Description
Book SynopsisForensic Chemistry: Fundamentals and Applications presents a new approach to the study of applications of chemistry to forensic science. It is edited by one of the leading forensic scientists with each chapter written by international experts specializing in their respective fields, and presents the applications of chemistry, especially analytical chemistry, to various topics that make up the forensic scientists toolkit.
This comprehensive, textbook includes in-depth coverage of the major topics in forensic chemistry including: illicit drugs, fibers, fire and explosive residues, soils, glass and paints, the chemistry of fingerprint recovery on porous surfaces, the chemistry of firearms analysis, as well as two chapters on the key tools of forensic science, microscopy and chemometrics. Each topic is explored at an advanced college level, with an emphasis, throughout the text, on the use of chemical tools in evidence analysis.
Forensic Chemistry: Fundamentals a
Table of Contents
About the editor, xii
Contributors, xiii
Series preface, xv
Preface, xvi
1 Drugs of abuse, 1
Niamh Nic Daéid
1.1 Introduction, 1
1.2 Law and legislation, 2
1.3 Sampling, 4
1.3.1 Random sampling and representative sampling, 6
1.3.2 Arbitrary sampling, 7
1.3.3 Statistical sampling methods, 8
1.4 Specific drug types, 9
1.4.1 Cannabis, 9
1.4.2 Heroin, 14
1.4.3 Cocaine, 22
1.4.4 Amphetamine]type stimulants, 27
1.4.5 New psychoactive substances, 33
1.5 Conclusions, 36
Acknowledgements, 36
References, 36
2 Textiles, 40
Max Houck
2.1 Introduction, 40
2.2 A science of reconstruction, 40
2.2.1 Classification, 41
2.2.2 Comparison, 42
2.2.3 Transfer and persistence, 43
2.3 Textiles, 43
2.3.1 Information, 44
2.3.2 Morphology, 45
2.4 Natural fibers, 48
2.4.1 Animal fibers, 48
2.4.2 Plant fibers, 51
2.5 Manufactured fibers, 52
2.6 Yarns and fabrics, 55
2.6.1 Fabric construction, 56
2.6.2 Finishes, 59
2.7 Fiber types, 59
2.7.1 Acetate, 59
2.7.2 Acrylic, 59
2.7.3 Aramids, 60
2.7.4 Modacrylic, 60
2.7.5 Nylon, 61
2.7.6 Olefins (polypropylene and polyethylene), 61
2.7.7 Polyester, 62
2.7.8 Rayon, 62
2.7.9 Spandex, 65
2.7.10 Triacetate, 66
2.7.11 Bicomponent fibers, 66
2.8 Chemistry, 67
2.8.1 General analysis, 67
2.8.2 Instrumental analysis, 68
2.8.3 Color, 69
2.8.4 Raman spectroscopy, 70
2.8.5 Interpretation, 71
2.9 The future, 72
References, 72
3 Paint and coatings examination, 75
Paul Kirkbride
3.1 Introduction, 75
3.2 Paint chemistry, 76
3.2.1 Binders, 76
3.2.2 Dyes and pigments, 86
3.2.3 Additives, 89
3.3 Automotive paint application, 91
3.4 Forensic examination of paint, 92
3.4.1 General considerations, 92
3.4.2 Microscopy, 95
3.4.3 Vibrational spectrometry, 96
3.4.4 SEM]EDX and XRF, 106
3.4.5 Pyrolytic techniques, 111
3.4.6 Color analysis, 116
3.5 Paint evidence evaluation and expert opinion, 120
References, 128
Contents vii
4 Forensic fire debris analysis, 135
Reta Newman
4.1 Introduction, 135
4.2 Process overview, 135
4.3 Sample collection, 136
4.4 Ignitable liquid classification, 137
4.5 Petroleum]based ignitable liquids, 144
4.6 Non]petroleum]based ignitable liquids, 160
4.7 Sample preparation, 161
4.8 Sample analysis and data interpretation, 166
4.9 Summary, 172
References, 173
5 Explosives, 175
John Goodpaster
5.1 The nature of an explosion, 175
5.1.1 Types of explosions, 175
5.1.2 Explosive effects, 176
5.2 Physical and chemical properties of explosives, 180
5.2.1 Low explosives, 181
5.2.2 High explosives, 186
5.3 Protocols for the forensic examination of explosives and explosive devices, 192
5.3.1 Recognition of evidence, 192
5.3.2 Portable technology and on]scene analysis, 193
5.3.3 In the laboratory, 194
5.4 Chemical analysis of explosives, 200
5.4.1 Consensus standards (TWGFEX), 201
5.4.2 Chemical tests, 203
5.4.3 X]ray techniques, 204
5.4.4 Spectroscopy, 207
5.4.5 Separations, 212
5.4.6 Gas chromatography, 213
5.4.7 Mass spectrometry, 215
5.4.8 Provenance and attribution determinations, 219
5.5 Ongoing research, 221
Acknowledgements, 222
References, 222
Further reading, 226
6 Analysis of glass evidence, 228
Jose Almirall and Tatiana Trejos
6.1 Introduction to glass examinations and comparisons, 228
6.2 Glass, the material, 231
6.2.1 Physical and chemical properties, 231
6.2.2 Manufacturing, 233
6.2.3 Fractures and their significance, 236
6.2.4 Forensic considerations: Transfer and persistence of glass, 238
6.3 A brief history of glass examinations, 241
6.4 Glass examinations and comparison, standard laboratory practices, 242
6.4.1 Physical measurements, 243
6.4.2 Optical measurements, 244
6.4.3 Chemical measurements: elemental analysis, 247
6.5 Interpretation of glass evidence examinations and comparisons, 256
6.5.1 Defining the match criteria, 256
6.5.2 Descriptive statistics, 256
6.5.3 Match criteria for refractive index measurements, 257
6.5.4 Informing power of analytical methods, forming the opinion, 260
6.5.5 Report writing and testimony, 262
6.6 Case examples, 263
6.6.1 Case 1: Hit]and]run case, 263
6.6.2 Case 2: Multiple transfer of glass in breaking]and]entry case, 264
6.7 Conclusions, 265
References, 266
7 The forensic comparison of soil and geologic microtraces, 273
Richard E. Bisbing
7.1 Soil and geologic microtraces as trace evidence, 273
7.2 Comparison process, 274
7.3 Developing expertise, 278
7.4 Genesis of soil, 279
7.5 Genesis of geologic microtraces, 284
7.6 Collecting questioned samples of unknown origin, 287
7.7 Collecting soil samples of known origin, 288
7.8 Initial comparisons, 290
7.9 Color comparison, 290
7.10 Texture comparison, 293
7.11 Mineral comparison, 297
7.12 Modal analysis, 301
7.13 Automated instrumental modal analysis, 308
7.14 Ecological constituents, 310
7.15 Anthropogenic constituents, 312
7.16 Reporting comparison results, 312
7.17 Future directions and research, 314
Acknowledgments, 314
References, 315
Further reading, 316
8 Chemical analysis for the scientific examination of questioned documents, 318
Gerald M. LaPorte
8.1 Static approach, 320
8.2 Dynamic approach, 324
8.3 Ink composition, 324
8.4 Examinations, 328
8.4.1 Physical examinations, 329
8.4.2 Optical examinations, 332
8.4.3 Chemical examinations, 333
8.4.4 Paper examinations, 339
8.5 Questioned documents, crime scenes and evidential considerations, 342
8.5.1 How was the questioned document produced?, 342
8.5.2 What evidence can be used to associate a questioned document with the crime scene and/or victim?, 343
8.5.3 Are there other forensic examinations that can be performed?, 345
8.5.4 Demonstrating that a suspect altered a document, 346
8.6 Interpreting results and rendering conclusions, 347
References, 350
9 Chemical methods for the detection of latent fingermarks, 354
Amanda A. Frick, Patrick Fritz, and Simon W. Lewis
9.1 Introduction, 354
9.2 Sources of latent fingermark residue, 355
9.2.1 Aqueous components, 356
9.2.2 Lipid components, 357
9.2.3 Sources of compositional variation, 359
9.3 Chemical processing of latent fingermarks, 361
9.3.1 Amino acid sensitive reagents, 361
9.3.2 Reagents based on colloidal metals, 370
9.3.3 Lipid]sensitive reagents, 377
9.3.4 Other techniques, 383
9.4 Experimental considerations for latent fingermark chemistry research, 384
9.5 Conclusions and future directions, 387
Acknowledgements, 388
References, 388
Further reading, 398
10 Chemical methods in firearms analysis, 400
Walter F. Rowe
10.1 Introduction, 400
10.2 Basic firearms examination, 400
10.2.1 Cleaning bullets and cartridges, 402
10.2.2 Analysis of bullet lead, 404
10.2.3 Serial number restoration, 406
10.3 Shooting incident reconstruction, 408
10.3.1 Muzzle]to]target determinations, 411
10.3.2 Firearm primers, 416
10.3.3 Collection of gunshot residue, 425
10.4 Conclusion, 433
References, 433
11 Forensic microscopy, 439
Christopher S. Palenik
11.1 The microscope as a tool, 439
11.2 Motivation, 440
11.2.1 Intimidation, 442
11.2.2 Limitations, 442
11.3 Scale, 442
11.3.1 Scale and magnification, 443
11.3.2 Noting scale, 443
11.3.3 Analytical volume and limits of detection, 443
11.4 Finding, 445
11.4.1 Spatial resolution, 445
11.4.2 Recovery resolution, 447
11.4.3 Stereomicroscope, 447
11.5 Preparing, 448
11.5.1 Preservation and documentation, 448
11.5.2 Isolation, 450
11.5.3 Mounting, 451
11.6 Looking, 455
11.6.1 Light microscopy, 456
11.6.2 Scanning electron microscopy, 457
11.7 Analyzing, 458
11.7.1 Polarized light microscopy, 458
11.7.2 Energy dispersive X]ray spectroscopy, 462
11.7.3 FTIR and Raman spectroscopy, 464
11.7.4 Other methods, 465
11.8 Thinking, 465
11.9 Thanking, 467
References, 467
12 Chemometrics, 469
Ruth Smith
12.1 Introduction, 469
12.2 Chromatograms and spectra as multivariate data, 470
12.3 Data preprocessing, 470
12.3.1 Baseline correction, 471
12.3.2 Smoothing, 473
12.3.3 Retention]time alignment, 473
12.3.4 Normalization and scaling, 475
12.4 Unsupervised pattern recognition, 477
12.4.1 Hierarchical cluster analysis, 478
12.4.2 Principal components analysis, 480
12.5 Supervised pattern recognition procedures, 485
12.5.1 k]Nearest neighbors, 486
12.5.2 Discriminant analysis, 487
12.5.3 Soft independent modeling of class analogy, 492
12.5.4 Model validation, 493
12.6 Applications of chemometric procedures in forensic science, 494
12.6.1 Fire debris and explosives, 495
12.6.2 Controlled substances and counterfeit medicines, 496
12.6.3 Trace evidence, 497
12.6.4 Impression evidence, 499
12.7 Conclusions, 499
Acknowledgements, 500
References, 500
Index, 504
