Description

Volume 80 in the venerable Organic Reactions series contains two chapters. The first describes the use of chiral rhodium complexes to effect catalytic, asymmetric carbon-hydrogen insertion reactions intramolecularly. It details the structural scenarios in which diazocarbonyl compounds can be generated and activated to form, inter alia, lactones, lactams and cyclic ketones. The second chapter describes the use of (chiral) rhodium complexes in combination with diazocarbonyl compounds, but in this case to effect a remarkable transformation that dramatically increases the molecular complexity of the substrates.

Organic Reactions, Volume 80

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Hardback by Scott E. Denmark

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Volume 80 in the venerable Organic Reactions series contains two chapters. The first describes the use of chiral rhodium complexes... Read more

    Publisher: John Wiley & Sons Inc
    Publication Date: 05/02/2013
    ISBN13: 9781118513088, 978-1118513088
    ISBN10: 1118513088

    Number of Pages: 544

    Non Fiction , Mathematics & Science , Education

    Description

    Volume 80 in the venerable Organic Reactions series contains two chapters. The first describes the use of chiral rhodium complexes to effect catalytic, asymmetric carbon-hydrogen insertion reactions intramolecularly. It details the structural scenarios in which diazocarbonyl compounds can be generated and activated to form, inter alia, lactones, lactams and cyclic ketones. The second chapter describes the use of (chiral) rhodium complexes in combination with diazocarbonyl compounds, but in this case to effect a remarkable transformation that dramatically increases the molecular complexity of the substrates.

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