Description

Book Synopsis
This monograph on the chemistry of ylides and their related imines is directed principally towards the organic synthesis researcher. It relates current understanding of the structure, bonding and behaviour of each type of ylide as well as its preparation, handling and composition.

Table of Contents
Theoretical Description of the Bonding in Ylides.

Introduction to Phosphonium Ylides.

Preparation of Phosphonium Ylides.

Reactions of Phosphonium Ylides 1: Cleavages andDecompositions.

Reactions of Phosphonium Ylides 2: With ElectrophilicReagents.

Reactions of Phosphonium Ylides 3: With Multiple-Bonded Compoundsand Three-Membered Rings.

The Wittig Reaction 1: Scope and Applications.

The Wittig Reaction 2: Mechanism and Stereochemistry.

Phosphonate Carbanions (Phosphono Ylides).

Phosphinoxy Carbanions (Phosphino Ylides).

Other Phosphorus Ylides/Carbanions.

Iminophosphoranes and Related Compounds.

Transition Metal Complexes with Ylides.

Index.

Ylides and Imines of Phosphorus

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    A Hardback by A. William Johnson

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      Publisher: John Wiley & Sons Inc
      Publication Date: 25/08/1993
      ISBN13: 9780471522171, 978-0471522171
      ISBN10: 0471522171
      Also in:
      Chemistry

      Description

      Book Synopsis
      This monograph on the chemistry of ylides and their related imines is directed principally towards the organic synthesis researcher. It relates current understanding of the structure, bonding and behaviour of each type of ylide as well as its preparation, handling and composition.

      Table of Contents
      Theoretical Description of the Bonding in Ylides.

      Introduction to Phosphonium Ylides.

      Preparation of Phosphonium Ylides.

      Reactions of Phosphonium Ylides 1: Cleavages andDecompositions.

      Reactions of Phosphonium Ylides 2: With ElectrophilicReagents.

      Reactions of Phosphonium Ylides 3: With Multiple-Bonded Compoundsand Three-Membered Rings.

      The Wittig Reaction 1: Scope and Applications.

      The Wittig Reaction 2: Mechanism and Stereochemistry.

      Phosphonate Carbanions (Phosphono Ylides).

      Phosphinoxy Carbanions (Phosphino Ylides).

      Other Phosphorus Ylides/Carbanions.

      Iminophosphoranes and Related Compounds.

      Transition Metal Complexes with Ylides.

      Index.

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