{"product_id":"xray-absorption-and-xray-emission-spectroscopy-2-volume-set-9781118844236","title":"XRay Absorption and XRay Emission Spectroscopy 2","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eDuring the last two decades, remarkable and often spectacular progress has been made in the methodological and instrumental aspects of x   ray absorption and emission spectroscopy.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eVOLUME I\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eList of Contributors\u003c\/p\u003e \u003cp\u003eForeword\u003c\/p\u003e \u003cp\u003e\u003cb\u003eI INTRODUCTION: HISTORY, XAS, XES, AND THEIR IMPACT ON SCIENCE\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction: Historical Perspective on XAS\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJeroen A. van Bokhoven and Carlo Lamberti\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Historical Overview of 100 Years of X-Ray Absorption: A Focus on the Pioneering 1913−1971 Period\u003c\/p\u003e \u003cp\u003e1.2 About the Book: A Few Curiosities, Some Statistics, and a Brief Overview\u003cb\u003eII EXPERIMENTAL AND THEORY\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 From Synchrotrons to FELs: How Photons Are Produced; Beamline Optics and Beam Characteristics\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eGiorgio Margaritondo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Photon Emission by Accelerated Charges: from the Classical Case to the Relativistic Limit\u003c\/p\u003e \u003cp\u003e2.2 Undulators, Wigglers, and Bending Magnets\u003c\/p\u003e \u003cp\u003e2.2.1 Undulators\u003c\/p\u003e \u003cp\u003e2.2.2 Wigglers\u003c\/p\u003e \u003cp\u003e2.2.3 Bending magnets\u003c\/p\u003e \u003cp\u003e2.2.4 High flux, high brightness\u003c\/p\u003e \u003cp\u003e2.3 The Time Structure of Synchrotron Radiation\u003c\/p\u003e \u003cp\u003e2.4 Elements of Beamline Optics\u003c\/p\u003e \u003cp\u003e2.4.1 Focusing devices\u003c\/p\u003e \u003cp\u003e2.4.2 Monochromators\u003c\/p\u003e \u003cp\u003e2.4.3 Detectors\u003c\/p\u003e \u003cp\u003e2.5 Free Electron Lasers\u003c\/p\u003e \u003cp\u003e2.5.1 FEL optical amplification\u003c\/p\u003e \u003cp\u003e2.5.2 Optical amplification in an X-FEL: details\u003c\/p\u003e \u003cp\u003e2.5.3 Saturation\u003c\/p\u003e \u003cp\u003e2.5.4 X-FEL time structure: new opportunities for spectroscopy\u003c\/p\u003e \u003cp\u003e2.5.5 Time coherence and seeding\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Real-Space Multiple-Scattering Theory of X-ray Spectra\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJoshua J. Kas, Kevin Jorisson and John J. Rehr\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction\u003c\/p\u003e \u003cp\u003e3.2 Theory\u003c\/p\u003e \u003cp\u003e3.2.1 Independent-particle approximation\u003c\/p\u003e \u003cp\u003e3.2.2 Real-space multiple-scattering theory\u003c\/p\u003e \u003cp\u003e3.2.3 Many body effects in x-ray spectra\u003c\/p\u003e \u003cp\u003e3.3 Applications\u003c\/p\u003e \u003cp\u003e3.3.1 XAS, EXAFS, XANES\u003c\/p\u003e \u003cp\u003e3.3.2 EELS\u003c\/p\u003e \u003cp\u003e3.3.3 XES\u003c\/p\u003e \u003cp\u003e3.3.4 XMCD\u003c\/p\u003e \u003cp\u003e3.3.5 NRIXS\u003c\/p\u003e \u003cp\u003e3.3.6 RIXS\u003c\/p\u003e \u003cp\u003e3.3.7 Compton scattering\u003c\/p\u003e \u003cp\u003e3.3.8 Optical constants\u003c\/p\u003e \u003cp\u003e3.4 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Theory of X-ray Absorption Near Edge Structure\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eYves Joly and Stephane Grenier\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction\u003c\/p\u003e \u003cp\u003e4.2 The x-ray Absorption Phenomena\u003c\/p\u003e \u003cp\u003e4.2.1 Probing material\u003c\/p\u003e \u003cp\u003e4.2.2 The different spectroscopies\u003c\/p\u003e \u003cp\u003e4.3 X-ray Matter Interaction\u003c\/p\u003e \u003cp\u003e4.3.1 Interaction Hamiltonian\u003c\/p\u003e \u003cp\u003e4.3.2 Absorption cross-section for the transition between two states\u003c\/p\u003e \u003cp\u003e4.3.3 State description\u003c\/p\u003e \u003cp\u003e4.3.4 The transition matrix\u003c\/p\u003e \u003cp\u003e4.4 XANES General Formulation\u003c\/p\u003e \u003cp\u003e4.4.1 Interaction times and the multi-electronic problem\u003c\/p\u003e \u003cp\u003e4.4.2 Absorption cross-section main equation\u003c\/p\u003e \u003cp\u003e4.5 XANES Simulations in the Mono-Electronic Scheme\u003c\/p\u003e \u003cp\u003e4.5.1 From multi- to mono-electronic\u003c\/p\u003e \u003cp\u003e4.5.2 The different methods\u003c\/p\u003e \u003cp\u003e4.5.3 The multiple scattering theory\u003c\/p\u003e \u003cp\u003e4.6 Multiplet Ligand Field Theory\u003c\/p\u003e \u003cp\u003e4.6.1 Atomic multiplets\u003c\/p\u003e \u003cp\u003e4.6.2 The crystal field\u003c\/p\u003e \u003cp\u003e4.7 Current Theoretical Developments\u003c\/p\u003e \u003cp\u003e4.8 Tensorial Approaches\u003c\/p\u003e \u003cp\u003e4.9 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 How to Start an XAS Experiment\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eDiego Gianolio\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction\u003c\/p\u003e \u003cp\u003e5.2.1 Identify the scientific question\u003c\/p\u003e \u003cp\u003e5.2.2 Can XAS solve the problem?\u003c\/p\u003e \u003cp\u003e5.2.3 Select the best beamline and measurement mode\u003c\/p\u003e \u003cp\u003e5.2.4 Write the proposal\u003c\/p\u003e \u003cp\u003e5.3 Prepare the Experiment\u003c\/p\u003e \u003cp\u003e5.3.1 Experimental design\u003c\/p\u003e \u003cp\u003e5.3.2 Best sample conditions for data acquisition\u003c\/p\u003e \u003cp\u003e5.3.3 Sample preparation\u003c\/p\u003e \u003cp\u003e5.4 Perform the Experiment\u003c\/p\u003e \u003cp\u003e5.4.1 Initial set-up and optimization of signal\u003c\/p\u003e \u003cp\u003e5.4.2 Data acquisition\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Hard X-ray Photon-in\/Photon-out Spectroscopy: Instrumentation, Theory and Applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePieter Glatzel, Roberto Alonso-Mori, and Dimosthenis Sokaras\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction\u003c\/p\u003e \u003cp\u003e6.2 History\u003c\/p\u003e \u003cp\u003e6.3 Basic Theory of XES\u003c\/p\u003e \u003cp\u003e6.3.1 One- and multi-electron description\u003c\/p\u003e \u003cp\u003e6.3.2 X-ray Raman scattering spectroscopy\u003c\/p\u003e \u003cp\u003e6.4 Chemical Sensitivity of x-ray Emission\u003c\/p\u003e \u003cp\u003e6.4.1 Core-to-core transitions\u003c\/p\u003e \u003cp\u003e6.4.2 Valence-to-core transitions\u003c\/p\u003e \u003cp\u003e6.5 HERFD and RIXS\u003c\/p\u003e \u003cp\u003e6.6 Experimental x-ray Emission Spectroscopy\u003c\/p\u003e \u003cp\u003e6.6.1 Sources for x-ray emission spectroscopy\u003c\/p\u003e \u003cp\u003e6.6.2 X-ray emission spectrometers\u003c\/p\u003e \u003cp\u003e6.6.3 Detectors\u003c\/p\u003e \u003cp\u003e6.7 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 QEXAFS: Techniques and Scientific Applications for Time-Resolved XAS\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eMaarten Nachtegaal, Oliver Muller, Christian Konig and Ronald Frahm\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction\u003c\/p\u003e \u003cp\u003e7.2 History and Basics of QEXAFS\u003c\/p\u003e \u003cp\u003e7.3 Monochromators and Beamlines for QEXAFS\u003c\/p\u003e \u003cp\u003e7.3.1 QEXAFS with conventional monochromators\u003c\/p\u003e \u003cp\u003e7.3.2 Piezo-QEXAFS for the millisecond time range\u003c\/p\u003e \u003cp\u003e7.3.3 Dedicated oscillating monochromators for QEXAFS\u003c\/p\u003e \u003cp\u003e7.4 Detectors and Readout Systems\u003c\/p\u003e \u003cp\u003e7.4.1 Requirements for detectors\u003c\/p\u003e \u003cp\u003e7.4.2 Gridded ionization chambers\u003c\/p\u003e \u003cp\u003e7.4.3 Data acquisition\u003c\/p\u003e \u003cp\u003e7.4.4 Angular encoder\u003c\/p\u003e \u003cp\u003e7.5 Applications of QEXAFS in Chemistry\u003c\/p\u003e \u003cp\u003e7.5.1 Following the fate of metal contaminants at the mineral–water interface\u003c\/p\u003e \u003cp\u003e7.5.2 Identifying the catalytic active sites in gas phase reactions\u003c\/p\u003e \u003cp\u003e7.5.4 Synthesis of nanoparticles\u003c\/p\u003e \u003cp\u003e7.5.5 Identification of reaction intermediates: modulation excitation XAS\u003c\/p\u003e \u003cp\u003e7.6 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Time-Resolved XAS Using an Energy Dispersive Spectrometer: Techniques and Applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eOlivier Mathon, Innokenty Kantor and Sakura Pascarelli\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction\u003c\/p\u003e \u003cp\u003e8.2 Energy Dispersive X-Ray Absorption Spectroscopy\u003c\/p\u003e \u003cp\u003e8.2.1 Historical development of EDXAS and overview of existing facilities\u003c\/p\u003e \u003cp\u003e8.2.2 Principles: source, optics, detection\u003c\/p\u003e \u003cp\u003e8.2.3 Dispersive versus scanning spectrometer for time-resolved experiments\u003c\/p\u003e \u003cp\u003e8.2.4 Description of the EDXAS beamline at ESRF\u003c\/p\u003e \u003cp\u003e8.3 From the Minute Down to the Ms: Filming a Chemical Reaction \u003ci\u003e\u003ci\u003ein Situ \u003c\/i\u003e\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.3.1 Technical aspects\u003c\/p\u003e \u003cp\u003e8.3.2 First stages of nanoparticle formation\u003c\/p\u003e \u003cp\u003e8.3.3 Working for cleaner cars: automotive exhaust catalyst\u003c\/p\u003e \u003cp\u003e8.3.4 Reaction mechanisms and intermediates\u003c\/p\u003e \u003cp\u003e8.3.5 High temperature oxidation of metallic iron\u003c\/p\u003e \u003cp\u003e8.4 Down to the μs Regime: Matter under Extreme Conditions\u003c\/p\u003e \u003cp\u003e8.4.1 Technical aspects\u003c\/p\u003e \u003cp\u003e8.4.2 Melts at extreme pressure and temperature\u003c\/p\u003e \u003cp\u003e8.4.3 Spin transitions at high magnetic field\u003c\/p\u003e \u003cp\u003e8.4.4 Fast ohmic ramp excitation towards the warm dense matter regime\u003c\/p\u003e \u003cp\u003e8.5 Playing with a 100 ps Single Bunch\u003c\/p\u003e \u003cp\u003e8.5.1 Technical aspects\u003c\/p\u003e \u003cp\u003e8.5.2 Detection and characterization of photo-excited states in Cu+ complexes\u003c\/p\u003e \u003cp\u003e8.5.3 Opportunities for investigating laser-shocked matter\u003c\/p\u003e \u003cp\u003e8.5.4 Non-synchrotron EDXAS\u003c\/p\u003e \u003cp\u003e8.6 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 X-Ray Transient Absorption Spectroscopy\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eLin X. Chen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction\u003c\/p\u003e \u003cp\u003e9.2 Pump-Probe Spectroscopy\u003c\/p\u003e \u003cp\u003e9.2.1 Background\u003c\/p\u003e \u003cp\u003e9.2.2 The basic set-up\u003c\/p\u003e \u003cp\u003e9.3 Experimental Considerations\u003c\/p\u003e \u003cp\u003e9.3.1 XTA at a synchrotron source\u003c\/p\u003e \u003cp\u003e9.3.2 XTA at X-ray free electron laser sources\u003c\/p\u003e \u003cp\u003e9.4 Transient Structural Information Investigated by XTA\u003c\/p\u003e \u003cp\u003e9.4.1 Metal center oxidation state\u003c\/p\u003e \u003cp\u003e9.4.2 Electron configuration and orbital energies of X-ray absorbing atoms\u003c\/p\u003e \u003cp\u003e9.4.3 Transient coordination geometry of the metal center\u003c\/p\u003e \u003cp\u003e9.5 X-Ray Pump-Probe Absorption Spectroscopy: Examples\u003c\/p\u003e \u003cp\u003e9.5.1 Excited state dynamics of transition metal complexes (TMCs)\u003c\/p\u003e \u003cp\u003e9.5.2 Interfacial charge transfer in hybrid systems\u003c\/p\u003e \u003cp\u003e9.5.3 XTA studies of metal center active site structures in metalloproteins\u003c\/p\u003e \u003cp\u003e9.5.4 XTA using the X-ray free electron lasers\u003c\/p\u003e \u003cp\u003e9.5.5 Other XTA application examples\u003c\/p\u003e \u003cp\u003e9.6 Perspective of Pump-Probe X-Ray Spectroscopy\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Space-Resolved XAFS, Instrumentations and Applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eYoshio Suzuki and Yasuko Terada\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Space-Resolving Techniques for XAFS\u003c\/p\u003e \u003cp\u003e10.2 Beam-Focusing Instrumentation for Microbeam Production\u003c\/p\u003e \u003cp\u003e10.2.1 Total reflection mirror systems\u003c\/p\u003e \u003cp\u003e10.2.2 Fresnel zone plate optics for x-ray microbeam\u003c\/p\u003e \u003cp\u003e10.2.3 General issues of beam-focusing optics\u003c\/p\u003e \u003cp\u003e10.2.4 Requirements on beam stability in microbeam XAFS experiments\u003c\/p\u003e \u003cp\u003e10.3 Examples of Beam-Focusing Instrumentation\u003c\/p\u003e \u003cp\u003e10.3.1 The total-reflection mirror system\u003c\/p\u003e \u003cp\u003e10.3.2 Fresnel zone plate system\u003c\/p\u003e \u003cp\u003e10.4 Examples of Applications of Microbeam-XAFS Technique to Biology and nenvironmental Science\u003c\/p\u003e \u003cp\u003e10.4.1 Speciation of heavy metals in willow\u003c\/p\u003e \u003cp\u003e10.4.2 Characterization of arsenic-accumulating mineral in a sedimentary iron deposit\u003c\/p\u003e \u003cp\u003e10.4.3 Feasibility study for microbeam XAFS analysis using FZP optics\u003c\/p\u003e \u003cp\u003e10.4.4 Micro-XAFS studies of plutonium sorbed on tuff\u003c\/p\u003e \u003cp\u003e10.4.5 Micro-XANES analysis of vanadium accumulation in ascidian blood cell\u003c\/p\u003e \u003cp\u003e10.5 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Quantitative EXAFS Analysis\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eBruce Ravel\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 A Brief History of EXAFS Theory\u003c\/p\u003e \u003cp\u003e11.1.1 The n-body decomposition in GNXAS\u003c\/p\u003e \u003cp\u003e11.1.2 The exact curved wave theory in EXCURVE\u003c\/p\u003e \u003cp\u003e11.1.3 The path expansion in FEFF\u003c\/p\u003e \u003cp\u003e11.2 Theoretical Calculation of EXAFS Scattering Factors\u003c\/p\u003e \u003cp\u003e11.2.1 The pathfinder\u003c\/p\u003e \u003cp\u003e11.2.2 The fitting metric\u003c\/p\u003e \u003cp\u003e11.2.3 Constraints on parameters of the fit\u003c\/p\u003e \u003cp\u003e11.2.4 Fitting statistics\u003c\/p\u003e \u003cp\u003e11.2.5 Extending the evaluation of χ2\u003c\/p\u003e \u003cp\u003e11.2.6 Other analytic methods\u003c\/p\u003e \u003cp\u003e11.3 Practical Examples of EXAFS Analysis\u003c\/p\u003e \u003cp\u003e11.3.1 Geometric constraints on bond lengths\u003c\/p\u003e \u003cp\u003e11.3.2 Constraints on the coordination environment\u003c\/p\u003e \u003cp\u003e11.3.3 Constraints and multiple data set analysis\u003c\/p\u003e \u003cp\u003e11.4 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 XAS Spectroscopy: Related Techniques and Combination with Other Spectroscopic and Scattering Methods\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eCarlo Lamberti, Elisa Borfecchia, Jeroen A. van Bokhoven and Marcos Fernández-Garcia\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction\u003c\/p\u003e \u003cp\u003e12.2 Atomic Pair Distribution Analysis of Total Scattering Data\u003c\/p\u003e \u003cp\u003e12.2.1 Theoretical description\u003c\/p\u003e \u003cp\u003e12.2.2 Examples of PDF analysis\u003c\/p\u003e \u003cp\u003e12.3 Diffraction Anomalous Fine Structure (DAFS)\u003c\/p\u003e \u003cp\u003e12.3.1 Theoretical description\u003c\/p\u003e \u003cp\u003e12.3.2 Examples of DAFS\u003c\/p\u003e \u003cp\u003e12.4 Inelastic Scattering Techniques\u003c\/p\u003e \u003cp\u003e12.4.1 Extended energy-loss fine structure (EXELFS)\u003c\/p\u003e \u003cp\u003e12.4.2 X-ray Raman scattering (XRS)\u003c\/p\u003e \u003cp\u003e12.5 β-Environmental Fine Structure (BEFS)\u003c\/p\u003e \u003cp\u003e12.6 Combined Techniques\u003c\/p\u003e \u003cp\u003e12.6.1 General considerations\u003c\/p\u003e \u003cp\u003e12.6.2 Selected examples\u003c\/p\u003e \u003cp\u003e12.7 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003eVOLUME II\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eList of Contributors\u003c\/p\u003e \u003cp\u003eForeword\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIII APPLICATIONS: FROM SEMICONDUCTORS TO MEDICINE TO NUCLEAR MATERIALS\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 X-Ray Absorption and Emission Spectroscopy for Catalysis\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJeroen A. van Bokhoven and Carlo Lamberti\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction\u003c\/p\u003e \u003cp\u003e13.2 The Catalytic Process\u003c\/p\u003e \u003cp\u003e13.2.1 From vacuum and single crystals to realistic pressure and relevant samples\u003c\/p\u003e \u003cp\u003e13.2.2 From chemisorption to conversion and reaction kinetics\u003c\/p\u003e \u003cp\u003e13.2.3 Structural differences within a single catalytic reactor\u003c\/p\u003e \u003cp\u003e13.2.4 Determining the structure of the active site\u003c\/p\u003e \u003cp\u003e13.3 Reaction Kinetics from Time-Resolved XAS\u003c\/p\u003e \u003cp\u003e13.3.1 Oxygen storage materials\u003c\/p\u003e \u003cp\u003e13.3.2 Selective propene oxidation over α-MoO3\u003c\/p\u003e \u003cp\u003e13.3.3 Active sites of the dream reaction, the direct conversion of benzene to phenol\u003c\/p\u003e \u003cp\u003e13.4 Sub-Micrometer Space Resolved Measurements\u003c\/p\u003e \u003cp\u003e13.5 Emerging Methods\u003c\/p\u003e \u003cp\u003e13.5.1 X-ray emission spectroscopy\u003c\/p\u003e \u003cp\u003e13.5.2 Pump probe methods\u003c\/p\u003e \u003cp\u003e13.6 Conclusion and outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 High Pressure XAS, XMCD and IXS 383\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJean-Paul Itie, Francois Baudelet and Jean-Pascal Rueff\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction\u003c\/p\u003e \u003cp\u003e14.1.1 Why pressure matters\u003c\/p\u003e \u003cp\u003e14.1.2 High-pressure generation and measurements\u003c\/p\u003e \u003cp\u003e14.1.3 Specific drawbacks of a high-pressure set-up\u003c\/p\u003e \u003cp\u003e14.2 High Pressure EXAFS and XANES\u003c\/p\u003e \u003cp\u003e14.2.1 Introduction\u003c\/p\u003e \u003cp\u003e14.2.2 Local equation of state\u003c\/p\u003e \u003cp\u003e14.2.3 Pressure-induced phase transitions\u003c\/p\u003e \u003cp\u003e14.2.4 Glasses, amorphous materials, amorphization\u003c\/p\u003e \u003cp\u003e14.2.5 Extension to low and high energy edges\u003c\/p\u003e \u003cp\u003e14.3 High-Pressure Magnetism and XMCD\u003c\/p\u003e \u003cp\u003e14.3.1 Introduction\u003c\/p\u003e \u003cp\u003e14.3.2 Transition metal\u003c\/p\u003e \u003cp\u003e14.3.3 Magnetic insulator\u003c\/p\u003e \u003cp\u003e14.3.4 The rare earth system\u003c\/p\u003e \u003cp\u003e14.4 High Pressure Inelastic X-Ray Scattering\u003c\/p\u003e \u003cp\u003e14.4.1 Electronic structure\u003c\/p\u003e \u003cp\u003e14.4.2 Magnetic transitions in 3d and 4f electron systems\u003c\/p\u003e \u003cp\u003e14.4.3 Metal insulator transitions in correlated systems\u003c\/p\u003e \u003cp\u003e14.4.4 Valence transition in mixed valent rare-earth compounds\u003c\/p\u003e \u003cp\u003e14.4.5 Low-energy absorption edges: chemical bonding and orbital configuration\u003c\/p\u003e \u003cp\u003e14.5 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 X-Ray Absorption and RIXS on Coordination Complexes\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eThomas Kroll, Marcus Lundberg and Edward I. Solomon\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction\u003c\/p\u003e \u003cp\u003e15.1.1 Geometric and electronic structure of coordination complexes\u003c\/p\u003e \u003cp\u003e15.1.2 X-ray probes of coordination complexes\u003c\/p\u003e \u003cp\u003e15.1.3 Extracting electronic structure from X-ray spectra\u003c\/p\u003e \u003cp\u003e15.2 Metal K-Edges\u003c\/p\u003e \u003cp\u003e15.2.1 The case of a single 3d hole: Cu(II)\u003c\/p\u003e \u003cp\u003e15.2.2 Multiple 3d holes: Fe(III) and Fe(II)\u003c\/p\u003e \u003cp\u003e15.3 Metal L-Edges\u003c\/p\u003e \u003cp\u003e15.3.1 The case of a single 3d hole: Cu(II)\u003c\/p\u003e \u003cp\u003e15.3.2 Multiple 3d holes: Fe(III) and Fe(II)\u003c\/p\u003e \u003cp\u003e15.4 Resonant Inelastic X-Ray Scattering\u003c\/p\u003e \u003cp\u003e15.4.1 Ferrous systems\u003c\/p\u003e \u003cp\u003e15.4.2 Ferric systems\u003c\/p\u003e \u003cp\u003e15.5 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Semiconductors\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eFederico Boscherini\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction\u003c\/p\u003e \u003cp\u003e16.2 XAS Instrumental Aspects\u003c\/p\u003e \u003cp\u003e16.3 Applications\u003c\/p\u003e \u003cp\u003e16.3.1 Dopants and defects\u003c\/p\u003e \u003cp\u003e16.3.2 Thin films and heterostructures\u003c\/p\u003e \u003cp\u003e16.3.3 Nanostructures\u003c\/p\u003e \u003cp\u003e16.3.4 Dilute magnetic semiconductors\u003c\/p\u003e \u003cp\u003e16.4 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 XAS Studies on Mixed Valence Oxides\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJoaquýn Garcýa, Gloria Subýas and Javier Blasco\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction\u003c\/p\u003e \u003cp\u003e17.1.1 X-ray absorption spectroscopy (XAS)\u003c\/p\u003e \u003cp\u003e17.1.2 XES and XAS\u003c\/p\u003e \u003cp\u003e17.1.3 Resonant x-ray scattering\u003c\/p\u003e \u003cp\u003e17.2 Solid State Applications (Mixed Valence Oxides)\u003c\/p\u003e \u003cp\u003e17.2.1 High tc superconductors\u003c\/p\u003e \u003cp\u003e17.2.2 Manganites\u003c\/p\u003e \u003cp\u003e17.2.3 Perovskite cobaltites\u003c\/p\u003e \u003cp\u003e17.3 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Novel XAS Techniques for Probing Fuel Cells and Batteries\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eDavid E. Ramaker\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction\u003c\/p\u003e \u003cp\u003e18.2 XANES Techniques\u003c\/p\u003e \u003cp\u003e18.2.1 Data analysis\u003c\/p\u003e \u003cp\u003e18.2.2 Data collection\u003c\/p\u003e \u003cp\u003e18.2.3 Comparison of techniques by examination of O(H)\/Pt and CO\/Pt\u003c\/p\u003e \u003cp\u003e18.3 \u003ci\u003e\u003ci\u003eIn Operando \u003c\/i\u003e\u003c\/i\u003eMeasurements\u003c\/p\u003e \u003cp\u003e18.3.1 Fuel cells\u003c\/p\u003e \u003cp\u003e18.3.2 Batteries\u003c\/p\u003e \u003cp\u003e18.4 Future Trends\u003c\/p\u003e \u003cp\u003e18.5 Appendix\u003c\/p\u003e \u003cp\u003e18.5.1 Details of the ΔμXANES analysis technique\u003c\/p\u003e \u003cp\u003e18.5.2 FEFF8 theoretical calculations\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 X-ray Spectroscopy in Studies of the Nuclear Fuel Cycle\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eMelissa A. Denecke\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Background\u003c\/p\u003e \u003cp\u003e19.1.1 Introduction\u003c\/p\u003e \u003cp\u003e19.1.2 Radioactive materials at synchrotron sources\u003c\/p\u003e \u003cp\u003e19.2 Application Examples\u003c\/p\u003e \u003cp\u003e19.2.1 Studies related to uranium mining\u003c\/p\u003e \u003cp\u003e19.2.2 Studies related to fuel\u003c\/p\u003e \u003cp\u003e19.2.3 Investigations of reactor components\u003c\/p\u003e \u003cp\u003e19.2.4 Studies related to recycle and lanthanide\/actinide separations\u003c\/p\u003e \u003cp\u003e19.2.5 Studies concerning legacy remediation and waste disposal (waste forms, near-field and far-field)\u003c\/p\u003e \u003cp\u003e19.3 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Planetary, Geological and Environmental Sciences\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eFrancois Farges and Max Wilke\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction\u003c\/p\u003e \u003cp\u003e20.2 Planetary and Endogenous Earth Sciences\u003c\/p\u003e \u003cp\u003e20.2.1 Planetary materials and meteorites\u003c\/p\u003e \u003cp\u003e20.2.2 Crystalline deep earth materials\u003c\/p\u003e \u003cp\u003e20.2.3 Magmatic and volcanic processes\u003c\/p\u003e \u003cp\u003e20.2.4 Element complexation in aqueous fluids at P and T\u003c\/p\u003e \u003cp\u003e20.3 Environmental Geosciences\u003c\/p\u003e \u003cp\u003e20.3.1 General trends\u003c\/p\u003e \u003cp\u003e20.3.2 Environmentally relevant minerals and phases\u003c\/p\u003e \u003cp\u003e20.3.3 Mechanisms and reactivity at the mineral-water interfaces\u003c\/p\u003e \u003cp\u003e20.3.4 Some environmental applications of x-ray absorption spectroscopy\u003c\/p\u003e \u003cp\u003e20.4 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 X-Ray Absorption Spectroscopy and Cultural Heritage: Highlights and Perspectives\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eFrançois Farges and Marine Cotte\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction\u003c\/p\u003e \u003cp\u003e21.2 Instrumentation: Standard and Recently Developed Approaches\u003c\/p\u003e \u003cp\u003e21.2.1 From centimetric objects to micrometric cross-sections\u003c\/p\u003e \u003cp\u003e21.2.2 Improving the spectral resolution of XRF detectors\u003c\/p\u003e \u003cp\u003e21.2.3 From hard X-rays to soft X-rays\u003c\/p\u003e \u003cp\u003e21.2.4 Spectro-imaging in the hard X-ray domain\u003c\/p\u003e \u003cp\u003e21.3 Some Applications\u003c\/p\u003e \u003cp\u003e21.3.1 Glasses\u003c\/p\u003e \u003cp\u003e21.3.2 Ceramics\u003c\/p\u003e \u003cp\u003e21.3.3 Pigments and Paintings\u003c\/p\u003e \u003cp\u003e21.3.4 Inks\u003c\/p\u003e \u003cp\u003e21.3.5 Woods: from historical to fossils\u003c\/p\u003e \u003cp\u003e21.3.6 Bones and ivory\u003c\/p\u003e \u003cp\u003e21.3.7 Metals\u003c\/p\u003e \u003cp\u003e21.3.8 Rock-formed monuments\u003c\/p\u003e \u003cp\u003e21.4 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e22 X-ray Spectroscopy at Free Electron Lasers\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eWojciech Gawelda, Jakub Szlachetko and Christopher J. Milne\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e22.1 Introduction to X-ray Free Electron Lasers in Comparison to Synchrotrons\u003c\/p\u003e \u003cp\u003e22.1.1 Overview of facilities\u003c\/p\u003e \u003cp\u003e22.1.2 X-ray properties from an XFEL\u003c\/p\u003e \u003cp\u003e22.1.3 Scanning the X-ray energy\u003c\/p\u003e \u003cp\u003e22.1.4 Comparison with existing time-resolved techniques at synchrotrons\u003c\/p\u003e \u003cp\u003e22.2 Current Implementations of X-Ray Spectroscopy Techniques at XFELs\u003c\/p\u003e \u003cp\u003e22.2.1 X-ray absorption spectroscopy\u003c\/p\u003e \u003cp\u003e22.2.2 X-ray emission spectroscopy\u003c\/p\u003e \u003cp\u003e22.3 Examples of Time-Resolved X-Ray Spectroscopy at XFELs\u003c\/p\u003e \u003cp\u003e22.3.1 Ultrafast spin-crossover excitation probed with X-ray absorption spectroscopy\u003c\/p\u003e \u003cp\u003e22.3.2 Ultrafast spin cross-over excitation probed with X-ray emission spectroscopy\u003c\/p\u003e \u003cp\u003e22.3.3 Simultaneous measurement of the structural and electronic changes in Photosystem II after photoexcitation\u003c\/p\u003e \u003cp\u003e22.3.4 Investigating surface photochemistry\u003c\/p\u003e \u003cp\u003e22.3.5 Soft X-ray emission spectroscopy measurements of dilute systems\u003c\/p\u003e \u003cp\u003e22.4 Examples of Nonlinear X-Ray Spectroscopy at XFELs\u003c\/p\u003e \u003cp\u003e22.4.1 X-ray-induced transparency\u003c\/p\u003e \u003cp\u003e22.4.2 Sequential ionization and core-to-core resonances\u003c\/p\u003e \u003cp\u003e22.4.3 Hollow atoms\u003c\/p\u003e \u003cp\u003e22.4.4 Solid-density plasma\u003c\/p\u003e \u003cp\u003e22.4.5 Two-photon absorption\u003c\/p\u003e \u003cp\u003e22.5 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e23 X-ray Magnetic Circular Dichroism\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eAndrei Rogalev, Katharina Ollefs and Fabrice Wilhelm\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e23.1 Historical Introduction\u003c\/p\u003e \u003cp\u003e23.2 Physical Content of XMCD and the Sum Rules\u003c\/p\u003e \u003cp\u003e23.3 Experimental Aspects and Data Analysis\u003c\/p\u003e \u003cp\u003e23.3.1 Sources of circularly polarized x-rays\u003c\/p\u003e \u003cp\u003e23.3.2 Sample environment\u003c\/p\u003e \u003cp\u003e23.3.3 Detection modes\u003c\/p\u003e \u003cp\u003e23.3.4 Standard analysis\u003c\/p\u003e \u003cp\u003e23.4 Examples of Recent Research\u003c\/p\u003e \u003cp\u003e23.4.1 Paramagnetism of pure metallic clusters\u003c\/p\u003e \u003cp\u003e23.4.2 Magnetism in diluted magnetic semiconductors\u003c\/p\u003e \u003cp\u003e23.4.3 Photomagnetic molecular magnets\u003c\/p\u003e \u003cp\u003e23.5 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e24 Industrial Applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eSimon R. Bare and Jeffrey Cutler\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e24.1 Introduction\u003c\/p\u003e \u003cp\u003e24.2 The Patent Literature\u003c\/p\u003e \u003cp\u003e24.2.1 Catalysts\u003c\/p\u003e \u003cp\u003e24.2.2 Batteries\u003c\/p\u003e \u003cp\u003e24.2.3 Other applications\u003c\/p\u003e \u003cp\u003e24.3 The Open Literature\u003c\/p\u003e \u003cp\u003e24.3.1 Semiconductors, thin films, and electronic materials\u003c\/p\u003e \u003cp\u003e24.3.2 Fuel cells, batteries, and electrocatalysts\u003c\/p\u003e \u003cp\u003e24.3.3 Metallurgy and tribology\u003c\/p\u003e \u003cp\u003e24.3.4 Homogeneous and heterogeneous catalysts\u003c\/p\u003e \u003cp\u003e24.3.5 Miscellaneous applications: from sludge to thermographic films\u003c\/p\u003e \u003cp\u003e24.4 Examples of Applications from Light Sources\u003c\/p\u003e \u003cp\u003e24.4.1 Introduction\u003c\/p\u003e \u003cp\u003e24.4.2 Industrial science at the Canadian Light Source\u003c\/p\u003e \u003cp\u003e24.4.3 Use of SOLEIL beamlines by industry\u003c\/p\u003e \u003cp\u003e24.4.4 Industrial research enhancement program at NSLS\u003c\/p\u003e \u003cp\u003e24.4.5 The Swiss Light Source: cutting-edge research facilities for industry\u003c\/p\u003e \u003cp\u003e24.5 Examples of Applications from Companies\u003c\/p\u003e \u003cp\u003e24.5.1 Introduction\u003c\/p\u003e \u003cp\u003e24.5.2 Haldor Topsøe A\/S\u003c\/p\u003e \u003cp\u003e24.5.3 UOP LLC, a Honeywell Company\u003c\/p\u003e \u003cp\u003e24.5.4 General Electric Company\u003c\/p\u003e \u003cp\u003e24.5.5 IBM Research Center\u003c\/p\u003e \u003cp\u003e24.6 Conducting Industrial Research at Light Sources\u003c\/p\u003e \u003cp\u003e24.7 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003e\u003cb\u003e25 XAS in Liquid Systems\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eAdriano Filipponi and Paola D'Angelo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e25.1 The Liquid State of Matter\u003c\/p\u003e \u003cp\u003e25.1.1 Thermodynamic considerations\u003c\/p\u003e \u003cp\u003e25.1.2 Pair and higher order distribution functions\u003c\/p\u003e \u003cp\u003e25.2 Computer Modelling of Liquid Structures\u003c\/p\u003e \u003cp\u003e25.2.1 Molecular Dynamics simulations\u003c\/p\u003e \u003cp\u003e25.2.2 Classical Molecular Dynamics\u003c\/p\u003e \u003cp\u003e25.2.3 Born-Oppenheimer Molecular Dynamics\u003c\/p\u003e \u003cp\u003e25.2.4 Car-Parrinello Molecular Dynamics\u003c\/p\u003e \u003cp\u003e25.2.5 Monte Carlo simulation approaches\u003c\/p\u003e \u003cp\u003e25.3 XAFS Calculations in Liquids\/Disordered Systems\u003c\/p\u003e \u003cp\u003e25.3.1 XAFS sensitivity and its specific role\u003c\/p\u003e \u003cp\u003e25.3.2 XAFS signal decomposition\u003c\/p\u003e \u003cp\u003e25.3.3 XAFS signal from the pair distribution\u003c\/p\u003e \u003cp\u003e25.3.4 The triplet distribution case in elemental systems\u003c\/p\u003e \u003cp\u003e25.4 Experimental and Data-Analysis Approaches\u003c\/p\u003e \u003cp\u003e25.4.1 Sample confinement strategies and detection techniques\u003c\/p\u003e \u003cp\u003e25.4.2 High pressure, temperature control, and XAS sensitivity to phase transitions\u003c\/p\u003e \u003cp\u003e25.4.3 Traditional versus atomistic data-analysis approaches\u003c\/p\u003e \u003cp\u003e25.5 Examples of Data Analysis Applications\u003c\/p\u003e \u003cp\u003e25.5.1 Elemental systems: icosahedral order in metals\u003c\/p\u003e \u003cp\u003e25.5.3 Transition metal aqua ions\u003c\/p\u003e \u003cp\u003e25.5.4 Lanthanide aqua ions\u003c\/p\u003e \u003cp\u003e25.5.5 Halide aqua ions: the bromide case\u003c\/p\u003e \u003cp\u003e\u003cb\u003e26 Surface Metal Complexes and Their Applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eJoseph D. Kistler, Pedro Serna, Kiyotaka Asakura and Bruce C. Gates\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e26.1 Introduction\u003c\/p\u003e \u003cp\u003e26.1.1 Ligands other than supports\u003c\/p\u003e \u003cp\u003e26.1.2 Supports\u003c\/p\u003e \u003cp\u003e26.1.3 Techniques complementing x-ray absorption spectroscopy\u003c\/p\u003e \u003cp\u003e26.1.4 Data-fitting techniques\u003c\/p\u003e \u003cp\u003e26.2 Aim of the Chapter\u003c\/p\u003e \u003cp\u003e26.3 Mononuclear Iridium Complexes Supported on Zeolite HSSZ-53: Illustration of EXAFS Data Fitting and Model Discrimination\u003c\/p\u003e \u003cp\u003e26.4 Iridium Complexes Supported on MgO and on Zeolites: Precisely Synthesized Isostructural Metal Complexes on Supports with Contrasting Properties as Ligands\u003c\/p\u003e \u003cp\u003e26.5 Supported Chromium Complex Catalysts for Ethylene Polymerization Characterization of Samples Resembling Industrial Catalysts\u003c\/p\u003e \u003cp\u003e26.6 Copper Complexes on Titania: Insights Gained from Samples Incorporating Single-Crystal Supports\u003c\/p\u003e \u003cp\u003e26.7 Gold Complexes Supported on Zeolite NaY: Determining Crystallographic Locations of Metal Complexes on a Support by Combining EXAFS Spectroscopy and TEM\u003c\/p\u003e \u003cp\u003e26.8 Gold Supported on CeO2: Conversion of Gold Complexes into Clusters in a CO Oxidation Catalyst Characterized by Transient XAFS Spectroscopy\u003c\/p\u003e \u003cp\u003e26.9 Mononuclear Rhodium Complexes and Dimers on MgO: Discovery of a Catalyst for Selective Hydrogenation of 1,3-Butadiene\u003c\/p\u003e \u003cp\u003e26.10 Osmium Complexes Supported on MgO: Determining Structure of the Metal-Support Interface and the Importance of Support Surface Defect Sites\u003c\/p\u003e \u003cp\u003e26.11 Conclusion\u003c\/p\u003e \u003cp\u003e\u003cb\u003e27 Nanostructured Materials\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eAlexander V. Soldatov and Kirill A. Lomachenko\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e27.1 Introduction\u003c\/p\u003e \u003cp\u003e27.2 Small Nanoclusters\u003c\/p\u003e \u003cp\u003e27.3 XAS and XES for the Study of Nanoparticles\u003c\/p\u003e \u003cp\u003e27.4 Nanostructures and Defects in Solids\u003c\/p\u003e \u003cp\u003e27.5 Conclusion and Outlook\u003c\/p\u003e \u003cp\u003eIndex\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49406933500247,"sku":"9781118844236","price":187.16,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/xray-absorption-and-xray-emission-spectroscopy-2-volume-set-9781118844236","provider":"Book Curl","version":"1.0","type":"link"}