{"product_id":"organic-chemistry-9781119504580","title":"Organic Chemistry","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eProvides an in-depth study of organic compounds that bridges the gap between general and organic chemistry \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eOrganic Chemistry: Concepts and Applications\u003c\/i\u003e presents a comprehensive review of organic compounds that is appropriate for a two-semester sophomore organic chemistry course. The text covers the fundamental concepts needed to understand organic chemistry and clearly shows how to apply the concepts of organic chemistry to problem-solving. In addition, the book highlights the relevance of organic chemistry to the environment, industry, and biological and medical sciences. The author includes multiple-choice questions similar to aptitude exams for professional schools, including the Medical College Admissions Test (MCAT) and Dental Aptitude Test (DAT) to help in the preparation for these important exams.\u003c\/p\u003e \u003cp\u003eRather than categorize content information by functional groups, which often stresses memorization, this textbook instead divides the information into r\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003c\/p\u003e\u003cp\u003ePreface xvii\u003c\/p\u003e \u003cp\u003eAbout the Campanion Website xxiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Bonding and Structure of Organic Compounds 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Electronic Structure of Atoms 4\u003c\/p\u003e \u003cp\u003e1.3 Chemical Bonds 9\u003c\/p\u003e \u003cp\u003e1.4 Chemical Formulas 18\u003c\/p\u003e \u003cp\u003e1.5 The Covalent Bond 20\u003c\/p\u003e \u003cp\u003e1.6 Bonding– Concept Summary and Applications 28\u003c\/p\u003e \u003cp\u003e1.7 Intermolecular Attractions 29\u003c\/p\u003e \u003cp\u003e1.8 Intermolecular Molecular Interactions – Concept Summary and Applications 31\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 34\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Carbon Functional Groups and Organic Nomenclature 39\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 39\u003c\/p\u003e \u003cp\u003e2.2 Functional Groups 39\u003c\/p\u003e \u003cp\u003e2.3 Saturated Hydrocarbons 41\u003c\/p\u003e \u003cp\u003e2.4 Organic Nomenclature 45\u003c\/p\u003e \u003cp\u003e2.5 Structure and Nomenclature of Alkanes 45\u003c\/p\u003e \u003cp\u003e2.6 Unsaturated Hydrocarbons 54\u003c\/p\u003e \u003cp\u003e2.7 Structure and Nomenclature of Alkenes 56\u003c\/p\u003e \u003cp\u003e2.8 Structure and Nomenclature of Substituted Benzenes 58\u003c\/p\u003e \u003cp\u003e2.9 Structure and Nomenclature of Alkynes 60\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 61\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Heteroatomic Functional Groups and Organic Nomenclature 63\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Properties and Structure of Alcohols, Phenols, and Thiols 63\u003c\/p\u003e \u003cp\u003e3.2 Nomenclature of Alcohols 66\u003c\/p\u003e \u003cp\u003e3.3 Nomenclature of Thiols 68\u003c\/p\u003e \u003cp\u003e3.4 Structure and Properties of Aldehydes and Ketones 69\u003c\/p\u003e \u003cp\u003e3.5 Nomenclature of Aldehydes 70\u003c\/p\u003e \u003cp\u003e3.6 Nomenclature of Ketones 71\u003c\/p\u003e \u003cp\u003e3.7 Structure and Properties of Carboxylic Acids 73\u003c\/p\u003e \u003cp\u003e3.8 Nomenclature of Carboxylic Acids 75\u003c\/p\u003e \u003cp\u003e3.9 Structure and Properties of Esters 78\u003c\/p\u003e \u003cp\u003e3.10 Structure and Properties of Acid Chlorides 82\u003c\/p\u003e \u003cp\u003e3.11 Structure and Properties of Anhydrides 83\u003c\/p\u003e \u003cp\u003e3.12 Structure and Properties of Amines 84\u003c\/p\u003e \u003cp\u003e3.13 Structure and Properties of Amides 88\u003c\/p\u003e \u003cp\u003e3.14 Structure and Properties of Nitriles 90\u003c\/p\u003e \u003cp\u003e3.15 Structure and Properties of Ethers 91\u003c\/p\u003e \u003cp\u003e3.16 An Overview of Spectroscopy and the Relationship to Functional Groups 94\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Alkanes, Cycloalkanes, and Alkenes: Isomers, Conformations, and Stabilities 103\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 103\u003c\/p\u003e \u003cp\u003e4.2 Structural Isomers 103\u003c\/p\u003e \u003cp\u003e4.3 Conformational Isomers of Alkanes 104\u003c\/p\u003e \u003cp\u003e4.4 Conformational Isomers of Cycloalkanes 108\u003c\/p\u003e \u003cp\u003e4.5 Geometric Isomers 114\u003c\/p\u003e \u003cp\u003e4.6 Stability of Alkanes 119\u003c\/p\u003e \u003cp\u003e4.7 Stability of Alkenes 121\u003c\/p\u003e \u003cp\u003e4.8 Stability of Alkynes 122\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 123\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Stereochemistry 125\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 125\u003c\/p\u003e \u003cp\u003e5.2 Chiral Stereoisomers 126\u003c\/p\u003e \u003cp\u003e5.3 Significance of Chirality 129\u003c\/p\u003e \u003cp\u003e5.4 Nomenclature of the Absolute Configuration of Chiral Molecules 131\u003c\/p\u003e \u003cp\u003e5.5 Properties of Stereogenic Compounds 133\u003c\/p\u003e \u003cp\u003e5.6 Compounds with More Than One Stereogenic Carbon 134\u003c\/p\u003e \u003cp\u003e5.7 Resolution of Enantiomers 137\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 140\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 An Overview of the Reactions of Organic Chemistry 145\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 145\u003c\/p\u003e \u003cp\u003e6.2 Acid–Base Reactions 145\u003c\/p\u003e \u003cp\u003e6.3 Addition Reactions 149\u003c\/p\u003e \u003cp\u003e6.4 Reduction Reactions 150\u003c\/p\u003e \u003cp\u003e6.5 Oxidation Reactions 153\u003c\/p\u003e \u003cp\u003e6.6 Elimination Reactions 154\u003c\/p\u003e \u003cp\u003e6.7 Substitution Reactions 156\u003c\/p\u003e \u003cp\u003e6.8 Pericyclic Reactions 158\u003c\/p\u003e \u003cp\u003e6.9 Catalytic Coupling Reactions 158\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 159\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Acid–Base Reactions in Organic Chemistry 165\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 165\u003c\/p\u003e \u003cp\u003e7.2 Lewis Acids and Bases 165\u003c\/p\u003e \u003cp\u003e7.3 Relative Strengths of Acids and Conjugate Bases 166\u003c\/p\u003e \u003cp\u003e7.4 Predicting the Relative Strengths of Acids and Bases 169\u003c\/p\u003e \u003cp\u003e7.5 Factors That Affect Acid and Base Strengths 170\u003c\/p\u003e \u003cp\u003e7.6 Applications of Acid–Bases Reactions in Organic Chemistry 176\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 180\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Addition Reactions Involving Alkenes and Alkynes 183\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 183\u003c\/p\u003e \u003cp\u003e8.2 The Mechanism for Addition Reactions Involving Alkenes 183\u003c\/p\u003e \u003cp\u003e8.3 Addition of Hydrogen Halide to Alkenes (Hydrohalogenation of Alkenes) 185\u003c\/p\u003e \u003cp\u003e8.4 Addition of Halogens to Alkenes (Halogenation of Alkenes) 196\u003c\/p\u003e \u003cp\u003e8.5 Addition of Halogens and Water to Alkenes (Halohydrin Formation) 198\u003c\/p\u003e \u003cp\u003e8.6 Addition of Water to Alkenes (Hydration of Alkenes) 199\u003c\/p\u003e \u003cp\u003e8.7 Addition of Carbenes to Alkenes 207\u003c\/p\u003e \u003cp\u003e8.8 The Mechanism for Addition Reactions Involving Alkynes 209\u003c\/p\u003e \u003cp\u003e8.9 Applications of Addition Reactions to Synthesis 213\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 214\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Addition Reactions Involving Carbonyls and Nitriles 223\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 223\u003c\/p\u003e \u003cp\u003e9.2 Mechanism for Addition Reactions Involving Carbonyl Compounds 223\u003c\/p\u003e \u003cp\u003e9.3 Addition of HCN to Carbonyl Compounds 224\u003c\/p\u003e \u003cp\u003e9.4 Addition of Water to Carbonyl Compounds 226\u003c\/p\u003e \u003cp\u003e9.5 Addition of Alcohols to Carbonyl Compounds 230\u003c\/p\u003e \u003cp\u003e9.6 Addition of Ylides to Carbonyl Compounds (The Wittig Reaction) 235\u003c\/p\u003e \u003cp\u003e9.7 Addition of Enolates to Carbonyl Compounds 237\u003c\/p\u003e \u003cp\u003e9.8 Addition of Amines to Carbonyl Compounds 240\u003c\/p\u003e \u003cp\u003e9.9 Mechanism for Addition Reactions Involving Imines 241\u003c\/p\u003e \u003cp\u003e9.10 Mechanism for Addition Reactions Involving Nitriles 242\u003c\/p\u003e \u003cp\u003e9.11 Applications of Addition Reactions to Synthesis 244\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 246\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Reduction Reactions in Organic Chemistry 251\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 251\u003c\/p\u003e \u003cp\u003e10.2 Reducing Agents of Organic Chemistry 252\u003c\/p\u003e \u003cp\u003e10.3 Reduction of C=O and C=S Containing Compounds 255\u003c\/p\u003e \u003cp\u003e10.4 Reduction of Imines 263\u003c\/p\u003e \u003cp\u003e10.5 Reduction of Oxiranes 266\u003c\/p\u003e \u003cp\u003e10.6 Reduction of Aromatic Compounds, Alkynes, and Alkenes 268\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 272\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Oxidation Reactions in Organic Chemistry 275\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 275\u003c\/p\u003e \u003cp\u003e11.2 Oxidation 275\u003c\/p\u003e \u003cp\u003e11.3 Oxidation of Alcohols and Aldehydes 279\u003c\/p\u003e \u003cp\u003e11.4 Oxidation of Alkenes Without Bond Cleavage 288\u003c\/p\u003e \u003cp\u003e11.5 Oxidation of Alkenes with Bond Cleavage 293\u003c\/p\u003e \u003cp\u003e11.6 Applications of Oxidation Reactions of Alkenes 296\u003c\/p\u003e \u003cp\u003e11.7 Oxidation of Alkynes 299\u003c\/p\u003e \u003cp\u003e11.8 Oxidation of Aromatic Compounds 300\u003c\/p\u003e \u003cp\u003e11.9 Autooxidation of Ethers and Alkenes 301\u003c\/p\u003e \u003cp\u003e11.10 Applications of Oxidation Reactions to Synthesis 302\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 304\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Elimination Reactions of Organic Chemistry 309\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 309\u003c\/p\u003e \u003cp\u003e12.2 Mechanisms of Elimination Reactions 309\u003c\/p\u003e \u003cp\u003e12.3 Elimination of Hydrogen and Halide (Dehydrohalogenation) 316\u003c\/p\u003e \u003cp\u003e12.4 Elimination of Water (Dehydration) 319\u003c\/p\u003e \u003cp\u003e12.5 Applications of Elimination Reactions to Synthesis 323\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 326\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Spectroscopy Revisited, A More Detailed Examination 331\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 331\u003c\/p\u003e \u003cp\u003e13.2 The Electromagnetic Spectrum 331\u003c\/p\u003e \u003cp\u003e13.3 UV‐Vis Spectroscopy and Conjugated Systems 334\u003c\/p\u003e \u003cp\u003e13.4 Infrared Spectroscopy 337\u003c\/p\u003e \u003cp\u003e13.5 Mass Spectrometry 343\u003c\/p\u003e \u003cp\u003e13.6 Nuclear Magnetic Resonance (NMR) Spectroscopy 346\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 367\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Free Radical Substitution Reactions Involving Alkanes 369\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 369\u003c\/p\u003e \u003cp\u003e14.2 Types of Alkanes and Alkyl Halides 371\u003c\/p\u003e \u003cp\u003e14.3 Chlorination of Alkanes 376\u003c\/p\u003e \u003cp\u003e14.4 Bromination of Alkanes 380\u003c\/p\u003e \u003cp\u003e14.5 Applications of Free Radical Substitution Reactions 386\u003c\/p\u003e \u003cp\u003e14.6 Free Radical Inhibitors 388\u003c\/p\u003e \u003cp\u003e14.7 Environmental Impact of Organohalides and Free Radicals 389\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 391\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Nucleophilic Substitution Reactions at sp\u003csup\u003e3\u003c\/sup\u003e Carbons 393\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 393\u003c\/p\u003e \u003cp\u003e15.2 The Electrophile 393\u003c\/p\u003e \u003cp\u003e15.3 The Leaving Group 394\u003c\/p\u003e \u003cp\u003e15.4 The Nucleophile 397\u003c\/p\u003e \u003cp\u003e15.5 Nucleophilic Substitution Reactions 397\u003c\/p\u003e \u003cp\u003e15.6 Bimolecular Substitution Reaction Mechanism (S\u003csub\u003eN\u003c\/sub\u003e2 Mechanism) 400\u003c\/p\u003e \u003cp\u003e15.7 Unimolecular Substitution Reaction Mechanism (S\u003csub\u003eN\u003c\/sub\u003e1 Mechanism) 406\u003c\/p\u003e \u003cp\u003e15.8 Applications of Nucleophilic Substitution Reactions – Synthesis 414\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 420\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Nucleophilic Substitution Reactions at Acyl Carbons 425\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 425\u003c\/p\u003e \u003cp\u003e16.2 Mechanism for Acyl Substitution 426\u003c\/p\u003e \u003cp\u003e16.3 Substitution Reactions Involving Acid Chlorides 428\u003c\/p\u003e \u003cp\u003e16.4 Substitution Reactions Involving Anhydrides 436\u003c\/p\u003e \u003cp\u003e16.5 Substitution Reactions Involving Esters 442\u003c\/p\u003e \u003cp\u003e16.6 Substitution Reactions Involving Amides 451\u003c\/p\u003e \u003cp\u003e16.7 Substitution Reactions Involving Carboxylic Acids 454\u003c\/p\u003e \u003cp\u003e16.8 Substitution Reactions Involving Oxalyl Chloride 458\u003c\/p\u003e \u003cp\u003e16.9 Substitution Reactions Involving Sulfur Containing Compounds 458\u003c\/p\u003e \u003cp\u003e16.10 Applications of Acyl Substitution Reactions 460\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 462\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Aromaticity and Aromatic Substitution Reactions 467\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 467\u003c\/p\u003e \u003cp\u003e17.2 Structure and Properties of Benzene 468\u003c\/p\u003e \u003cp\u003e17.3 Nomenclature of Substituted Benzene 470\u003c\/p\u003e \u003cp\u003e17.4 Stability of Benzene 473\u003c\/p\u003e \u003cp\u003e17.5 Characteristics of Aromatic Compounds 475\u003c\/p\u003e \u003cp\u003e17.6 Electrophilic Aromatic Substitution Reactions of Benzene 478\u003c\/p\u003e \u003cp\u003e17.7 Electrophilic Aromatic Substitution Reactions of Substituted Benzene 484\u003c\/p\u003e \u003cp\u003e17.8 Applications– Synthesis of Substituted Benzene Compounds 491\u003c\/p\u003e \u003cp\u003e17.9 Electrophilic Substitution Reactions of Polycyclic Aromatic Compounds 494\u003c\/p\u003e \u003cp\u003e17.10 Electrophilic Substitution Reactions of Pyrrole 496\u003c\/p\u003e \u003cp\u003e17.11 Electrophilic Substitution Reactions of Pyridine 497\u003c\/p\u003e \u003cp\u003e17.12 Nucleophilic Aromatic Substitution 499\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 504\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Conjugated Systems and Pericyclic Reactions 511\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18.1 Conjugated Systems 511\u003c\/p\u003e \u003cp\u003e18.2 Pericyclic Reactions 513\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 522\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Catalytic Carbon–Carbon Coupling Reactions 525\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 525\u003c\/p\u003e \u003cp\u003e19.2 Reactions of Transition Metal Complexes 525\u003c\/p\u003e \u003cp\u003e19.3 Palladium‐ Catalyzed Coupling Reactions 528\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 535\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Synthetic Polymers and Biopolymers 537\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 537\u003c\/p\u003e \u003cp\u003e20.2 Cationic Polymerization of Alkenes 537\u003c\/p\u003e \u003cp\u003e20.3 Anionic Polymerization of Alkenes 540\u003c\/p\u003e \u003cp\u003e20.4 Free Radical Polymerization of Alkenes 540\u003c\/p\u003e \u003cp\u003e20.5 Copolymerization of Alkenes 542\u003c\/p\u003e \u003cp\u003e20.6 Properties of Polymers 543\u003c\/p\u003e \u003cp\u003e20.7 Biopolymers 544\u003c\/p\u003e \u003cp\u003e20.8 Amino Acids, Monomers of Peptides and Proteins 545\u003c\/p\u003e \u003cp\u003e20.9 Acid–Base Properties of Amino Acids 547\u003c\/p\u003e \u003cp\u003e20.10 Synthesis of α‐Amino Acids 547\u003c\/p\u003e \u003cp\u003e20.11 Reactions of α‐Amino Acids 550\u003c\/p\u003e \u003cp\u003e20.12 Primary Structure and Properties of Peptides 556\u003c\/p\u003e \u003cp\u003e20.13 Secondary Structure of Proteins 558\u003c\/p\u003e \u003cp\u003e20.14 Monosaccharides, Monomers of Carbohydrates 559\u003c\/p\u003e \u003cp\u003e20.15 Reactions of Monosaccharides 560\u003c\/p\u003e \u003cp\u003e20.16 Disaccharides and Polysaccharides 566\u003c\/p\u003e \u003cp\u003e20.17 N‐Glycosides and Amino Sugars 567\u003c\/p\u003e \u003cp\u003e20.18 Lipids 568\u003c\/p\u003e \u003cp\u003e20.19 Properties and Reactions of Waxes 569\u003c\/p\u003e \u003cp\u003e20.20 Properties and Reactions of Triglycerides 569\u003c\/p\u003e \u003cp\u003e20.21 Properties and Reactions of Phospholipids 572\u003c\/p\u003e \u003cp\u003e20.22 Structure and Properties of Steroids, Prostaglandins, and Terpenes 572\u003c\/p\u003e \u003cp\u003eEnd of Chapter Problems 573\u003c\/p\u003e \u003cp\u003eIndex 577\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49407067128151,"sku":"9781119504580","price":103.46,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119504580.jpg?v=1730498059","url":"https:\/\/bookcurl.com\/products\/organic-chemistry-9781119504580","provider":"Book Curl","version":"1.0","type":"link"}