{"product_id":"nitrogen-rich-energetic-materials-9783527349296","title":"Nitrogen-Rich Energetic Materials","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eNitrogen-Rich Energetic Materials\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eProvides in-depth and comprehensive knowledge on both the chemistry and practical applications of nitrogen-rich energetic materials\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eEnergetic materials, a class of material with high amounts of stored chemical energy, include explosives, pyrotechnics, and propellants. Initially used for military applications, nitrogen-rich energetic materials have become important in the civil engineering and aerospace sectors, they are increasingly used in commercial mining and construction as well as in rocket propulsion. Making these nitrogen-rich energetic materials safer, more powerful, and more cost-effective requires a thorough understanding of their chemistry, physics, synthesis, properties, and applications.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eNitrogen-Rich Energetic Materials\u003c\/i\u003e presents a detailed summary of the development of nitrogen-rich energetic materials over the past decade and provides up-to-date knowledge on their applications in various areas of advanced engineering. Edited by a panel of international experts in the field, this book examines the chemistry of pentazoles, fused ring and laser ignitable nitrogen-rich compounds, polynitrogen and tetrazole-based energetic compounds, and more. The text also introduces applications of nitrogen-rich energetic materials in energetic polymers and metal-organic frameworks, as pyrotechnics materials for light and smoke, and in oxadiazoles from precursor molecules. This authoritative volume:\u003c\/p\u003e \u003cul\u003e\n\u003cli\u003ePresents in-depth chapters written by leading experts in each sub-field covered\u003c\/li\u003e\n\u003cli\u003eOffers a systematic introduction to new and emerging applications of nitrogen-rich energetic materials such as in computational chemistry\u003c\/li\u003e\n\u003cli\u003eDiscusses recent advances in nitrate ester chemistry with focus on propellant applications\u003c\/li\u003e\n\u003cli\u003eDiscusses green and eco-friendly approaches to nitrogen-rich compounds\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003e\u003ci\u003eNitrogen-Rich Energetic Materials\u003c\/i\u003e is an important resource for researchers, academics, and industry professionals across fields, including explosives specialists, pyrotechnicians, materials scientists, polymer chemists, laser specialists, physical chemists, environmental chemists, chemical engineers, and safety officers.\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003eAbout the Editors xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Chemistry of Pentazole 1\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMing Lu, Pengcheng Wang, Yuangang Xu, and Qiuhan Lin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Substituted Pentazoles 1\u003c\/p\u003e \u003cp\u003e1.3 Strategies for the Preparation of cyclo-N5- 5\u003c\/p\u003e \u003cp\u003e1.4 Complexes of Metal and cyclo-N5- 9\u003c\/p\u003e \u003cp\u003e1.5 cyclo-N5--Based Nonmetallic Ionic Salts 25\u003c\/p\u003e \u003cp\u003e1.6 Conclusions 43\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Aromatic Fused-Ring-Based Energetic Compounds 47\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eKangcai Wang and Qinghua Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 47\u003c\/p\u003e \u003cp\u003e2.2 Fused-Ring Aromatic Energetic Compounds 49\u003c\/p\u003e \u003cp\u003e2.3 Conclusions 68\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Advances in Computations of Nitrogen-Rich Materials 73\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eLei Zhang and Chuang Yao\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Why Computation and What Role It Plays? 73\u003c\/p\u003e \u003cp\u003e3.2 Why Nitrogen-Rich HEDMs and How TheyWork? 74\u003c\/p\u003e \u003cp\u003e3.3 Advances in Computation of First-Generation Nitrogen-Rich HEDMs 75\u003c\/p\u003e \u003cp\u003e3.4 Advances in Computation of Second-Generation Nitrogen-Rich HEDMs 81\u003c\/p\u003e \u003cp\u003e3.5 Advances in Computation of Third-Generation Nitrogen-Rich HEDMs: Polynitrogen Materials 84\u003c\/p\u003e \u003cp\u003e3.6 Final Remarks 97\u003c\/p\u003e \u003cp\u003eAcknowledgement 98\u003c\/p\u003e \u003cp\u003eReferences 98\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Laser Ignition of Energetic Transition Metal Complexes 107\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMaximilian Wurzenberger, Daniel Shem-Tov, and Jörg Stierstorfer\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 107\u003c\/p\u003e \u003cp\u003e4.2 Synthesis of Energetic Coordination Compounds 116\u003c\/p\u003e \u003cp\u003e4.3 Synthesis of Energetic Tetrazole Ligands 116\u003c\/p\u003e \u003cp\u003e4.4 Synthesis Energetic Coordination Complexes 121\u003c\/p\u003e \u003cp\u003e4.5 Examples of Molecular Structures 122\u003c\/p\u003e \u003cp\u003e4.6 Energetic Properties of Ligands and Corresponding Energetic Coordination Compounds 122\u003c\/p\u003e \u003cp\u003e4.7 UV-Vis Spectroscopy of Energetic Coordination Compounds 128\u003c\/p\u003e \u003cp\u003e4.8 Studies of Ignition Mechanism 128\u003c\/p\u003e \u003cp\u003e4.9 Conclusions 134\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Energetic 1,2,3,4-Tetrazines 139\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eAleksandr M. Churakov, Michael S. Klenov, Aleksey A. Voronin, and Vladimir A. Tartakovsky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 139\u003c\/p\u003e \u003cp\u003e5.2 Methods of Synthesis and Reactivity of 1,2,3,4-Tetrazines 141\u003c\/p\u003e \u003cp\u003e5.3 NMR and X-ray Studies 164\u003c\/p\u003e \u003cp\u003e5.4 Thermal Stability 168\u003c\/p\u003e \u003cp\u003e5.5 Applications 177\u003c\/p\u003e \u003cp\u003eReferences 179\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Recent Advances in Chemistry of Nitrogen-Rich Energetic Polymers and Plasticizers 189\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMichael Gozin and Leonid L. Fershtat\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 189\u003c\/p\u003e \u003cp\u003e6.2 Heterocyclic Energetic Polymers and Plasticizers 189\u003c\/p\u003e \u003cp\u003e6.3 Nitrogen-Rich Energetic Polymers Lacking Traditional Explosophoric Groups 201\u003c\/p\u003e \u003cp\u003e6.4 Azido-Rich Energetic Polymers and Plasticizers 202\u003c\/p\u003e \u003cp\u003e6.5 Azido Fluoropolymers 216\u003c\/p\u003e \u003cp\u003e6.6 Azido Plasticizers 219\u003c\/p\u003e \u003cp\u003e6.7 Nitro Group Containing Polymers 225\u003c\/p\u003e \u003cp\u003e6.8 Aromatic C-NO2 Containing Polymers 230\u003c\/p\u003e \u003cp\u003e6.9 Conclusions 234\u003c\/p\u003e \u003cp\u003eReferences 234\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Tetrazole Energetic Salts Based on Various Explosophores: Recent Overview of Synthesis and Energetic Properties 239\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eSaira Manzoor, Qamar-un-nisa Tariq, and Jian-Guo Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 239\u003c\/p\u003e \u003cp\u003e7.2 Tetrazole-Based Energetic Salts 241\u003c\/p\u003e \u003cp\u003e7.3 Conclusion and Future Trends 278\u003c\/p\u003e \u003cp\u003e7.4 Cautions 280\u003c\/p\u003e \u003cp\u003eAcknowledgments 280\u003c\/p\u003e \u003cp\u003eReferences 280\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Properties and Application of Nitrogen-Rich Compound BTATz in Low-Signature Propellants 285\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJianhua Yi, Zhihua Sun, Yi Xu, Zhao Qin, Changjian Wang, Bozhou Wang, Hui Li, Haijian Li, Chao Chen, Xiao Xie, and Fengqi Zhao\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 285\u003c\/p\u003e \u003cp\u003e8.2 Synthesis of BTATz 286\u003c\/p\u003e \u003cp\u003e8.3 Structure of BTATz 287\u003c\/p\u003e \u003cp\u003e8.4 Properties of BTATz 290\u003c\/p\u003e \u003cp\u003e8.5 Energetic Properties of the Propellants 291\u003c\/p\u003e \u003cp\u003e8.6 Plume Smoke Signature of the Propellants 295\u003c\/p\u003e \u003cp\u003e8.7 Preparation of the Propellants 296\u003c\/p\u003e \u003cp\u003e8.8 Decomposition Reaction Kinetics and Thermal Safety of the Propellants 297\u003c\/p\u003e \u003cp\u003e8.9 Combustion Properties of the Propellants 319\u003c\/p\u003e \u003cp\u003e8.10 Correlation Between PDSC Characteristic Values and Burning Rates 324\u003c\/p\u003e \u003cp\u003e8.11 Conclusions 326\u003c\/p\u003e \u003cp\u003eReferences 327\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Nitro-substituted Oxadiazoles: Important Building Blocks in the Synthesis of Energetic Compounds 331\u003c\/b\u003e\u003cbr\u003e\u003ci\u003ePhilip Pagoria\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 331\u003c\/p\u003e \u003cp\u003e9.2 Enthalpy of Formation of Oxadiazoles 331\u003c\/p\u003e \u003cp\u003e9.3 1,2,4-Oxadiazoles 332\u003c\/p\u003e \u003cp\u003e9.4 1,3,4-Oxadiazoles 339\u003c\/p\u003e \u003cp\u003e9.5 Furazans (1,2,5-Oxadiazole) and Furoxans (1,2,5-Oxadiazole-2-Oxides) 344\u003c\/p\u003e \u003cp\u003e9.6 Summary 365\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Insensitive High Explosives Containing Tetraazapentalene Moiety 377\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eErnst-Christian Koch\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 377\u003c\/p\u003e \u003cp\u003e10.2 Synthesis of TACOT Derivatives 377\u003c\/p\u003e \u003cp\u003e10.3 Crystal and Molecular Structure 383\u003c\/p\u003e \u003cp\u003e10.4 Spectroscopy 385\u003c\/p\u003e \u003cp\u003e10.4.1 NMR Spectroscopy 385\u003c\/p\u003e \u003cp\u003e10.5 Thermochemistry 386\u003c\/p\u003e \u003cp\u003e10.6 Detonation Performance 388\u003c\/p\u003e \u003cp\u003e10.7 Thermal Behavior 390\u003c\/p\u003e \u003cp\u003e10.8 Sensitivity 391\u003c\/p\u003e \u003cp\u003e10.9 Conclusions 392\u003c\/p\u003e \u003cp\u003eAcknowledgments 392\u003c\/p\u003e \u003cp\u003eAbbreviations 392\u003c\/p\u003e \u003cp\u003eReferences 393\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Nitrogen-Rich Pyrotechnic Materials for Light and Smoke 397\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eThomas M. Klapötke and Magdalena Rusan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Light-Generating Pyrotechnics 397\u003c\/p\u003e \u003cp\u003e11.2 Smokes 405\u003c\/p\u003e \u003cp\u003e11.2.1 White Smoke 411\u003c\/p\u003e \u003cp\u003e11.2.2 Colored Smoke 412\u003c\/p\u003e \u003cp\u003eAcknowledgments 413\u003c\/p\u003e \u003cp\u003eReferences 413\u003c\/p\u003e \u003cp\u003eIndex 415\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":49419453628759,"sku":"9783527349296","price":114.75,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527349296.jpg?v=1730538355","url":"https:\/\/bookcurl.com\/products\/nitrogen-rich-energetic-materials-9783527349296","provider":"Book Curl","version":"1.0","type":"link"}