{"product_id":"membrane-materials-for-gas-and-separation-9781119112716","title":"Membrane Materials for Gas and Separation","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eSi containing polymers have been instrumental in the development of membrane gas separation practices since the early 1970s. Their function is to provide a selective barrier for different molecular species, where selection takes place either on the basis of size or on the basis of physical interactions or both. \u003c\/p\u003e \u003cul\u003e \u003cli\u003eCombines membrane science, organosilicon chemistry, polymer science, materials science, and physical chemistry\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e\u003c\/p\u003e \u003cul\u003e \u003cli\u003eOnly book to consider polymerization chemistry and synthesis of Si-containing polymers (both glassy and rubbery), and their role as membrane materials\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e\u003c\/p\u003e \u003cul\u003e \u003cli\u003eMembrane operations present environmental benefits such as reduced waste, and recovered\/recycled valuable raw materials that are currently lost to fuel or to flares\u003c\/li\u003e \u003c\/ul\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eContributors xi\u003c\/p\u003e \u003cp\u003ePreface xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Permeability of Polymers 1\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eYuri Yampolskii\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Detailed mechanism of sorption and transport 3\u003c\/p\u003e \u003cp\u003e1.2.1 Transition-state model 3\u003c\/p\u003e \u003cp\u003e1.2.2 Free volume model 4\u003c\/p\u003e \u003cp\u003e1.2.3 Sorption isotherms 5\u003c\/p\u003e \u003cp\u003e1.3 Concentration dependence of permeability and diffusion coefficients 6\u003c\/p\u003e \u003cp\u003e1.4 Effects of properties of gases and polymers on permeation parameters 10\u003c\/p\u003e \u003cp\u003eAcknowledgement 13\u003c\/p\u003e \u003cp\u003eReferences 13\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Organosiloxanes (Silicones), Polyorganosiloxane Block Copolymers: Synthesis, Properties, and Gas Permeation Membranes Based on Them 17\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eIgor Raygorodsky, Victor Kopylov, and Alexander Kovyazin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 17\u003c\/p\u003e \u003cp\u003e2.2 Synthesis and transformations of organosiloxanes 17\u003c\/p\u003e \u003cp\u003e2.2.1 Polyorganosiloxanes with aminoalkyl groups at silicon 19\u003c\/p\u003e \u003cp\u003e2.2.2 Organosilicon alcohols and phenols 21\u003c\/p\u003e \u003cp\u003e2.3 Synthesis of polyorganosiloxane block copolymers 23\u003c\/p\u003e \u003cp\u003e2.3.1 Polyester(ether)–polyorganosiloxane block copolymers 24\u003c\/p\u003e \u003cp\u003e2.3.2 Synthesis of polyurethane–, polyurea–, polyamide–, polyimide– organosiloxane POBCs 25\u003c\/p\u003e \u003cp\u003e2.4 Properties of polyorganosiloxane block copolymers 29\u003c\/p\u003e \u003cp\u003e2.4.1 Phase state of polyblock organosiloxane copolymers 29\u003c\/p\u003e \u003cp\u003e2.5 Morphology of POBCs and its effects on their diffusion properties 30\u003c\/p\u003e \u003cp\u003e2.5.1 Types of heterogeneous structure 30\u003c\/p\u003e \u003cp\u003e2.6 Some representatives of POBC as membrane materials and their properties 32\u003c\/p\u003e \u003cp\u003e2.6.1 Polycarbonate–polysiloxanes 32\u003c\/p\u003e \u003cp\u003e2.6.2 Polyurethane(urea)–polysiloxanes 39\u003c\/p\u003e \u003cp\u003e2.6.3 Polyimide(amide)–polysiloxanes 42\u003c\/p\u003e \u003cp\u003e2.7 Conclusions 45\u003c\/p\u003e \u003cp\u003eReferences 46\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Polysilalkylenes 53\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eNikolay V. Ushakov, Stepan Guselnikov, and Eugene Finkelshtein\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eAcknowledgement 65\u003c\/p\u003e \u003cp\u003eReferences 65\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Polyvinylorganosilanes: The Materials for Membrane Gas Separation 69\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eNikolay V. Ushakov\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction: Historical background 69\u003c\/p\u003e \u003cp\u003e4.2 Syntheses and polymerization of vinyltriorganosilanes 71\u003c\/p\u003e \u003cp\u003e4.2.1 Syntheses of vinyltriorganosilanes 71\u003c\/p\u003e \u003cp\u003e4.2.2 Vinyltriorganosilane (VTOS) polymerization 73\u003c\/p\u003e \u003cp\u003e4.3 Physico-chemical and membrane properties of polymeric PVTOS materials 88\u003c\/p\u003e \u003cp\u003e4.4 Concluding remarks 94\u003c\/p\u003e \u003cp\u003eAcknowledgement 95\u003c\/p\u003e \u003cp\u003eReferences 95\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Substituted Polyacetylenes 107\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eToshikazu Sakaguchi, Yanming Hu, and Toshio Masuda\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 107\u003c\/p\u003e \u003cp\u003e5.2 Poly(1-trimethylsilyl-1-propyne) (PTMSP) and related polymers 110\u003c\/p\u003e \u003cp\u003e5.2.1 Synthesis and general properties 110\u003c\/p\u003e \u003cp\u003e5.2.2 Permeation of gases and liquids 112\u003c\/p\u003e \u003cp\u003e5.2.3 Aging effect and cross-linking 114\u003c\/p\u003e \u003cp\u003e5.2.4 Free volume 115\u003c\/p\u003e \u003cp\u003e5.2.5 Nanocomposites and hybrids 116\u003c\/p\u003e \u003cp\u003e5.3 Poly[1-phenyl-2-(p-trimethylsilylphenyl)acetylene] and related polymers 117\u003c\/p\u003e \u003cp\u003e5.3.1 Polymer synthesis 118\u003c\/p\u003e \u003cp\u003e5.3.2 Gas separation 121\u003c\/p\u003e \u003cp\u003e5.4 Desilylated polyacetylenes 124\u003c\/p\u003e \u003cp\u003e5.4.1 Desilylation of poly[1(p-trimethylsilylphenyl)-2-phenylacetylene] 124\u003c\/p\u003e \u003cp\u003e5.4.2 PDPAs from precursor polymers with various silyl groups 125\u003c\/p\u003e \u003cp\u003e5.4.3 Soluble poly(diphenylacetylene)s obtained by desilylation 127\u003c\/p\u003e \u003cp\u003e5.4.4 Poly(diarylacetylene)s 128\u003c\/p\u003e \u003cp\u003e5.5 Polar-group-containing polyacetylenes 130\u003c\/p\u003e \u003cp\u003e5.5.1 Hydroxy group 130\u003c\/p\u003e \u003cp\u003e5.5.2 Sulfonated and nitrated poly(diphenylacetylene)s 132\u003c\/p\u003e \u003cp\u003e5.5.3 Other polar groups 134\u003c\/p\u003e \u003cp\u003e5.6 Concluding remarks 135\u003c\/p\u003e \u003cp\u003eReferences 136\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Polynorbornenes 143\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eEugene Finkelshtein, Maria Gringolts, Maksim Bermeshev, Pavel Chapala, and Yulia Rogan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 143\u003c\/p\u003e \u003cp\u003e6.2 Monomer synthesis 144\u003c\/p\u003e \u003cp\u003e6.2.1 Synthesis of silicon-substituted norbornenes and norbornadienes 145\u003c\/p\u003e \u003cp\u003e6.2.2 Synthesis of Si-containing exo-tricyclo[4.2.1.02,5]non-7-enes 152\u003c\/p\u003e \u003cp\u003e6.3 Metathesis polynorbornenes 163\u003c\/p\u003e \u003cp\u003e6.4 Addition polymerization 183\u003c\/p\u003e \u003cp\u003e6.4.1 Addition polynorbornenes and polynorbornenes with alkyl side groups 184\u003c\/p\u003e \u003cp\u003e6.4.2 Silicon and germanium-substituted polynorbornenes 187\u003c\/p\u003e \u003cp\u003e6.4.3 Composites with addition silicon-containing polytricyclononenes 205\u003c\/p\u003e \u003cp\u003e6.5 Conclusions 209\u003c\/p\u003e \u003cp\u003eAcknowledgement 210\u003c\/p\u003e \u003cp\u003eReferences 210\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Polycondensation Materials Containing Bulky Side Groups: Synthesis and Transport Properties 223\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eSusanta Banerjee and Debaditya Bera\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 223\u003c\/p\u003e \u003cp\u003e7.2 Synthesis of the polymers 224\u003c\/p\u003e \u003cp\u003e7.2.1 Polyimides 224\u003c\/p\u003e \u003cp\u003e7.2.2 Poly(arylene ether)s (PAEs) 227\u003c\/p\u003e \u003cp\u003e7.2.3 Aromatic polyamides (PAs) 228\u003c\/p\u003e \u003cp\u003e7.3 Effect of different bulky groups on polymer gas transport properties 229\u003c\/p\u003e \u003cp\u003e7.3.1 Gas transport properties of the polyimides containing different bulky groups 229\u003c\/p\u003e \u003cp\u003e7.3.2 Gas transport properties of polyamides containing different bulky groups 241\u003c\/p\u003e \u003cp\u003e7.3.3 Gas transport properties of poly(arylene ether)s containing different bulky groups 248\u003c\/p\u003e \u003cp\u003e7.3.4 Concluding remarks 263\u003c\/p\u003e \u003cp\u003eReferences 265\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Gas and Vapor Transport Properties of Si-Containing and Related Polymers 271\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eYuri Yampolskii\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 271\u003c\/p\u003e \u003cp\u003e8.2 Rubbery Si-containing polymers 272\u003c\/p\u003e \u003cp\u003e8.2.1 Polysiloxanes 272\u003c\/p\u003e \u003cp\u003e8.2.2 Siloxane-containing copolymers (block copolymers, random copolymers and graft copolymers) 274\u003c\/p\u003e \u003cp\u003e8.2.3 Polysilmethylenes 277\u003c\/p\u003e \u003cp\u003e8.3 Glassy Si-containing polymers 278\u003c\/p\u003e \u003cp\u003e8.3.1 Polymers with Si–O–Si bonds in side chains 278\u003c\/p\u003e \u003cp\u003e8.3.2 Poly(vinyltrimethyl silane) and related vinylic polymers 282\u003c\/p\u003e \u003cp\u003e8.3.3 Metathesis norbornene polymers 285\u003c\/p\u003e \u003cp\u003e8.3.4 Additive norbornene polymers 286\u003c\/p\u003e \u003cp\u003e8.3.5 Polyacetylenes 290\u003c\/p\u003e \u003cp\u003e8.3.6 Other glassy Si-containing polymers 293\u003c\/p\u003e \u003cp\u003e8.4 Free volume in Si-containing polymers 294\u003c\/p\u003e \u003cp\u003e8.5 Concluding remarks 296\u003c\/p\u003e \u003cp\u003eAcknowledgement 298\u003c\/p\u003e \u003cp\u003eReferences 298\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Modeling of Si-Containing Polymers 307\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJoel R. Fried, Timothy Dubbs, and Morteza Azizi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 307\u003c\/p\u003e \u003cp\u003e9.2 Main-chain silicon-containing polymers 309\u003c\/p\u003e \u003cp\u003e9.2.1 Polysiloxanes 309\u003c\/p\u003e \u003cp\u003e9.2.2 Polysilanes and silalkylene polymers 314\u003c\/p\u003e \u003cp\u003e9.3 Side-chain silicon-containing polymers 316\u003c\/p\u003e \u003cp\u003e9.3.1 Poly(vinyltrimethylsilane) 316\u003c\/p\u003e \u003cp\u003e9.3.2 Poly[1-(trimethylsilyl)-1-propyne] 317\u003c\/p\u003e \u003cp\u003e9.4 Conclusions 324\u003c\/p\u003e \u003cp\u003eAppendices 325\u003c\/p\u003e \u003cp\u003e9.A Molecular flexibility 325\u003c\/p\u003e \u003cp\u003e9.B Simulation of diffusivity 325\u003c\/p\u003e \u003cp\u003e9.B.1 Einstein relationship 325\u003c\/p\u003e \u003cp\u003e9.B.2 VACF method 325\u003c\/p\u003e \u003cp\u003e9.C Simulation of solubility: Widom method 325\u003c\/p\u003e \u003cp\u003e9.D Molecular mechanics force fields 326\u003c\/p\u003e \u003cp\u003e9.D.1 DREIDING 326\u003c\/p\u003e \u003cp\u003e9.D.2 Polymer-consistent force field (pcff ) 326\u003c\/p\u003e \u003cp\u003e9.D.3 GROMOS 326\u003c\/p\u003e \u003cp\u003e9.D.4 COMPASS 326\u003c\/p\u003e \u003cp\u003eReferences 327\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Pervaporation and Evapomeation with Si-Containing Polymers 335\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eTadashi Uragami\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 335\u003c\/p\u003e \u003cp\u003e10.2 Structural design of Si-containing polymer membranes 335\u003c\/p\u003e \u003cp\u003e10.2.1 Chemical design of Si-containing polymer membrane materials 336\u003c\/p\u003e \u003cp\u003e10.2.2 Physical construction of Si-containing polymer membranes 336\u003c\/p\u003e \u003cp\u003e10.3 Pervaporation 337\u003c\/p\u003e \u003cp\u003e10.3.1 Principle of pervaporation 337\u003c\/p\u003e \u003cp\u003e10.3.2 Fundamentals of pervaporation 338\u003c\/p\u003e \u003cp\u003e10.3.3 Solution–diffusion model in pervaporation 339\u003c\/p\u003e \u003cp\u003e10.4 Evapomeation 340\u003c\/p\u003e \u003cp\u003e10.4.1 Principle of evapomeation 340\u003c\/p\u003e \u003cp\u003e10.4.2 Principle of temperature-difference controlled evapomeation 341\u003c\/p\u003e \u003cp\u003e10.5 Technology of pervaporation with Si-containing polymer membranes 342\u003c\/p\u003e \u003cp\u003e10.5.1 Alcohol permselective membranes 342\u003c\/p\u003e \u003cp\u003e10.5.2 Hydrocarbon permselective membranes 353\u003c\/p\u003e \u003cp\u003e10.5.3 Organic permselective membranes 360\u003c\/p\u003e \u003cp\u003e10.5.4 Membranes for separation of organic–organic mixtures 361\u003c\/p\u003e \u003cp\u003e10.5.5 Membranes for optical resolution 362\u003c\/p\u003e \u003cp\u003e10.6 Technology of evapomeation with Si-containing polymer membranes 363\u003c\/p\u003e \u003cp\u003e10.6.1 Permeation and separation by evapomeation 363\u003c\/p\u003e \u003cp\u003e10.6.2 Concentration of ethanol by temperature-difference controlled evapomeation 364\u003c\/p\u003e \u003cp\u003e10.7 Conclusions 365\u003c\/p\u003e \u003cp\u003eReferences 365\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Si-Containing Polymers in Membrane Gas Separation 373\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eAdele Brunetti, Leonardo Melone, Enrico Drioli, and Giuseppe Barbieri\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eExecutive summary 373\u003c\/p\u003e \u003cp\u003e11.1 Introduction 373\u003c\/p\u003e \u003cp\u003e11.2 Si-containing polymer membranes used in gas separation 375\u003c\/p\u003e \u003cp\u003e11.2.1 Silicon rubber membrane materials 375\u003c\/p\u003e \u003cp\u003e11.2.2 Polyacetylene membrane materials 376\u003c\/p\u003e \u003cp\u003e11.2.3 Polynorbornene membrane materials 378\u003c\/p\u003e \u003cp\u003e11.2.4 Other Si-containing membrane materials 378\u003c\/p\u003e \u003cp\u003e11.3 Separations 379\u003c\/p\u003e \u003cp\u003e11.4 Membrane modules 381\u003c\/p\u003e \u003cp\u003e11.5 Competing technologies for separation of gases 384\u003c\/p\u003e \u003cp\u003e11.6 Applications 385\u003c\/p\u003e \u003cp\u003e11.6.1 Air separation 385\u003c\/p\u003e \u003cp\u003e11.6.2 Hydrogen separation 386\u003c\/p\u003e \u003cp\u003e11.6.3 Hydrocarbon separation 390\u003c\/p\u003e \u003cp\u003e11.6.4 VOC separation 392\u003c\/p\u003e \u003cp\u003eReferences 393\u003c\/p\u003e \u003cp\u003eIndex 399\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49528847204695,"sku":"9781119112716","price":135.8,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119112716.jpg?v=1731873257","url":"https:\/\/bookcurl.com\/products\/membrane-materials-for-gas-and-separation-9781119112716","provider":"Book Curl","version":"1.0","type":"link"}