{"product_id":"polymeric-chiral-catalyst-design-and-chiral-polymer-synthesis-9780470568200","title":"Polymeric Chiral Catalyst Design and Chiral","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselective synthesis, optically-active polymers, and continuous flow processes.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePREFACE xiii  \u003cp\u003eFOREWORD xvii\u003c\/p\u003e \u003cp\u003eCONTRIBUTORS xix\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 An Overview of Polymer-Immobilized Chiral Catalysts and Synthetic Chiral Polymers 1\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eShinichi Itsuno\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction \/ 1\u003c\/p\u003e \u003cp\u003e1.2 Polymeric Chiral Catalyst \/ 2\u003c\/p\u003e \u003cp\u003e1.3 Synthesis of Optically Active Polymers \/ 8\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Polymer-Immobilized Chiral Organocatalyst 17\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eNaoki Haraguchi and Shinichi Itsuno\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction \/ 17\u003c\/p\u003e \u003cp\u003e2.2 Synthesis of Polymer-immobilized Chiral Organocatalyst \/ 18\u003c\/p\u003e \u003cp\u003e2.3 Polymer-immobilized Cinchona Alkaloids \/ 22\u003c\/p\u003e \u003cp\u003e2.4 Other Polymer-immobilized Chiral Basic Organocatalysts \/ 27\u003c\/p\u003e \u003cp\u003e2.5 Polymer-immobilized Cinchona Alkaloid Quaternary Ammonium Salts \/ 28\u003c\/p\u003e \u003cp\u003e2.6 Polymer-immobilized MacMillan Catalysts \/ 35\u003c\/p\u003e \u003cp\u003e2.7 Polymer-immobilized Pyrrolidine Derivatives \/ 42\u003c\/p\u003e \u003cp\u003e2.8 Other Polymer-immobilized Chiral Quaternary Ammonium Salts \/ 46\u003c\/p\u003e \u003cp\u003e2.9 Polymer-immobilized Proline Derivatives \/ 46\u003c\/p\u003e \u003cp\u003e2.10 Polymer-immobilized Peptides and Poly(amino acid)s \/ 50\u003c\/p\u003e \u003cp\u003e2.11 Polymer-immobilized Chiral Acidic Organocatalysts \/ 50\u003c\/p\u003e \u003cp\u003e2.12 Helical Polymers as Chiral Organocatalysts \/ 51\u003c\/p\u003e \u003cp\u003e2.13 Cascade Reactions Using Polymer-immobilized Chiral Organocatalysts \/ 52\u003c\/p\u003e \u003cp\u003e2.14 Conclusions \/ 54\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Asymmetric Synthesis Using Polymer-Immobilized Proline Derivatives 63\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMichelangelo Gruttadauria, Francesco Giacalone, and Renato Noto\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction \/ 63\u003c\/p\u003e \u003cp\u003e3.2 Polymer-supported Proline \/ 66\u003c\/p\u003e \u003cp\u003e3.3 Polymer-supported Prolinamides \/ 73\u003c\/p\u003e \u003cp\u003e3.4 Polymer-supported Proline-Peptides \/ 75\u003c\/p\u003e \u003cp\u003e3.5 Polymer-supported Pyrrolidines \/ 78\u003c\/p\u003e \u003cp\u003e3.6 Polymer-supported Prolinol and Diarylprolinol Derivatives \/ 80\u003c\/p\u003e \u003cp\u003e3.7 Conclusions and Outlooks \/ 84\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Peptide-Catalyzed Asymmetric Synthesis 91\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKazuaki Kudo and Kengo Akagawa\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction \/ 91\u003c\/p\u003e \u003cp\u003e4.2 Poly(amino acid) Catalysts \/ 94\u003c\/p\u003e \u003cp\u003e4.3 Tri- and Tetrapeptide Catalysts \/ 99\u003c\/p\u003e \u003cp\u003e4.4 Longer Peptides with a Secondary Structure \/ 110\u003c\/p\u003e \u003cp\u003e4.5 Others \/ 118\u003c\/p\u003e \u003cp\u003e4.6 Conclusions and Outlooks \/ 119\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Continuous Flow System using Polymer-Supported Chiral Catalysts 125\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eSantiago V. Luis and Eduardo Garcıa-Verdugo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction \/ 125\u003c\/p\u003e \u003cp\u003e5.2 Asymmetric Polymer-supported, Metal-based Catalysts and Reagents \/ 132\u003c\/p\u003e \u003cp\u003e5.3 Polymer-supported Asymmetric Organocatalysts \/ 147\u003c\/p\u003e \u003cp\u003e5.4 Polymer-supported Biocatalysts \/ 151\u003c\/p\u003e \u003cp\u003e5.5 Conclusions \/ 152\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Chiral Synthesis on Polymer Support: A Combinatorial Approach 157\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eDeepak B. Salunke and Chung-Ming Sun\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction \/ 157\u003c\/p\u003e \u003cp\u003e6.2 Chiral Synthesis of Complex Polyfunctional Molecules on Polymer Support \/ 160\u003c\/p\u003e \u003cp\u003e6.3 Conclusions \/ 194\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Synthesis and Application of Helical Polymers with Macromolecular Helicity Memory 201\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eHiroki Iida and Eiji Yashima\u003c\/i\u003e\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e7.1 Introduction \/ 201\u003c\/p\u003e \u003cp\u003e7.2 Macromolecular Helicity Memory \/ 203\u003c\/p\u003e \u003cp\u003e7.3 Enantioselective Reaction Assisted by Helical Polymers with Helicity Memory \/ 218\u003c\/p\u003e \u003cp\u003e7.4 Conclusions \/ 219\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Poly(isocyanide)s, Poly(quinoxaline-2,3-diyl)s, and Related Helical Polymers Used as Chiral Polymer Catalysts in Asymmetric Synthesis 223\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eYuuya Nagata and Michinori Suginome\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction \/ 223\u003c\/p\u003e \u003cp\u003e8.2 Asymmetric Synthesis of Poly(isocyanide)s \/ 224\u003c\/p\u003e \u003cp\u003e8.3 Asymmetric Synthesis of Poly(quinoxaline)s \/ 244\u003c\/p\u003e \u003cp\u003e8.4 Enantioselective Catalysis using Helical Polymers \/ 255\u003c\/p\u003e \u003cp\u003e8.5 Conclusions \/ 262\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9\u003c\/b\u003e \u003cb\u003eC2\u003c\/b\u003e \u003cb\u003eChiral Biaryl Unit-Based Helical Polymers and Their Application to Asymmetric Catalysis 267\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eTakeshi Maeda and Toshikazu Takata\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction \/ 267\u003c\/p\u003e \u003cp\u003e9.2 Synthesis of C2 Chiral Unit-based Helical Polymers \/ 269\u003c\/p\u003e \u003cp\u003e9.3 Asymmetric Reactions Catalyzed by Helical Polymer Catalysts \/ 282\u003c\/p\u003e \u003cp\u003e9.4 Conclusions \/ 289\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Immobilization of Multicomponent Asymmetric Catalysts (MACs) 293\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eHiroaki Sasai and Shinobu Takizawa\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction \/ 293\u003c\/p\u003e \u003cp\u003e10.2 Dendrimer-Supported and Dendronized Polymer-supported MACs \/ 294\u003c\/p\u003e \u003cp\u003e10.3 Nanoparticles as Supports for Chiral Catalysts [13] \/ 302\u003c\/p\u003e \u003cp\u003e10.4 The Catalyst Analog Approach [24] \/ 311\u003c\/p\u003e \u003cp\u003e10.5 Metal-bridged Polymers as Heterogeneous Catalysts: An Immobilization Method for MACs Without Using Any Support [26] \/ 314\u003c\/p\u003e \u003cp\u003e10.6 Conclusion \/ 318\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Optically Active Polymer and Dendrimer Synthesis and Their Use in Asymmetric Synthesis 323\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eQiao-Sheng Hu and Lin Pu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction \/ 323\u003c\/p\u003e \u003cp\u003e11.2 Synthesis and Application of BINOL\/BINAP-based Optically Active Polymers \/ 324\u003c\/p\u003e \u003cp\u003e11.3 Synthesis and Application of Optically Active Dendrimers \/ 355\u003c\/p\u003e \u003cp\u003e11.4 Conclusions \/ 360\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Asymmetric Polymerizations of\u003c\/b\u003e \u003cb\u003eN\u003c\/b\u003e\u003cb\u003e-Substituted Maleimides 365\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKenjiro Onimura and Tsutomu Oishi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction \/ 365\u003c\/p\u003e \u003cp\u003e12.2 Chirality of 1-Mono- or 1,1-Disubstituted and 1,2-Disubstituted Olefins \/ 365\u003c\/p\u003e \u003cp\u003e12.3 Asymmetric Polymerizations of Achiral N-Substituted Maleimides \/ 368\u003c\/p\u003e \u003cp\u003e12.4 Anionic Polymerization Mechanism of RMI \/ 371\u003c\/p\u003e \u003cp\u003e12.5 Asymmetric Polymerizations of Chiral N-Substituted Maleimides \/ 372\u003c\/p\u003e \u003cp\u003e12.6 Structure and Absolute Stereochemistry of Poly(RMI) \/ 373\u003c\/p\u003e \u003cp\u003e12.7 Asymmetric Radical Polymerizations ofN-Substituted Maleimides \/ 378\u003c\/p\u003e \u003cp\u003e12.8 Chiral Discrimination Using Poly(RMI) \/ 378\u003c\/p\u003e \u003cp\u003e12.9 Conclusions \/ 384\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Synthesis of Hyperbranched Polymer Having Binaphthol Units via Oxidative Cross-Coupling Polymerization 389\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eShigeki Habaue\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction \/ 389\u003c\/p\u003e \u003cp\u003e13.2 Oxidative Cross-coupling Reaction between 2-Naphthol and 3-Hydroxy-2-naphthoate \/ 391\u003c\/p\u003e \u003cp\u003e13.3 Oxidative Cross-coupling Polymerization Affording Linear Poly(binaphthol) \/ 392\u003c\/p\u003e \u003cp\u003e13.4 Oxidative Cross-coupling Polymerization Leading to a Hyperbranched Polymer \/ 396\u003c\/p\u003e \u003cp\u003e13.5 Photoluminescence Properties of Hyperbranched Polymers \/ 400\u003c\/p\u003e \u003cp\u003e13.6 Conclusions \/ 403\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Optically Active Polyketones 407\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKyoko Nozaki\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction \/ 407\u003c\/p\u003e \u003cp\u003e14.2 Asymmetric Synthesis of Isotactic Poly(propylene-alt-co) \/ 409\u003c\/p\u003e \u003cp\u003e14.3 Asymmetric Synthesis of Isotactic Syndiotactic Poly(styrene-alt-co) \/ 411\u003c\/p\u003e \u003cp\u003e14.4 Asymmetric Terpolymers Consisting of Two Kinds of Olefins and Carbon Monoxide \/ 413\u003c\/p\u003e \u003cp\u003e14.5 Asymmetric Polymerization of Other Olefins with CO \/ 414\u003c\/p\u003e \u003cp\u003e14.6 Chemical Transformations of Optically Active Polyketones \/ 415\u003c\/p\u003e \u003cp\u003e14.7 Conformational Studies on the Optically Active Polyketones \/ 416\u003c\/p\u003e \u003cp\u003e14.8 Conclusions \/ 419\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Synthesis and Function of Chiral\u003c\/b\u003e \u003cb\u003ep\u003c\/b\u003e\u003cb\u003e-Conjugated Polymers from Phenylacetylenes 423\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eToshiki Aoki, Takashi Kaneko, and Masahiro Teraguchi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction \/ 423\u003c\/p\u003e \u003cp\u003e15.2 Helix-sense-selective Polymerization (HSSP) of Substituted Phenylacetylenes and Function of the Resulting One-handed Helical Poly(phenylacetylene)s \/ 425\u003c\/p\u003e \u003cp\u003e15.3 Chiral Desubstitution of Side Groups in Membrane State \/ 439\u003c\/p\u003e \u003cp\u003e15.4 Synthesis of Chiral Polyradicals \/ 446\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 P-Stereogenic Oligomers, Polymers, and Related Cyclic Compounds 457\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eYasuhiro Morisaki and Yoshiki Chujo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction \/ 457\u003c\/p\u003e \u003cp\u003e16.2 P-Stereogenic Oligomers Containing Chiral \"P\" Atoms in the Main Chain \/ 458\u003c\/p\u003e \u003cp\u003e16.3 P-Stereogenic Polymers Containing Chiral \"P\" Atoms in the Main Chain \/ 470\u003c\/p\u003e \u003cp\u003e16.4 Cyclic Phosphines Using P-Stereogenic Oligomers as Building Blocks \/ 475\u003c\/p\u003e \u003cp\u003e16.5 Conclusions \/ 485\u003c\/p\u003e \u003cp\u003e\u003cb\u003eINDEX 489\u003c\/b\u003e\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49525380251991,"sku":"9780470568200","price":136.75,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780470568200.jpg?v=1731860294","url":"https:\/\/bookcurl.com\/products\/polymeric-chiral-catalyst-design-and-chiral-polymer-synthesis-9780470568200","provider":"Book Curl","version":"1.0","type":"link"}