Description
Book SynopsisThe
Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects properties, synthesis, reactions, physiological and industrial significance of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the
Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.
Table of ContentsIntroduction 1
I. Cyanuric Acid and Derivatives 17
I. Introduction 17
II. Cyanunc Acid 20
III. Cyanuric Halides 48
IV. Cyanuric Acid Esters 67
V. Acyloxy-s-triazines 90
VI. Cyanuric Azides 100
VII. Thiocyanuric Acids 105
VIII. Triazinylthioglycolic Acids and Their Derivatives 114
IX. 2.4.6-Tri(acetonylthio).s.triazine 115
X. Triselenocyanuric Acid 116
XI. Esters of s-Triazine-2,4.6-triphosphonite 117
XII. Uses and Industrial Applications of Cyanuric Chloride and Derivatives 117
II. Alkyl(Ary1)-s-triazines 147
I. Introduction 147
II. General Synthetic Methods 149
III. Reactions 162
IV. Trialkyl-s-Triazines 165
V. Triaryl-s-triazines 171
VI. Alkyl-aryl-s-Triazines 179
VII. Alkyl-aryl-dihydro-s-triazines 179
VIII. Applications 182
III. Monohydroxy-, Hydroxyamino-, Dihydroxy-s-triazines and Related Compounds 185
I. Monohydroxy-s-triazines 185
II. Monochloro-s-triazines 185
III. Hydroxyamino-s-triazines 187
IV. Dihydroxy-s-triazines 202
V. Hydrogenated Derivatives 209
VI. Dihalo-s-triazines 214
lV. Monoamino- and Diamino-s-triazines 217
I. Monoamino-s-triazines 217
II. Diamino-s-triazines 222
III. Diamino dihydro-s-triazines 258
V. Ammelide. Ammeline. and Related Compounds 269
I. Ammelide 269
II. Ammelide Ethers 274
III. Aminodichloro-s-triazines 279
IV.Ammeline 281
V. Ammeline Ethers 285
VI. Diaminochloro-s-triazines 292
VII. Dithioammelide 297
VIII. Thioammeline 298
IX. Thioammeline Ethers 301
X. Related Compounds 305
VI. Melamine and Substituted Melamines 309
I. Introduction 309
II. Physical Properties 309
III. Synthesis of Melamine 309
IV. Reactions of Melamine 321
V. Structure 348
VI. Substituted "Normal" Melamines 349
VII. Applications of Melamine and Derivatives 373
VIII. IsomelaminES 379
VII. Isocyanuric Acid and Derivatives 389
I. Isocyanuric Acid 389
II. 1.3.5.Trihalo.2.4.6.trioxohexahydro-s-triazines 390
III. Esters ofIsocyanuric Acid 393
IV. Isothiocyanuric Acid 416
V. Other Isocyanuric Compounds 420
VIII. Condensed Ring s-Triazine Systems 423
I.Endo Compounds 423
II. Condensed Five-Membered Ring Compounds 426
III. Condensed-Six-Membered Ring Compounds 445
IX. Hexahydro-s-triazines 473
I. Introduction 473
II. Hexahydro-s-triazine and Nitrate 473
III. 1.3.5.Trialkylhexahydro-s-triazine 476
IV. Aryl and Arylalkylhexahydro-s-triazines 490
V. 2.4,6-Trialkyl- and Triarylhexahydro-s-triazines 505
VI. Halogen Derivatives of Hexahydro-s-triazine and Alkylhexahydro-s-triazines 506
VII. Nitro- and Nitrosohexahydro-s-triazines 509
VIII. Amino Derivatives of Hexahydro-s-triazines 526
IX. Sulfonyl Derivatives 528
X. Hydroxy Derivatives: 1.3.5-Trihydroxyhexahydro-s-triazines 1,3,5-Trinitrosohexahydros-s-triazines 531
XI. Carbonyl (Acyl) Derivatives 533
XII. Oxo and Thion Derivatives 536
XIII. Carboxylic Acid Derivatives 539
XIV. 1-Sulfo-4-alkylhexahydro.2,4,6-triazines 540
X. Hexamethylenetetramine 545
I. Introduction 545
II. Structure 545
III. Formation 546
IV. Physical Properties 550
V. Preparation 551
VI. Reactions 552
VII. Detection and Analysis of Hexamethylenetetramie 588
VIII. Uses of Hexamethylenetetramine 588
XI. s-Triazaborane and Its Derivatives 597
I. Introduction 597
II. s-Triazaborane 597
III. Alkyl Derivatives of s-Triazaborane 607
IV. Halogen Derivatives of s-Triazaborane 619
V. Hydroxy-s-triazaboranes 624
VI. Methoxy-s-triazaboranes 624
VII. Other s-Triazaborane Derivatives 625
