{"product_id":"molecular-encapsulation-9780470998076","title":"Molecular Encapsulation","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe inclusion of small guest molecules within suitable host compounds results in constrained systems that imbue novel properties upon the incarcerated organic substrates. Supramolecular tactics are becoming widely employed and this treatise spotlights them. Often, the impact of encapsulation on product formation is substantial. The use of constrained systems offers the means to steer reactions along desired pathways. A broad overview of various supramolecular approaches aimed to manipulate chemical reactions are featured.  \u003cp\u003eThe following topics are covered in detail:\u003c\/p\u003e \u003cp\u003e- general concepts governing the assembly of the substrate with the reaction vessel\u003c\/p\u003e \u003cp\u003e- preparation of molecular reactors\u003c\/p\u003e \u003cp\u003e- stabilization of reactive intermediates\u003c\/p\u003e \u003cp\u003e- reactions in water, in organic solvents, and in the solid state\u003c\/p\u003e \u003cp\u003e- photochemical reactions\u003c\/p\u003e \u003cp\u003e- reactions with unusual regioselectivity\u003c\/p\u003e \u003cp\u003e\u003ci\u003eMolecular Encapsulation: Organic Reactions in Constrained Systems\u003c\/i\u003e is an \u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\"The book has a broad scope and serves its purpose very well for everyone who is interested in the preparation of molecular reactors, the stabilization of reactive intermediates, reactions of unusual regioselectivity, confined photochemical reactions, or supramolecularly enhanced reactions in water, organic solvents, or the solid state. Thus, the book is well suited both for beginners and for experts, and it is an essential addition to the bookshelf of a supramolecular chemist.\" (Angewandte Chemie, 1 February 2011)  \u003c\/p\u003e\u003cp\u003e \u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cb\u003ePreface page.\u003c\/b\u003e  \u003cp\u003e\u003cb\u003eList of Contributors.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Reaction Control by Molecular Recognition – A Survey from the Photochemical Perspective\u003c\/b\u003e (\u003ci\u003eCheng Yang, Chenfeng Ke, Yu Liu, and Yoshihisa Inoue\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e1.1 Introduction.\u003c\/p\u003e \u003cp\u003e1.2 Photochemical Reactions Mediated by Macrocyclic Compounds.\u003c\/p\u003e \u003cp\u003e1.3 Photochemical Reactions with Biomolecules.\u003c\/p\u003e \u003cp\u003e1.4 Photochemical Reactions with Confined Cages Based on Inorganic and Organic–Inorganic Hybrid Materials.\u003c\/p\u003e \u003cp\u003e1.5 Photochemical Reactions with other Artificial Hosts.\u003c\/p\u003e \u003cp\u003e1.6 Photoreaction Control by External Variants.\u003c\/p\u003e \u003cp\u003e1.7 Conclusions.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Cyclodextrins\u003c\/b\u003e (\u003ci\u003eRonald Breslow\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Acylations of the Cyclodextrins by Bound Substrates.\u003c\/p\u003e \u003cp\u003e2.3 Catalytic Reactions in Cyclodextrin Cavities: Aromatic Substitution.\u003c\/p\u003e \u003cp\u003e2.4 Other Solvents than Water.\u003c\/p\u003e \u003cp\u003e2.5 Catalytic Reactions Produced by Cyclodextrins With Covalently Attached Catalytic Groups.\u003c\/p\u003e \u003cp\u003e2.6 Binding by Cyclodextrins and their Dimers and Trimers.\u003c\/p\u003e \u003cp\u003e2.7 Mimics of Enzymes that Use Thiamine Pyrophosphate as a Co-Enzyme.\u003c\/p\u003e \u003cp\u003e2.8 Aldol Condensations Catalysed by Cyclodextrin Derivatives.\u003c\/p\u003e \u003cp\u003e2.9 Mimics of Enzymes Using Coenzyme B12 as a Cofactor.\u003c\/p\u003e \u003cp\u003e2.10 Mimics of Cytochrome P-450.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Cyclodextrins as Molecular Reactors\u003c\/b\u003e (\u003ci\u003eChristopher J. Easton and Hideki Onagi\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 Regiocontrolled Electrophilic Aromatic Substitutions.\u003c\/p\u003e \u003cp\u003e3.3 Catalysis of Hydrolytic Reactions.\u003c\/p\u003e \u003cp\u003e3.4 A Molecular Reactor for the Synthesis of Indigoid Dyes.\u003c\/p\u003e \u003cp\u003e3.5 Manipulation of Cycloadditions.\u003c\/p\u003e \u003cp\u003e3.6 Conclusion.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Reactions Mediated by Cyclodextrins\u003c\/b\u003e (\u003ci\u003eKeiko Takahashi\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e4.1 Introduction.\u003c\/p\u003e \u003cp\u003e4.2 The Inclusion Phenomena of Cyclodextrins.\u003c\/p\u003e \u003cp\u003e4.3 Origin of Microvessels as Molecular Flasks.\u003c\/p\u003e \u003cp\u003e4.4 Organic Reactions Mediated by CD in Water.\u003c\/p\u003e \u003cp\u003e4.5 Conclusion.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Reactions in Zeolites\u003c\/b\u003e (\u003ci\u003eStéphane Walspurger and Jean Sommer\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e5.1 The Confi nement Effect.\u003c\/p\u003e \u003cp\u003e5.2 Superelectrophilic Activation in Zeolites.\u003c\/p\u003e \u003cp\u003e5.3 Huisgen [3+2]-Cycloadditions.\u003c\/p\u003e \u003cp\u003e5.4 Multicomponent Reactions.\u003c\/p\u003e \u003cp\u003e5.5 Conclusion.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Chemistry in Self-Assembled Nanoreactors\u003c\/b\u003e (\u003ci\u003eJarl Ivar van der Vlugt, Tehila S. Koblenz, Jeroen Wassenaar, and Joost N. H. Reek\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e6.1 Introduction.\u003c\/p\u003e \u003cp\u003e6.2 Self-Assembled Nanocapsules.\u003c\/p\u003e \u003cp\u003e6.3 Encapsulation Effects in Catalysis.\u003c\/p\u003e \u003cp\u003e6.4 Hydrogen Bonded Capsules.\u003c\/p\u003e \u003cp\u003e6.5 Capsules Based on Metal–Ligand Interactions.\u003c\/p\u003e \u003cp\u003e6.6 Tetrahedral Cages Based on Octahedral M3+ Ions.\u003c\/p\u003e \u003cp\u003e6.7 Octahedral and Square Pyramidal Cages Based on Square-Planar M2+ Ions.\u003c\/p\u003e \u003cp\u003e6.8 Hydrophobic Effects as the Driving Force for the Self-Assembly of Nanocapsules.\u003c\/p\u003e \u003cp\u003e6.9 Ligand Template Approach Using Lewis Acid\/Base Interactions.\u003c\/p\u003e \u003cp\u003e6.10 Virus Capsids, Proteins and Micellar Systems.\u003c\/p\u003e \u003cp\u003e6.11 Micellar Systems.\u003c\/p\u003e \u003cp\u003e6.12 Conclusions and Outlook.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Concave Reagents\u003c\/b\u003e (\u003ci\u003eUlrich Lü\u003c\/i\u003e\u003ci\u003ening\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e7.1 Introduction.\u003c\/p\u003e \u003cp\u003e7.2 Classes of Concave Reagents.\u003c\/p\u003e \u003cp\u003e7.3 Reactions and Catalyses.\u003c\/p\u003e \u003cp\u003e7.4 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Reactivity Control by Calixarenes\u003c\/b\u003e (\u003ci\u003eLuigi Mandolini, Roberta Cacciapaglia, and Stefano Di Stefano\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e8.1 Introduction.\u003c\/p\u003e \u003cp\u003e8.2 Calixarenes as Hosts.\u003c\/p\u003e \u003cp\u003e8.3 Calixarenes as Molecular Platforms.\u003c\/p\u003e \u003cp\u003e8.4 Concluding Remarks.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Reactions Inside Carcerands\u003c\/b\u003e (\u003ci\u003eRalf Warmuth\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e9.1 Introduction.\u003c\/p\u003e \u003cp\u003e9.2 Types of Inner Phase Reactions.\u003c\/p\u003e \u003cp\u003e9.3 Probing the Properties of the Inner Phase.\u003c\/p\u003e \u003cp\u003e9.4 Through-Shell Reactions.\u003c\/p\u003e \u003cp\u003e9.5 Intramolecular Thermal Reactions.\u003c\/p\u003e \u003cp\u003e9.6 Inner Phase Photochemistry.\u003c\/p\u003e \u003cp\u003e9.7 Conclusions and Outlook.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Encapsulation of Reactive Intermediates\u003c\/b\u003e (\u003ci\u003eJean-Luc Mieusset and Udo H. Brinker\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e10.1 Introduction.\u003c\/p\u003e \u003cp\u003e10.2 Encapsulation of Labile Species.\u003c\/p\u003e \u003cp\u003e10.3 Isolation of Non-covalently Bonded Aggregates.\u003c\/p\u003e \u003cp\u003e10.4 Inclusion of Reactive Intermediates.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Dye Encapsulation\u003c\/b\u003e (\u003ci\u003eJeremiah J. Gassensmith, Easwaran Arunkumar, and Bradley D. Smith\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e11.1 Introduction.\u003c\/p\u003e \u003cp\u003e11.2 Reversible Dye Encapsulation Inside Organic Container Molecules.\u003c\/p\u003e \u003cp\u003e11.3 Reversible Dye Encapsulation by Biological Receptors.\u003c\/p\u003e \u003cp\u003e11.4 Permanent Dye Encapsulation Inside Rotaxanes.\u003c\/p\u003e \u003cp\u003e11.5 Permanent Encapsulation Inside Inorganic Matrices.\u003c\/p\u003e \u003cp\u003e11.6 Conclusion.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Organic Cations in Constrained Systems\u003c\/b\u003e (\u003ci\u003eWerner Abraham and Lutz Grubert\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e12.1 Introduction.\u003c\/p\u003e \u003cp\u003e12.2 Host–guest Complexes with Organic Cations.\u003c\/p\u003e \u003cp\u003e12.3 Extended Hosts and Capsules.\u003c\/p\u003e \u003cp\u003e12.4 Cucurbiturils.\u003c\/p\u003e \u003cp\u003e12.5 Complex Systems and Applications.\u003c\/p\u003e \u003cp\u003e12.6 Conclusions.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Proteins as Host for Enantioselective Catalysis: Artificial Metalloenzymes Based on the Biotin–Streptavidin Technology\u003c\/b\u003e (\u003ci\u003eJincheng Mao and Thomas R. Ward\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e13.1 Introduction.\u003c\/p\u003e \u003cp\u003e13.2 The Biotin–Avidin Technology.\u003c\/p\u003e \u003cp\u003e13.3 Artifi cial Hydrogenases.\u003c\/p\u003e \u003cp\u003e13.4 Artifi cial Allylic Alkylases.\u003c\/p\u003e \u003cp\u003e13.5 Artifi cial Transfer Hydrogenase.\u003c\/p\u003e \u003cp\u003e13.6 Enantioselective Sulfoxidation Based on Vanadyl-loaded Streptavidin 372\u003c\/p\u003e \u003cp\u003e13.7 Conclusions and Outlook.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Chemical Reactions with RNA and DNA Enzymes\u003c\/b\u003e (\u003ci\u003eAndres Jä\u003c\/i\u003e\u003ci\u003eschke\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e14.1 Introduction.\u003c\/p\u003e \u003cp\u003e14.2 Catalysis by Naturally Occurring Ribozymes.\u003c\/p\u003e \u003cp\u003e14.3 How to Generate Artifi cial RNA and DNA Catalysts.\u003c\/p\u003e \u003cp\u003e14.4 The Catalytic Spectrum of Artifi cial Ribozymes.\u003c\/p\u003e \u003cp\u003e14.5 Deoxyribozymes – DNA Molecules with Catalytic Properties.\u003c\/p\u003e \u003cp\u003e14.6 Catalysis of C−C Bond Formation by Diels–Alderase Ribozymes.\u003c\/p\u003e \u003cp\u003e14.7 Conclusion.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Reactions in Supramolecular Systems\u003c\/b\u003e (\u003ci\u003eLucia Zakharova, Alla Mirgorodskaya, Elena Zhiltsova, Ludmila Kudryavtseva, and Alexander Konovalov\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e15.1 Introduction.\u003c\/p\u003e \u003cp\u003e15.2 The Single Micellar Systems: Factors of Concentration and Micellar Microenvironment.\u003c\/p\u003e \u003cp\u003e15.3 The Role of the Structural Factor in Supramolecular Catalytic Systems.\u003c\/p\u003e \u003cp\u003e15.4 Binary Surfactant Systems.\u003c\/p\u003e \u003cp\u003e15.5 Polycomponent Catalytic Systems Based on Amphiphiles and Polymers.\u003c\/p\u003e \u003cp\u003e15.6 Conclusions.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Encapsulation Processes by Bilayer Vesicles\u003c\/b\u003e (\u003ci\u003eMarc C. A. Stuart and Jan B. F. N. Engberts\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e16.1 Introduction.\u003c\/p\u003e \u003cp\u003e16.2 Catalysis by Vesicles. Encapsulation of Reactants.\u003c\/p\u003e \u003cp\u003e16.3 Liposomal Encapsulation in Drug Delivery.\u003c\/p\u003e \u003cp\u003e16.4 Vesicle–Nucleic Acid Interactions: Gene Transfer Using Lipoplexes.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Reactions in Liposomes\u003c\/b\u003e (\u003ci\u003ePasquale Stano and Pier Luigi Luisi\u003c\/i\u003e).\u003c\/p\u003e \u003cp\u003e17.1 Introduction.\u003c\/p\u003e \u003cp\u003e17.2 Lipid Vesicles (Liposomes).\u003c\/p\u003e \u003cp\u003e17.3 Experimental Strategies and Theoretical Aspects.\u003c\/p\u003e \u003cp\u003e17.4 A Theoretical Framework for Complex Reactions in Liposomes.\u003c\/p\u003e \u003cp\u003e17.5 Four Cases of Compartmentalized Reactions.\u003c\/p\u003e \u003cp\u003e17.6 Conclusion.\u003c\/p\u003e \u003cp\u003eAcknowledgements.\u003c\/p\u003e \u003cp\u003eAbbreviations.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49525399748951,"sku":"9780470998076","price":142.45,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780470998076.jpg?v=1731860366","url":"https:\/\/bookcurl.com\/products\/molecular-encapsulation-9780470998076","provider":"Book Curl","version":"1.0","type":"link"}