Description
Book SynopsisThe Handbook is a compilation of 99 articles on diverse reagents and catalysts that describe the synthesis of heteroarenes, the building blocks of a wide range of chemicals used in pharma and chemical industries. Articles are selected from thee-EROS databaseand edited to make sure that it includes only the material relevant to the topic of the book and focus on the synthetic aspects. This makes the articles very focused on the needs of readers wanting information on specific syntheses of specific heteroarenes. In addition, the chemistry of each ?parent heteroarene? is also included to ensure that the reader rapidly finds important information.
The Handbook is a part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis.
Table of ContentsPreface ix
Introduction xi
Recent Review Articles and Monographs xiii
Short Note on InChIs and InChIKeys xvii
Acetaldoxime 1
Acetone Hydrazone 7
Acetonitrile 11
Acetonitrile N-Oxide 18
N-Aminophthalimide 19
1-Amino-pyridinium iodide 24
Ammonium Nitrate 27
Ammonium Acetate 29
Ammonium Bicarbonate 30
Benzonitrile N-Oxide 33
Benzoyl Isothiocyanate 36
N-[Bis(methylthio)methylene]-p-toluenesulfonamide 37
Bromoacetone 47
1-tert-Butyloxycarbonyl-1-methylhydrazine 52
2-Chloro-1,3-dimethylimidazolinium chloride 57
Copper(I) Chloride 61
Copper(II) Chloride 75
Copper(I) Iodide 83
Copper(II) Sulfate 93
Copper(II) Trifluoromethanesulfonate 104
Cyclopentadienylbis(triphenylphosphine)cobalt(I) 115
(Diacetoxyiodo)benzene 119
Diaminomaleonitrile 128
Diazo(trimethylsilyl)methyllithium 129
Dibromoformaldehyde Oxime 135
Dichloro Bis(acetonitrile) Palladium 137
Dichlorobis(triphenylphosphine)-palladium(II) 142
Di-𝜇-chlorodichlorobis[(1,2,3,4,5-𝜂)-1,2,-3,4,5-
pentamethyl-2,4-cyclopentadien-1-yl]diiridium 146
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone 172
Dichloroformaldehyde Oxime 184
Dichlorotris(triphenylphosphine)ruthenium(II) 186
(Diethoxyphosphoryl)acetonitrile oxide 191
Diethyl Oxalate 192
2,2-Difluoroethylamine 195
Diiminosuccinonitrile 199
1,3-Diisopropyl-1,3-propanedione 200
2,5-Dimethoxytetrahydrofuran 203
N,N-Dimethylacetamide Dimethyl Acetal 208
Dimethyl Diazomalonate 215
Dimethyl 2,3-Pentadienedioate 230
Dimethyl 1,2,4,5-Tetrazine-3,6-dicarboxylate 236
2,4-Dinitrophenylhydrazine 244
Diphenyl Cyanocarbonimidate 247
Dirhodium(II) Tetraacetate 249
Dirhodium Tetrakis(heptafluorobutyramide) 265
Di-p-tolylcarbodiimide 267
Ethyl 2-Diazo-3-oxo-3-phenylpropanoate 273
Ethyl 2-Diazo-3-oxybutyrate 275
Ethyl 2-Diazo-4,4,4-trifluoro-3-oxobutanoate 281
Ethyl Ethoxymethylenecyanoacetate 284
Formamidine Acetate 289
Gold(I) Chloride 291
Gold(III) Chloride 298
Guanidine 322
2,5-Hexanedione 327
Hydrogen Sulfide 330
Hydroxylamine 335
Indium Tribromide 343
Iodine 358
Iron(III) Bromide 374
Iron(III) Chloride 379
Malonyl Chloride 387
𝛼-Methacrolein N-tert-Butylimine 389
Methyl glycine 390
Methyl Isocyanate 393
S-Methylisothiourea 395
4-Methyloxazole 397
Methyl Thioglycolate 398
Oxo(trimanganese) Heptaacetate 401
Oxygen 402
Palladium(II) Acetate 415
Palladium(II) Chloride 449
Phenyl Isocyanide 467
Phenylhydrazine 468
Phenyliodine(III) Bis(trifluoroacetate) 472
Phosphorus Oxychloride 481
Pivalic Acid 489
Polyphosphoric Acid 497
Potassium Ethyl Xanthate 503
Potassium Monoperoxysulfate 512
Selenium(IV) Oxide 531
Semicarbazide 542
Silver(I) Hexafluoroantimonate 547
Sodium Nitrite 550
Sodium Sulfide 561
Sodium Tetrachloroaurate(III) 573
Sulfur 577
N,N,N’,N’-Tetrabromobenzene-1,3-disulfonamide
(TBBDS) 583
Tetrakis(triphenylphosphine)-palladium(0) 585
3-Thiapentanedioic acid 594
Thiourea 596
o-Tolyl Isocyanide 598
p-Tolylsulfonylmethyl isocyanide 599
Trifluomethyldiazomethane 607
Trifluoroethylamine 612
Trifluoromethanesulfonic anhydride 616
1,1,1-Trifluoro-N-phenylmethanesulfenamide 633
2-(Trimethylsilyl)phenyl Triflate 635
Triphenylphosphinegold(I) Chloride 638
List of Contributors 000
Reagent Formula Index 000
Subject Index 000
