Description

Book Synopsis
Alpha-diazocarbonyl compounds are used in syntheses which produce drugs, agrichemicals, pesticides and other compounds. The chemistry of these compounds is widely recognized to have significant synthetic importance.

Table of Contents
Synthesis of Alpha-Diazocarbonyl Compounds.

Catalysts for Metal Carbene Transformations.

Insertion Reactions.

Intermolecular Cyclopropanation and Related Addition Reactions.

Intramolecular Cyclopropanation and Related Addition Reactions.

Cycloaddition and Substitution Reactions with Aromatic and Heteroaromatic Compounds.

Generation and Reactions of Ylides from Diazocarbonyl Compounds.

X-H Insertion Reactions of Diazocarbonyl Compounds (X = N,O,S,Se,P, Halogen).

The Wolff Rearrangement and Related Reactions.

Reactions of Alpha-Diazocarbonyl Compounds with Aldehydes and Ketones.

Acid-Promoted Cyclization of Unsaturated and Aromatic Diazo Ketones.

Miscellaneous Diazocarbonyl Reactions.

Index.

Modern Catalytic Methods for Organic Synthesis

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A Hardback by Michael P. Doyle, M. Anthony McKervey, Tao Ye

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    View other formats and editions of Modern Catalytic Methods for Organic Synthesis by Michael P. Doyle

    Publisher: John Wiley & Sons Inc
    Publication Date: 26/01/1998
    ISBN13: 9780471135562, 978-0471135562
    ISBN10: 0471135569

    Description

    Book Synopsis
    Alpha-diazocarbonyl compounds are used in syntheses which produce drugs, agrichemicals, pesticides and other compounds. The chemistry of these compounds is widely recognized to have significant synthetic importance.

    Table of Contents
    Synthesis of Alpha-Diazocarbonyl Compounds.

    Catalysts for Metal Carbene Transformations.

    Insertion Reactions.

    Intermolecular Cyclopropanation and Related Addition Reactions.

    Intramolecular Cyclopropanation and Related Addition Reactions.

    Cycloaddition and Substitution Reactions with Aromatic and Heteroaromatic Compounds.

    Generation and Reactions of Ylides from Diazocarbonyl Compounds.

    X-H Insertion Reactions of Diazocarbonyl Compounds (X = N,O,S,Se,P, Halogen).

    The Wolff Rearrangement and Related Reactions.

    Reactions of Alpha-Diazocarbonyl Compounds with Aldehydes and Ketones.

    Acid-Promoted Cyclization of Unsaturated and Aromatic Diazo Ketones.

    Miscellaneous Diazocarbonyl Reactions.

    Index.

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