{"product_id":"organometallic-compounds-of-lowcoordinate-si-ge-sn-and-pb-9780470725436","title":"Organometallic Compounds of LowCoordinate Si Ge","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eUntil recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents.  \u003cp\u003e\u003ci\u003eOrganometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb\u003c\/i\u003e describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of :\u003c\/p\u003e \u003cul\u003e \u003cli\u003eSi-, Ge-, Sn and Pb-centered cations, radicals and anions\u003c\/li\u003e \u003cli\u003eheavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes\u003c\/li\u003e \u003cli\u003e\n\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e“In effect, the body of work described constitutes one of the cornerstones of modern main group chemistry and this\u003c\/p\u003e \u003cp\u003eaccount provides a highly useful reference source for the specialist as well as a non-intimidating guide for the beginner.”  (\u003ci\u003eApplied Organometallic Chemistry\u003c\/i\u003e, 6 March 2015)\u003c\/p\u003e \u003cp\u003e \u003c\/p\u003e \u003cbr\u003e \u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cb\u003ePreface.\u003c\/b\u003e  \u003cp\u003e\u003cb\u003eAbbreviations.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1. Heavy Analogs of Carbenium Ions: Si-, Ge-, Sn- and Pb-Centered Cations.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction.\u003c\/p\u003e \u003cp\u003e1.2 Synthesis of RR'R\"E\u003csup\u003e+\u003c\/sup\u003eCations (E = Si-Pb).\u003c\/p\u003e \u003cp\u003e1.3 Reactions and Synthetic Applications of RRRE\u003csup\u003e+\u003c\/sup\u003e Cations\u003csup\u003e16\u003c\/sup\u003e.\u003c\/p\u003e \u003cp\u003e1.4 Theoretical Studies.\u003c\/p\u003e \u003cp\u003e1.5 Early Studies of RR'R\"E\u003csup\u003e+\u003c\/sup\u003e Cations: Free or Coordinated?\u003c\/p\u003e \u003cp\u003e1.6 Stable RR'R\"E\u003csup\u003e+\u003c\/sup\u003e Cations.\u003c\/p\u003e \u003cp\u003e1.7 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e1.8 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2. Heavy Analogs of Organic Free Radicals: Si-, Ge-, Sn- and Pb-Centered Radicals.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Early Studies: Transient Species RR'R\"E.\u003c\/p\u003e \u003cp\u003e2.3 Persistent Radicals (Generation and Identification).\u003c\/p\u003e \u003cp\u003e2.4 Stable Radicals.\u003c\/p\u003e \u003cp\u003e2.5 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e2.6 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3. Heavy Analogs of Carbanions: Si-, Ge-, Sn- and Pb-Centered Anions.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 Synthesis.\u003c\/p\u003e \u003cp\u003e3.3 Structure.\u003c\/p\u003e \u003cp\u003e3.4 Reactions and Synthetic Applications.\u003c\/p\u003e \u003cp\u003e3.5 Recent Developments.\u003c\/p\u003e \u003cp\u003e3.6 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e3.7 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4. Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction.\u003c\/p\u003e \u003cp\u003e4.2 Generation.\u003c\/p\u003e \u003cp\u003e4.3 Spectroscopic Identification.\u003c\/p\u003e \u003cp\u003e4.4 Structure.\u003c\/p\u003e \u003cp\u003e4.5 Reactions of Transient Species.\u003c\/p\u003e \u003cp\u003e4.6 Stable\/Persistent Silylenes, Germylenes, Stannylenes and Plumbylenes.\u003c\/p\u003e \u003cp\u003e4.7 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e4.8 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5. Heavy Analogs of Alkenes, 1,3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.2 Early Studies: Generation and Identification.\u003c\/p\u003e \u003cp\u003e5.3 Stable Derivatives (Synthesis and Structure).\u003c\/p\u003e \u003cp\u003e5.4 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e5.5 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6. Heavy Analogs of Aromatic Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction.\u003c\/p\u003e \u003cp\u003e6.2 Early Studies.\u003c\/p\u003e \u003cp\u003e6.3 Stable Compounds (Synthesis and Structure).\u003c\/p\u003e \u003cp\u003e6.4 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e6.5 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e\n\u003c\/li\u003e\n\u003c\/ul\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49402419609943,"sku":"9780470725436","price":138.56,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780470725436.jpg?v=1730480343","url":"https:\/\/bookcurl.com\/products\/organometallic-compounds-of-lowcoordinate-si-ge-sn-and-pb-9780470725436","provider":"Book Curl","version":"1.0","type":"link"}