Description

Book Synopsis
Focuses on bonds in organometallic chemistry and resulting physical properties. This book shows how to measure them by physical chemical methods, such as NMR and Moessbauer Spectroscopy.

Trade Review
"...This book is valuable..." (Chemistry & Industry, 17 March 2003)

"...chemists will benefit from this broad survey volume..." (Journal of the American Chemical Society, Vol. 125, No. 25, 2003)



Table of Contents
Contributors.

Series Preface.

Preface.

1. Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides (Piero Zanello).

2. Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations (Bernd Wrackmeyer).

3. Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution (Vladimir I. Bakhmutov).

4. NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques (Guy M. Bernard and Roderick E. Wasylishen).

5. Metal Atom Motion in Some Iron Organometallics (Rolfe H. Herber).

6. Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges (Frédéric Paul and Claude Lapinte).

7. Molecular Cluster Complexes with Facial Arene Ligands (Herbert Wadepohl).

8. Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties (Herbert Wadepohl).

9. Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes (Norbert Kuhn, Martin Göhner, Gernot Frenking and Yu Chen).

10. Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds (Gabor Balázs and Hans Joachim Breunig).

Index.

Unusual Structures and Physical Properties in Organometallic Chemistry Physical Organometallic Chemistry 1

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    A Hardback by M Gielen, Rudolph Willem, Bernd Wrackmeyer

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      View other formats and editions of Unusual Structures and Physical Properties in Organometallic Chemistry Physical Organometallic Chemistry 1 by M Gielen

      Publisher: Wiley
      Publication Date: 10/09/2002
      ISBN13: 9780471496359, 978-0471496359
      ISBN10:

      Description

      Book Synopsis
      Focuses on bonds in organometallic chemistry and resulting physical properties. This book shows how to measure them by physical chemical methods, such as NMR and Moessbauer Spectroscopy.

      Trade Review
      "...This book is valuable..." (Chemistry & Industry, 17 March 2003)

      "...chemists will benefit from this broad survey volume..." (Journal of the American Chemical Society, Vol. 125, No. 25, 2003)



      Table of Contents
      Contributors.

      Series Preface.

      Preface.

      1. Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides (Piero Zanello).

      2. Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations (Bernd Wrackmeyer).

      3. Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution (Vladimir I. Bakhmutov).

      4. NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques (Guy M. Bernard and Roderick E. Wasylishen).

      5. Metal Atom Motion in Some Iron Organometallics (Rolfe H. Herber).

      6. Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges (Frédéric Paul and Claude Lapinte).

      7. Molecular Cluster Complexes with Facial Arene Ligands (Herbert Wadepohl).

      8. Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties (Herbert Wadepohl).

      9. Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes (Norbert Kuhn, Martin Göhner, Gernot Frenking and Yu Chen).

      10. Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds (Gabor Balázs and Hans Joachim Breunig).

      Index.

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