{"product_id":"spincrossover-materials-9781119998679","title":"SpinCrossover Materials","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eThe phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eSpin-Crossover Materials: Properties and Applications \u003c\/i\u003epresents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including\u003c\/p\u003e \u003cul\u003e \u003cli\u003eSpin-crossover in mononuclear, polynucle\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eList of Contributors xv\u003c\/p\u003e \u003cp\u003ePreface xvii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The Development of Spin-Crossover Research 1\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKeith S. Murray\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Discrete Clusters of SCO Compounds 4\u003c\/p\u003e \u003cp\u003e1.3 1D Chains of FeII SCO Materials 22\u003c\/p\u003e \u003cp\u003e1.4 1D Chains of FeIII SCO Materials 28\u003c\/p\u003e \u003cp\u003e1.5 2D Sheets of FeII SCO Materials 29\u003c\/p\u003e \u003cp\u003e1.6 3D Porous SCO Materials 30\u003c\/p\u003e \u003cp\u003e1.7 Some Recent Developments in Mononuclear SCO FeII, FeIII and CoII Compounds 33\u003c\/p\u003e \u003cp\u003e1.8 Multifunctional\/Hybrid SCO Materials 37\u003c\/p\u003e \u003cp\u003e1.9 Developments in Instrumental Methods in Spin-Crossover Measurements 40\u003c\/p\u003e \u003cp\u003e1.10 Applications of Molecular Spin-Crossover Compounds 41\u003c\/p\u003e \u003cp\u003e1.11 Summary 42\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Novel Mononuclear Spin-Crossover Complexes 55\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eBirgit Weber\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction and General Considerations 55\u003c\/p\u003e \u003cp\u003e2.2 Novel Coordination Numbers (CN), Coordination Geometries and Metal Centres 57\u003c\/p\u003e \u003cp\u003e2.3 Iron Complexes with Novel Ligand Donor Atoms and New Ligand Systems 65\u003c\/p\u003e \u003cp\u003e2.4 Other Examples 70\u003c\/p\u003e \u003cp\u003e2.5 Conclusion and Outlook 72\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Spin-Crossover in Discrete Polynuclear Complexes 77\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eJuan Olguin and Sally Brooker\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 77\u003c\/p\u003e \u003cp\u003e3.2 Dinuclear Iron(II) Complexes 79\u003c\/p\u003e \u003cp\u003e3.3 Higher Nuclearity Iron(II) Compounds 98\u003c\/p\u003e \u003cp\u003e3.4 Iron(III) 104\u003c\/p\u003e \u003cp\u003e3.5 Cobalt(II) 109\u003c\/p\u003e \u003cp\u003e3.6 Dinuclear Chromium(II) Complex 111\u003c\/p\u003e \u003cp\u003e3.7 Concluding Remarks 112\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Polymeric Spin-Crossover Materials 121\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eM. Carmen Munoz and Jose Antonio Real\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 121\u003c\/p\u003e \u003cp\u003e4.2 One-Dimensional SCO-CPs 121\u003c\/p\u003e \u003cp\u003e4.3 Two-d = Dimensional SCO-CPs 128\u003c\/p\u003e \u003cp\u003e4.4 Three-Dimensional SCO-CPs 133\u003c\/p\u003e \u003cp\u003e4.5 Conclusion 138\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Structure:Function Relationships in Molecular Spin-Crossover Materials 147\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMalcolm A. Halcrow\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 147\u003c\/p\u003e \u003cp\u003e5.2 Molecular Shape 150\u003c\/p\u003e \u003cp\u003e5.3 Crystal Packing 155\u003c\/p\u003e \u003cp\u003e5.4 Cooperativity Mediated by Disorder 158\u003c\/p\u003e \u003cp\u003e5.5 Compounds Showing Wide Thermal Hysteresis 158\u003c\/p\u003e \u003cp\u003e5.6 Other Noteworthy Compounds 162\u003c\/p\u003e \u003cp\u003e5.7 Conclusions 164\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Charge Transfer-Induced Spin-Transitions in Cyanometallate Materials 171\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKim R. Dunbar, Catalina Achim and Michael Shatruk\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 171\u003c\/p\u003e \u003cp\u003e6.2 Characterization of CTIST Compounds 173\u003c\/p\u003e \u003cp\u003e6.3 CTIST in Coordination Polymers 174\u003c\/p\u003e \u003cp\u003e6.4 CTIST in Nanoscale Materials 189\u003c\/p\u003e \u003cp\u003e6.5 CTIST in Polynuclear Transition Metal Complexes 195\u003c\/p\u003e \u003cp\u003e6.6 Summary and Outlook 198\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Valence Tautomeric Transitions in Cobalt-dioxolene Complexes 203\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eColette Boskovic\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 203\u003c\/p\u003e \u003cp\u003e7.2 Induction of Valence Tautomeric Transitions 205\u003c\/p\u003e \u003cp\u003e7.3 Other Factors that Contribute to the Valence Tautomeric Transition 210\u003c\/p\u003e \u003cp\u003e7.4 Polynuclear Valence Tautomeric Complexes 214\u003c\/p\u003e \u003cp\u003e7.5 Bifunctional Valence Tautomeric Complexes 218\u003c\/p\u003e \u003cp\u003e7.6 Concluding Remarks 220\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Reversible Spin Pairing in Crystalline Organic Radicals 225\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eJeremy M. Rawson and John J. Hayward\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 225\u003c\/p\u003e \u003cp\u003e8.2 Radical Pairs: Solution and Gas Phase Studies 226\u003c\/p\u003e \u003cp\u003e8.3 Dimerisation in the Solid State 229\u003c\/p\u003e \u003cp\u003e8.4 Summary and Future Perspectives 234\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Breathing Crystals from Copper Nitroxyl Complexes 239\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eVictor Ovcharenko and Elena Bagryanskaya\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 239\u003c\/p\u003e \u003cp\u003e9.2 Structural and Magnetic Anomalies 241\u003c\/p\u003e \u003cp\u003e9.3 Relationship Between the Chemical Step and the Physical Property 245\u003c\/p\u003e \u003cp\u003e9.4 Relationship Between the Thermally Induced Reorientation of Aromatic Solvate Molecules and the Character of the Magnetic Anomaly 251\u003c\/p\u003e \u003cp\u003e9.5 EPR Study of Breathing Crystals 255\u003c\/p\u003e \u003cp\u003e9.6 Classification of Spin-Transitions in Breathing Crystals and Correlations with Magnetic Susceptibility 261\u003c\/p\u003e \u003cp\u003e9.7 The Detailed Magnetic Structure of Breathing Crystals 266\u003c\/p\u003e \u003cp\u003e9.8 EPR-detected LIESST on Breathing Crystals 272\u003c\/p\u003e \u003cp\u003e9.9 Conclusion 275\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Spin-State Switching in Solution 281\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMatthew P. Shores, Christina M. Klug and Stephanie R. Fiedler\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction and Scope 281\u003c\/p\u003e \u003cp\u003e10.2 Spin-Crossover: Solid State Versus Solution 282\u003c\/p\u003e \u003cp\u003e10.3 Practical Considerations 283\u003c\/p\u003e \u003cp\u003e10.4 Spin-Crossover in Solution 285\u003c\/p\u003e \u003cp\u003e10.5 Ligation Changes Driving Spin-State Switching in Solution 288\u003c\/p\u003e \u003cp\u003e10.6 Second Coordination Sphere Triggers for Spin-State Switching 291\u003c\/p\u003e \u003cp\u003e10.7 Challenges and Opportunities 294\u003c\/p\u003e \u003cp\u003e10.8 Conclusions\/Outlook 295\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Multifunctional Materials Combining Spin-Crossover with Conductivity and Magnetic Ordering 303\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eOsamu Sato, Zhao-Yang Li, Zi-Shuo Yao, Soonchul Kang and Shinji Kanegawa\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 303\u003c\/p\u003e \u003cp\u003e11.2 Spin-Crossover and Conductivity: Spin-Crossover Conductors 303\u003c\/p\u003e \u003cp\u003e11.3 Spin-Crossover and Magnetic Interaction: Spin-Crossover Magnets 308\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Amphiphilic and Liquid Crystalline Spin-Crossover Complexes 321\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eShinya Hayami\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 321\u003c\/p\u003e \u003cp\u003e12.2 Unique Magnetic Properties of SCO Cobalt(II) Compounds with Long Alkyl Chains 322\u003c\/p\u003e \u003cp\u003e12.3 Liquid Crystalline SCO Compounds 325\u003c\/p\u003e \u003cp\u003e12.4 Langmuir–Blodgett Films and Amphiphilic SCO Compounds 331\u003c\/p\u003e \u003cp\u003e12.5 Conclusion and Outlook 339\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Luminescent Spin-Crossover Materials 347\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eHelena J. Shepherd, Carlos M. Quintero, G´abor Molnar, Lionel Salmon and Azzedine Bousseksou\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 General Introduction 347\u003c\/p\u003e \u003cp\u003e13.2 Introduction to Luminescent Materials and Luminescence Energy Transfer 348\u003c\/p\u003e \u003cp\u003e13.3 Electronic Transitions and Optical Properties of Spin-Crossover Complexes 358\u003c\/p\u003e \u003cp\u003e13.4 Materials with Combined Spin-Crossover and Luminescent Functionalities 361\u003c\/p\u003e \u003cp\u003e13.5 Concluding Remarks 371\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Nanoparticles, Thin Films and Surface Patterns from Spin-Crossover Materials and Electrical Spin State Control 375\u003c\/b\u003e\u003cbr\u003e \u003ci\u003ePaulo Nuno Martinho, Cyril Rajnak and Mario Ruben\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 375\u003c\/p\u003e \u003cp\u003e14.2 Nanoparticles and Nanocrystals 376\u003c\/p\u003e \u003cp\u003e14.3 Thin Films 387\u003c\/p\u003e \u003cp\u003e14.4 Surface Patterns 393\u003c\/p\u003e \u003cp\u003e14.5 Electrical Spin State Control 396\u003c\/p\u003e \u003cp\u003e14.6 Conclusion 399\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Ultrafast Studies of the Light-Induced Spin Change in Fe(II)-Polypyridine Complexes 405\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMajed Chergui\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 405\u003c\/p\u003e \u003cp\u003e15.2 Properties of Fe(II) Complexes 406\u003c\/p\u003e \u003cp\u003e15.3 From the Singlet to the Quintet State 408\u003c\/p\u003e \u003cp\u003e15.4 Ultrafast X-Ray Studies 415\u003c\/p\u003e \u003cp\u003e15.5 Summary and Outlook 417\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Real-Time Observation of Spin-Transitions by Optical Microscopy 425\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eFrancois Varret, Ahmed Slimani, Damien Garrot, Yann Garcia and Anil D. Naik\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 425\u003c\/p\u003e \u003cp\u003e16.2 Experimental Aspects 426\u003c\/p\u003e \u003cp\u003e16.3 Selected Investigations 429\u003c\/p\u003e \u003cp\u003e16.4 Conclusions and Prospects 439\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Theoretical Prediction of Spin-Crossover at the Molecular Level 443\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eRobert J. Deeth, Christopher M. Handley and Benjamin J. Houghton\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 443\u003c\/p\u003e \u003cp\u003e17.2 Beginnings: Valence Bond and Ligand Field Theories 443\u003c\/p\u003e \u003cp\u003e17.3 Quantum Chemistry 446\u003c\/p\u003e \u003cp\u003e17.4 Empirical Methods 449\u003c\/p\u003e \u003cp\u003e17.5 Conclusions 452\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Theoretical Descriptions of Spin-Transitions in Bulk Lattices 455\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eCristian, Enachescu, Masamichi Nishino and Seiji Miyashita\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 455\u003c\/p\u003e \u003cp\u003e18.2 Elastic Interaction Models for Spin-Crossover Systems 457\u003c\/p\u003e \u003cp\u003e18.3 Mechano-Elastic Model 463\u003c\/p\u003e \u003cp\u003e18.4 Conclusions 471\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Optimizing the Stability of Trapped Metastable Spin States 475\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eJean-Francois Letard, Guillaume Chastanet, Philippe Guionneau and Cedric Desplanches\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 475\u003c\/p\u003e \u003cp\u003e19.2 Light-Induced Excited Spin-State Trapping (LIESST) Effect 476\u003c\/p\u003e \u003cp\u003e19.3 The T(LIESST) Approach: The Case of Mononuclear Compounds 479\u003c\/p\u003e \u003cp\u003e19.4 The T(LIESST) Approach: An Extension to Polynuclear Iron(II) Complexes 487\u003c\/p\u003e \u003cp\u003e19.5 Simulation and Extrapolation of a T(LIESST) Experiment 495\u003c\/p\u003e \u003cp\u003e19.6 Conclusions 500\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Piezo- and Photo-Crystallography Applied to Spin-Crossover Materials 507\u003c\/b\u003e\u003cbr\u003e \u003ci\u003ePhilippe Guionneau and Eric Collet\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 507\u003c\/p\u003e \u003cp\u003e20.2 Spin-Crossover and Piezo-Crystallography 507\u003c\/p\u003e \u003cp\u003e20.3 Crystallography of Photoexcited SCO Materials 512\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 Spin-Transitions in Metal Oxides 527\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eJean-Pascal RUEFF\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction 527\u003c\/p\u003e \u003cp\u003e21.2 RIXS: A Probe of the 3d Electronic Properties 530\u003c\/p\u003e \u003cp\u003e21.3 Experimental Results 533\u003c\/p\u003e \u003cp\u003e21.4 Conclusions and Perspectives 538\u003c\/p\u003e \u003cp\u003eReferences 540\u003c\/p\u003e \u003cp\u003eIndex\u003c\/p\u003e\n\u003c\/li\u003e\n\u003c\/ul\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49407201771863,"sku":"9781119998679","price":999.99,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/spincrossover-materials-9781119998679","provider":"Book Curl","version":"1.0","type":"link"}