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Book Synopsis
This book describes the synthesis, photophysical and photochemical properties of inorganic polymers containing-Re(CO)3L+ pendants. Marked differences were found between the photochemical and photophysical properties of the polymers and those of the related monomeric complexes, pyRe(CO)3L+ (py = pyridine). The main cause of these differences is the photogeneration of the metal-to-ligand charge transfer (MLCT) excited sates in concentrations that are much larger when -Re(CO)3 L+ chromophores are bound to (vpy)n~600.

Inorganic Polymers Containing -Re(CO)3L+ Pendants

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    A Paperback / softback by Ezequiel Wolcan, Mario R Féliz

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      Book details

      Publisher Nova Science Publishers Inc
      Published 8 February 2011
      ISBN-13 9781616689285
      978-1616689285
      ISBN-10 1616689285
      Also in:
      Science & Nature Polymer chemistry

      Description

      Book Synopsis
      This book describes the synthesis, photophysical and photochemical properties of inorganic polymers containing-Re(CO)3L+ pendants. Marked differences were found between the photochemical and photophysical properties of the polymers and those of the related monomeric complexes, pyRe(CO)3L+ (py = pyridine). The main cause of these differences is the photogeneration of the metal-to-ligand charge transfer (MLCT) excited sates in concentrations that are much larger when -Re(CO)3 L+ chromophores are bound to (vpy)n~600.

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