{"product_id":"palladium-reagents-and-catalysts-new-perspectives-for-the-21st-century-9780470850329","title":"Palladium Reagents and Catalysts New Perspectives","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eImproving upon excellence, this second edition of its best-selling predecessor brings to synthetic organic chemists the many applications of organopalladium chemistry, highlighting the most recent discoveries in this rapidly expanding field. This is an ideal text\/reference book for those studying this topics.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\"... covers the vast amount of innovation that has occurred in this important chemistry field in the last several years.\" (\u003ci\u003eE-STREAMS\u003c\/i\u003e, September 2005)\u003c\/p\u003e \u003cp\u003e\"This book is beautifully illustrated, very well referenced and covers a wide range of exciting synthetic methods....\" (\u003ci\u003eApplied Organometallic Chemistry\u003c\/i\u003e, March 2005)\u003c\/p\u003e \u003cp\u003e\"...amazing that a single book of such scope could actually be written...achieved just the right balance...\" (www.organische-chemie.ch, 08 June 2004)\u003c\/p\u003e \u003cp\u003e\"...For the modest price, this book should find its way onto the shelves of all good chemistry libraries....\" (\u003ci\u003eChemistry \u0026amp; Industry\u003c\/i\u003e, No.22 15\u003csup\u003eth\u003c\/sup\u003e November, 2004)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePreface.  \u003cp\u003eAbbreviations.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The Basic Chemistry of Organopalladium Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Characteristic Features of Pd-Promoted or –Catalyzed Reactions.\u003c\/p\u003e \u003cp\u003e1.2 Palladium Compounds, Complexes, and Ligands Widely Used in Organic Synthesis.\u003c\/p\u003e \u003cp\u003e1.3 Fundamental Reactions of Pd Compounds.\u003c\/p\u003e \u003cp\u003e1.3.1 ‘Oxidative’ Addition.\u003c\/p\u003e \u003cp\u003e1.3.2 Insertion.\u003c\/p\u003e \u003cp\u003e1.3.3 Transmetallation.\u003c\/p\u003e \u003cp\u003e1.3.4 Reductive Elimination.\u003c\/p\u003e \u003cp\u003e1.3.5 \u003ci\u003eβ\u003c\/i\u003e-H Elimination (\u003ci\u003eβ\u003c\/i\u003e-Elimination, Dehydropalladation).\u003c\/p\u003e \u003cp\u003e1.3.6 Elimination of \u003ci\u003eβ\u003c\/i\u003e-Heteroatom Groups and \u003ci\u003eβ\u003c\/i\u003e-Carbon.\u003c\/p\u003e \u003cp\u003e1.3.7 Electrophilic Attack by Organopalladium Species.\u003c\/p\u003e \u003cp\u003e1.3.8 Termination of Pd-Catalyzed or –Promoted Reactions and a Catalytic Cycle.\u003c\/p\u003e \u003cp\u003e1.3.9 Reactions Involving Pd(II) Compounds and Pd(0) Complexes.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Oxidative Reactions with Pd(II) Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Reactions of Alkenes.\u003c\/p\u003e \u003cp\u003e2.2.1 Introducti on.\u003c\/p\u003e \u003cp\u003e2.2.2 Reaction with Water.\u003c\/p\u003e \u003cp\u003e2.2.3 Reactions with Alcohols and Phenols.\u003c\/p\u003e \u003cp\u003e2.2.4 Reactions with Carboxylic Acids.\u003c\/p\u003e \u003cp\u003e2.2.5 Reactions with Amines.\u003c\/p\u003e \u003cp\u003e2.2.6 Reactions with Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e2.2.7 Oxidative Carbonylation.\u003c\/p\u003e \u003cp\u003e2.2.8 Reactions with Aromatic Compounds.\u003c\/p\u003e \u003cp\u003e2.2.9 Coupling of Alkenes with Organometallic Compounds.\u003c\/p\u003e \u003cp\u003e2.3 Stoichiometric Reactions of \u003ci\u003eπ\u003c\/i\u003e-Allyl Complexes.\u003c\/p\u003e \u003cp\u003e2.4 Reactions of Conjugated Dienes.\u003c\/p\u003e \u003cp\u003e2.5 Reactions of Allenes.\u003c\/p\u003e \u003cp\u003e2.6 Reaction of Alkynes.\u003c\/p\u003e \u003cp\u003e2.7 Homocoupling and Oxidative Substitution Reactions of Aromatic Compounds.\u003c\/p\u003e \u003cp\u003e2.8 Regioselective Reactions Based on Chelation and Participation of Heteroatoms.\u003c\/p\u003e \u003cp\u003e2.9 Oxidative Carbonylation of Alcohols and Amines.\u003c\/p\u003e \u003cp\u003e2.10 Oxidation of Alcohols.\u003c\/p\u003e \u003cp\u003e2.11 Enone Formation from Ketones and Cycloalkenylation.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Pd(0)-Catalyzed Reactions of sp\u003csup\u003e2\u003c\/sup\u003eOrganic Halides and Pseudohalides.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 Reactions with Alkenes (Mizoroki–Heck Reaction).\u003c\/p\u003e \u003cp\u003e3.2.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2.2 Catalysts and Ligands.\u003c\/p\u003e \u003cp\u003e3.2.3 Reaction Conditions (Bases, Solvents, and Additives).\u003c\/p\u003e \u003cp\u003e3.2.4 Halides and Pseudohalides.\u003c\/p\u003e \u003cp\u003e3.2.5 Alkenes.\u003c\/p\u003e \u003cp\u003e3.2.6 Formation of Neopentylpalladium and its Termination by Anion Capture.\u003c\/p\u003e \u003cp\u003e3.2.7 Intramolecular Reactions.\u003c\/p\u003e \u003cp\u003e3.2.8. Asymmetric Reactions.\u003c\/p\u003e \u003cp\u003e3.2.9 Reactions with 1,2-, 1,3-, and 1,4-Dienes.\u003c\/p\u003e \u003cp\u003e3.2.10 Amino Heck Reactions of Oximes.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.3 Reactions of Aromatics and Heteroaromatics.\u003c\/p\u003e \u003cp\u003e3.3.1 Arylation of Heterocycles.\u003c\/p\u003e \u003cp\u003e3.3.2 Intermolecular Arylation of Phenols.\u003c\/p\u003e \u003cp\u003e3.3.3 Intermolecular Polyarylation of Ketones.\u003c\/p\u003e \u003cp\u003e3.3.4 Intramolecular Arylation of Aromatics.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.4 Reactions with Alkynes.\u003c\/p\u003e \u003cp\u003e3.4.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.4.2 Reactions of Terminal Alkynes to Form Aryl- and Alkenylalkynes (Sonogashira Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.4.3 Reactions of Internal and Terminal Alkynes with Aryl and Alkenyl Halides via Insertion.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.5 Carbonylation and Reactions of Acyl Chlorides.\u003c\/p\u003e \u003cp\u003e3.5.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.5.2 Formation of Carboxylic Acids, Esters, and Amides.\u003c\/p\u003e \u003cp\u003e3.5.3 Formation of Aldehydes and Ketones.\u003c\/p\u003e \u003cp\u003e3.5.4 Reactions of Acyl Halides and Related Compounds.\u003c\/p\u003e \u003cp\u003e3.5.5 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.6 Cross-Coupling Reactions with Organometallic Compounds of the Main Group Metals via Transmetallation.\u003c\/p\u003e \u003cp\u003e3.6.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.6.2 Organoboron Compounds (Suzuki–Miyaura Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.6.3 Organostannanes (Kosugi–Migita–Stille Coupling).\u003c\/p\u003e \u003cp\u003e3.6.4 Organozinc Compounds (Negishi Coupling).\u003c\/p\u003e \u003cp\u003e3.6.5 Organomagnesium Compounds.\u003c\/p\u003e \u003cp\u003e3.6.6 Organosilicon Compounds (Hiyama Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7 Arylation and Alkenylation of C, N, O, S, and P Nucleophiles.\u003c\/p\u003e \u003cp\u003e3.7.1 \u003ci\u003eα\u003c\/i\u003e-Arylation and \u003ci\u003eα\u003c\/i\u003e-Alkenylation of Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e3.7.2 Intramolecular Attack of Aryl Halides on Carbonyl Groups.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.3 Arylation of Nitrogen Nucleophiles.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.4 Arylation of Phenols, Alcohols, and Thiols.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.5 Arylation of Phosphines, Phosphonates, and Phosphinates.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8 Miscellaneous Reactions of Aryl Halides.\u003c\/p\u003e \u003cp\u003e3.8.1 The Catellani Reactions using Norbornene as a Template for \u003ci\u003eortho\u003c\/i\u003e-Substitution.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8.2 Reactions of Alcohols with Aryl Halides Involving \u003ci\u003eβ\u003c\/i\u003e-Carbon Elimination.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8.3 Hydrogenolysis with Various Hydrides.\u003c\/p\u003e \u003cp\u003e3.8.4 Homocoupling of Organic Halides (Reductive Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Pd(0)-Catalyzed Reactions of Allylic Compounds via \u003ci\u003eΠ\u003c\/i\u003e-Allylpalladium Complexes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction and Range of Leaving Groups.\u003c\/p\u003e \u003cp\u003e4.2 Allylation.\u003c\/p\u003e \u003cp\u003e4.2.1 Stereo- and Regiochemistry of Allylation.\u003c\/p\u003e \u003cp\u003e4.2.2 Asymmetric Allylation.\u003c\/p\u003e \u003cp\u003e4.2.3 Allylation of Stabilized Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e4.2.4 Allylation of Oxygen and Nitrogen Nucleophiles.\u003c\/p\u003e \u003cp\u003e4.2.5 Allylation with Bis-Allylic Compounds and Cycloadditions.\u003c\/p\u003e \u003cp\u003e4.3 Reactions with Main Group Organometallic Compounds via Transmetallation.\u003c\/p\u003e \u003cp\u003e4.3.1 Cross-Coupling with Main Group Organometallic Compounds.\u003c\/p\u003e \u003cp\u003e4.3.2 Formation of Allylic Metal Compounds.\u003c\/p\u003e \u003cp\u003e4.3.3 Allylation Involving Umpolung.\u003c\/p\u003e \u003cp\u003e4.3.4 Reactions of Amphiphilic Bis-\u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Compounds.\u003c\/p\u003e \u003cp\u003e4.4 Carbonylation Reactions.\u003c\/p\u003e \u003cp\u003e4.5 Intramolecular Reactions with Alkenes and Alkynes.\u003c\/p\u003e \u003cp\u003e4.6 Hydrogenolysis of Allylic Compounds.\u003c\/p\u003e \u003cp\u003e4.6.1 Preparation of 1-Alkenes by Hydrogenolysis with Formates.\u003c\/p\u003e \u003cp\u003e4.6.2 Hydrogenolysis of Internal and Cyclic Allylic Compounds.\u003c\/p\u003e \u003cp\u003e4.7 Allyl Group as a Protecting Group.\u003c\/p\u003e \u003cp\u003e4.8 1,4-Elimination.\u003c\/p\u003e \u003cp\u003e4.9 Reactions via \u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Enolates.\u003c\/p\u003e \u003cp\u003e4.9.1 Generation of \u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Enolates from Silyl and Tin Enolates.\u003c\/p\u003e \u003cp\u003e4.9.2 Reactions of Allyl \u003ci\u003eβ\u003c\/i\u003e-Keto Carboxylates and Related Compounds.\u003c\/p\u003e \u003cp\u003e4.10 Pd(0) and Pd(II)-Catalyzed Allylic Rearrangement.\u003c\/p\u003e \u003cp\u003e4.11 Reactions of 2,3-Alkadienyl Derivatives via Methylene-\u003ci\u003eπ\u003c\/i\u003e -allylpalladiums.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Pd(0)-Catalyzed Reactions of 1,3-Dienes, 1,2-Dienes (Allenes), and Methylenecyclopropanes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Reactions of Conjugated Dienes.\u003c\/p\u003e \u003cp\u003e5.2 Reactions of Allenes.\u003c\/p\u003e \u003cp\u003e5.2.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.2.2 Reactions with Pronucleophiles.\u003c\/p\u003e \u003cp\u003e5.2.3 Carbonylation.\u003c\/p\u003e \u003cp\u003e5.2.4 Hydrometallation and Dimetallation.\u003c\/p\u003e \u003cp\u003e5.2.5 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003e5.3 Reactions of Methylenecyclopropanes.\u003c\/p\u003e \u003cp\u003e5.3.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.3.2 Hydrostannation and Dimetallation.\u003c\/p\u003e \u003cp\u003e5.3.3 Hydrocarbonation and Hydroamination.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Pd(0)-Catalyzed Reactions of Propargyl Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction and Classification of Reactions.\u003c\/p\u003e \u003cp\u003e6.2 Reactions via Insertion of Alkenes and Alkynes.\u003c\/p\u003e \u003cp\u003e6.3 Carbonylations.\u003c\/p\u003e \u003cp\u003e6.4 Reactions of Main Group Metal Compounds.\u003c\/p\u003e \u003cp\u003e6.5 Reactions of Terminal Alkynes; Formation of 1,2-Alkadien-4-ynes.\u003c\/p\u003e \u003cp\u003e6.6 Reactions of Nucleophiles on Central sp Carbon of Allenylpalladium Intermediates.\u003c\/p\u003e \u003cp\u003e6.7 Hydrogenolysis and Elimination of Propargyl Compounds.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Pd(0)- and Pd(II)-Catalyzed Reactions of Alkynes and Benzynes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Reactions of Alkynes.\u003c\/p\u003e \u003cp\u003e7.1.1 Carbonylation.\u003c\/p\u003e \u003cp\u003e7.1.2 Hydroarylation.\u003c\/p\u003e \u003cp\u003e7.1.3 Hydroamination, Hydrocarbonation, and Related Reactions.\u003c\/p\u003e \u003cp\u003e7.1.4 Hydrometallation and Hydro-Heteroatom Addition.\u003c\/p\u003e \u003cp\u003e7.1.5 Dimetallation and Related Reactions.\u003c\/p\u003e \u003cp\u003e7.1.6 Cyclization of 1,6-Enynes and 1,7-Diynes.\u003c\/p\u003e \u003cp\u003e7.1.7 Benzannulation.\u003c\/p\u003e \u003cp\u003e7.1.8 Homo- and Cross-Coupling of Alkynes.\u003c\/p\u003e \u003cp\u003e7.1.9 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003e7.2 Reactions of Benzynes.\u003c\/p\u003e \u003cp\u003e7.2.1 Cyclotrimerization and Cocyclization.\u003c\/p\u003e \u003cp\u003e7.2.2 Addition Reactions of Arynes 595 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Pd(0)-Catalyzed Reactions of Alkenes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Carbonylation.\u003c\/p\u003e \u003cp\u003e8.2 Hydroamination.\u003c\/p\u003e \u003cp\u003e8.3 Hydrometallation.\u003c\/p\u003e \u003cp\u003e8.4 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Pd(0)-Catalyzed Miscellaneous Reactions of Carbon Monoxide.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Miscellaneous Reactions Catalyzed by Chiral and Achiral Pd(II) Complexes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eTables 1.1 to 1.18.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49402441400663,"sku":"9780470850329","price":115.16,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780470850329.jpg?v=1730480405","url":"https:\/\/bookcurl.com\/products\/palladium-reagents-and-catalysts-new-perspectives-for-the-21st-century-9780470850329","provider":"Book Curl","version":"1.0","type":"link"}