{"product_id":"organo-main-group-chemistry-9780470450338","title":"Organo Main Group Chemistry","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis vital resource book captures the essential scope of organic chemistry of all main group elements and covers all main group elements dealing with syntheses and reactions of their organic compounds.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e“Summing Up: Highly recommended.  Chemistry libraries serving academic students at all levels, researchers\/faculty, and professionals.”  (\u003ci\u003eChoice\u003c\/i\u003e, 1 March 2012)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cb\u003ePreface ix\u003c\/b\u003e  \u003cp\u003e\u003cb\u003e1 Main Group Elements and Heteroatoms: Scope and Characteristics 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Aufbau Principle and Sign of Orbitals \/ 1\u003c\/p\u003e \u003cp\u003e1.2 Electronic Configuration of an Atom: Main Group Elements and Heteroatoms \/ 3\u003c\/p\u003e \u003cp\u003e1.3 Fundamental Properties of Main Group Elements \/ 5\u003c\/p\u003e \u003cp\u003e1.4 Acidity of Carboxylic Acid and Substituent Effect \/ 7\u003c\/p\u003e \u003cp\u003e1.5 Heteroatom Effect \/ 10\u003c\/p\u003e \u003cp\u003e1.5.1 Stabilization of \u003ci\u003eα\u003c\/i\u003e-Carbocation by Resonance: Stereoelectronic Effect \/ 10\u003c\/p\u003e \u003cp\u003e1.5.2 Coordination with Lewis Acids \/ 15\u003c\/p\u003e \u003cp\u003eReferences \/ 16\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 1: Electronegativity 17\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 2: Importance of Formal Logic-I: Oxidation Number and Formal Charge 19\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 3: Importance of Formal Logic-II: Octet Rule, Eighteen-Electron Rule, Hypervalence 23\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Main Group Element Effect 25\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 What Is Main Group Element Effect? \/ 25\u003c\/p\u003e \u003cp\u003e2.2 Single Bond Energy and \u003ci\u003eπ\u003c\/i\u003e –Bond Energy \/ 27\u003c\/p\u003e \u003cp\u003e2.3 Hypervalent Compound \/ 31\u003c\/p\u003e \u003cp\u003e2.4 Effect of Hypervalent Bond (1): 3c–4e Bond and Structure \/ 33\u003c\/p\u003e \u003cp\u003e2.5 Effect of Hypervalent Bond (2): Apicophilicity and Pseudorotation \/ 41\u003c\/p\u003e \u003cp\u003e2.6 Effect of Hypervalent Bond (3): Ligand Coupling Reaction (LCR) and Edge Inversion \/ 45\u003c\/p\u003e \u003cp\u003e2.7 Effect of \u003ci\u003eσ\u003c\/i\u003eX−C \/ 46\u003c\/p\u003e \u003cp\u003e2.8 Effect of \u003ci\u003eσ\u003c\/i\u003e ∗ X−C \/ 48\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 4: (\u003ci\u003eσ\u003c\/i\u003e, \u003ci\u003eσ\u003c\/i\u003e ∗) and (\u003ci\u003eπ\u003c\/i\u003e, \u003ci\u003eπ\u003c\/i\u003e ∗): HMO (Hueckel Molecular Orbital) and Electrocyclic Reaction 57\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Lithium, Magnesium, and Copper Compounds 63\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Synthesis \/ 64\u003c\/p\u003e \u003cp\u003e3.2 Structure \/ 66\u003c\/p\u003e \u003cp\u003e3.3 Reaction \/ 68\u003c\/p\u003e \u003cp\u003e3.3.1 Deprotonation as Base \/ 69\u003c\/p\u003e \u003cp\u003e3.3.2 Nucleophilic Reaction \/ 72\u003c\/p\u003e \u003cp\u003e3.3.3 Conjugate Addition of Lithium Dimethylcuprate \/ 76\u003c\/p\u003e \u003cp\u003eReferences \/ 77\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Boron and Aluminum Compounds 79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Synthesis \/ 80\u003c\/p\u003e \u003cp\u003e4.2 Structure \/ 82\u003c\/p\u003e \u003cp\u003e4.3 Reaction \/ 84\u003c\/p\u003e \u003cp\u003eReferences \/ 88\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Silicon, Tin, and Lead Compounds 91\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Synthesis \/ 92\u003c\/p\u003e \u003cp\u003e5.2 Reaction \/ 94\u003c\/p\u003e \u003cp\u003e5.3 Organotin and Lead Compounds \/ 100\u003c\/p\u003e \u003cp\u003eReferences \/ 104\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 5: Stable Carbene and Its Complex 105\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Phosphorus, Antimony, and Bismuth Compounds 111\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Phosphorus Compounds \/ 112\u003c\/p\u003e \u003cp\u003e6.2 Synthesis of Organophosphorus Compounds \/ 113\u003c\/p\u003e \u003cp\u003e6.3 Tertiary Phosphine and Its Nucleophilic Reaction \/ 115\u003c\/p\u003e \u003cp\u003e6.4 Arbuzov Reaction \/ 117\u003c\/p\u003e \u003cp\u003e6.5 Perkow Reaction \/ 118\u003c\/p\u003e \u003cp\u003e6.6 Synthesis of Optically Active Phosphines \/ 119\u003c\/p\u003e \u003cp\u003e6.7 Ylide and Wittig Reaction and Related Ones \/ 123\u003c\/p\u003e \u003cp\u003e6.8 Reactions of Phosphonium Salts and Formation of Phosphoranes \/ 131\u003c\/p\u003e \u003cp\u003e6.9 Freezing BPR and Its Effect \/ 138\u003c\/p\u003e \u003cp\u003e6.10 Antimony and Bismuth Compounds \/ 143\u003c\/p\u003e \u003cp\u003eReferences \/ 146\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 6: Dreams of Staudinger and Wittig 149\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 7: Stereochemistry in Nucleophilic Substitution of MX4-type Compounds: Inversion or Retention 155\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Sulfur, Selenium, and Tellurium Compounds 159\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Sulfur Compounds \/ 160\u003c\/p\u003e \u003cp\u003e7.2 Synthesis of Organosulfur Compounds \/ 160\u003c\/p\u003e \u003cp\u003e7.3 Reactions of Organosulfur Compounds \/ 166\u003c\/p\u003e \u003cp\u003e7.4 Structure and Reaction of Hypervalent Organosulfur\u003c\/p\u003e \u003cp\u003eCompounds \/ 170\u003c\/p\u003e \u003cp\u003e7.5 Selenium and Tellurium Compounds \/ 175\u003c\/p\u003e \u003cp\u003eReferences \/ 178\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 8: Inversion Mechanism of NH3 and NF3: Vertex Inversion or Edge Inversion 181\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Organohalogen Compounds: Fluorine and Iodine Compounds 187\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Synthesis of Chlorine and Bromine Compounds \/ 188\u003c\/p\u003e \u003cp\u003e8.2 Fluorine Compounds \/ 190\u003c\/p\u003e \u003cp\u003e8.3 Iodine Compounds \/ 195\u003c\/p\u003e \u003cp\u003eReferences \/ 199\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Atrane and Transannular Interaction: Formation of Hypervalent Bond 201\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction \/ 201\u003c\/p\u003e \u003cp\u003e9.2 Silatrane and Atrane \/ 202\u003c\/p\u003e \u003cp\u003e9.3 Transannular Interaction (1) \/ 208\u003c\/p\u003e \u003cp\u003e9.4 Transannular Interaction (2) \/ 210\u003c\/p\u003e \u003cp\u003eReferences \/ 211\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Unsaturated Compounds of Main Group Elements of Third Period and Heavier 213\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction \/ 213\u003c\/p\u003e \u003cp\u003e10.2 Unsaturated Bonds of Group 15 Elements of Third Period and Heavier \/ 215\u003c\/p\u003e \u003cp\u003e10.3 Unsaturated Bonds of Group 14 Elements of Third Period and Heavier \/ 219\u003c\/p\u003e \u003cp\u003e10.4 Aromatic Compounds of Group 14 Elements \/ 222\u003c\/p\u003e \u003cp\u003eReferences \/ 223\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Ligand Coupling Reaction 225\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction \/ 225\u003c\/p\u003e \u003cp\u003e11.2 Selectivity of Ligand Coupling Reaction: Theoretical Investigation \/ 226\u003c\/p\u003e \u003cp\u003e11.3 Ligand Coupling Reaction of Organic Compounds of Phosphorus, Antimony, and Bismuth \/ 227\u003c\/p\u003e \u003cp\u003e11.4 Ligand Coupling Reaction of Organic Compounds of Sulfur, Selenium, and Tellurium \/ 237\u003c\/p\u003e \u003cp\u003e11.5 Ligand Coupling Reaction of Organoiodine Compounds \/ 241\u003c\/p\u003e \u003cp\u003eReferences \/ 245\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 9: Hexavalent Organotellurium Compounds 247\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Hypervalent Carbon Compounds: Can Hexavalent Carbon Exist? 251\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction \/ 251\u003c\/p\u003e \u003cp\u003e12.2 Attempts for Pentacoordinate Hypervalent Carbon Species \/ 253\u003c\/p\u003e \u003cp\u003e12.3 Synthesis of Pentacoordinate Hypervalent Carbon Species (10-C-5) and Bond Switching at Carbon and Boron \/ 254\u003c\/p\u003e \u003cp\u003e12.4 Attempts to Hexacoordinate Hypervalent Carbon Species (12-C-6) \/ 259\u003c\/p\u003e \u003cp\u003eReferences \/ 262\u003c\/p\u003e \u003cp\u003e\u003cb\u003eNotes 10: Main Group Element Porphyrins 265\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex 269\u003c\/b\u003e\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":53515417354583,"sku":"9780470450338","price":72.86,"currency_code":"GBP","in_stock":true}],"url":"https:\/\/bookcurl.com\/products\/organo-main-group-chemistry-9780470450338","provider":"Book Curl","version":"1.0","type":"link"}