{"product_id":"main-group-strategies-towards-functional-hybrid-materials-9781119235972","title":"Main Group Strategies towards Functional Hybrid","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eShowcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials.    Main Group Strategies towards FunctionalHybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of bor\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eList of Contributors xv\u003c\/p\u003e \u003cp\u003ePreface xix\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Incorporation of Boron into π-Conjugated Scaffolds to Produce Electron-Accepting π-Electron Systems 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAtsushi Wakamiya\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Boron-Containing Five-Membered Rings: Boroles and Dibenzoboroles 2\u003c\/p\u003e \u003cp\u003e1.3 Annulated Boroles 8\u003c\/p\u003e \u003cp\u003e1.4 Boron-Containing Seven-Membered Rings: Borepins 11\u003c\/p\u003e \u003cp\u003e1.5 Boron-Containing Six-Membered Rings: Diborins 14\u003c\/p\u003e \u003cp\u003e1.6 Planarized Triphenylboranes and Boron-Doped Nanographenes 17\u003c\/p\u003e \u003cp\u003e1.7 Conclusion and Outlook 21\u003c\/p\u003e \u003cp\u003eReferences 22\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Organoborane Donor–Acceptor Materials 27\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSanjoy Mukherjee and Pakkirisamy Thilagar\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Organoboranes: Form and Functions 27\u003c\/p\u003e \u003cp\u003e2.2 Linear D-A Systems 29\u003c\/p\u003e \u003cp\u003e2.3 Non-conjugated D-A Organoboranes 32\u003c\/p\u003e \u003cp\u003e2.4 Conjugated Nonlinear D-A Systems 33\u003c\/p\u003e \u003cp\u003e2.5 Polymeric Systems 36\u003c\/p\u003e \u003cp\u003e2.6 Cyclic D-A Systems: Macrocycles and Fused-Rings 39\u003c\/p\u003e \u003cp\u003e2.7 Conclusions and Outlook 43\u003c\/p\u003e \u003cp\u003eReferences 43\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Photoresponsive Organoboron Systems 47\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSoren K. Mellerup and Suning Wang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 47\u003c\/p\u003e \u003cp\u003e3.1.1 Four-Coordinate Organoboron Compounds for OLEDs 47\u003c\/p\u003e \u003cp\u003e3.1.2 Photochromism 49\u003c\/p\u003e \u003cp\u003e3.2 Photoreactivity of (ppy)BMes2 and Related Compounds 50\u003c\/p\u003e \u003cp\u003e3.2.1 Photochromism of (ppy)BMes2 50\u003c\/p\u003e \u003cp\u003e3.2.2 Mechanism 51\u003c\/p\u003e \u003cp\u003e3.2.3 Derivatizing (ppy)BMes2: Impact of Steric and Electronic Factors on Photochromism 52\u003c\/p\u003e \u003cp\u003e3.2.3.1 Substituents on the ppy Backbone 52\u003c\/p\u003e \u003cp\u003e3.2.3.2 Aryl Groups on Boron: Steric versus Electronic Effect 54\u003c\/p\u003e \u003cp\u003e3.2.3.3 π-Conjugation and Heterocyclic Backbones 56\u003c\/p\u003e \u003cp\u003e3.2.3.4 Impact of Different Donors 58\u003c\/p\u003e \u003cp\u003e3.2.3.5 Polyboryl Species 60\u003c\/p\u003e \u003cp\u003e3.3 Photoreactivity of BN-Heterocycles 62\u003c\/p\u003e \u003cp\u003e3.3.1 BN-Isosterism and BN-Doped Polycyclic Aromatic Hydrocarbons (PAHs) 62\u003c\/p\u003e \u003cp\u003e3.3.2 Photoelimination of (2-Benzylpyridyl)BMes2 62\u003c\/p\u003e \u003cp\u003e3.3.3 Mechanism 64\u003c\/p\u003e \u003cp\u003e3.3.4 Scope of Photoelimination: The Chelate Backbone 65\u003c\/p\u003e \u003cp\u003e3.3.5 Strategies of Enhancing ΦPE: Metalation and Substituents on Boron 66\u003c\/p\u003e \u003cp\u003e3.4 New Photochromism of BN-Heterocycles 68\u003c\/p\u003e \u003cp\u003e3.4.1 Photochromism of (2-Benzylpyridyl)BMesF 2 and Related Compounds 68\u003c\/p\u003e \u003cp\u003e3.4.2 Mechanism 70\u003c\/p\u003e \u003cp\u003e3.5 Exciton Driven Elimination (EDE): In situ Fabrication of OLEDs 70\u003c\/p\u003e \u003cp\u003e3.6 Summary and Future Prospects 73\u003c\/p\u003e \u003cp\u003eReferences 74\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Incorporation of Group 13 Elements into Polymers 79\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYi Ren and Frieder Jäkle\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 79\u003c\/p\u003e \u003cp\u003e4.2 Tricoordinate Boron in Conjugated Polymers 80\u003c\/p\u003e \u003cp\u003e4.3 Tetracoordinate Boron Chelate Complexes in Polymeric Materials 87\u003c\/p\u003e \u003cp\u003e4.3.1 N-N Boron Chelates 88\u003c\/p\u003e \u003cp\u003e4.3.2 N-O Boron Chelates 91\u003c\/p\u003e \u003cp\u003e4.3.3 N-C Boron Chelates 92\u003c\/p\u003e \u003cp\u003e4.4 Polymeric Materials with B-P and B-N in the Backbone 92\u003c\/p\u003e \u003cp\u003e4.5 Polymeric Materials Containing Borane and Carborane Clusters 97\u003c\/p\u003e \u003cp\u003e4.6 Polymeric Materials Containing Higher Group 13 Elements 101\u003c\/p\u003e \u003cp\u003e4.7 Conclusions 105\u003c\/p\u003e \u003cp\u003eAcknowledgements 106\u003c\/p\u003e \u003cp\u003eReferences 106\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Tetracoordinate Boron Materials for Biological Imaging 111\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eChristopher A. DeRosa and Cassandra L. Fraser\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 111\u003c\/p\u003e \u003cp\u003e5.1.1 Introduction to Luminescence 111\u003c\/p\u003e \u003cp\u003e5.1.2 Tetracoordinate Boron Dye Scaffolds 113\u003c\/p\u003e \u003cp\u003e5.2 Small Molecule Fluorescence Imaging Agents 114\u003c\/p\u003e \u003cp\u003e5.2.1 Bright Fluorophores 116\u003c\/p\u003e \u003cp\u003e5.2.2 Solvatochromophores 117\u003c\/p\u003e \u003cp\u003e5.2.3 Molecular Motions of Boron Dyes 118\u003c\/p\u003e \u003cp\u003e5.2.3.1 Molecular Rotors 121\u003c\/p\u003e \u003cp\u003e5.2.3.2 Turn-On Probes 121\u003c\/p\u003e \u003cp\u003e5.3 Polymer Conjugated Materials 124\u003c\/p\u003e \u003cp\u003e5.3.1 Dye–Polymer Systems 124\u003c\/p\u003e \u003cp\u003e5.3.2 Oxygen-Sensing Polymers 126\u003c\/p\u003e \u003cp\u003e5.3.3 Energy Transfer in Polymers 129\u003c\/p\u003e \u003cp\u003e5.3.4 Conjugated Polymers 130\u003c\/p\u003e \u003cp\u003e5.3.5 Aggregation-Induced Emission Polymers 130\u003c\/p\u003e \u003cp\u003e5.4 Conclusion and Future Outlook 133\u003c\/p\u003e \u003cp\u003eReferences 133\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Advances and Properties of Silanol-Based Materials 141\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRudolf Pietschnig\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 141\u003c\/p\u003e \u003cp\u003e6.2 Preparation 141\u003c\/p\u003e \u003cp\u003e6.3 Reactivity 143\u003c\/p\u003e \u003cp\u003e6.3.1 Adduct Formation 143\u003c\/p\u003e \u003cp\u003e6.3.2 Metallation 145\u003c\/p\u003e \u003cp\u003e6.3.3 Condensation 146\u003c\/p\u003e \u003cp\u003e6.4 Properties and Application 148\u003c\/p\u003e \u003cp\u003e6.4.1 Surface Modification 148\u003c\/p\u003e \u003cp\u003e6.4.2 Catalysis 154\u003c\/p\u003e \u003cp\u003e6.4.3 Bioactivity 155\u003c\/p\u003e \u003cp\u003e6.4.3.1 Monosilanols 155\u003c\/p\u003e \u003cp\u003e6.4.3.2 Silanediols 156\u003c\/p\u003e \u003cp\u003e6.4.3.3 Silanetriols 157\u003c\/p\u003e \u003cp\u003e6.4.4 Supramolecular Assembly 158\u003c\/p\u003e \u003cp\u003eReferences 159\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Silole-Based Materials in Optoelectronics and Sensing 163\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMasaki Shimizu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 163\u003c\/p\u003e \u003cp\u003e7.2 Basic Aspects of Silole-Based Materials 164\u003c\/p\u003e \u003cp\u003e7.3 Silole-Based Electron-Transporting Materials 167\u003c\/p\u003e \u003cp\u003e7.4 Silole-Based Host and Hole-Blocking Materials for OLEDs 170\u003c\/p\u003e \u003cp\u003e7.5 Silole-Based Light-Emitting Materials 171\u003c\/p\u003e \u003cp\u003e7.6 Silole-Based Semiconducting Materials 175\u003c\/p\u003e \u003cp\u003e7.7 Silole-Based Light-Harvesting Materials for Solar Cells 179\u003c\/p\u003e \u003cp\u003e7.8 Silole-Based Sensing Materials 185\u003c\/p\u003e \u003cp\u003e7.9 Conclusion 189\u003c\/p\u003e \u003cp\u003eReferences 190\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Materials Containing Homocatenated Polysilanes 197\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eTakanobu Sanji\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 197\u003c\/p\u003e \u003cp\u003e8.2 Synthesis 197\u003c\/p\u003e \u003cp\u003e8.3 Functional Modification of Polysilanes 198\u003c\/p\u003e \u003cp\u003e8.4 Control of the Stereochemistry of Polysilanes 199\u003c\/p\u003e \u003cp\u003e8.5 Control of the Secondary Structure of Polysilanes 200\u003c\/p\u003e \u003cp\u003e8.6 Polysilanes with 3D Architectures 202\u003c\/p\u003e \u003cp\u003e8.7 Applications 203\u003c\/p\u003e \u003cp\u003e8.8 Summary 205\u003c\/p\u003e \u003cp\u003eReferences 205\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Catenated Germanium and Tin Oligomers and Polymers 209\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eDaniel Foucher\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 209\u003c\/p\u003e \u003cp\u003e9.2 Oligogermanes and Oligostannanes 209\u003c\/p\u003e \u003cp\u003e9.3 Preparation of Polygermanes 212\u003c\/p\u003e \u003cp\u003e9.3.1 Wurtz Coupling 212\u003c\/p\u003e \u003cp\u003e9.3.2 Reductive coupling of Dihalogermylenes 214\u003c\/p\u003e \u003cp\u003e9.3.3 Electrochemical Reduction of Dihalodiorganogermanes and Trihaloorganogermanes 215\u003c\/p\u003e \u003cp\u003e9.3.4 Transition Metal-Catalyzed Polymerizations of Germanes 215\u003c\/p\u003e \u003cp\u003e9.3.4.1 Demethanative Coupling of Germanes 216\u003c\/p\u003e \u003cp\u003e9.3.5 Photodecomposition of Germanes 218\u003c\/p\u003e \u003cp\u003e9.3.6 Properties and Characterization of Polygermanes 218\u003c\/p\u003e \u003cp\u003e9.3.6.1 Thermal Properties of Polygermanes 218\u003c\/p\u003e \u003cp\u003e9.3.6.2 Electronic Properties of Polygermanes 219\u003c\/p\u003e \u003cp\u003e9.4 Preparation of Polystannanes 220\u003c\/p\u003e \u003cp\u003e9.4.1 Wurtz Coupling 220\u003c\/p\u003e \u003cp\u003e9.4.2 Electrochemical Synthesis 221\u003c\/p\u003e \u003cp\u003e9.4.3 Dehydropolymerization 224\u003c\/p\u003e \u003cp\u003e9.4.4 Alternating Polystannanes 227\u003c\/p\u003e \u003cp\u003e9.4.5 Properties and Characterization of Polystannanes 227\u003c\/p\u003e \u003cp\u003e9.4.5.1 Sn NMR 227\u003c\/p\u003e \u003cp\u003e9.4.5.2 Thermal and Photostability 228\u003c\/p\u003e \u003cp\u003e9.4.5.3 Electronic Properties 230\u003c\/p\u003e \u003cp\u003e9.4.5.4 Conductivity 231\u003c\/p\u003e \u003cp\u003e9.4.6 Molecular Modeling of Oligostannanes and Comparison of Group 14 Polymetallanes 231\u003c\/p\u003e \u003cp\u003e9.5 Conclusions and Outlook 233\u003c\/p\u003e \u003cp\u003eAcknowledgements 233\u003c\/p\u003e \u003cp\u003eReferences 234\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Germanium and Tin in Conjugated Organic Materials 237\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYohei Adachi and Joji Ohshita\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 237\u003c\/p\u003e \u003cp\u003e10.2 Germanium and Tin-Linked Conjugated Polymers 238\u003c\/p\u003e \u003cp\u003e10.2.1 Germylene-Ethynylene Polymers 238\u003c\/p\u003e \u003cp\u003e10.2.2 Fluorene- and Carbazole-Containing Germylene Polymers 240\u003c\/p\u003e \u003cp\u003e10.2.3 Germanium- and Tin-Linked Ferrocenes and Related Compounds 241\u003c\/p\u003e \u003cp\u003e10.3 Germanium- and Tin-Containing Conjugated Cyclic Systems 242\u003c\/p\u003e \u003cp\u003e10.3.1 Non-fused Germoles and Stannoles 242\u003c\/p\u003e \u003cp\u003e10.3.2 Dibenzogermoles and Dibenzostannoles 248\u003c\/p\u003e \u003cp\u003e10.3.3 Dithienogermole and Dithienostannole 253\u003c\/p\u003e \u003cp\u003e10.3.4 Other Fused Germoles 258\u003c\/p\u003e \u003cp\u003e10.3.5 Germacycloheptatriene and Digermacyclohexadiene 259\u003c\/p\u003e \u003cp\u003e10.4 Summary and Outlook 260\u003c\/p\u003e \u003cp\u003eReferences 260\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Phosphorus-Based Porphyrins 265\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYoshihiro Matano\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 265\u003c\/p\u003e \u003cp\u003e11.2 Porphyrins Bearing Phosphorus-Based Functional Groups at their Periphery 266\u003c\/p\u003e \u003cp\u003e11.2.1 Porphyrins Bearing meso\/β-Diphenylphosphino Groups 266\u003c\/p\u003e \u003cp\u003e11.2.2 Porphyrins Bearing meso\/β-Triphenylphosphonio Groups 269\u003c\/p\u003e \u003cp\u003e11.2.3 Porphyrins Bearing meso\/β-Diphenylphosphoryl Groups 273\u003c\/p\u003e \u003cp\u003e11.2.4 Porphyrins Bearing meso\/β-Dialkoxyphosphoryl Groups 276\u003c\/p\u003e \u003cp\u003e11.2.5 Phthalocyanines Bearing Phosphorus-Based Functional Groups 280\u003c\/p\u003e \u003cp\u003e11.3 Porphyrins and Related Macrocycles Containing Phosphorus Atoms at their Core 283\u003c\/p\u003e \u003cp\u003e11.3.1 Core-Modified Phosphaporphyrins 284\u003c\/p\u003e \u003cp\u003e11.3.2 Core-Modified Phosphacalixpyrroles 287\u003c\/p\u003e \u003cp\u003e11.3.3 Core-Modified Phosphacalixphyrins 289\u003c\/p\u003e \u003cp\u003e11.4 Conclusions 290\u003c\/p\u003e \u003cp\u003eAcknowledgements 292\u003c\/p\u003e \u003cp\u003eReferences 292\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Applications of Phosphorus-Based Materials in Optoelectronics 295\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMatthew P. Duffy, Pierre-Antoine Bouit, and Muriel Hissler\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 295\u003c\/p\u003e \u003cp\u003e12.2 Phosphines 296\u003c\/p\u003e \u003cp\u003e12.2.1 Application as Charge-Transport Layer 296\u003c\/p\u003e \u003cp\u003e12.2.2 Application as Host for Phosphorescent Complexes 299\u003c\/p\u003e \u003cp\u003e12.2.3 Application as Emitting Materials 303\u003c\/p\u003e \u003cp\u003e12.3 Four-Membered P-Heterocyclic Rings 306\u003c\/p\u003e \u003cp\u003e12.3.1 Diphosphacyclobutanediyls 306\u003c\/p\u003e \u003cp\u003e12.3.2 Phosphetes 307\u003c\/p\u003e \u003cp\u003e12.4 Five-Membered P-Heterocyclic Rings: Phospholes 307\u003c\/p\u003e \u003cp\u003e12.4.1 Application as Charge-Transport Layers 308\u003c\/p\u003e \u003cp\u003e12.4.2 Application as Host for Phosphorescent Complexes 309\u003c\/p\u003e \u003cp\u003e12.4.3 Application as Emitter in OLEDs 309\u003c\/p\u003e \u003cp\u003e12.4.4 Dyes for Dye-Sensitized Solar Cells (DSSCs) 316\u003c\/p\u003e \u003cp\u003e12.4.5 Donors in Organic Solar Cells (OSCs) 316\u003c\/p\u003e \u003cp\u003e12.4.6 Application in Electrochromic Cells 317\u003c\/p\u003e \u003cp\u003e12.4.7 Application in Memory Devices 318\u003c\/p\u003e \u003cp\u003e12.5 Six-Membered P-Heterocyclic Rings 319\u003c\/p\u003e \u003cp\u003e12.5.1 Phosphazenes 319\u003c\/p\u003e \u003cp\u003e12.5.1.1 Application as Electrolyte for Solar Cells 319\u003c\/p\u003e \u003cp\u003e12.5.1.2 Application as Host for Triplet Emitters in PhOLEDs 320\u003c\/p\u003e \u003cp\u003e12.5.1.3 Application as Emitter for OLEDs 321\u003c\/p\u003e \u003cp\u003e12.6 Conclusion 321\u003c\/p\u003e \u003cp\u003eAbbreviations 322\u003c\/p\u003e \u003cp\u003eReferences 324\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Main-Chain, Phosphorus-Based Polymers 329\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKlaus Dück and Derek P. Gates\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 329\u003c\/p\u003e \u003cp\u003e13.2 Polyphosphazenes 330\u003c\/p\u003e \u003cp\u003e13.3 Poly(phosphole)s 333\u003c\/p\u003e \u003cp\u003e13.4 Poly(methylenephosphine)s 336\u003c\/p\u003e \u003cp\u003e13.5 Poly(arylene-\/vinylene-\/ethynylene-phosphine)s 341\u003c\/p\u003e \u003cp\u003e13.6 Phospha-PPVs 343\u003c\/p\u003e \u003cp\u003e13.7 Poly(phosphinoborane)s 345\u003c\/p\u003e \u003cp\u003e13.8 Metal-Containing Phosphorus Polymers 347\u003c\/p\u003e \u003cp\u003e13.9 Additional P-Containing Polymers 349\u003c\/p\u003e \u003cp\u003e13.10 Summary 350\u003c\/p\u003e \u003cp\u003eAcknowledgements 351\u003c\/p\u003e \u003cp\u003eReferences 351\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Synthons for the Development of New Organophosphorus Functional Materials 357\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRobert J. Gilliard, Jr., Jerod M. Kieser, and John D. Protasiewicz\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 General Introduction 357\u003c\/p\u003e \u003cp\u003e14.1.1 Phosphorus-Based Functional Materials 357\u003c\/p\u003e \u003cp\u003e14.1.2 Phosphorus Allotropes 359\u003c\/p\u003e \u003cp\u003e14.2 Phosphorus Transfer Reagents as Emerging Synthetic Approaches to Materials 360\u003c\/p\u003e \u003cp\u003e14.2.1 Introduction to Phosphorus Transfer Reagents 360\u003c\/p\u003e \u003cp\u003e14.2.2 Phosphaethynolate Salts 360\u003c\/p\u003e \u003cp\u003e14.2.3 Phospha-Wittig Reagents 367\u003c\/p\u003e \u003cp\u003e14.2.4 Phospha-Wittig–Horner Reagents 371\u003c\/p\u003e \u003cp\u003e14.2.5 Phosphadibenzonorbornadiene Derivatives 373\u003c\/p\u003e \u003cp\u003e14.3 Carbene-Stabilized Molecules as Phosphorus Reagents 375\u003c\/p\u003e \u003cp\u003e14.3.1 Introduction to Carbene Phosphorus Complexes 375\u003c\/p\u003e \u003cp\u003e14.3.2 N-Heterocyclic Carbene-Stabilized Phosphorus Complexes 375\u003c\/p\u003e \u003cp\u003e14.3.3 Cyclic (Alkyl)(Amino) Carbene-Stabilized Phosphorus Compounds 376\u003c\/p\u003e \u003cp\u003e14.3.4 Reactions of N-Heterocyclic Carbenes with Phosphaalkenes 377\u003c\/p\u003e \u003cp\u003e14.4 Conclusions and Outlook 378\u003c\/p\u003e \u003cp\u003eReferences 379\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Arsenic-Containing Oligomers and Polymers 383\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHiroaki Imoto and Kensuke Naka\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 383\u003c\/p\u003e \u003cp\u003e15.2 Chemistry of Organoarsenic Compounds 384\u003c\/p\u003e \u003cp\u003e15.3 Arsenic Homocycles 384\u003c\/p\u003e \u003cp\u003e15.4 Development of C–As Bond Formation for Organoarsenic\u003c\/p\u003e \u003cp\u003e15.4.1 Classical Methodologies 386\u003c\/p\u003e \u003cp\u003e15.4.2 In Situ-Generated Organoarsenic Electrophiles from Arsenic Homocycles 387\u003c\/p\u003e \u003cp\u003e15.4.3 In Situ-Generated Organoarsenic Nucleophiles from Arsenic Homocycles 388\u003c\/p\u003e \u003cp\u003e15.4.4 Bismetallation Based on Arsenic Homocycles 388\u003c\/p\u003e \u003cp\u003e15.5 Properties of Poly(vinylene-arsine)s 391\u003c\/p\u003e \u003cp\u003e15.6 Properties of 1,4-Dihydro-1,4-diarsinines 391\u003c\/p\u003e \u003cp\u003e15.7 Properties of Arsole Derivatives 394\u003c\/p\u003e \u003cp\u003e15.8 Arsole-Containing Polymers 396\u003c\/p\u003e \u003cp\u003e15.9 Conclusions 399\u003c\/p\u003e \u003cp\u003eReferences 400\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Antimony-and Bismuth-Based Materials and Applications 405\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAnna M. Christianson and François P. Gabbaï\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 405\u003c\/p\u003e \u003cp\u003e16.2 Anion Binding and Sensing Applications 406\u003c\/p\u003e \u003cp\u003e16.3 Small-Molecule Binding 418\u003c\/p\u003e \u003cp\u003e16.4 Antimony and Bismuth Chromophores 426\u003c\/p\u003e \u003cp\u003e16.5 Conclusion 430\u003c\/p\u003e \u003cp\u003eReferences 430\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 High Sulfur Content Organic\/Inorganic Hybrid Polymeric Materials 433\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJeffrey Pyun, Richard S. Glass, Michael M. Mackay, Robert Norwood, and Kookheon Char\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 433\u003c\/p\u003e \u003cp\u003e17.2 The Chemistry of Liquid Sulfur 434\u003c\/p\u003e \u003cp\u003e17.2.1 Ring-Opening Polymerization of Elemental Sulfur 434\u003c\/p\u003e \u003cp\u003e17.2.2 Synthesis of Inorganic Nanoparticles in Liquid Sulfur 435\u003c\/p\u003e \u003cp\u003e17.2.3 Inverse Vulcanization of Elemental Sulfur 437\u003c\/p\u003e \u003cp\u003e17.2.4 Transformation Polymerizations with Elemental Sulfur: Combining Inverse Vulcanization with Electropolymerization 441\u003c\/p\u003e \u003cp\u003e17.3 Waterborne Reactions of Polysulfides 442\u003c\/p\u003e \u003cp\u003e17.4 Controlled Polymerization with High Sulfur-Content Monomers 442\u003c\/p\u003e \u003cp\u003e17.5 Modern Applications of High Sulfur-Content Copolymers 444\u003c\/p\u003e \u003cp\u003e17.5.1 High Sulfur-Content Polymers as Cathode Materials for Li-S Batteries 444\u003c\/p\u003e \u003cp\u003e17.5.2 High Sulfur-Content Polymers as Transmissive Materials for IR Thermal Imaging 445\u003c\/p\u003e \u003cp\u003e17.6 Conclusion and Outlook 448\u003c\/p\u003e \u003cp\u003eAcknowledgements 448\u003c\/p\u003e \u003cp\u003eReferences 449\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Selenium and Tellurium Containing Conjugated Polymers 451\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eZhen Zhang, Wenhan He, and Yang Qin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 451\u003c\/p\u003e \u003cp\u003e18.2 Selenium-Containing Conjugated Polymers 452\u003c\/p\u003e \u003cp\u003e18.2.1 Background 452\u003c\/p\u003e \u003cp\u003e18.2.2 Electron-Rich Homopolymers 453\u003c\/p\u003e \u003cp\u003e18.2.3 Donor–Acceptor (D-A) Copolymers 457\u003c\/p\u003e \u003cp\u003e18.2.3.1 Selenium-Containing Benzodithiophene-Benzothiadiazole (BDT-BT) Copolymer Derivatives 460\u003c\/p\u003e \u003cp\u003e18.2.3.2 Selenium-Containing Benzodithiophene-Thienothiophene (BDT-TT) Copolymer Derivatives 462\u003c\/p\u003e \u003cp\u003e18.2.3.3 Selenium-Containing Benzodithiophene-Diketopyrrolopyrrole (BDT-DPP) and Benzodithiophene-Thienopyrrole-4,6-dione (BDT-TPD) Copolymers 465\u003c\/p\u003e \u003cp\u003e18.3 Tellurium-Containing Conjugated Polymers 467\u003c\/p\u003e \u003cp\u003e18.3.1 Background 467\u003c\/p\u003e \u003cp\u003e18.3.2 Synthesis of Tellurium-Containing Polymers 467\u003c\/p\u003e \u003cp\u003e18.3.2.1 Early Examples of Insoluble Polymers 467\u003c\/p\u003e \u003cp\u003e18.3.2.2 Tellurium-Bridge Polymers 469\u003c\/p\u003e \u003cp\u003e18.3.2.3 Soluble Tellurophene-Containing Conjugated Polymers 469\u003c\/p\u003e \u003cp\u003e18.3.2.4 Regio-Regular Poly(3-alkyltellurophene) 472\u003c\/p\u003e \u003cp\u003e18.3.2.5 Other Tellurium-Containing Conjugated Polymers 473\u003c\/p\u003e \u003cp\u003e18.3.3 Application of Tellurium-Containing Conjugated Polymers 473\u003c\/p\u003e \u003cp\u003e18.4 Conclusions and Outlook 476\u003c\/p\u003e \u003cp\u003eReferences 476\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Hypervalent Iodine Compounds in Polymer Science and Technology 483\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAvichal Vaish and Nicolay V. Tsarevsky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 483\u003c\/p\u003e \u003cp\u003e19.1.1 Historical 483\u003c\/p\u003e \u003cp\u003e19.1.2 Bonding in Hypervalent Iodine Compounds 484\u003c\/p\u003e \u003cp\u003e19.1.3 Patterns of Reactivity Relevant to Applications in Polymer Science and Technology 486\u003c\/p\u003e \u003cp\u003e19.2 Applications of Hypervalent Iodine Compounds in Polymer Science and Technology 487\u003c\/p\u003e \u003cp\u003e19.2.1 HV Iodine Compounds as Initiators for Polymerization 487\u003c\/p\u003e \u003cp\u003e19.2.1.1 Direct Application of HV Iodine Compounds 487\u003c\/p\u003e \u003cp\u003e19.2.1.2 Functional Radical Initiators Generated as a result of Ligand-Exchange followed by Homolysis 493\u003c\/p\u003e \u003cp\u003e19.2.2 Post-Polymerization Modifications using HV Iodine Compounds 495\u003c\/p\u003e \u003cp\u003e19.2.3 HV Iodine Groups as Structural Elements in Polymers 496\u003c\/p\u003e \u003cp\u003e19.2.3.1 Polymers with HV Iodine-Based Pendant Groups 496\u003c\/p\u003e \u003cp\u003e19.2.3.2 HV Iodine Groups as part of the Polymer Backbone 505\u003c\/p\u003e \u003cp\u003e19.3 Conclusions 508\u003c\/p\u003e \u003cp\u003eAcknowledgements 508\u003c\/p\u003e \u003cp\u003eReferences 508\u003c\/p\u003e \u003cp\u003eIndex\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49528850383191,"sku":"9781119235972","price":151.95,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119235972.jpg?v=1731873269","url":"https:\/\/bookcurl.com\/products\/main-group-strategies-towards-functional-hybrid-materials-9781119235972","provider":"Book Curl","version":"1.0","type":"link"}