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Book Synopsis
Photoluminescence (abbreviated as PL) is a process in which a substance absorbs photons (electromagnetic radiation) and then radiates photons back out. Quantum mechanically, this can be described as an excitation to a higher energy state and then a return to a lower energy state accompanied by the emission of a photon. This is one of many forms of luminescence (light emission) and is distinguished by photoexcitation (excitation by photons), hence the prefix photo-. The period between absorption and emission is typically extremely short, in the order of 10 nanoseconds. Under special circumstances, however, this period can be extended into minutes or hours. Ultimately, available chemical energy states and allowed transitions between states (and therefore wavelengths of light preferentially absorbed and emitted) are determined by the rules of quantum mechanics. A basic understanding of the principles involved can be gained by studying the electron configurations and molecular orbitals of simple atoms and molecules. More complicated molecules and advanced subtleties are treated in the field of computational chemistry.

Photoluminescence Research Progress

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    A Hardback by Harry K Wright, Grace V Edwards

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      Book details

      Publisher Nova Science Publishers Inc
      Published 1 October 2008
      ISBN-13 9781604565386
      978-1604565386
      ISBN-10 1604565381

      Description

      Book Synopsis
      Photoluminescence (abbreviated as PL) is a process in which a substance absorbs photons (electromagnetic radiation) and then radiates photons back out. Quantum mechanically, this can be described as an excitation to a higher energy state and then a return to a lower energy state accompanied by the emission of a photon. This is one of many forms of luminescence (light emission) and is distinguished by photoexcitation (excitation by photons), hence the prefix photo-. The period between absorption and emission is typically extremely short, in the order of 10 nanoseconds. Under special circumstances, however, this period can be extended into minutes or hours. Ultimately, available chemical energy states and allowed transitions between states (and therefore wavelengths of light preferentially absorbed and emitted) are determined by the rules of quantum mechanics. A basic understanding of the principles involved can be gained by studying the electron configurations and molecular orbitals of simple atoms and molecules. More complicated molecules and advanced subtleties are treated in the field of computational chemistry.

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