Description

Book Synopsis
Since the introduction of the concept of synthons in 1967, it has become common among practitioners of organic synthesis to treat numerous synthetic reactions as simple combinations of the appropriate synthons instead of writing out the actual reagents in full. This book provides chemists who plan their synthetic routes manually with information on some of the new umpoled synthons and the use of synthons in planning organic syntheses. The major part of the text is devoted to acyl anions, hydroxycarbonyl and related anions, carbonyl (ALPHA)-cations, and carbonyl (BETA)-anions. Another group discussed comprises carbanionic synthons in which the carbon atom carries a singly bonded heteratom. Emphasis is on the aspects relating to synthetic use. This work includes a tabular presentation of known applications, along with relevant data on the sources, auxiliary reagents, yields, and restrictions. More than 2,000 references cited.

Table of Contents
Introduction: Classical and Umpoled Synthons (T. A, Hase).

Formyl and Acyl Anions (D. J. Ager).

Hydroxycarbonyl Anion and Related Synthons (M. Kolb).

Heteroatom-Substituted sp? Carbanionic Synthons (J. E.Saavedra).

Carbonyl a-Cations (T. A. Hase & J. K.

Koskimies).

Homoenolate Anions (N. Werstiuk).

Umpoled Synthons

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    A Hardback by Tapio A. Hase

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      Book details

      Publisher John Wiley & Sons Inc
      Published 23 June 1987
      ISBN-13 9780471806677
      978-0471806677
      ISBN-10 0471806676
      Also in:
      Chemistry

      Description

      Book Synopsis
      Since the introduction of the concept of synthons in 1967, it has become common among practitioners of organic synthesis to treat numerous synthetic reactions as simple combinations of the appropriate synthons instead of writing out the actual reagents in full. This book provides chemists who plan their synthetic routes manually with information on some of the new umpoled synthons and the use of synthons in planning organic syntheses. The major part of the text is devoted to acyl anions, hydroxycarbonyl and related anions, carbonyl (ALPHA)-cations, and carbonyl (BETA)-anions. Another group discussed comprises carbanionic synthons in which the carbon atom carries a singly bonded heteratom. Emphasis is on the aspects relating to synthetic use. This work includes a tabular presentation of known applications, along with relevant data on the sources, auxiliary reagents, yields, and restrictions. More than 2,000 references cited.

      Table of Contents
      Introduction: Classical and Umpoled Synthons (T. A, Hase).

      Formyl and Acyl Anions (D. J. Ager).

      Hydroxycarbonyl Anion and Related Synthons (M. Kolb).

      Heteroatom-Substituted sp? Carbanionic Synthons (J. E.Saavedra).

      Carbonyl a-Cations (T. A. Hase & J. K.

      Koskimies).

      Homoenolate Anions (N. Werstiuk).

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