{"product_id":"semiconductor-photocatalysis-principles-and-applications-9783527335534","title":"Semiconductor Photocatalysis: Principles and Applications","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eFocusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects.\u003cbr\u003e \u003cbr\u003e A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering semiconductor photocatalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface XI\u003c\/p\u003e \u003cp\u003eAcknowledgments XIII\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction 1 \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 A Brief History of Photochemistry 1\u003c\/p\u003e \u003cp\u003e1.2 Catalysis, Photochemistry, and Photocatalysis 5\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Molecular Photochemistry 9 \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Absorption and Emission 9\u003c\/p\u003e \u003cp\u003e2.2 Intensity of Electronic Transitions 14\u003c\/p\u003e \u003cp\u003e2.2.1 Contribution of Nuclei 14\u003c\/p\u003e \u003cp\u003e2.2.2 Contribution of Spin 17\u003c\/p\u003e \u003cp\u003e2.2.3 Contribution of Orbitals 17\u003c\/p\u003e \u003cp\u003e2.3 Excited States Radiative Lifetimes 17\u003c\/p\u003e \u003cp\u003e2.4 Energy and Electron Transfer 19\u003c\/p\u003e \u003cp\u003e2.4.1 Energy Transfer 19\u003c\/p\u003e \u003cp\u003e2.4.2 Electron Transfer 21\u003c\/p\u003e \u003cp\u003e2.5 Proton Transfer and Hydrogen Abstraction 23\u003c\/p\u003e \u003cp\u003e2.6 Photosensitization 23\u003c\/p\u003e \u003cp\u003e2.7 Rates and Quantum Yields 25\u003c\/p\u003e \u003cp\u003e2.8 Quenching of Excited States 26\u003c\/p\u003e \u003cp\u003e2.8.1 Identification of the Reactive Excited State 28\u003c\/p\u003e \u003cp\u003e2.9 Absorption, Emission, and Excitation Spectra 28\u003c\/p\u003e \u003cp\u003e2.10 Classification and Reactivity of Excited States 30\u003c\/p\u003e \u003cp\u003e2.10.1 Organic Molecules 30\u003c\/p\u003e \u003cp\u003e2.10.1.1 π,π* States 30\u003c\/p\u003e \u003cp\u003e2.10.1.2 n,π* States 30\u003c\/p\u003e \u003cp\u003e2.10.1.3 Charge-Transfer (CT) States 32\u003c\/p\u003e \u003cp\u003e2.10.1.4 Triplet and Singlet Oxygen Reactions 36\u003c\/p\u003e \u003cp\u003e2.10.2 Inorganic and Organometallic Complexes 38\u003c\/p\u003e \u003cp\u003e2.10.2.1 Metal-Centered (MC) States 39\u003c\/p\u003e \u003cp\u003e2.10.2.2 Ligand-Centered (LC) States 42\u003c\/p\u003e \u003cp\u003e2.10.2.3 Charge Transfer Metal to Ligand (CTML) States 42\u003c\/p\u003e \u003cp\u003e2.10.2.4 Charge Transfer Ligand to Metal (CTLM) States 42\u003c\/p\u003e \u003cp\u003e2.10.2.5 Charge Transfer to Solvent (CTTS) States 43\u003c\/p\u003e \u003cp\u003e2.10.2.6 Intervalence Transfer (IT) States 43\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Molecular Photocatalysis 47 \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Hydrogenation of 1,3-Dienes 47\u003c\/p\u003e \u003cp\u003e3.2 Co-Cyclization of Alkynes with Nitriles 47\u003c\/p\u003e \u003cp\u003e3.3 Enantioselective Trifluoromethylation of Aldehydes 48\u003c\/p\u003e \u003cp\u003e3.4 Photoinduced Electron Transfer Catalysis 50\u003c\/p\u003e \u003cp\u003e3.5 Reduction and Oxidation of Water 51\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Photoelectrochemistry 55 \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Electronic Structure and Nature of Excited States 55\u003c\/p\u003e \u003cp\u003e4.1.1 The (Optical) Bandgap 55\u003c\/p\u003e \u003cp\u003e4.1.1.1 Measurement of the Bandgap Energy 58\u003c\/p\u003e \u003cp\u003e4.1.1.2 Influence of Crystal Size 63\u003c\/p\u003e \u003cp\u003e4.1.2 The Photonic Bandgap 64\u003c\/p\u003e \u003cp\u003e4.1.3 Emission Spectra 65\u003c\/p\u003e \u003cp\u003e4.2 Photocorrosion 68\u003c\/p\u003e \u003cp\u003e4.3 Interfacial Electron Transfer 70\u003c\/p\u003e \u003cp\u003e4.3.1 Introduction 70\u003c\/p\u003e \u003cp\u003e4.3.2 Thermal Interfacial Electron Transfer (IFET) 73\u003c\/p\u003e \u003cp\u003e4.3.2.1 IFET at the Metal\/Liquid Interface 73\u003c\/p\u003e \u003cp\u003e4.3.2.2 IFET at the Semiconductor\/Liquid Interface 76\u003c\/p\u003e \u003cp\u003e4.3.3 Photochemical Interfacial Electron Transfer 78\u003c\/p\u003e \u003cp\u003e4.3.3.1 IFET in Large Semiconductor Crystals 78\u003c\/p\u003e \u003cp\u003e4.3.3.2 IFET in Small Semiconductor Crystals 82\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Semiconductor Photocatalysis 85 \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Mechanisms, Kinetics, and Adsorption 85\u003c\/p\u003e \u003cp\u003e5.1.1 General Classification of Reactions 85\u003c\/p\u003e \u003cp\u003e5.1.2 Rates, Quantum Yields, and Their Comparability 91\u003c\/p\u003e \u003cp\u003e5.1.2.1 Direct Semiconductor Photocatalysis 91\u003c\/p\u003e \u003cp\u003e5.1.3 Influence of Semiconductor Nature and Particle Size on Chemical Selectivity 108\u003c\/p\u003e \u003cp\u003e5.1.3.1 Control of Chemoselectivity by Surface States and Redox Amplification 110\u003c\/p\u003e \u003cp\u003e5.2 Characterization of Photocatalysts 111\u003c\/p\u003e \u003cp\u003e5.2.1 General Methods 111\u003c\/p\u003e \u003cp\u003e5.2.2 Flatband and Quasi-Fermi Potentials 112\u003c\/p\u003e \u003cp\u003e5.2.2.1 Measurements in Absence of Light 112\u003c\/p\u003e \u003cp\u003e5.3 Preparation and Properties of Photocatalysts 124\u003c\/p\u003e \u003cp\u003e5.3.1 Pristine Compounds and Solid Solutions 128\u003c\/p\u003e \u003cp\u003e5.3.1.1 TiO\u003csub\u003e2\u003c\/sub\u003e 128\u003c\/p\u003e \u003cp\u003e5.3.1.2 WO\u003csub\u003e3\u003c\/sub\u003e 129\u003c\/p\u003e \u003cp\u003e5.3.1.3 α-Fe\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e3\u003c\/sub\u003e 130\u003c\/p\u003e \u003cp\u003e5.3.1.4 BiVO\u003csub\u003e4\u003c\/sub\u003e 130\u003c\/p\u003e \u003cp\u003e5.3.1.5 Ta\u003csub\u003e2\u003c\/sub\u003eO\u003csub\u003e3\u003c\/sub\u003e, TaON, Ta\u003csub\u003e3\u003c\/sub\u003eN\u003csub\u003e5\u003c\/sub\u003e, and MTaO\u003csub\u003e2\u003c\/sub\u003eN 130\u003c\/p\u003e \u003cp\u003e5.3.1.6 CuO, Cu\u003csub\u003e2\u003c\/sub\u003eO 131\u003c\/p\u003e \u003cp\u003e5.3.1.7 GaN–ZnO 131\u003c\/p\u003e \u003cp\u003e5.3.1.8 CdS and ZnS 133\u003c\/p\u003e \u003cp\u003e5.3.2 Grafting of CdS and TiO\u003csub\u003e2\u003c\/sub\u003e onto Inorganic Supports 133\u003c\/p\u003e \u003cp\u003e5.3.2.1 Grafting onto a Nonconducting Support 133\u003c\/p\u003e \u003cp\u003e5.3.2.2 Grafting onto a Semiconducting Support 135\u003c\/p\u003e \u003cp\u003e5.3.3 Grafting of Metal Halides and Metal Oxides onto Titania 136\u003c\/p\u003e \u003cp\u003e5.3.3.1 Metal Chloride-Grafted Titania 136\u003c\/p\u003e \u003cp\u003e5.3.4 Metal-Loaded Powders 141\u003c\/p\u003e \u003cp\u003e5.3.5 Nonmetal-Modified Titania 141\u003c\/p\u003e \u003cp\u003e5.3.5.1 Nitrogen-Modified Titania 142\u003c\/p\u003e \u003cp\u003e5.3.5.2 “Carbon”-Modified Titania 146\u003c\/p\u003e \u003cp\u003e5.3.5.3 Miscellaneous 147\u003c\/p\u003e \u003cp\u003e5.4 Type A Reactions 148\u003c\/p\u003e \u003cp\u003e5.4.1 WaterSplitting 149\u003c\/p\u003e \u003cp\u003e5.4.1.1 One-Particle Photocatalysis 153\u003c\/p\u003e \u003cp\u003e5.4.1.2 Two-Particle Photocatalysis 155\u003c\/p\u003e \u003cp\u003e5.4.1.3 Reduction and Oxidation of Water 157\u003c\/p\u003e \u003cp\u003e5.4.2 Aerobic Oxidations 159\u003c\/p\u003e \u003cp\u003e5.4.2.1 Direct Photocatalysis 159\u003c\/p\u003e \u003cp\u003e5.4.2.2 Indirect Photocatalysis 165\u003c\/p\u003e \u003cp\u003e5.4.3 Nitrogen Fixation 165\u003c\/p\u003e \u003cp\u003e5.4.3.1 Fixation by UV Irradiation 165\u003c\/p\u003e \u003cp\u003e5.4.3.2 Fixation by Visible Irradiation 167\u003c\/p\u003e \u003cp\u003e5.4.3.3 Formation of Ammonia, Hydrazine, and Nitrate 169\u003c\/p\u003e \u003cp\u003e5.4.3.4 Role of ChlorideIons 171\u003c\/p\u003e \u003cp\u003e5.4.3.5 Mechanism 172\u003c\/p\u003e \u003cp\u003e5.4.4 Carbon Dioxide Fixation 173\u003c\/p\u003e \u003cp\u003e5.4.5 Organic Reactions 176\u003c\/p\u003e \u003cp\u003e5.4.5.1 Oxidative C–N Cleavage 177\u003c\/p\u003e \u003cp\u003e5.4.5.2 Intramolecular C–N and C–C Coupling 178\u003c\/p\u003e \u003cp\u003e5.4.5.3 Intermolecular C–C and C–N Coupling 178\u003c\/p\u003e \u003cp\u003e5.4.5.4 Intermolecular C–O Coupling 181\u003c\/p\u003e \u003cp\u003e5.4.5.5 Anaerobic Dehydrodimerization and Intermediary Water Reduction 182\u003c\/p\u003e \u003cp\u003e5.5 Type B Reactions 188\u003c\/p\u003e \u003cp\u003e5.5.1 C–N Coupling 188\u003c\/p\u003e \u003cp\u003e5.5.2 C–C Coupling 192\u003c\/p\u003e \u003cp\u003e5.5.2.1 Addition of Olefins to Imines 192\u003c\/p\u003e \u003cp\u003e5.5.2.2 Addition of Olefins to Amines 198\u003c\/p\u003e \u003cp\u003e5.5.3 C–H Activation of Alkanes 198\u003c\/p\u003e \u003cp\u003e5.6 Environmental Aspects 202\u003c\/p\u003e \u003cp\u003e5.6.1 Abiotic Nitrogen Fixation 202\u003c\/p\u003e \u003cp\u003e5.6.2 Photocatalysis and Chemical Evolution 203\u003c\/p\u003e \u003cp\u003e5.6.3 Detoxification of Air and Water 204\u003c\/p\u003e \u003cp\u003e5.6.4 Antibacterial and Antiviral Effects 204\u003c\/p\u003e \u003cp\u003e5.6.5 Amphiphilic Properties of Titania 205\u003c\/p\u003e \u003cp\u003e5.7 Titaniain Food and Personal Care Products 206\u003c\/p\u003e \u003cp\u003e5.8 Photoreactors 206\u003c\/p\u003e \u003cp\u003e5.8.1 Laboratory Photoreactors 206\u003c\/p\u003e \u003cp\u003e5.8.2 Solar Photoreactors and Kinetic Modeling 208\u003c\/p\u003e \u003cp\u003eReferences 211\u003c\/p\u003e \u003cp\u003eIndex 245\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":53196948013399,"sku":"9783527335534","price":125.35,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/semiconductor-photocatalysis-principles-and-applications-9783527335534","provider":"Book Curl","version":"1.0","type":"link"}