{"product_id":"perovskites-9781118935668","title":"Perovskites","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eUniquely describes both the crystallography and properties of perovskite related materials.\u003c\/p\u003e \u003cul\u003e \u003cli\u003ePractical applications in solar cells, microelectronics and telecommunications\u003c\/li\u003e \u003cli\u003eInterdisciplinary topic drawing on materials science, chemistry, physics, and geology\u003c\/li\u003e \u003cli\u003eContains problems and answers to enhance knowledge retention\u003c\/li\u003e \u003c\/ul\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The ABX3 Perovskite Structure 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Perovskites 1\u003c\/p\u003e \u003cp\u003e1.2 The Cubic Perovskite Structure: SrTiO3 4\u003c\/p\u003e \u003cp\u003e1.3 The Goldschmidt Tolerance Factor 6\u003c\/p\u003e \u003cp\u003e1.4 ABX3 Perovskite Structure Variants 11\u003c\/p\u003e \u003cp\u003e1.5 Cation Displacement: BaTiO3 as an Example 12\u003c\/p\u003e \u003cp\u003e1.6 Jahn–Teller Octahedral Distortion: KCuF3 as an Example 16\u003c\/p\u003e \u003cp\u003e1.7 Octahedral Tilting 19\u003c\/p\u003e \u003cp\u003e1.7.1 Tilt Descriptions 19\u003c\/p\u003e \u003cp\u003e1.7.2 Trigonal Symmetry: LaAlO3 as an Example 24\u003c\/p\u003e \u003cp\u003e1.7.3 Orthorhombic Symmetry: GdFeO3 and CaTiO3 as Examples 26\u003c\/p\u003e \u003cp\u003e1.8 Symmetry Relationships 30\u003c\/p\u003e \u003cp\u003e1.9 Hybrid Organic–Inorganic Perovskites 33\u003c\/p\u003e \u003cp\u003e1.10 Antiperovskites 34\u003c\/p\u003e \u003cp\u003e1.10.1 Cubic and Related Structures 34\u003c\/p\u003e \u003cp\u003e1.10.2 Other Structures 36\u003c\/p\u003e \u003cp\u003e1.11 Structure‐Field Maps 36\u003c\/p\u003e \u003cp\u003e1.12 Theoretical Calculations 38\u003c\/p\u003e \u003cp\u003eReferences 40\u003c\/p\u003e \u003cp\u003eFurther Reading 40\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 ABX3–Related Structures 42\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Double Perovskites and Related Ordered Structures 42\u003c\/p\u003e \u003cp\u003e2.1.1 Rock‐Salt Ordered Double Perovskites 42\u003c\/p\u003e \u003cp\u003e2.1.2 Other Ordered Perovskites 45\u003c\/p\u003e \u003cp\u003e2.1.3 AA′3B4O12‐Related Phases 48\u003c\/p\u003e \u003cp\u003e2.2 Anion Substituted Perovskites 51\u003c\/p\u003e \u003cp\u003e2.2.1 Nitrides and Oxynitrides 51\u003c\/p\u003e \u003cp\u003e2.2.2 Oxyfluorides 53\u003c\/p\u003e \u003cp\u003e2.3 A‐Site‐Deficient Perovskite Structures 54\u003c\/p\u003e \u003cp\u003e2.3.1 ReO3, WO3 and Related Structures 54\u003c\/p\u003e \u003cp\u003e2.3.2 Perovskite Tungsten Bronzes 55\u003c\/p\u003e \u003cp\u003e2.3.3 A‐Site‐Deficient Titanates, Niobates and Tantalates 55\u003c\/p\u003e \u003cp\u003e2.4 Anion‐Deficient Phases Containing Tetrahedra 57\u003c\/p\u003e \u003cp\u003e2.4.1 Brownmillerites 57\u003c\/p\u003e \u003cp\u003e2.4.2 Brownmillerite Microstructures 62\u003c\/p\u003e \u003cp\u003e2.4.3 Temperature Variation and Disorder 63\u003c\/p\u003e \u003cp\u003e2.4.4 B‐Site Doped Brownmillerite Phases 64\u003c\/p\u003e \u003cp\u003e2.4.5 B‐Site Doping and Oxygen Pressure 65\u003c\/p\u003e \u003cp\u003e2.4.6 A‐Site Doped Brownmillerite Phases 65\u003c\/p\u003e \u003cp\u003e2.4.7 Brownmillerite‐Related Phases 66\u003c\/p\u003e \u003cp\u003e2.5 Anion‐Deficient Phases Containing Square Pyramids 69\u003c\/p\u003e \u003cp\u003e2.5.1 Manganites 69\u003c\/p\u003e \u003cp\u003e2.5.2 SrFeO2.5 and Related Phases 71\u003c\/p\u003e \u003cp\u003e2.5.3 Cobaltite‐Related Phases 73\u003c\/p\u003e \u003cp\u003e2.6 Point Defects, Microdomains and Modulated Phases 74\u003c\/p\u003e \u003cp\u003eFurther Reading 78\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Hexagonal Perovskite–Related Structures 79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 The BaNiO3 Structure 79\u003c\/p\u003e \u003cp\u003e3.2 BaNiO3‐Related Phases Containing Trigonal Prisms 81\u003c\/p\u003e \u003cp\u003e3.2.1 Commensurate Structures 81\u003c\/p\u003e \u003cp\u003e3.2.2 Modulated Structures 89\u003c\/p\u003e \u003cp\u003e3.3 Perovskites with Mixed Hexagonal\/Cubic Packing: Nomenclature 92\u003c\/p\u003e \u003cp\u003e3.4 Perovskites with Mixed Hexagonal\/Cubic Packing: Stacking Sequences 95\u003c\/p\u003e \u003cp\u003e3.5 Hexagonal Perovskites with chq and cph Stacking 98\u003c\/p\u003e \u003cp\u003e3.5.1 (chq) Structures 98\u003c\/p\u003e \u003cp\u003e3.5.2 (cph) Structures 99\u003c\/p\u003e \u003cp\u003e3.5.3 cphq Intergrowth Structures 104\u003c\/p\u003e \u003cp\u003e3.6 Hexagonal Perovskites with cphh Stacking 106\u003c\/p\u003e \u003cp\u003e3.6.1 (cc…chh) AnBnO3n Structures 107\u003c\/p\u003e \u003cp\u003e3.6.2 (cc…chh) AnBn−1O3n Structures 108\u003c\/p\u003e \u003cp\u003e3.6.3 (hhcc…chhcc…c) Intergrowth Phases 110\u003c\/p\u003e \u003cp\u003e3.6.4 (cc…ch) AnBn−1O3n Shift and Twinned Phases 112\u003c\/p\u003e \u003cp\u003e3.7 Anion‐Deficient Phases Containing BaO2 (c′) Layers 112\u003c\/p\u003e \u003cp\u003e3.7.1 (c…c′…ch) Structures 113\u003c\/p\u003e \u003cp\u003e3.7.2 (c…c′…chh) Structures 113\u003c\/p\u003e \u003cp\u003e3.7.3 (c…c′…chhh) Structures 115\u003c\/p\u003e \u003cp\u003e3.8 Anion‐Deficient Phases with BaOX Layers 117\u003c\/p\u003e \u003cp\u003e3.8.1 (h′) Layers 117\u003c\/p\u003e \u003cp\u003e3.8.2 (c′c′) Layers 119\u003c\/p\u003e \u003cp\u003e3.9 Sr4Mn3O10 and Ba6Mn5O16 120\u003c\/p\u003e \u003cp\u003e3.10 Temperature and Pressure Variation 120\u003c\/p\u003e \u003cp\u003eReference 122\u003c\/p\u003e \u003cp\u003eFurther Reading 122\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Modular Structures 123\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 K2NiF4 (A2BX4) and Ruddlesden–Popper Phases 123\u003c\/p\u003e \u003cp\u003e4.1.1 The K2NiF4 (T or T\/O) Structure 123\u003c\/p\u003e \u003cp\u003e4.1.2 Ruddlesden–Popper Phases 127\u003c\/p\u003e \u003cp\u003e4.2 The Nd2CuO4 (T′) and T* Structures 129\u003c\/p\u003e \u003cp\u003e4.3 Dion–Jacobson and Related Phases 131\u003c\/p\u003e \u003cp\u003e4.4 Aurivillius Phases 134\u003c\/p\u003e \u003cp\u003e4.5 The Ca2Nb2O7‐Related Phases 136\u003c\/p\u003e \u003cp\u003e4.6 Cuprate Superconductors and Related Phases 138\u003c\/p\u003e \u003cp\u003e4.6.1 La2CuO4, Nd2CuO4 and YBa2Cu3O7 139\u003c\/p\u003e \u003cp\u003e4.6.2 Layered Perovskite Structures 141\u003c\/p\u003e \u003cp\u003e4.6.3 Structures Related to the Layered Cuprate Phases 142\u003c\/p\u003e \u003cp\u003e4.7 Composition Variation 146\u003c\/p\u003e \u003cp\u003e4.8 Intercalation and Exfoliation 151\u003c\/p\u003e \u003cp\u003eFurther Reading 154\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Diffusion and Ionic Conductivity 156\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Diffusion 156\u003c\/p\u003e \u003cp\u003e5.2 Ionic Conductivity 159\u003c\/p\u003e \u003cp\u003e5.3 Proton Conductivity 162\u003c\/p\u003e \u003cp\u003e5.4 Oxygen Pressure Dependence and Electronic Conductivity 165\u003c\/p\u003e \u003cp\u003e5.5 Oxide Ion Mixed Conductors 167\u003c\/p\u003e \u003cp\u003e5.6 Proton Mixed Conductors 169\u003c\/p\u003e \u003cp\u003e5.7 Solid Oxide Fuel Cells 172\u003c\/p\u003e \u003cp\u003eReferences 174\u003c\/p\u003e \u003cp\u003eFurther Reading 174\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Dielectric Properties 176\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Insulating Perovskites 176\u003c\/p\u003e \u003cp\u003e6.2 Dielectric Perovskites 178\u003c\/p\u003e \u003cp\u003e6.2.1 General Properties 178\u003c\/p\u003e \u003cp\u003e6.2.2 Colossal Dielectric Constant Materials 181\u003c\/p\u003e \u003cp\u003e6.3 Ferroelectric\/Piezoelectric Perovskites 182\u003c\/p\u003e \u003cp\u003e6.3.1 Spontaneous Polarisation and Domains 182\u003c\/p\u003e \u003cp\u003e6.3.2 Ferroelectric Domain Switching 185\u003c\/p\u003e \u003cp\u003e6.3.3 Ferroelectric Hysteresis Loops 188\u003c\/p\u003e \u003cp\u003e6.3.4 Temperature Dependence of Ferroelectricity 189\u003c\/p\u003e \u003cp\u003e6.3.5 Pyroelectrics, Piezoelectrics and Crystal Symmetry 191\u003c\/p\u003e \u003cp\u003e6.3.6 Strain versus Electric Field Loops 192\u003c\/p\u003e \u003cp\u003e6.4 The Development of Ferroelectric\/Piezoelectric Ceramic Bodies 193\u003c\/p\u003e \u003cp\u003e6.4.1 Ceramic Piezoelectrics 193\u003c\/p\u003e \u003cp\u003e6.4.2 Electrostriction 195\u003c\/p\u003e \u003cp\u003e6.5 Antiferroelectrics 196\u003c\/p\u003e \u003cp\u003e6.6 Ferrielectrics 199\u003c\/p\u003e \u003cp\u003e6.7 Relaxor Ferroelectrics 200\u003c\/p\u003e \u003cp\u003e6.7.1 Macroscopic Characteristics of Relaxor Ferroelectrics 200\u003c\/p\u003e \u003cp\u003e6.7.2 Microstructures of Relaxor Ferroelectrics 202\u003c\/p\u003e \u003cp\u003e6.8 Improper Ferroelectricity 206\u003c\/p\u003e \u003cp\u003e6.9 Doping and Modification of Properties 208\u003c\/p\u003e \u003cp\u003e6.10 Nanoparticles and Thin Films 212\u003c\/p\u003e \u003cp\u003eReferences 215\u003c\/p\u003e \u003cp\u003eFurther Reading 215\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Magnetic Properties 217\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Magnetism in Perovskites 217\u003c\/p\u003e \u003cp\u003e7.2 Paramagnetic Perovskites 219\u003c\/p\u003e \u003cp\u003e7.3 Antiferromagnetic Perovskites 222\u003c\/p\u003e \u003cp\u003e7.3.1 Cubic Perovskite‐Related Structures 222\u003c\/p\u003e \u003cp\u003e7.3.2 Hexagonal Perovskites 229\u003c\/p\u003e \u003cp\u003e7.4 Ferromagnetic Perovskites 233\u003c\/p\u003e \u003cp\u003e7.5 Ferrimagnetic Perovskites 236\u003c\/p\u003e \u003cp\u003e7.6 Spin Glass Behaviour 237\u003c\/p\u003e \u003cp\u003e7.7 Canted Spins and Other Magnetic Ordering 238\u003c\/p\u003e \u003cp\u003e7.8 Thin Films 240\u003c\/p\u003e \u003cp\u003e7.9 Nanoparticles 243\u003c\/p\u003e \u003cp\u003e7.10 Multiferroic Perovskites 243\u003c\/p\u003e \u003cp\u003eReferences 246\u003c\/p\u003e \u003cp\u003eFurther Reading 246\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Electronic Conductivity 247\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Perovskite Band Structure: Metallic Perovskites 247\u003c\/p\u003e \u003cp\u003e8.2 Metal–Insulator Transitions 250\u003c\/p\u003e \u003cp\u003e8.2.1 Titanates and Related Phases 250\u003c\/p\u003e \u003cp\u003e8.2.2 LnNiO3 252\u003c\/p\u003e \u003cp\u003e8.2.3 Lanthanoid Manganites 253\u003c\/p\u003e \u003cp\u003e8.2.4 Lanthanoid Cobaltites 254\u003c\/p\u003e \u003cp\u003e8.2.5 (Sr, Ca)2RuO4 and Ca2Ru1−xCrxO4 255\u003c\/p\u003e \u003cp\u003e8.2.6 NaOsO3 256\u003c\/p\u003e \u003cp\u003e8.3 Perovskite Superconductors 257\u003c\/p\u003e \u003cp\u003e8.4 Cuprate High‐Temperature Superconductors 258\u003c\/p\u003e \u003cp\u003e8.4.1 Overview 258\u003c\/p\u003e \u003cp\u003e8.4.2 Lanthanum Cuprate, La2CuO4 259\u003c\/p\u003e \u003cp\u003e8.4.3 Neodymium Cuprate, Nd2CuO4 260\u003c\/p\u003e \u003cp\u003e8.4.4 Yttrium Barium Copper Oxide, YBa2Cu3O7 261\u003c\/p\u003e \u003cp\u003e8.4.5 Perovskite‐Related Structures and Series 263\u003c\/p\u003e \u003cp\u003e8.4.6 The Generic Superconductivity Phase Diagram 263\u003c\/p\u003e \u003cp\u003e8.4.7 Defects and Conductivity 265\u003c\/p\u003e \u003cp\u003e8.5 Spin Polarisation and Half‐Metals 267\u003c\/p\u003e \u003cp\u003e8.6 Charge Ordering and Orbital Ordering 268\u003c\/p\u003e \u003cp\u003e8.7 Magnetoresistance 270\u003c\/p\u003e \u003cp\u003e8.7.1 Collosal Magnetoresistance (CMR) in Manganites 270\u003c\/p\u003e \u003cp\u003e8.7.2 Low‐Field Magnetoresistance 272\u003c\/p\u003e \u003cp\u003e8.8 Semiconductivity in Perovskites 272\u003c\/p\u003e \u003cp\u003e8.9 Thin Films and Surface Conductivity 275\u003c\/p\u003e \u003cp\u003eReferences 275\u003c\/p\u003e \u003cp\u003eFurther Reading 275\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Thermal and Optical Properties 277\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Thermal Expansion 277\u003c\/p\u003e \u003cp\u003e9.1.1 Normal Thermal Expansion 277\u003c\/p\u003e \u003cp\u003e9.1.2 Thermal Contraction 280\u003c\/p\u003e \u003cp\u003e9.1.3 Zero Thermal Expansion Materials 283\u003c\/p\u003e \u003cp\u003e9.2 Thermoelectric Properties 284\u003c\/p\u003e \u003cp\u003e9.3 The Magnetocaloric Effect 287\u003c\/p\u003e \u003cp\u003e9.4 The Pyroelectric and Electrocaloric Effect 288\u003c\/p\u003e \u003cp\u003e9.5 Transparency 289\u003c\/p\u003e \u003cp\u003e9.6 Electrochromic Films 291\u003c\/p\u003e \u003cp\u003e9.7 Electro‐optic Properties 293\u003c\/p\u003e \u003cp\u003e9.7.1 Refractive Index Changes 293\u003c\/p\u003e \u003cp\u003e9.7.2 Electro‐optic Phase Modulators 294\u003c\/p\u003e \u003cp\u003e9.7.3 Electro‐optic Intensity Modulators 296\u003c\/p\u003e \u003cp\u003e9.7.4 Ceramic Modulators 299\u003c\/p\u003e \u003cp\u003e9.8 Perovskite Solar Cells 299\u003c\/p\u003e \u003cp\u003eReference 302\u003c\/p\u003e \u003cp\u003eFurther Reading 302\u003c\/p\u003e \u003cp\u003eAppendix A The Bond Valence Model for Perovskites 303\u003c\/p\u003e \u003cp\u003eAppendix B Summary of the Kröger–Vink Defect Notation 307\u003c\/p\u003e \u003cp\u003eIndex 309\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49406950736215,"sku":"9781118935668","price":113.36,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781118935668.jpg?v=1730497665","url":"https:\/\/bookcurl.com\/products\/perovskites-9781118935668","provider":"Book Curl","version":"1.0","type":"link"}