Description

Book Synopsis

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of t

Table of Contents
FOREWORD vii

PREFACE ix

ALLYLBORATION OF CARBONYL COMPOUNDS
Dennis G. Hall and Hugo Lachance 1

INDEX 581

Organic Reactions Volume 73

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    A Paperback / softback by Dennis G. Hall, Hugo Lachance, Scott E. Denmark

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      Publisher: John Wiley & Sons Inc
      Publication Date: Publication Date: 29/06/2012
      ISBN13: 9781118344453, 978-1118344453
      ISBN10: 1118344456
      Also in:
      Chemistry

      Description

      Book Synopsis

      Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of t

      Table of Contents
      FOREWORD vii

      PREFACE ix

      ALLYLBORATION OF CARBONYL COMPOUNDS
      Dennis G. Hall and Hugo Lachance 1

      INDEX 581

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