Description

Book Synopsis
Alpha-diazocarbonyl compounds are used in syntheses which produce drugs, agrichemicals, pesticides and other compounds. The chemistry of these compounds is widely recognized to have significant synthetic importance.

Table of Contents
Synthesis of Alpha-Diazocarbonyl Compounds.

Catalysts for Metal Carbene Transformations.

Insertion Reactions.

Intermolecular Cyclopropanation and Related Addition Reactions.

Intramolecular Cyclopropanation and Related Addition Reactions.

Cycloaddition and Substitution Reactions with Aromatic and Heteroaromatic Compounds.

Generation and Reactions of Ylides from Diazocarbonyl Compounds.

X-H Insertion Reactions of Diazocarbonyl Compounds (X = N,O,S,Se,P, Halogen).

The Wolff Rearrangement and Related Reactions.

Reactions of Alpha-Diazocarbonyl Compounds with Aldehydes and Ketones.

Acid-Promoted Cyclization of Unsaturated and Aromatic Diazo Ketones.

Miscellaneous Diazocarbonyl Reactions.

Index.

Modern Catalytic Methods for Organic Synthesis

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    A Hardback by Michael P. Doyle, M. Anthony McKervey, Tao Ye

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      View other formats and editions of Modern Catalytic Methods for Organic Synthesis by Michael P. Doyle

      Publisher: John Wiley & Sons Inc
      Publication Date: Publication Date: 26/01/1998
      ISBN13: 9780471135562, 978-0471135562
      ISBN10: 0471135569

      Description

      Book Synopsis
      Alpha-diazocarbonyl compounds are used in syntheses which produce drugs, agrichemicals, pesticides and other compounds. The chemistry of these compounds is widely recognized to have significant synthetic importance.

      Table of Contents
      Synthesis of Alpha-Diazocarbonyl Compounds.

      Catalysts for Metal Carbene Transformations.

      Insertion Reactions.

      Intermolecular Cyclopropanation and Related Addition Reactions.

      Intramolecular Cyclopropanation and Related Addition Reactions.

      Cycloaddition and Substitution Reactions with Aromatic and Heteroaromatic Compounds.

      Generation and Reactions of Ylides from Diazocarbonyl Compounds.

      X-H Insertion Reactions of Diazocarbonyl Compounds (X = N,O,S,Se,P, Halogen).

      The Wolff Rearrangement and Related Reactions.

      Reactions of Alpha-Diazocarbonyl Compounds with Aldehydes and Ketones.

      Acid-Promoted Cyclization of Unsaturated and Aromatic Diazo Ketones.

      Miscellaneous Diazocarbonyl Reactions.

      Index.

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