{"product_id":"materials-thermodynamics-9780470484142","title":"Materials Thermodynamics","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eMuch needed update in field, with respected existing texts dating back almost 60 years and inaccessible for today's student. Teaches Alloy Thermodynamics using a broader,   applications driven text with a more industry-oriented lens than any other book on the market, preparing students for the real world.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003eQuantities, Units, and Nomenclature xix\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Review of Fundamentals 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Systems, Surroundings, and Work 2\u003c\/p\u003e \u003cp\u003e1.2 Thermodynamic Properties 4\u003c\/p\u003e \u003cp\u003e1.3 The Laws of Thermodynamics 5\u003c\/p\u003e \u003cp\u003e1.4 The Fundamental Equation 8\u003c\/p\u003e \u003cp\u003e1.5 Other Thermodynamic Functions 9\u003c\/p\u003e \u003cp\u003e1.5.1 Maxwell’s Equations 11\u003c\/p\u003e \u003cp\u003e1.5.2 Defining Other Forms of Work 11\u003c\/p\u003e \u003cp\u003e1.6 Equilibrium State 14\u003c\/p\u003e \u003cp\u003eExercises 15\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Thermodynamics of Unary Systems 19\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Standard State Properties 19\u003c\/p\u003e \u003cp\u003e2.2 The Effect of Pressure 27\u003c\/p\u003e \u003cp\u003e2.2.1 Gases 28\u003c\/p\u003e \u003cp\u003e2.2.2 Condensed Phases 29\u003c\/p\u003e \u003cp\u003e2.3 The Gibbs–Duhem Equation 30\u003c\/p\u003e \u003cp\u003e2.4 Experimental Methods 31\u003c\/p\u003e \u003cp\u003eExercises 32\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Calculation of Thermodynamic Properties of Unary Systems 35\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Constant-Pressure\/Constant-Volume Conversions 36\u003c\/p\u003e \u003cp\u003e3.2 Excitations in Gases 37\u003c\/p\u003e \u003cp\u003e3.2.1 Perfect Monatomic Gas 37\u003c\/p\u003e \u003cp\u003e3.2.2 Molecular Gases 39\u003c\/p\u003e \u003cp\u003e3.3 Excitations in Pure Solids 39\u003c\/p\u003e \u003cp\u003e3.4 The Thermodynamic Properties of a Pure Solid 43\u003c\/p\u003e \u003cp\u003e3.4.1 Inadequacies of the Model 46\u003c\/p\u003e \u003cp\u003eExercises 46\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Phase Equilibria in Unary Systems 49\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 The Thermodynamic Condition for Phase Equilibrium 52\u003c\/p\u003e \u003cp\u003e4.2 Phase Changes 54\u003c\/p\u003e \u003cp\u003e4.2.1 The Slopes of Boundaries in Phase Diagrams 54\u003c\/p\u003e \u003cp\u003e4.2.2 Gibbs Energy Changes for Phase Transformations 57\u003c\/p\u003e \u003cp\u003e4.3 Stability and Critical Phenomena 59\u003c\/p\u003e \u003cp\u003e4.4 Gibbs’s Phase Rule 61\u003c\/p\u003e \u003cp\u003eExercises 63\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Thermodynamics of Binary Solutions I: Basic Theory and Application to Gas Mixtures 67\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Expressing Composition 67\u003c\/p\u003e \u003cp\u003e5.2 Total (Integral) and Partial Molar Quantities 68\u003c\/p\u003e \u003cp\u003e5.2.1 Relations between Partial and Integral Quantities 70\u003c\/p\u003e \u003cp\u003e5.2.2 Relation between Partial Quantities: the Gibbs–Duhem Equation 72\u003c\/p\u003e \u003cp\u003e5.3 Application to Gas Mixtures 73\u003c\/p\u003e \u003cp\u003e5.3.1 Partial Pressures 73\u003c\/p\u003e \u003cp\u003e5.3.2 Chemical Potentials in Perfect Gas Mixtures 74\u003c\/p\u003e \u003cp\u003e5.3.3 Real Gas Mixtures: Component Fugacities and Activities 75\u003c\/p\u003e \u003cp\u003eExercises 75\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Thermodynamics of Binary Solutions II: Theory and Experimental Methods 79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Ideal Solutions 79\u003c\/p\u003e \u003cp\u003e6.1.1 Real Solutions 82\u003c\/p\u003e \u003cp\u003e6.1.2 Dilute Solution Reference States 83\u003c\/p\u003e \u003cp\u003e6.2 Experimental Methods 85\u003c\/p\u003e \u003cp\u003e6.2.1 Chemical Potential Measurements 86\u003c\/p\u003e \u003cp\u003eExercises 89\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Thermodynamics of Binary Solutions III: Experimental Results and Their Analytical Representation 93\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Some Experimental Results 93\u003c\/p\u003e \u003cp\u003e7.1.1 Liquid Alloys 93\u003c\/p\u003e \u003cp\u003e7.1.2 Solid Alloys 95\u003c\/p\u003e \u003cp\u003e7.2 Analytical Representation of Results for Liquid or Solid Solutions 97\u003c\/p\u003e \u003cp\u003eExercises 102\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Two-Phase Equilibrium I: Theory 103\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 103\u003c\/p\u003e \u003cp\u003e8.2 Criterion for Phase Equilibrium Between Two Specified Phases 104\u003c\/p\u003e \u003cp\u003e8.2.1 Equilibrium between Two Solution Phases 104\u003c\/p\u003e \u003cp\u003e8.2.2 Equilibrium between a Solution Phase and a Stoichiometric Compound Phase 107\u003c\/p\u003e \u003cp\u003e8.3 Gibbs’s Phase Rule 108\u003c\/p\u003e \u003cp\u003eExercises 110\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Two-Phase Equilibrium II: Example Calculations 113\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExercises 121\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Binary Phase Diagrams: Temperature–Composition Diagrams 125\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 True Phase Diagrams 126\u003c\/p\u003e \u003cp\u003e10.2 T –x\u003csub\u003ei\u003c\/sub\u003e Phase Diagrams for Strictly Regular Solutions 128\u003c\/p\u003e \u003cp\u003e10.2.1 Some General Observations 131\u003c\/p\u003e \u003cp\u003e10.2.2 More on Miscibility Gaps 133\u003c\/p\u003e \u003cp\u003e10.2.3 The Chemical Spinodal 134\u003c\/p\u003e \u003cp\u003e10.3 Polymorphism 135\u003c\/p\u003e \u003cp\u003eExercises 136\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Binary Phase Diagrams: Temperature–Chemical Potential Diagrams 139\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Some General Points 140\u003c\/p\u003e \u003cp\u003eExercises 146\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Phase Diagram Topology 149\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Gibbs’s Phase Rule 151\u003c\/p\u003e \u003cp\u003e12.2 Combinatorial Analysis 151\u003c\/p\u003e \u003cp\u003e12.3 Schreinemaker’s Rules 153\u003c\/p\u003e \u003cp\u003e12.4 The Gibbs–Konovalov Equations 154\u003c\/p\u003e \u003cp\u003e12.4.1 Slopes of T –μ\u003csub\u003ei\u003c\/sub\u003e Phase Boundaries 155\u003c\/p\u003e \u003cp\u003e12.4.2 Slopes of T –x\u003csub\u003ei\u003c\/sub\u003e Phase Boundaries 157\u003c\/p\u003e \u003cp\u003e12.4.3 Some Applications of Gibbs–Konovalov Equations 159\u003c\/p\u003e \u003cp\u003eExercises 162\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Solution Phase Models I: Configurational Entropies 165\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Substitutional Solutions 168\u003c\/p\u003e \u003cp\u003e13.2 Intermediate Phases 169\u003c\/p\u003e \u003cp\u003e13.3 Interstitial Solutions 172\u003c\/p\u003e \u003cp\u003eExercises 174\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Solution Phase Models II: Configurational Energy 177\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Pair Interaction Model 178\u003c\/p\u003e \u003cp\u003e14.1.1 Ground-State Structures 179\u003c\/p\u003e \u003cp\u003e14.1.2 Nearest Neighbor Model 180\u003c\/p\u003e \u003cp\u003e14.2 Cluster Model 183\u003c\/p\u003e \u003cp\u003eExercises 188\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Solution Models III: The Configurational Free Energy 189\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Helmholtz Energy Minimization 190\u003c\/p\u003e \u003cp\u003e15.2 Critical Temperature for Order\/Disorder 193\u003c\/p\u003e \u003cp\u003eExercises 196\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Solution Models IV: Total Gibbs Energy 197\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Atomic Size Mismatch Contributions 199\u003c\/p\u003e \u003cp\u003e16.2 Contributions from Thermal Excitations 202\u003c\/p\u003e \u003cp\u003e16.2.1 Coupling between Configurational and Thermal Excitations 203\u003c\/p\u003e \u003cp\u003e16.3 The Total Gibbs Energy in Empirical Model Calculations 204\u003c\/p\u003e \u003cp\u003eExercises 205\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Chemical Equilibria I: Single Chemical Reaction Equations 207\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 207\u003c\/p\u003e \u003cp\u003e17.2 The Empirical Equilibrium Constant 207\u003c\/p\u003e \u003cp\u003e17.3 The Standard Equilibrium Constant 208\u003c\/p\u003e \u003cp\u003e17.3.1 Relation to Δ\u003csub\u003er\u003c\/sub\u003e G◦ 208\u003c\/p\u003e \u003cp\u003e17.3.2 Measurement of Δ\u003csub\u003er\u003c\/sub\u003e G◦ 211\u003c\/p\u003e \u003cp\u003e17.4 Calculating the Equilibrium Position 213\u003c\/p\u003e \u003cp\u003e17.5 Application of the Phase Rule 217\u003c\/p\u003e \u003cp\u003eExercises 218\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Chemical Equilibria II: Complex Gas Equilibria 221\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18.1 The Importance of System Definition 221\u003c\/p\u003e \u003cp\u003e18.2 Calculation of Chemical Equilibrium 224\u003c\/p\u003e \u003cp\u003e18.2.1 Using the Extent of Reaction 225\u003c\/p\u003e \u003cp\u003e18.2.2 Using Lagrangian Multipliers 227\u003c\/p\u003e \u003cp\u003e18.3 Evaluation of Elemental Chemical Potentials in Complex Gas Mixtures 229\u003c\/p\u003e \u003cp\u003e18.4 Application of the Phase Rule 231\u003c\/p\u003e \u003cp\u003eExercises 232\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Chemical Equilibria Between Gaseous and Condensed Phases I 233\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e19.1 Graphical Presentation of Standard Thermochemical Data 233\u003c\/p\u003e \u003cp\u003e19.2 Ellingham Diagrams 234\u003c\/p\u003e \u003cp\u003e19.2.1 Chemical Potentials 238\u003c\/p\u003e \u003cp\u003eExercises 240\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Chemical Equilibria Between Gaseous and Condensed Phases II 243\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e20.1 Subsidiary Scales on Ellingham Diagrams 244\u003c\/p\u003e \u003cp\u003e20.2 System Definition 247\u003c\/p\u003e \u003cp\u003eExercises 252\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 Thermodynamics of Ternary Systems 255\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e21.1 Analytical Representation of Thermodynamic Properties 256\u003c\/p\u003e \u003cp\u003e21.1.1 Substitutional Solution Phases 256\u003c\/p\u003e \u003cp\u003e21.1.2 Sublattice Phases 259\u003c\/p\u003e \u003cp\u003e21.2 Phase Equilibria 260\u003c\/p\u003e \u003cp\u003eExercises 264\u003c\/p\u003e \u003cp\u003e\u003cb\u003e22 Generalized Phase Diagrams for Ternary Systems 267\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e22.1 System Definition 276\u003c\/p\u003e \u003cp\u003eExercises 278\u003c\/p\u003e \u003cp\u003eAppendix A Some Linearized Standard Gibbs Energies of Formation 279\u003c\/p\u003e \u003cp\u003eAppendix B Some Useful Calculus 281\u003c\/p\u003e \u003cp\u003eIndex 289 \u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default 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