{"product_id":"new-frontiers-in-asymmetric-catalysis-9780471680260","title":"New Frontiers in Asymmetric Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis book covers recent developments and findings in asymmetric catalysis research, including nonlinear phenomena, auto-catalysis, asymmetric activation, and de-activation of racemic catalysts, as well as asymmetric catalysis of carbon-carbon forming reactions such as \"metathesis,\" a topic of rapidly developing interest.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\"[The] editors have succeeded admirably in inviting interesting authors to assemble a handy overview of the most important reactions and a number of concepts ... .The present monograph has achieved the goal of covering truly interesting reactions and catalysts.\" (\u003ci\u003eOrganic Chemistry Portal\u003c\/i\u003e, May 2009)  \u003cp\u003e\"...this book has definite value and is strongly recommended for inclusion in both academic and industrial research libraries.\"  (\u003ci\u003eAngewandte Chemie, Intern. Edition\u003c\/i\u003e, November 2007)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePREFACE.  \u003cp\u003eCONTRIBUTORS.\u003c\/p\u003e \u003cp\u003e1 Ligand Design for Catalytic Asymmetric Reduction (\u003ci\u003eTakeshi Ohkuma, Masato Kitamura, and Ryoji Noyori\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003e1.1 Introduction.\u003c\/p\u003e \u003cp\u003e1.2 Hydrogenation of Olefins.\u003c\/p\u003e \u003cp\u003e1.3 Reduction of Ketones.\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e1.4 Reduction of Imines.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Ligand Design for Oxidation\u003c\/b\u003e (\u003ci\u003eTohru Yamada\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Catalytic Enantioselective Epoxidation of Unfunctionalized Olefins.\u003c\/p\u003e \u003cp\u003e2.3 Enantioselective Metal-Catalyzed Baeyer–Villiger Oxidation.\u003c\/p\u003e \u003cp\u003e2.4 Optical Resolution during Oxidation of Alcohols.\u003c\/p\u003e \u003cp\u003e2.5 Catalytic Enantioselective Oxidative Coupling of 2-Naphthols.\u003c\/p\u003e \u003cp\u003e2.6 Concluding Remarks.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Ligand Design for C–C Bond Formation\u003c\/b\u003e (\u003ci\u003eRyo Shintani and Tamio Hayashi\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 1,4-Addition and Related Reactions.\u003c\/p\u003e \u003cp\u003e3.3 Cross-Coupling Reactions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Activation of Small Molecules (CO, HCN, RNC, and CO\u003c\/b\u003e\u003cb\u003e\u003csub\u003e2\u003c\/sub\u003e\u003c\/b\u003e\u003cb\u003e)\u003c\/b\u003e (\u003ci\u003eKyoko Nozaki\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e4.1 Introduction.\u003c\/p\u003e \u003cp\u003e4.2 Asymmetric Hydroformylation of Olefins.\u003c\/p\u003e \u003cp\u003e4.3 Asymmetric Hydrocarbohydroxylation and Related Reactions.\u003c\/p\u003e \u003cp\u003e4.4 Asymmetric Ketone Formation from Carbon–Carbon Multiple Bonds and CO.\u003c\/p\u003e \u003cp\u003e4.5 Asymmetric Hydrocyanation of Olefins.\u003c\/p\u003e \u003cp\u003e4.6 Asymmetric Addition of Cyanide and Isocyanide to Aldehydes or Imines.\u003c\/p\u003e \u003cp\u003e4.7 Asymmetric Addition of Carbon Dioxide.\u003c\/p\u003e \u003cp\u003e4.8 Conclusion and Outlook.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Asymmetric Synthesis Based on Catalytic Activation of CH Bonds and CC Bonds\u003c\/b\u003e (\u003ci\u003eZhiping Li and Chao-Jun Li\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003e5.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.2 Asymmetric Synthesis via Activation of C–H Bonds.\u003c\/p\u003e \u003cp\u003e5.3 Asymmetric Synthesis via Activation of C–C Bonds.\u003c\/p\u003e \u003cp\u003e5.4 Conclusions and Outlook.\u003c\/p\u003e \u003cp\u003eAcknowledgments.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Recent Progress in the Metathesis Reaction\u003c\/b\u003e (\u003ci\u003eMiwako Mori\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e6.1 Introduction.\u003c\/p\u003e \u003cp\u003e6.2 Olefin Metathesis.\u003c\/p\u003e \u003cp\u003e6.3 Enyne Metathesis.\u003c\/p\u003e \u003cp\u003e6.4 Alkyne Metathesis.\u003c\/p\u003e \u003cp\u003e6.5 Conclusions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Nonlinear Effects in Asymmetric Catalysis\u003c\/b\u003e (\u003ci\u003eHenri B. Kagan\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003e7.1 Introduction.\u003c\/p\u003e \u003cp\u003e7.2 Properties of Enantiomer Mixtures.\u003c\/p\u003e \u003cp\u003e7.3 Nonlinear Effect in Asymmetric Catalysis.\u003c\/p\u003e \u003cp\u003e7.4 Main Classes of Reactions.\u003c\/p\u003e \u003cp\u003e7.5 Asymmetric Amplification.\u003c\/p\u003e \u003cp\u003e7.6 Current Trends.\u003c\/p\u003e \u003cp\u003e7.7 Conclusion.\u003c\/p\u003e \u003cp\u003eAcknowledgment.\u003c\/p\u003e \u003cp\u003eReferences and Notes.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Asymmetric Activation and Deactivation of Racemic Catalysts\u003c\/b\u003e (\u003ci\u003eKoichi Mikami and Kohsuke Aikawa\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e8.1 Introduction.\u003c\/p\u003e \u003cp\u003e8.2 Racemic Catalysis.\u003c\/p\u003e \u003cp\u003e8.2.1 Asymmetric Deactivation.\u003c\/p\u003e \u003cp\u003e8.3 Future Perspectives.\u003c\/p\u003e \u003cp\u003eReferences and Notes.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Asymmetric Autocatalysis with Amplification of Chirality and Origin of Chiral Homogeneity of Biomolecules\u003c\/b\u003e (\u003ci\u003eKenso Soai, Tsuneomi Kawasaki, and Itaru Sato\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e9.1 Introduction.\u003c\/p\u003e \u003cp\u003e9.2 Asymmetric Autocatalysis.\u003c\/p\u003e \u003cp\u003e9.3 Amplification of Chirality by Asymmetric Autocatalysis.\u003c\/p\u003e \u003cp\u003e9.4 Asymmetric Autocatalysis and Its Role in the Origin and Amplification of Chirality.\u003c\/p\u003e \u003cp\u003e9.5 Conclusions.\u003c\/p\u003e \u003cp\u003eAcknowledgment.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Recent Advances in Catalytic Asymmetric Desymmetrization Reactions\u003c\/b\u003e (\u003ci\u003eTomislav Rovis\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e10.1 Introduction.\u003c\/p\u003e \u003cp\u003e10.2 Allylic Alkylation.\u003c\/p\u003e \u003cp\u003e10.3 Ring Opening of Epoxides and Aziridines.\u003c\/p\u003e \u003cp\u003e10.4 Ring Opening of Bridged Systems.\u003c\/p\u003e \u003cp\u003e10.5 Olefin Metathesis.\u003c\/p\u003e \u003cp\u003e10.6 Acylation.\u003c\/p\u003e \u003cp\u003e10.7 Asymmetric Deprotonation.\u003c\/p\u003e \u003cp\u003e10.8 Oxidations.\u003c\/p\u003e \u003cp\u003e10.9 Cyclic Anhydride Desymmetrization.\u003c\/p\u003e \u003cp\u003e10.10 Miscellaneous.\u003c\/p\u003e \u003cp\u003e10.11 Concluding Remarks.\u003c\/p\u003e \u003cp\u003eAcknowledgments.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 History and Perspective of Chiral Organic Catalysts\u003c\/b\u003e (\u003ci\u003eGerald Lelais and David W. C. MacMillan\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e11.1 Introduction.\u003c\/p\u003e \u003cp\u003e11.2 Historical Background.\u003c\/p\u003e \u003cp\u003e11.3 Iminium Catalysis: A New Concept in Organocatalysis.\u003c\/p\u003e \u003cp\u003e11.4 Enamine Catalysis: Birth, Rebirth, and Rapid Growth.\u003c\/p\u003e \u003cp\u003e11.5 Brønsted Acid Catalysis: Hydrogen-Bonding Activation.\u003c\/p\u003e \u003cp\u003e11.6 Phase Transfer Catalysis (PTC).\u003c\/p\u003e \u003cp\u003e11.7 Future Perspective.\u003c\/p\u003e \u003cp\u003eAcknowledgments.\u003c\/p\u003e \u003cp\u003eReferences and Notes.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Chiral Br\u003c\/b\u003e\u003cb\u003eø\u003c\/b\u003e\u003cb\u003ensted\/Lewis Acid Catalysts\u003c\/b\u003e (\u003ci\u003eKazuaki Ishihara and Hisashi Yamamoto\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e12.1 Introduction.\u003c\/p\u003e \u003cp\u003e12.2 Chiral Brønsted Acid Catalysts.\u003c\/p\u003e \u003cp\u003e12.3 Chiral Lewis Acid Catalysts.\u003c\/p\u003e \u003cp\u003e12.4 Lewis Acid--Assisted Chiral Brønsted Acid Catalysts.\u003c\/p\u003e \u003cp\u003e12.5 Conclusions and Outlook.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Chiral Bifunctional Acid\/Base Catalysts\u003c\/b\u003e (\u003ci\u003eMasakatsu Shibasaki and Motomu Kanai\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003e13.1 Introduction.\u003c\/p\u003e \u003cp\u003e13.2 Chiral Bro¨nsted Base Catalysis.\u003c\/p\u003e \u003cp\u003e13.3 Chiral Bronsted Base--Lewis Acid Bifunctional Catalysis.\u003c\/p\u003e \u003cp\u003e13.4 Chiral Bronsted Base--Bronsted Acid Bifunctional Catalysis.\u003c\/p\u003e \u003cp\u003e13.5 Chiral Lewis Base Catalysis.\u003c\/p\u003e \u003cp\u003e13.6 Chiral Lewis Base--Lewis Acid Bifunctional Catalysis.\u003c\/p\u003e \u003cp\u003e13.7 Conclusion.\u003c\/p\u003e \u003cp\u003eReferences and Notes.\u003c\/p\u003e \u003cp\u003eIndex.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":53515431510359,"sku":"9780471680260","price":125.96,"currency_code":"GBP","in_stock":true}],"url":"https:\/\/bookcurl.com\/products\/new-frontiers-in-asymmetric-catalysis-9780471680260","provider":"Book Curl","version":"1.0","type":"link"}