Description
Book SynopsisThis book introduces systematically the concept of weakly-bound complexes into the broad field of atmospheric sciences. To fill up the gap between our rapidly expanding knowledge of the individual properties of Van der Waals and hydrogen-bonded molecules, and our understanding of their role in the atmospheric processes, an ensemble of related topics are covered by a team of expert co-authors. The general properties of the weakly bound molecular complexes (or “clusters”) are discussed, as well as their distribution in the planetary atmospheres. Collision-induced and dimeric absorption and emission are considered in the context of atmospheric spectroscopy. The advanced experimental techniques which enable us to study the spectroscopic features of molecular complexes in the gas phase, or which are adsorbed, are reviewed. The role of molecular complexes in the cometary atmosphere, the Earth mesosphere, and the atmospheres of the giant planets and some of their satellites are also discussed in detail.
Table of ContentsStatistical physics and thermodynamics of bimolecular complexes, a.A. Vigasin; non-rigidity in Van der Waals molecules - some case studies, R.G.A. Bone; the Earth's atmosphere - (N2)2, (N2)-(O2), (O2)2, Z. Slanina; association in planetary atmospheres - the (CO2)2, (H2)2, Ar-N2 cases, Z. Slanina; dimeric absorption in the atmosphere, A.A. Vigasin; planetary atmospheres - the role of collision-induced absorption, L. Trafton; molecular complexes in Earth's upper atmosphere, J.S. Francisco; water clusters in the upper terrestrial, and inner cometary atmospheres, J.F. Crifo; determination of optical and chemical properties of molecular complexes and heterogeneous ices using matrix isolation spectroscopy, L. Schriver-Mazzuoli, A. Schriver; infrared spectroscopy of size-selected free and adsorbed water clusters, F. Huisken.
