{"product_id":"multicatalyst-system-in-asymmetric-catalysis-9781118071861","title":"Multicatalyst System in Asymmetric Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis book introduces multi-catalyst systems by describing their mechanism and advantages in asymmetric catalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003eContributors xiv\u003c\/p\u003e \u003cp\u003e1 Toward Ideal Asymmetric Catalysis 1\u003cbr\u003e Jian Zhou and Jin-Sheng Yu\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Challenges to Realize Ideal Asymmetric Catalysis 7\u003c\/p\u003e \u003cp\u003e1.3 Solutions 13\u003c\/p\u003e \u003cp\u003e1.4 Borrow Ideas from Nature 22\u003c\/p\u003e \u003cp\u003e1.5 Conclusion 32\u003c\/p\u003e \u003cp\u003eReferences 32\u003c\/p\u003e \u003cp\u003e2 Multicatalyst System 37\u003cbr\u003e Zhong-Yan Cao Feng Zhu and Jian Zhou\u003c\/p\u003e \u003cp\u003e2.1 Introduction 37\u003c\/p\u003e \u003cp\u003e2.2 Models of Substrate Activation 42\u003c\/p\u003e \u003cp\u003e2.2.1 The Activation of Electrophiles 43\u003c\/p\u003e \u003cp\u003e2.2.2 The Activation of Nucleophiles 54\u003c\/p\u003e \u003cp\u003e2.2.3 SOMO Catalysis 64\u003c\/p\u003e \u003cp\u003e2.3 Early Examples of the Application of Multicatalyst System in Asymmetric Catalysis 66\u003c\/p\u003e \u003cp\u003e2.4 A General Introduction of Multicatalyst-Promoted Asymmetric Reactions 85\u003c\/p\u003e \u003cp\u003e2.5 Classification of Multicatalyst-Promoted Asymmetric Reactions 95\u003c\/p\u003e \u003cp\u003e2.6 Challenges and Possible Solutions 97\u003c\/p\u003e \u003cp\u003e2.7 Multicatalyst System Versus Multifunctional Catalyst 103\u003c\/p\u003e \u003cp\u003e2.8 Multicatalyst System Versus Additives-Enhanced Catalysis 105\u003c\/p\u003e \u003cp\u003e2.9 Additive-Enhanced Catalysis 107\u003c\/p\u003e \u003cp\u003e2.9.1 Nitrogen-containing Organobase 109\u003c\/p\u003e \u003cp\u003e2.9.2 Inorganic Bases 111\u003c\/p\u003e \u003cp\u003e2.9.3 H2O 114\u003c\/p\u003e \u003cp\u003e2.9.4 Molecular Sieves and Dehydrators 120\u003c\/p\u003e \u003cp\u003e2.9.5 N-oxide P-oxide and As-oxide 125\u003c\/p\u003e \u003cp\u003e2.9.6 Alcohols and Phenols 129\u003c\/p\u003e \u003cp\u003e2.9.7 Ammonium Halides and Metal Halides 133\u003c\/p\u003e \u003cp\u003e2.9.8 Amides 137\u003c\/p\u003e \u003cp\u003e2.9.9 Brønsted Acids and Lewis Acids 140\u003c\/p\u003e \u003cp\u003e2.9.10 Two or More Additives Together 144\u003c\/p\u003e \u003cp\u003e2.10 Conclusion 147\u003c\/p\u003e \u003cp\u003eReferences 148\u003c\/p\u003e \u003cp\u003e3 Asymmetric Multifunctional Catalysis 159\u003cbr\u003e Jin-Sheng Yu and Jian Zhou\u003c\/p\u003e \u003cp\u003e3.1 Introduction 159\u003c\/p\u003e \u003cp\u003e3.2 Asymmetric Multifunctional Organocatalysis 164\u003c\/p\u003e \u003cp\u003e3.2.1 H-Bond Donor–Tertiary Amine Catalysis 165\u003c\/p\u003e \u003cp\u003e3.2.2 H-Bond Donor–Enamine Catalysis 193\u003c\/p\u003e \u003cp\u003e3.2.3 H-Bond Donor–Phase Transfer Catalysis 203\u003c\/p\u003e \u003cp\u003e3.2.4 H-Bond Donor–Tertiary Phosphine Catalysis 209\u003c\/p\u003e \u003cp\u003e3.2.5 Chiral Phosphoric Acid Catalysis 214\u003c\/p\u003e \u003cp\u003e3.2.6 Asymmetric Bifunctional Salt Catalysis 217\u003c\/p\u003e \u003cp\u003e3.2.7 Miscellaneous 222\u003c\/p\u003e \u003cp\u003e3.3 Asymmetric Hybrid Organo\/Metal Catalysis 227\u003c\/p\u003e \u003cp\u003e3.3.1 Brønsted Base\/Lewis Acid Bifunctional Catalysis 228\u003c\/p\u003e \u003cp\u003e3.3.2 Lewis Base\/Lewis Acid Bifunctional Catalysis 233\u003c\/p\u003e \u003cp\u003e3.3.3 Brønsted Acid\/Lewis Acid Bifunctional Catalysis 236\u003c\/p\u003e \u003cp\u003e3.3.4 Enamine\/Lewis Acid Bifunctional Catalysis 238\u003c\/p\u003e \u003cp\u003e3.3.5 Hemilable Trisoxazolines 240\u003c\/p\u003e \u003cp\u003e3.4 Asymmetric Multifunctional Multimetallic Catalysis 242\u003c\/p\u003e \u003cp\u003e3.4.1 Asymmetric Multifunctional Heteromultimetallic Catalysis 243\u003c\/p\u003e \u003cp\u003e3.4.2 Asymmetric Multifunctional Homomultimetallic Catalysis 251\u003c\/p\u003e \u003cp\u003e3.5 Anion-Enabled Bifunctional Asymmetric Catalysis 259\u003c\/p\u003e \u003cp\u003e3.5.1 Ammonium Fluorides or Metal Fluorides 262\u003c\/p\u003e \u003cp\u003e3.5.2 Metal Phosphates 265\u003c\/p\u003e \u003cp\u003e3.5.3 Metal Carboxylates 265\u003c\/p\u003e \u003cp\u003e3.5.4 Ammonium or Metal Aryloxides 269\u003c\/p\u003e \u003cp\u003e3.5.5 Hydroxides and Alkoxides 271\u003c\/p\u003e \u003cp\u003e3.5.6 Metal Amides 276\u003c\/p\u003e \u003cp\u003e3.6 Conclusion 277\u003c\/p\u003e \u003cp\u003eReferences 277\u003c\/p\u003e \u003cp\u003e4 Asymmetric Cooperative Catalysis 291\u003cbr\u003e Long Chen Yun-Lin Liu and Jian Zhou\u003c\/p\u003e \u003cp\u003e4.1 Introduction 291\u003c\/p\u003e \u003cp\u003e4.2 Catalytic Asymmetric Michael Addition Reaction 292\u003c\/p\u003e \u003cp\u003e4.2.1 Combining Multiple Metal Catalysts 292\u003c\/p\u003e \u003cp\u003e4.2.2 Combining Two Distinct Organocatalysts 293\u003c\/p\u003e \u003cp\u003e4.2.3 Combining Metal Catalyst with Organocatalyst 297\u003c\/p\u003e \u003cp\u003e4.3 Catalytic Asymmetric Mannich Reaction 299\u003c\/p\u003e \u003cp\u003e4.3.1 Combining Lewis Acid Catalyst and Brønsted Base Catalyst 300\u003c\/p\u003e \u003cp\u003e4.3.2 Combining Brønsted Acid Catalyst and Lewis Acid Catalyst 301\u003c\/p\u003e \u003cp\u003e4.3.3 Combining Brønsted Acid Catalyst and Secondary Amine Catalyst 303\u003c\/p\u003e \u003cp\u003e4.4 Catalytic Asymmetric Conia-Ene Reaction 304\u003c\/p\u003e \u003cp\u003e4.4.1 Combining Chiral Lewis Acid and Achiral Lewis Acid 304\u003c\/p\u003e \u003cp\u003e4.4.2 Combining Chiral Brønsted Base and Achiral Lewis Acid 306\u003c\/p\u003e \u003cp\u003e4.5 Catalytic Asymmetric Umpolung Reaction 307\u003c\/p\u003e \u003cp\u003e4.5.1 Combining NHC Catalyst and Lewis Acid Catalyst 307\u003c\/p\u003e \u003cp\u003e4.5.2 Combining NHC Catalyst and Brønsted Acid Catalyst 313\u003c\/p\u003e \u003cp\u003e4.6 Catalytic Asymmetric Cyanosilylation Reaction 315\u003c\/p\u003e \u003cp\u003e4.7 α-Alkylation Reaction of Carbonyl Compounds 317\u003c\/p\u003e \u003cp\u003e4.7.1 α-Alkylation of Carbonyl Compounds using Alcohols as Alkylation Reagents 317\u003c\/p\u003e \u003cp\u003e4.7.2 α-Alkylation of Carbonyl Compounds through Benzylic C H Bond Oxidation 325\u003c\/p\u003e \u003cp\u003e4.8 Catalytic Asymmetric Allylic Alkylation Reaction 326\u003c\/p\u003e \u003cp\u003e4.8.1 Combining Achiral Transition Metal with Chiral LUMO-Lowering Catalysis 327\u003c\/p\u003e \u003cp\u003e4.8.2 Combining Chiral Transition Metal Catalysis with Achiral Organocatalyst 331\u003c\/p\u003e \u003cp\u003e4.9 Catalytic Asymmetric Aldol-Type Reaction 335\u003c\/p\u003e \u003cp\u003e4.10 Catalytic Asymmetric (Aza)-Morita–Baylis–Hillman Reaction 338\u003c\/p\u003e \u003cp\u003e4.10.1 Chiral Lewis Base\/Achiral Acid Cocatalyzed (aza)-MBH Reaction 341\u003c\/p\u003e \u003cp\u003e4.10.2 Achiral Lewis Base\/Chiral Acid Cocatalyzed (aza)-MBH Reaction 342\u003c\/p\u003e \u003cp\u003e4.11 Catalytic Asymmetric Hydrogenation Reaction 346\u003c\/p\u003e \u003cp\u003e4.12 Catalytic Asymmetric Cycloaddition Reaction 350\u003c\/p\u003e \u003cp\u003e4.12.1 [2 + 2] Reaction 351\u003c\/p\u003e \u003cp\u003e4.12.2 [4 + 2] Reaction 352\u003c\/p\u003e \u003cp\u003e4.13 Catalytic Asymmetric N H Insertion Reaction 356\u003c\/p\u003e \u003cp\u003e4.14 Catalytic Asymmetric α-Functionalization of Aldehydes 358\u003c\/p\u003e \u003cp\u003e4.15 Miscellaneous Reaction 360\u003c\/p\u003e \u003cp\u003e4.16 Conclusion 364\u003c\/p\u003e \u003cp\u003eReferences 365\u003c\/p\u003e \u003cp\u003e5 Asymmetric Double Activation Catalysis by Multicatalyst System 373\u003cbr\u003e Long Chen Zhong-Yan Cao and Jian Zhou\u003c\/p\u003e \u003cp\u003e5.1 Introduction 373\u003c\/p\u003e \u003cp\u003e5.2 Double Activation by Aminocatalysis and Lewis Base Catalysis 374\u003c\/p\u003e \u003cp\u003e5.3 Asymmetric Double Primary Amine and Brønsted Acid Catalysis 378\u003c\/p\u003e \u003cp\u003e5.3.1 Diels–Alder (DA)Reaction 379\u003c\/p\u003e \u003cp\u003e5.3.2 Michael Addition 379\u003c\/p\u003e \u003cp\u003e5.3.3 Epoxidation 386\u003c\/p\u003e \u003cp\u003e5.3.4 Miscellaneous Reaction 390\u003c\/p\u003e \u003cp\u003e5.4 Asymmetric Double Metal and Brønsted Base Catalysis 391\u003c\/p\u003e \u003cp\u003e\u003cbr\u003e 5.4.1 [3 + 2] Cycloaddition 392\u003c\/p\u003e \u003cp\u003e5.4.2 Aldol Reaction 396\u003c\/p\u003e \u003cp\u003e5.4.3 Miscellaneous Reactions 399\u003c\/p\u003e \u003cp\u003e5.5 Asymmetric H-Bond Donor Catalysis and Lewis Base Catalysis 401\u003c\/p\u003e \u003cp\u003e5.6 Sequential Double Activation Catalysis 404\u003c\/p\u003e \u003cp\u003e5.7 Conclusion 408\u003c\/p\u003e \u003cp\u003eReferences 408\u003c\/p\u003e \u003cp\u003e6 Asymmetric Assisted Catalysis by Multicatalyst System 411\u003cbr\u003e Xing-Ping Zeng and Jian Zhou\u003c\/p\u003e \u003cp\u003e6.1 Introduction 411\u003c\/p\u003e \u003cp\u003e6.2 Asymmetric Assisted Catalysis within Acids and Bases 414\u003c\/p\u003e \u003cp\u003e6.2.1 Acid Assisted Acid Catalysis 415\u003c\/p\u003e \u003cp\u003e6.2.2 Base Assisted Brønsted Acid Catalysis 433\u003c\/p\u003e \u003cp\u003e6.2.3 Lewis Base Assisted Brønsted Base Catalysis 435\u003c\/p\u003e \u003cp\u003e6.2.4 Acid Assisted Base Catalysis 437\u003c\/p\u003e \u003cp\u003e6.2.5 Miscellaneous 439\u003c\/p\u003e \u003cp\u003e6.3 Modulation of a Metal Complex by a Chiral Ligand 443\u003c\/p\u003e \u003cp\u003e6.3.1 Modulation of a Chiral Metal Complex with a Chiral Ligand 444\u003c\/p\u003e \u003cp\u003e6.3.2 Asymmetric Deactivation Activation and Deactivation\/Activation 451\u003c\/p\u003e \u003cp\u003e6.3.3 Asymmetric Activation of Racemic Catalysts Bearing Tropos Ligand 460\u003c\/p\u003e \u003cp\u003e6.4 Supramolecular-Type Assisted Catalysis 462\u003c\/p\u003e \u003cp\u003e6.5 Conclusion 469\u003c\/p\u003e \u003cp\u003eReferences 469\u003c\/p\u003e \u003cp\u003e7 Asymmetric Catalysis Facilitated by Photochemical or Electrochemical Methods 475\u003cbr\u003e Zhong-Yan Cao and Jian Zhou\u003c\/p\u003e \u003cp\u003e7.1 Introduction 475\u003c\/p\u003e \u003cp\u003e7.2 Catalytic Asymmetric Reaction Facilitated by Photochemical Method 476\u003c\/p\u003e \u003cp\u003e7.2.1 Asymmetric Oxidation Reactions 477\u003c\/p\u003e \u003cp\u003e7.2.2 α-Functionalization of Tertiary Amines 479\u003c\/p\u003e \u003cp\u003e7.2.3 α-Functionalization of Aldehydes 482\u003c\/p\u003e \u003cp\u003e7.2.4 [2 + 2] Photocycloaddition Reaction 488\u003c\/p\u003e \u003cp\u003e7.2.5 Miscellaneous Reactions 489\u003c\/p\u003e \u003cp\u003e7.3 Catalytic Asymmetric Reactions Facilitated by Electrochemical Method 493\u003c\/p\u003e \u003cp\u003e7.4 Conclusion 497\u003c\/p\u003e \u003cp\u003eReferences 498\u003c\/p\u003e \u003cp\u003e8 Multicatalyst System Realized Asymmetric Tandem Reactions 501\u003cbr\u003e Feng Zhou Yun-Lin Liu and Jian Zhou\u003c\/p\u003e \u003cp\u003e8.1 Introduction 501\u003c\/p\u003e \u003cp\u003e8.1.1 Basic Models of MSRATR 502\u003c\/p\u003e \u003cp\u003e8.1.2 Challenges and Solutions for the Development of MSRATR 507\u003c\/p\u003e \u003cp\u003e8.2 Multicatalyst Systems of Homocombination 509\u003c\/p\u003e \u003cp\u003e8.2.1 By Multiple Metal Catalysts 509\u003c\/p\u003e \u003cp\u003e8.2.2 By Multiple Organocatalysts 522\u003c\/p\u003e \u003cp\u003e8.2.3 By Multiple Enzymes 558\u003c\/p\u003e \u003cp\u003e8.3 Hetero Combination System Realized MSRATR 566\u003c\/p\u003e \u003cp\u003e8.3.1 By Combination of Metal and Organocatalysts 566\u003c\/p\u003e \u003cp\u003e8.3.2 By Combination of Metal Catalysis and Biocatalysis 604\u003c\/p\u003e \u003cp\u003e8.3.3 By Combination of Organocatalysis and Biocatalysis 620\u003c\/p\u003e \u003cp\u003e8.4 Conclusion 622\u003c\/p\u003e \u003cp\u003eReferences 623\u003c\/p\u003e \u003cp\u003e9 Waste-Mediated Reactions 633\u003cbr\u003e Jian Zhou and Xing-Ping Zeng\u003c\/p\u003e \u003cp\u003e9.1 Introduction 633\u003c\/p\u003e \u003cp\u003e9.2 Historical Background 636\u003c\/p\u003e \u003cp\u003e9.3 Waste-Promoted Single Reactions 637\u003c\/p\u003e \u003cp\u003e9.3.1 Waste Act as a Brønsted Base 638\u003c\/p\u003e \u003cp\u003e9.3.2 By-product as Lewis Base 649\u003c\/p\u003e \u003cp\u003e9.4 By-Products as Acidic Promoter 653\u003c\/p\u003e \u003cp\u003e9.5 Waste-Promoted Tandem Reactions 654\u003c\/p\u003e \u003cp\u003e9.6 Waste-Catalyzed Tandem Reactions 657\u003c\/p\u003e \u003cp\u003e9.7 Conclusions 666\u003c\/p\u003e \u003cp\u003eReferences 667\u003c\/p\u003e \u003cp\u003e10 Multicatalyst System Mediated Asymmetric Reactions in Total Synthesis 671\u003cbr\u003e Yun-Lin Liu and Jian Zhou\u003c\/p\u003e \u003cp\u003e10.1 Introduction 671\u003c\/p\u003e \u003cp\u003e10.2 Application of Multicatalyst System Mediated Single Reactions 672\u003c\/p\u003e \u003cp\u003e10.3 Application of Multicatalyst Mediated Tandem Reaction 677\u003c\/p\u003e \u003cp\u003e10.4 Conclusion 685\u003c\/p\u003e \u003cp\u003eReferences 686\u003c\/p\u003e \u003cp\u003eIndex 689\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49406826086743,"sku":"9781118071861","price":141.26,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781118071861.jpg?v=1730497247","url":"https:\/\/bookcurl.com\/products\/multicatalyst-system-in-asymmetric-catalysis-9781118071861","provider":"Book Curl","version":"1.0","type":"link"}