{"product_id":"the-importance-of-piinteractions-in-crystal-engineering-9780470688274","title":"The Importance of PiInteractions in Crystal","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCrystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of supramolecular architectures.  \u003cp\u003e\u003ci\u003eThe Importance of Pi-Interactions in Crystal Engineering\u003c\/i\u003ecovers topics ranging from the identification of interactions involving p-systems, their impact on molecular and crystal structure in both organic and metallorganic systems, and how these interactions might be exploited in the design of new materials. Specialist reviews are written by internationally r\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePreface xiii  \u003c\/p\u003e\u003cp\u003eList of Contributors xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The CH\/\u003ci\u003eπ\u003c\/i\u003e Hydrogen Bond: Implication in Crystal Engineering 1\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eMotohiro Nishio, Yoji Umezawa, Hiroko Suezawa and Sei Tsuboyama\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Cooperative Effect of the CH\/\u003ci\u003eπ\u003c\/i\u003e Hydrogen Bond 7\u003c\/p\u003e \u003cp\u003e1.3 CH\/\u003ci\u003eπ\u003c\/i\u003e Hydrogen Bonds in Supramolecular Chemistry 14\u003c\/p\u003e \u003cp\u003e1.4 Crystallographic Database Analyses 25\u003c\/p\u003e \u003cp\u003e1.5 Systematic CSD Analyses of the CH\/\u003ci\u003eπ\u003c\/i\u003e Hydrogen Bond 28\u003c\/p\u003e \u003cp\u003e1.6 Summary and Outlook 31\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 New Aspects of Aromatic \u003ci\u003eπ. . . π\u003c\/i\u003e and C-H \u003ci\u003e. . . π\u003c\/i\u003e Interactions in Crystal Engineering 41\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eRoger Bishop\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 41\u003c\/p\u003e \u003cp\u003e2.2 Three-Dimensional Aromatic Structures 44\u003c\/p\u003e \u003cp\u003e2.3 \u003ci\u003eEndo,Endo\u003c\/i\u003e-Facial Dimers 46\u003c\/p\u003e \u003cp\u003e2.4 Multiply Halogenated Heteroaromatic Molecules 49\u003c\/p\u003e \u003cp\u003e2.5 Expansion of the \u003ci\u003eEndo,Endo\u003c\/i\u003e-Facial Dimer 56\u003c\/p\u003e \u003cp\u003e2.6 (EF)6 Brick-Like Building Blocks 59\u003c\/p\u003e \u003cp\u003e2.7 Other Novel Multiple Edge–Face Assemblies 64\u003c\/p\u003e \u003cp\u003e2.8 Other Types of Aryl–Aryl Contacts 68\u003c\/p\u003e \u003cp\u003e2.9 Conclusions 75\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 CH\u003ci\u003e. . .π\u003c\/i\u003e and \u003ci\u003eπ. . .π\u003c\/i\u003e Interactions as Contributors to the Guest Binding in Reversible Inclusion and Encapsulation Complexes 79\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eDr. Pablo Ballester and Dr. Shannon M. Biros\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 79\u003c\/p\u003e \u003cp\u003e3.2 Probing Aromatic–Aromatic (\u003ci\u003eπ\u003c\/i\u003e–\u003ci\u003eπ\u003c\/i\u003e) Interactions and CH–\u003ci\u003eπ\u003c\/i\u003e Interactions with Solid-State Structures of Reversible Inclusion and Encapsulation Complexes 83\u003c\/p\u003e \u003cp\u003e3.2.1 Inclusion Complexes 83\u003c\/p\u003e \u003cp\u003e3.3 Summary and Outlook 104\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 A Rudimentary Method for Classification of \u003ci\u003eπ\u003c\/i\u003e···\u003ci\u003eπ\u003c\/i\u003e Packing Motifs for Aromatic Molecules 109\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eLeigh Loots and Leonard J. Barbour\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 109\u003c\/p\u003e \u003cp\u003e4.2 Theoretical Models 110\u003c\/p\u003e \u003cp\u003e4.3 \u003ci\u003eπ\u003c\/i\u003e···\u003ci\u003eπ\u003c\/i\u003e Interactions 111\u003c\/p\u003e \u003cp\u003e4.4 Structure Prediction and Comparisons 113\u003c\/p\u003e \u003cp\u003e4.5 \u003ci\u003eπ\u003c\/i\u003e···\u003ci\u003eπ\u003c\/i\u003e Interactions in Heteroaromatic Molecules 113\u003c\/p\u003e \u003cp\u003e4.6 \u003ci\u003eπ\u003c\/i\u003e···\u003ci\u003eπ\u003c\/i\u003e Interactions in Cocrystals 119\u003c\/p\u003e \u003cp\u003e4.7 Summary 123\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Conformational Flexibility and Selectivity in Host–Guest Systems 125\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eNikoletta B. Bathori and Luigi R. Nassimbeni\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 125\u003c\/p\u003e \u003cp\u003e5.2 Selectivity 129\u003c\/p\u003e \u003cp\u003e5.3 Concluding Remarks 139\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Organic \u003ci\u003eπ\u003c\/i\u003e-Radicals in the Solid-State: from Localised to Delocalised \u003ci\u003eσ\u003c\/i\u003e-Bonding 143\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eMarc Fourmigue\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 143\u003c\/p\u003e \u003cp\u003e6.2 Molecules for \u003ci\u003eπ\u003c\/i\u003e-Radical Formation 144\u003c\/p\u003e \u003cp\u003e6.3 Dimers of Radicals versus Radical Dimers (Pimers) 149\u003c\/p\u003e \u003cp\u003e6.4 Solid-State Magnetic and Conducting Properties 154\u003c\/p\u003e \u003cp\u003e6.5 Conclusions 159\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Arene–Perfluoroarene Interactions in Coordination Architectures 163\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eAkiko Hori\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 163\u003c\/p\u003e \u003cp\u003e7.2 Background 165\u003c\/p\u003e \u003cp\u003e7.3 Guest Recognition by Coordination Networks 169\u003c\/p\u003e \u003cp\u003e7.4 Fluorinated Coordination Complexes 172\u003c\/p\u003e \u003cp\u003e7.5 Cocrystals of Coordination Complexes 179\u003c\/p\u003e \u003cp\u003e7.6 Self-Assembly in Solution 181\u003c\/p\u003e \u003cp\u003e7.7 Conclusions 182\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Halogen\u003ci\u003e. . .π\u003c\/i\u003e Interactions as Important Contributors to Binding Affinity in Medicinal Chemistry 187\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eHans Matter, Marc Nazare, and Stefan Gussregen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 187\u003c\/p\u003e \u003cp\u003e8.2 General Aspects of Halogen Atoms in Medicinal Chemistry 189\u003c\/p\u003e \u003cp\u003e8.3 Fluorine: a Unique Halogen Atom 190\u003c\/p\u003e \u003cp\u003e8.4 Interactions of Higher Halogen Atoms 196\u003c\/p\u003e \u003cp\u003e8.5 Interactions of Higher Halogen Atoms to Aromatic Rings 204\u003c\/p\u003e \u003cp\u003e8.6 Conclusions 226\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Fuzzy Electron-Density Fragments as Building Blocks in Crystal-Engineering Design 233\u003cbr\u003e \u003c\/b\u003e\u003ci\u003ePaul G. Mezey\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 233\u003c\/p\u003e \u003cp\u003e9.2 A Brief Review of a Fuzzy Electron-Density Fragmentation Scheme Suitable for Molecular Design 235\u003c\/p\u003e \u003cp\u003e9.3 The Low-Density \"Glue\" Range of Globular Macromolecules, Functional Groups, and the Role of \u003ci\u003eπ\u003c\/i\u003e-Interactions in Fuzzy Fragment Selection 238\u003c\/p\u003e \u003cp\u003e9.4 Summary 239\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Noncovalent Interactions of \u003ci\u003eπ\u003c\/i\u003e-systems in Crystal Structures of Transition-Metal Complexes 243\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eGoran V. Janjic and Snezana D. Zaric\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 243\u003c\/p\u003e \u003cp\u003e10.2 Interactions with Organic \u003ci\u003eπ\u003c\/i\u003e-Systems 244\u003c\/p\u003e \u003cp\u003e10.3 Interactions with \u003ci\u003eπ\u003c\/i\u003e-Systems of Chelate Rings 254\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Intermolecular C–H · · · \u003ci\u003eπ\u003c\/i\u003e(Chelate) Interactions – Prevalence in the Crystal Structures of Metal 1,1-Dithiolates 275\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJulio Zukerman-Schpector and Edward R.T. Tiekink\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 275\u003c\/p\u003e \u003cp\u003e11.2 Methodology and Preliminary Survey 277\u003c\/p\u003e \u003cp\u003e11.3 Supramolecular Architectures Based on C–H· · ·\u003ci\u003eπ\u003c\/i\u003e Interactions 280\u003c\/p\u003e \u003cp\u003e11.4 Discussion and Conclusions 295\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Supramolecular Aggregation Patterns and Stereochemical Consequences of Tellurium(Lone Pair)· · ·\u003ci\u003eπ\u003c\/i\u003e(Aryl) Interactions 301\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eIonel Haiduc, Edward R.T. Tiekink and Julio Zukerman-Schpector\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 301\u003c\/p\u003e \u003cp\u003e12.2 Methodology 302\u003c\/p\u003e \u003cp\u003e12.3 Results 303\u003c\/p\u003e \u003cp\u003e12.4 The Influence of Te(Lone Pair)· · ·\u003ci\u003eπ\u003c\/i\u003e(Aryl) Synthons Upon Coordination Geometry 318\u003c\/p\u003e \u003cp\u003e12.5 Summary and Conclusions 319\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Supramolecular Assembly of Silver(I) Complexes with Argentophilic and Silver\u003ci\u003e. . .\u003c\/i\u003eCarbon Interactions 323\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eThomas C. W. Mak, Liang Zhao and Xiao-Li Zhao\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 323\u003c\/p\u003e \u003cp\u003e13.2 Silver Double\/Multiple Salts Containing Ag2C2 326\u003c\/p\u003e \u003cp\u003e13.3 Supramolecular Assembly of Silver(I) Double\/Triple Salts with Potentially Exo-Bidentate Ligands 332\u003c\/p\u003e \u003cp\u003e13.4 Silver(I) Multiple Salts of 1,3-Butadiynediide (C4\u003csup\u003e2−\u003c\/sup\u003e) 337\u003c\/p\u003e \u003cp\u003e13.5 Supramolecular Assembly with Silver tert-Butylethynide 338\u003c\/p\u003e \u003cp\u003e13.6 Double\/Multiple Salts of Silver Arylethynides 342\u003c\/p\u003e \u003cp\u003e13.7 Assembly of Silver–Heteroaromatic Ethynide Supramolecular Synthons R-C=C Ag\u003ci\u003en\u003c\/i\u003e (\u003ci\u003en\u003c\/i\u003e = 4, 5) (R = Thienyl, Pyridyl, Pyrazinyl, Pyrimidyl) 346\u003c\/p\u003e \u003cp\u003e13.8 Assembly of Silver–Ethynide Supramolecular Synthon Assisted by Silver\u003ci\u003e. . .\u003c\/i\u003eAromatic Interaction 350\u003c\/p\u003e \u003cp\u003e13.9 Assembly of Silver–Ethynide Supramolecular Synthon Assisted by Intermolecular Silver\u003ci\u003e. . .\u003c\/i\u003eHalogen Interaction 352\u003c\/p\u003e \u003cp\u003e13.10 Coordination Networks Constructed of Multinuclear C2@Ag\u003ci\u003en\u003c\/i\u003e Aggregates and Polyoxometalate Species 353\u003c\/p\u003e \u003cp\u003e13.11 Supramolecular Assembly of Large Silver–Ethynide Clusters 355\u003c\/p\u003e \u003cp\u003e13.12 Conclusion and Outlook 363\u003c\/p\u003e \u003cp\u003eAcknowledgments 363\u003c\/p\u003e \u003cp\u003eReferences 364\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex 367\u003c\/b\u003e\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49525388083543,"sku":"9780470688274","price":128.2,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780470688274.jpg?v=1731860325","url":"https:\/\/bookcurl.com\/products\/the-importance-of-piinteractions-in-crystal-engineering-9780470688274","provider":"Book Curl","version":"1.0","type":"link"}