{"product_id":"the-stille-reaction-9780471312734","title":"The Stille Reaction","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis text is devoted to the single definitive phase of the reaction. Presenting the subject from a preparative viewpoint, it pays particular attention to limitations, interfering influences, effects of structure and the selection of experimental techniques.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eMECHANISTIC CONSIDERATIONS, REGIOCHEMISTRY AND STEREOCHEMISTRY.\u003cbr\u003e \u003cbr\u003e SCOPE AND LIMITATIONS: THE ELECTROPHILE.\u003cbr\u003e \u003cbr\u003e Alkenyl Halides.\u003cbr\u003e \u003cbr\u003e Aryl and Heterocyclic Halides.\u003cbr\u003e \u003cbr\u003e Acyl Chlorides.\u003cbr\u003e \u003cbr\u003e Allylic, Benzylic, and Propargylic Electrophiles.\u003cbr\u003e \u003cbr\u003e Alkenyl Sulfonates and Other Electrophiles.\u003cbr\u003e \u003cbr\u003e Aryland Heterocyclic Sulfonates and Other Derivatives.\u003cbr\u003e \u003cbr\u003e Miscellaneous Electrophiles.\u003cbr\u003e \u003cbr\u003e SCOPE AND LIMITATIONS: THE STANNANE.\u003cbr\u003e \u003cbr\u003e Alkylstannanes.\u003cbr\u003e \u003cbr\u003e Alkenylstannes.\u003cbr\u003e \u003cbr\u003e Aryl and Heterocyclic Stannanes.\u003cbr\u003e \u003cbr\u003e Alkynylstannanes.\u003cbr\u003e \u003cbr\u003e Allylstannanes.\u003cbr\u003e \u003cbr\u003e Other Stannanes.\u003cbr\u003e \u003cbr\u003e CARBONYLATIVE COUPLINGS.\u003cbr\u003e \u003cbr\u003e Alkenyl Halides.\u003cbr\u003e \u003cbr\u003e Aryl and Heterocyclic Halides.\u003cbr\u003e \u003cbr\u003e Allylic and Benzylic Halides.\u003cbr\u003e \u003cbr\u003e Alkenyl Sulfonates.\u003cbr\u003e \u003cbr\u003e Aryl and Heterocyclic Sulfonates.\u003cbr\u003e \u003cbr\u003e Miscellaneous Substrates.\u003cbr\u003e \u003cbr\u003e COMPLEX SYNTHETIC SEQUENCES INVOLVING TIN-TO-PALLADIUM (II) METATHESIS STEPS.\u003cbr\u003e \u003cbr\u003e SIDE REACTIONS.\u003cbr\u003e \u003cbr\u003e Homocoupling Reactions.\u003cbr\u003e \u003cbr\u003e Transfer of \"Nontransferable\" Ligands.\u003cbr\u003e \u003cbr\u003e Destannylation.\u003cbr\u003e \u003cbr\u003e Cine Substitution.\u003cbr\u003e \u003cbr\u003e Phosphorus-to-Palladium Aryl Migration.\u003cbr\u003e \u003cbr\u003e Electrophile Reduction.\u003cbr\u003e \u003cbr\u003e Product Isomerization.\u003cbr\u003e \u003cbr\u003e Miscellaneous Side Reactions.\u003cbr\u003e \u003cbr\u003e COMPARISON WITH OTHER METHODS.\u003cbr\u003e \u003cbr\u003e EXPERIMENTAL CONDITIONS.\u003cbr\u003e \u003cbr\u003e The Stannane: Preparation and Handling.\u003cbr\u003e \u003cbr\u003e Alkenyl and Aryl Triflates.\u003cbr\u003e \u003cbr\u003e Choice of Nontransferable Ligands.\u003cbr\u003e \u003cbr\u003e Choice of Catalyst and Ligands.\u003cbr\u003e \u003cbr\u003e Choice of Solvent.\u003cbr\u003e \u003cbr\u003e Additives.\u003cbr\u003e \u003cbr\u003e Workup: Removal of Tin Halides.\u003cbr\u003e \u003cbr\u003e EXPERIMENTAL PROCEDURES.\u003cbr\u003e \u003cbr\u003e Trimethyl([3-(Cyclohexen-1-yl)-2-Propynyl)silane [Cross-Coupling of a Vinyl Halide with an Alkynylstannane Using Pd(PPh_3)_2Cl_2].\u003cbr\u003e \u003cbr\u003e 4-tert Butyl-1-Vinylcyclohexene [Cross-Coupling of a Vinyl Triflate with a Vinylstannane Using Pd(PPh_3)_4 and LiCl].\u003cbr\u003e \u003cbr\u003e 1-(4-Methoxyphenyl)-4-tert-Butylcyclohexene [Cross-Coupling of a Vinyl Triflate with an Arylstannane Using Pd_2(dba)_3 and AsPh_3].\u003cbr\u003e \u003cbr\u003e 3-Methyl-2-(4-Tolyl)-2-Cyclopentenone [Cross-Coupling of an Unreactive Alkenyl Halide under \"Modified\" Conditions Using Pd(PhCN)_2Cl_2 AsPh_3, and Cul as Cocatalyst].\u003cbr\u003e \u003cbr\u003e 1-(4-Nitrophenyl)-2-Propenone (Cross-Coupling of an Acid Chloride with an Arylstannane).\u003cbr\u003e \u003cbr\u003e 4-Allylacetophenone [Cross-Coupling of an Aryl Triflate under Mild Conditions using Tri(2-Furyl)Phosphine as Ligand.\u003cbr\u003e \u003cbr\u003e 8-(Trimethylstannyl)Quinoline (Preparation of an Arylstannane by Cross-Coupling and Aryl Triflate with Hexamethyldistannane).\u003cbr\u003e \u003cbr\u003e 4-(tert-Butyl-1-Vinylcyclohexen-1-Yl)-2-Propenone [Carbonylative Cross-Coupling of an Alkenyl Triflate with an Alkenylstannane using Pd(PPh_3)_4 and LiCl].\u003cbr\u003e \u003cbr\u003e (E)-1-(4-Methoxphenyl)-3-Phenyl-2-Propenone [Carbonylative Cross-Coupling of an Aryl Triflate with an Alkenylstannane using Pd(dppf)Cl_2 and LiCl].\u003cbr\u003e \u003cbr\u003e TUBULAR SURVEY.\u003cbr\u003e \u003cbr\u003e Tables.\u003cbr\u003e \u003cbr\u003e References.","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49402561986903,"sku":"9780471312734","price":137.66,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780471312734.jpg?v=1730480757","url":"https:\/\/bookcurl.com\/products\/the-stille-reaction-9780471312734","provider":"Book Curl","version":"1.0","type":"link"}