13 review articles written by subject experts and published in 2014 in the Journal Reviews of Adhesion and Adhesives. The rationale for publication of this book is that currently the RAA has limited circulation, so this book provides broad exposure and dissemination of the concise, critical, illuminating, and thought-provoking review articles.
The subjects of the reviews fall into 4 general areas:
1. Polymer surface modification
2. Biomedical, pharmaceutical and dental fields
3. Adhesives and adhesive joints
4. General Adhesion Aspects
The topics covered include: Adhesion of condensed bodies at microscale; imparting adhesion property to silicone material; functionally graded adhesively bonded joints; synthetic adhesives for wood panels; adhesion theories in wood adhesive bonding; adhesion and surface issues in biocomposites and bionanocomposites; adhesion phenomena in pharmaceutical products and applications
Table of Contents
Preface xv
1 Adhesion of Condensed Bodies at Microscale: Variation with Movable Boundary Conditions 1
Jian-Lin Liu, Jing Sun, Runni Wu and Re Xia
1.1 Introduction 1
1.2 Kinematics: Energy Variation with Movable Boundary Conditions 3
1.3 Microbeam/plate Adhesion 9
1.4 Droplet Adhesion to a Solid 13
1.5 Elastica Model of CNT Adhesion 17
1.6 Cell Adhesion 20
1.7 Summary and Prospects 23
Acknowledgements 24
References 24
2 Imparting Adhesion Property to Silicone Materials: Challenges and Solutions 31
R. Kalinova, R. Mincheva and Ph. Dubois
2.1 Introduction 32
2.2 Cured PDMS 32
2.3 Methods for Cross-Linked PDMS Surface Modification 37
2.4 Summary and Prospects 48
Acknowledgements 48
References 50
3 Functionally Graded Adhesively Bonded Joints 57
M. Kemal Apalak
3.1 Introduction 57
3.2 Functionally Graded Materials 61
3.3 Constitutive Relations 63
3.4 Joints with Functionally Graded Adherends 67
3.5 Functionally Graded Adhesives 73
3.6 Conclusions 77
References 78
4 Synthetic Adhesives for Wood Panels: Chemistry and Technology 85
A. Pizzi
4.1 Introduction 85
4.2 Urea-formaldehyde (UF) Adhesives 87
4.3 Melamine-formaldehyde (MF) and Melamine-ureaformaldehyde (MUF) Adhesives 93
4.4 Phenolic Resins 99
4.5 Isocyanate Wood Adhesives 106
4.6 Summary 116
References 116
5 Adhesion Theories in Wood Adhesive Bonding 125
Douglas J. Gardner, Melanie Blumentritt, Lu Wang and Nadir Yildirim
5.1 Introduction 125
5.2 Mechanical Interlocking and Mechanics of Adhesive-Wood Interactions 129
5.3 Electrostatic Adhesion 135
5.4 Wettability, Surface Energy, Thermodynamic Adhesion 137
5.5 Diffusion Theory of Adhesion 145
5.6 Covalent Bonding 148
5.7 Acid-base Theory 149
5.8 Weak Boundary Layer 150
5.9 Discussion and Future Research Prospects 155
5.10 Summary 157
References 158
6 Adhesion and Surface Issues in Biocomposites and Bionanocomposites 169
Cintil Jose, Merin Sara Thomas, B. Deepa, Laly A. Pothan and Sabu Thomas
6.1 Introduction 170
6.2 Biopolymers 170
6.3 Chemical Modification of Cellulose, Chitin and Starch 174
6.4 Bio-based Matrices 177
6.5 Processing Techniques 184
6.6 Interfacial Adhesion Issues 185
6.7 Interface Characterization Techniques 189
6.8 Summary and Conclusions 207
References 207
7 Adhesion Phenomena in Pharmaceutical Products and Applications of AFM 219
Emily Callard Preedy, Stefano Perni and Polina Prokopovich
7.1 Introduction 220
7.2 Adhesion in Pharmaceuticals 222
7.3 Atomic Force Microscopy 232
7.4 Prospects 236
7.5 Summary 237
Acknowledgments 237
References 237
8 Cyanoacrylate Adhesives in Surgical Applications 245
Edward M. Petrie
8.1 Introduction 245
8.2 Types of Surgical Adhesives 249
8.3 History of Cyanoacrylate Surgical Adhesives 257
8.4 Formulation Development 269
8.5 Properties 278
8.6 Clinical History 285
8.7 Future Potential 290
8.8 Summary 292
References 293
9 Ways to Generate Monosort Functionalized Polyolefin Surfaces 299
J. Friedrich, R. Mix and G. Hidde
9.1 Introduction 300
9.2 Production of Monotype Functional Groups 312
9.3 Other Methods for Introduction of Monotype Functional Groups onto the Polyolefin Surface (Plasma Polymerization, Underwater Plasma, ElectroSpray Ionization Deposition, Atmospheric-Pressure Chemical Ionization, Chemical Pretreatment) 329
9.4 Hydrophobic Recovery 335
9.5 Grafting onto Functionalized Polyolefin Surfaces 336
9.6 Summary and Conclusions 342
References 344
10 Nano-Enhanced Adhesives 357
Shahin Shadlou, Babak Ahmadi-Moghadam and Farid Taheri
10.1 Introduction 357
10.2 Why Nanostructured Reinforcements? 358
10.3 Development of Polymer-based Nanocomposites 360
10.4 Mechanical Properties of Nano-reinforced Adhesives 364
10.5 Other Advantages of Nano-Reinforced Adhesives 383
10.6 Conclusion 389
10.7 Acknowledgements 390
References 390
11 Bonding Dissimilar Materials in Dentistry 397
Muhammad Zakir, James Kit-Hon Tsoi, Chun Hung Chu, Christie Ying Kei Lung and Jukka Pekka Matinlinna
11.1 Introduction 398
11.2 Silane Coupling Agents 399
11.3 Zirconate Coupling Agents 403
11.4 Phosphate Coupling Agents 404
11.5 Thione/thiol Coupling Agents 405
11.6 Titanate Coupling Agents 406
11.7 Zircoaluminate Coupling Agents 408
11.8 Other Coupling Agents 408
11.9 Conclusion 410
References 411
12 Flame Treatment of Polymeric Materials: Relevance to Adhesion 417
L. Mazzola and A. Cusma
12.1 Introduction 418
12.2 Flame Treatment Equipment 418
12.3 Effects of Flame Treatment on Plastics 426
12.4 Conclusion 445
References 447
13 Mucoadhesive Polymers for Enhancing Retention in Ocular Drug Delivery 451
Anubha Khare, Kanchan Grover, Pravin Pawar and Inderbir Singh
13.1 Introduction 451
13.2 Composition of Mucus Layer 453
13.3 Natural Mucoadhesive Polymers 454
13.4 Synthetic Polymers 467
13.5 Gene Delivery 472
13.6 Patented Formulations 472
13.7 Future Prospects 472
13.8 Conclusion 473
Acknowledgement 474
References 474
Index 485
