Description
Book SynopsisTable of ContentsTo the Student vi
Introduction: “Solving the Puzzle” or “Structure Is Everything (almost)” vii
Chapter 1 The Basics: Bonding and Molecular Structure 1
Solutions to Problems 1
Quiz 16
Chapter 2 Families of Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared (ir) Spectroscopy 18
Solutions to Problems 18
Quiz 32
Chapter 3 Acids and Bases: An Introduction to Organic Reactions and Their Mechanisms 35
Solutions to Problems 35
Quiz 48
Chapter 4 Nomenclature and Conformations of Alkanes And Cycloalkanes 50
Solutions to Problems 50
Quiz 66
Chapter 5 Stereochemistry: Chiral Molecules 69
Solutions to Problems 69
Quiz 86
Chapter 6 Nucleophilic Reactions: Properties And Substitution Reactions of Alkyl Halides 89
Solutions to Problems 89
Quiz 104
Chapter 7 Alkenes and Alkynes I: Properties And Synthesis. Elimination Reactions of Alkyl Halides 106
Solutions to Problems 106
Quiz 134
Chapter 8 Alkenes and Alkynes II: Addition Reactions 137
Solutions to Problems 137
Quiz 162
Chapter 9 Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination 165
Solutions to Problems 165
Quiz 188
Chapter 10 Radical Reactions 190
Solutions to Problems 190
Quiz 209
Chapter 11 Alcohols and Ethers: Synthesis And Reactions 212
Solutions to Problems 212
Quiz 239
Chapter 12 Alcohols From Carbonyl Compounds: Oxidation-reduction And Organometallic Compounds 240
Solutions to Problems 240
Quiz 269
Answers to First Review Problem Set 275
(First Review Problem Set is available only in WileyPlus, www.wileyplus.com)
Chapter 13 Conjugated Unsaturated Systems 296
Solutions to Problems 296
Quiz 319
Summary of Reactions by Type, Chapters 1–13 321
Methods for Functional Group Preparation, Chapters 1–13 325
Chapter 14 Aromatic Compounds 328
Solutions to Problems 328
Quiz 344
Chapter 15 Reactions of Aromatic Compounds 346
Solutions to Problems 346
Quiz 383
Chapter 16 Aldehydes and Ketones. Nucleophilic Addition to the Carbonyl Group 385
Solutions to Problems 385
Quiz 418
Chapter 17 Carboxylic Acids and Their Derivatives: Nucleophilic Addition-elimination at the Acyl Carbon 420
Solutions to Problems 420
Quiz 452
Chapter 18 Reactions at the Carbon of Carbonyl Compounds: Enols and Enolates 455
Solutions to Problems 455
Quiz 485
Chapter 19 Condensation and Conjugate Addition Reactions of Carbonyl Compounds: More Chemistry of Enolates 487
Solutions to Problems 487
Quiz 529
Chapter 20 Amines 534
Solutions to Problems 537
Quiz 574
Chapter 21 Transition Metal Complexes: Promoters of Key Bond-forming Reactions 578
Solutions to Problems 578
Quiz 589
Answers to Second Review Problem Set 591
(Second Review Problem Set is available only in WileyPlus, www.wileyplus.com)
Chapter 22 Carbohydrates 610
Solutions to Problems 611
Quiz 636
Chapter 23 Lipids 640
Solutions to Problems 640
Quiz 652
Chapter 24 Amino Acids and Proteins 655
Solutions to Problems 655
Quiz 670
Chapter 25 Nucleic Acids and Protein Synthesis 671
Solutions to Problems 671
Special Topics are available only in WileyPlus,
www.wileyplus.com. Solutions to problems in
the Special Topics are found on the following
pages:
Special Topic A 13C NMR Spectroscopy 679
Special Topic B NMR Theory and Instrumentation 680
Special Topic C Chain-Growth Polymers 681
Special Topic D Electrocyclic and Cycloaddition Reactions 682
Special Topic E Step-Growth Polymers 687
Special Topic F Thiols, Sulfur Ylides, and Disulfides 693
Special Topic G Thiol Esters and Lipid Biosynthesis 695
Special Topic H Alkaloids 696
Appendix A Empirical and Molecular Formulas 701
Problems 703
Additional Problems 704
Solutions to Problems of Appendix A 705
Appendix B Answers to Quizzes 709
Appendix C Molecular Model Set Exercises 723
