Description
Book SynopsisThe newfound stability of carbenes has led to their development as catalysts and ligands for metal complexes of vast potential, including biomolecule labeling and surface modification of materials.
Trade Review“Overall I think that this book is generally well presented and free of obvious mistakes. I very much like the fact that there is consistency in structure throughout each chapter, indicating that the editorial process has been thorough. In particular, the conclusion and outlook sections provide a valuable summary of the state-of-the-art in each area, and how the future is foreseen.” (Applied Organometallic Chemistry, 10 October 2014)
Table of ContentsPreface
PART 1: PROPERTIES AND REACTIONS OF CARBENES
1 Carbene Stability
S. Gronert and R. M. O’Ferrall
2 Stable Carbenes
J. P. Moerdyk and C. W. Bielawski 3 Acid-Base Chemistry of Carbenes
A. M. O’Donoghue and R. S. Massey
4 Computational Methods for the Study of Carbenes and their Excited States
H. L. Luk, S. Vyas, and C. M. Hadad
5 Dynamics in Carbene Reactions
D. Merrer, K. Houk, and L. Xu
6 Ultrafast Kinetics of Carbene Reactions
G. Burdzinski and M. S. Platz 7 Tunneling in the Reactions of Carbenes and Oxacarbenes
D. Gerbig and P. R. Schreiner
8 Carbodicarbenes
G. Frenking and R. Tonner
9 Catalytic Reactions with N-Mesityl Substituted N-Heterocyclic Carbenes
J. Mahatthananchai and J. W. Bode
10 Supramolecular Carbene Chemistry
U. Brinker, J.-L. Mieusset, and M. G. Rosenberg
PART 2: METAL CARBENES
11 Modern Lithium Carbenoid Chemistry
V. Capriati 12 Rhodium Carbenes
H. Davies and B. Parr
13 Ruthenium Carbenes
S. T. Diver and J. M. French 14 Nucleophilic Carbenes of the Chromium Triad
Z. J. Tonzetich
15 Cobalt-Mediated Carbene Transfer Reactions
X. Cui and X. P. Zhang
16 Gold Carbenes
L. Zhang