{"product_id":"lanthanide-and-actinide-chemistry-9781118873496","title":"Lanthanide and Actinide Chemistry","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eAbout the Author xiii\u003c\/p\u003e \u003cp\u003ePreface to the Second Edition xiv\u003c\/p\u003e \u003cp\u003ePreface to the First Edition xv\u003c\/p\u003e \u003cp\u003eAbout the Companion Website xvi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction to the Lanthanides 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Characteristics of the Lanthanides 2\u003c\/p\u003e \u003cp\u003e1.3 Occurrence and Abundance of the Lanthanides 2\u003c\/p\u003e \u003cp\u003e1.4 Lanthanide Ores 3\u003c\/p\u003e \u003cp\u003e1.5 Extracting and Separating the Lanthanides 5\u003c\/p\u003e \u003cp\u003e1.5.1 Extraction 5\u003c\/p\u003e \u003cp\u003e1.5.2 Separating the Lanthanides 5\u003c\/p\u003e \u003cp\u003e1.6 The Position of the Lanthanides in the Periodic Table 8\u003c\/p\u003e \u003cp\u003e1.7 The Lanthanide Contraction 8\u003c\/p\u003e \u003cp\u003e1.8 Recycling Lanthanides 8\u003c\/p\u003e \u003cp\u003e1.9 Isotopes 9\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 The Lanthanides – Principles and Energetics 13\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Electron Configurations of the Lanthanides and f Orbitals 13\u003c\/p\u003e \u003cp\u003e2.2 What Do f Orbitals Look Like? 14\u003c\/p\u003e \u003cp\u003e2.3 How f Orbitals Affect Properties of the Lanthanides 15\u003c\/p\u003e \u003cp\u003e2.4 The Lanthanide Contraction 16\u003c\/p\u003e \u003cp\u003e2.5 Electron Configurations of the Lanthanide Elements and of Common Ions 16\u003c\/p\u003e \u003cp\u003e2.6 Patterns in Ionization Energies 17\u003c\/p\u003e \u003cp\u003e2.7 Atomic and Ionic Radii 18\u003c\/p\u003e \u003cp\u003e2.8 Patterns in Hydration Energies (Enthalpies) for the Lanthanide Ions 19\u003c\/p\u003e \u003cp\u003e2.9 Enthalpy Changes for the Formation of Simple Lanthanide Compounds 20\u003c\/p\u003e \u003cp\u003e2.9.1 Stability of Tetrahalides 20\u003c\/p\u003e \u003cp\u003e2.9.2 Stability of Dihalides 22\u003c\/p\u003e \u003cp\u003e2.9.3 Stability of Aqua Ions 23\u003c\/p\u003e \u003cp\u003e2.10 Patterns in Redox Potentials 24\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 The Lanthanide Elements and Simple Binary Compounds 28\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 28\u003c\/p\u003e \u003cp\u003e3.2 The Elements 28\u003c\/p\u003e \u003cp\u003e3.2.1 Properties 28\u003c\/p\u003e \u003cp\u003e3.2.2 Synthesis 29\u003c\/p\u003e \u003cp\u003e3.2.3 Alloys and Uses of the Metals 30\u003c\/p\u003e \u003cp\u003e3.3 Binary Compounds 30\u003c\/p\u003e \u003cp\u003e3.3.1 Trihalides 30\u003c\/p\u003e \u003cp\u003e3.3.2 Tetrahalides 32\u003c\/p\u003e \u003cp\u003e3.3.3 Dihalides 32\u003c\/p\u003e \u003cp\u003e3.3.4 Oxides 34\u003c\/p\u003e \u003cp\u003e3.4 Borides 36\u003c\/p\u003e \u003cp\u003e3.5 Carbides 36\u003c\/p\u003e \u003cp\u003e3.6 Nitrides 37\u003c\/p\u003e \u003cp\u003e3.7 Hydrides 37\u003c\/p\u003e \u003cp\u003e3.8 Sulfides 37\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Coordination Chemistry of the Lanthanides 40\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 40\u003c\/p\u003e \u003cp\u003e4.2 Stability of Complexes 40\u003c\/p\u003e \u003cp\u003e4.3 Complexes 42\u003c\/p\u003e \u003cp\u003e4.3.1 The Aqua Ions 42\u003c\/p\u003e \u003cp\u003e4.3.2 Hydrated Salts 43\u003c\/p\u003e \u003cp\u003e4.3.3 Other O-Donors 44\u003c\/p\u003e \u003cp\u003e4.3.4 Complexes of β-Diketonates 46\u003c\/p\u003e \u003cp\u003e4.3.5 Lewis Base Adducts of β-Diketonate Complexes 47\u003c\/p\u003e \u003cp\u003e4.3.6 Nitrate and Carbonate Complexes 47\u003c\/p\u003e \u003cp\u003e4.3.7 Crown Ether Complexes 48\u003c\/p\u003e \u003cp\u003e4.3.8 Complexes of EDTA and Related Ligands 49\u003c\/p\u003e \u003cp\u003e4.3.9 Complexes of N-Donors 50\u003c\/p\u003e \u003cp\u003e4.3.10 Complexes of Porphyrins and Related Systems 51\u003c\/p\u003e \u003cp\u003e4.3.11 Halide Complexes 52\u003c\/p\u003e \u003cp\u003e4.3.12 Complexes of S-Donors 52\u003c\/p\u003e \u003cp\u003e4.4 Alkoxides, Alkylamides, and Related Substances 53\u003c\/p\u003e \u003cp\u003e4.4.1 Alkylamides 53\u003c\/p\u003e \u003cp\u003e4.4.2 Alkoxides 54\u003c\/p\u003e \u003cp\u003e4.4.3 Thiolates 56\u003c\/p\u003e \u003cp\u003e4.4.4 Borohydrides 57\u003c\/p\u003e \u003cp\u003e4.5 Coordination Numbers in Lanthanide Complexes 57\u003c\/p\u003e \u003cp\u003e4.5.1 General Principles 57\u003c\/p\u003e \u003cp\u003e4.5.2 Examples of the Coordination Numbers 58\u003c\/p\u003e \u003cp\u003e4.5.3 The Lanthanide Contraction and Coordination Numbers 60\u003c\/p\u003e \u003cp\u003e4.5.4 Formulae and Coordination Numbers 63\u003c\/p\u003e \u003cp\u003e4.6 The Coordination Chemistry of the +2 and +4 States 63\u003c\/p\u003e \u003cp\u003e4.6.1 The (+2) State 63\u003c\/p\u003e \u003cp\u003e4.6.2 The (+4) State 66\u003c\/p\u003e \u003cp\u003e4.7 Lanthanides in Living Systems 69\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Electronic and Magnetic Properties of the Lanthanides 76\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Magnetic and Spectroscopic Properties of the Ln\u003csup\u003e3+\u003c\/sup\u003e Ions 76\u003c\/p\u003e \u003cp\u003e5.2 Magnetic Properties of the Ln\u003csup\u003e3+\u003c\/sup\u003e Ions 77\u003c\/p\u003e \u003cp\u003e5.2.1 Adiabatic Demagnetization 79\u003c\/p\u003e \u003cp\u003e5.2.2 Single Molecule Magnets (SMMs) and Single Ion Magnets (SIMs) 80\u003c\/p\u003e \u003cp\u003e5.3 Energy-Level Diagrams for the Lanthanide Ions, and Their Electronic Spectra 84\u003c\/p\u003e \u003cp\u003e5.3.1 Electronic Spectra 84\u003c\/p\u003e \u003cp\u003e5.3.2 Hypersensitive Transitions 86\u003c\/p\u003e \u003cp\u003e5.4 Luminescence Spectra 87\u003c\/p\u003e \u003cp\u003e5.4.1 Quenching 92\u003c\/p\u003e \u003cp\u003e5.4.2 Antenna Effects 92\u003c\/p\u003e \u003cp\u003e5.4.3 Lanthanides in Upconversion 93\u003c\/p\u003e \u003cp\u003e5.4.4 Applications of Luminescence to Sensory Probes 95\u003c\/p\u003e \u003cp\u003e5.4.4.1 Terbium Luminescence to Detect Anthrax 97\u003c\/p\u003e \u003cp\u003e5.4.4.2 Fingerprint Detection 97\u003c\/p\u003e \u003cp\u003e5.4.5 Fluorescence and TV 98\u003c\/p\u003e \u003cp\u003e5.4.6 Lighting Applications 99\u003c\/p\u003e \u003cp\u003e5.4.7 Lasers 99\u003c\/p\u003e \u003cp\u003e5.4.8 Euro Banknotes 100\u003c\/p\u003e \u003cp\u003e5.5 NMR Applications 100\u003c\/p\u003e \u003cp\u003e5.5.1 β-Diketonates as NMR Shift Reagents 100\u003c\/p\u003e \u003cp\u003e5.5.2 Magnetic Resonance Imaging (MRI) 102\u003c\/p\u003e \u003cp\u003e5.5.3 What Makes a Good MRI Agent? 102\u003c\/p\u003e \u003cp\u003e5.5.4 Health Issues with MRI Agents 104\u003c\/p\u003e \u003cp\u003e5.5.5 Texaphyrins 104\u003c\/p\u003e \u003cp\u003e5.6 Electron Paramagnetic Resonance Spectroscopy 105\u003c\/p\u003e \u003cp\u003e5.7 Lanthanides as Probes in Biological Systems 105\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Organometallic Chemistry of the Lanthanides 110\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 110\u003c\/p\u003e \u003cp\u003e6.2 The +3 Oxidation State 110\u003c\/p\u003e \u003cp\u003e6.2.1 Alkyls 111\u003c\/p\u003e \u003cp\u003e6.2.2 Aryls 112\u003c\/p\u003e \u003cp\u003e6.3 Cyclopentadienyls 113\u003c\/p\u003e \u003cp\u003e6.3.1 Compounds of the Unsubstituted Cyclopentadienyl Ligand (C\u003csub\u003e5\u003c\/sub\u003eH\u003csub\u003e5\u003c\/sub\u003e = Cp; C\u003csub\u003e5\u003c\/sub\u003eMe\u003csub\u003e5\u003c\/sub\u003e =Cp\u003csup\u003e∗\u003c\/sup\u003e) 113\u003c\/p\u003e \u003cp\u003e6.3.2 Compounds [LnCp\u003csup\u003e∗\u003c\/sup\u003e\u003csub\u003e3\u003c\/sub\u003e] (Cp\u003csup\u003e∗\u003c\/sup\u003e = Pentamethylcyclopentadienyl) 116\u003c\/p\u003e \u003cp\u003e6.3.3 Bis(cyclopentadienyl) Alkyls and Aryls LnCp\u003csub\u003e2\u003c\/sub\u003eR 117\u003c\/p\u003e \u003cp\u003e6.3.4 Bis(pentamethylcyclopentadienyl) Alkyls 118\u003c\/p\u003e \u003cp\u003e6.3.5 Hydride Complexes 121\u003c\/p\u003e \u003cp\u003e6.4 Cyclooctatetraene Dianion Complexes 121\u003c\/p\u003e \u003cp\u003e6.5 The +2 State 122\u003c\/p\u003e \u003cp\u003e6.5.1 Alkyls and Aryls 122\u003c\/p\u003e \u003cp\u003e6.5.2 Cyclopentadienyls 123\u003c\/p\u003e \u003cp\u003e6.5.3 Other Compounds 126\u003c\/p\u003e \u003cp\u003e6.6 The +4 State 126\u003c\/p\u003e \u003cp\u003e6.7 Metal–Arene Complexes 128\u003c\/p\u003e \u003cp\u003e6.8 Carbonyls 129\u003c\/p\u003e \u003cp\u003e6.9 Compounds with Lanthanide-Metal Bonds 129\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 The Misfits: Scandium, Yttrium, and Promethium 134\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 134\u003c\/p\u003e \u003cp\u003e7.2 Scandium 134\u003c\/p\u003e \u003cp\u003e7.2.1 Binary Compounds of Scandium 135\u003c\/p\u003e \u003cp\u003e7.3 Coordination Compounds of Scandium 136\u003c\/p\u003e \u003cp\u003e7.3.1 The Aqua Ion and Hydrated Salts 136\u003c\/p\u003e \u003cp\u003e7.3.2 Other Complexes 137\u003c\/p\u003e \u003cp\u003e7.3.3 Alkoxides and Alkylamides 139\u003c\/p\u003e \u003cp\u003e7.3.4 Patterns in Coordination Number 140\u003c\/p\u003e \u003cp\u003e7.3.5 Scandium and Yttrium in the (+2) State 144\u003c\/p\u003e \u003cp\u003e7.4 Organometallic Compounds of Scandium 145\u003c\/p\u003e \u003cp\u003e7.5 Yttrium 148\u003c\/p\u003e \u003cp\u003e7.6 Promethium 149\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Introduction to the Actinides 154\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction and Occurrence of the Actinides 154\u003c\/p\u003e \u003cp\u003e8.2 Synthesis 155\u003c\/p\u003e \u003cp\u003e8.3 Extraction of Th, Pa, and U 157\u003c\/p\u003e \u003cp\u003e8.3.1 Extraction of Thorium 157\u003c\/p\u003e \u003cp\u003e8.3.2 Extraction of Protactinium 157\u003c\/p\u003e \u003cp\u003e8.3.3 Extraction and Purification of Uranium 157\u003c\/p\u003e \u003cp\u003e8.3.4 Uranium Extraction from Seawater 157\u003c\/p\u003e \u003cp\u003e8.4 Uranium Isotope Separation 159\u003c\/p\u003e \u003cp\u003e8.4.1 Gaseous Diffusion 159\u003c\/p\u003e \u003cp\u003e8.4.2 Gas Centrifuge 160\u003c\/p\u003e \u003cp\u003e8.4.3 Electromagnetic Separation 160\u003c\/p\u003e \u003cp\u003e8.4.4 Laser Separation 160\u003c\/p\u003e \u003cp\u003e8.5 Characteristics of the Actinides 160\u003c\/p\u003e \u003cp\u003e8.6 Reduction Potentials of the Actinides 162\u003c\/p\u003e \u003cp\u003e8.7 Relativistic Effects 163\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Binary Compounds of the Actinides 165\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 165\u003c\/p\u003e \u003cp\u003e9.2 Halides 165\u003c\/p\u003e \u003cp\u003e9.2.1 Syntheses of the Halides 167\u003c\/p\u003e \u003cp\u003e9.2.2 Structure Types 168\u003c\/p\u003e \u003cp\u003e9.3 Thorium Halides 170\u003c\/p\u003e \u003cp\u003e9.4 Uranium Halides 170\u003c\/p\u003e \u003cp\u003e9.4.1 Uranium(VI) Compounds 170\u003c\/p\u003e \u003cp\u003e9.4.2 Uranium(V) Compounds 172\u003c\/p\u003e \u003cp\u003e9.4.3 Uranium(IV) Compounds 172\u003c\/p\u003e \u003cp\u003e9.4.4 Uranium(III) Compounds 173\u003c\/p\u003e \u003cp\u003e9.4.5 Uranium Hexafluoride and Isotope Separation 173\u003c\/p\u003e \u003cp\u003e9.5 Actinide Halides (Ac–Am) Excluding U and Th 175\u003c\/p\u003e \u003cp\u003e9.5.1 Actinium 175\u003c\/p\u003e \u003cp\u003e9.5.2 Protactinium 175\u003c\/p\u003e \u003cp\u003e9.5.3 Neptunium 176\u003c\/p\u003e \u003cp\u003e9.5.4 Plutonium 177\u003c\/p\u003e \u003cp\u003e9.5.5 Americium 177\u003c\/p\u003e \u003cp\u003e9.6 Halides of the Heavier Transactinides 178\u003c\/p\u003e \u003cp\u003e9.6.1 Curium(III) Chloride 178\u003c\/p\u003e \u003cp\u003e9.6.2 Californium(III) Chloride, Californium(III) Iodide, and Californium(II) Iodide 178\u003c\/p\u003e \u003cp\u003e9.6.3 Einsteinium(II) Chloride 179\u003c\/p\u003e \u003cp\u003e9.7 Oxides 179\u003c\/p\u003e \u003cp\u003e9.7.1 Thorium Oxide 179\u003c\/p\u003e \u003cp\u003e9.7.2 Uranium Oxides 180\u003c\/p\u003e \u003cp\u003e9.7.3 Plutonium Oxides 180\u003c\/p\u003e \u003cp\u003e9.8 Sulfides 180\u003c\/p\u003e \u003cp\u003e9.9 Uranium Hydride UH\u003csub\u003e3\u003c\/sub\u003e 181\u003c\/p\u003e \u003cp\u003e9.10 Oxyhalides 181\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Coordination Chemistry of the Actinides 184\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 184\u003c\/p\u003e \u003cp\u003e10.2 General Patterns in the Coordination Chemistry of the Actinides 185\u003c\/p\u003e \u003cp\u003e10.3 Coordination Numbers in Actinide Complexes 185\u003c\/p\u003e \u003cp\u003e10.4 Types of Complex Formed 187\u003c\/p\u003e \u003cp\u003e10.5 Uranium and Thorium Chemistry 187\u003c\/p\u003e \u003cp\u003e10.5.1 Uranyl Complexes 187\u003c\/p\u003e \u003cp\u003e10.5.2 Coordination Numbers and Geometries in Uranyl Complexes 190\u003c\/p\u003e \u003cp\u003e10.5.3 Some Other Complexes 192\u003c\/p\u003e \u003cp\u003e10.5.4 Uranyl Nitrate and Its Complexes; Their Role in Processing Nuclear Waste 193\u003c\/p\u003e \u003cp\u003e10.5.5 Nuclear Waste Processing 193\u003c\/p\u003e \u003cp\u003e10.5.6 Uranium Oxo Complexes 194\u003c\/p\u003e \u003cp\u003e10.5.7 Uranium Nitrido Complexes 195\u003c\/p\u003e \u003cp\u003e10.5.8 Uranium(V) Complexes 196\u003c\/p\u003e \u003cp\u003e10.5.9 Uranium(III) Complexes 197\u003c\/p\u003e \u003cp\u003e10.5.10 Uranium(II) Complexes 198\u003c\/p\u003e \u003cp\u003e10.6 Complexes of the Actinide(IV) Nitrates and Halides 199\u003c\/p\u003e \u003cp\u003e10.6.1 Thorium Nitrate Complexes 199\u003c\/p\u003e \u003cp\u003e10.6.2 Uranium(IV) Nitrate Complexes 200\u003c\/p\u003e \u003cp\u003e10.6.3 Complexes of the Actinide(IV) Halides 200\u003c\/p\u003e \u003cp\u003e10.7 Thiocyanates 202\u003c\/p\u003e \u003cp\u003e10.8 Amides, Alkoxides, and Thiolates 203\u003c\/p\u003e \u003cp\u003e10.8.1 Amide Chemistry 203\u003c\/p\u003e \u003cp\u003e10.8.2 Alkoxides and Aryloxides 207\u003c\/p\u003e \u003cp\u003e10.8.3 Borohydrides 209\u003c\/p\u003e \u003cp\u003e10.8.4 Uranium Chelate Compounds 209\u003c\/p\u003e \u003cp\u003e10.9 Chemistry of Actinium 210\u003c\/p\u003e \u003cp\u003e10.10 Chemistry of Protactinium 211\u003c\/p\u003e \u003cp\u003e10.11 Chemistry of Neptunium 212\u003c\/p\u003e \u003cp\u003e10.11.1 Complexes of Neptunium 213\u003c\/p\u003e \u003cp\u003e10.12 Chemistry of Plutonium 214\u003c\/p\u003e \u003cp\u003e10.12.1 Aqueous Chemistry 214\u003c\/p\u003e \u003cp\u003e10.12.2 Stability of the Oxidation States of Plutonium 215\u003c\/p\u003e \u003cp\u003e10.12.3 Coordination Chemistry of Plutonium 216\u003c\/p\u003e \u003cp\u003e10.12.4 Plutonium in the Environment 218\u003c\/p\u003e \u003cp\u003e10.13 Chemistry of Americium and Subsequent Actinides 220\u003c\/p\u003e \u003cp\u003e10.13.1 Potentials 220\u003c\/p\u003e \u003cp\u003e10.14 Chemistry of the Later Actinides 222\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Electronic and Magnetic Properties of the Actinides 228\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 228\u003c\/p\u003e \u003cp\u003e11.2 Absorption Spectra 229\u003c\/p\u003e \u003cp\u003e11.2.1 Uranium (VI) – UO\u003csub\u003e2\u003c\/sub\u003e\u003csup\u003e2+\u003c\/sup\u003e – f\u003csup\u003e0\u003c\/sup\u003e \u003ci\u003e229\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.2.2 Uranium(V) – f\u003csup\u003e1\u003c\/sup\u003e 230\u003c\/p\u003e \u003cp\u003e11.2.3 Uranium(IV) – f\u003csup\u003e2\u003c\/sup\u003e 230\u003c\/p\u003e \u003cp\u003e11.2.4 Spectra of the Later Actinides 233\u003c\/p\u003e \u003cp\u003e11.3 Magnetic Properties 234\u003c\/p\u003e \u003cp\u003e11.3.1 Uranium Single Molecule Magnets 236\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Organometallic Chemistry of the Actinides 238\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 238\u003c\/p\u003e \u003cp\u003e12.2 Simple σ-Bonded Organometallics 238\u003c\/p\u003e \u003cp\u003e12.3 Cyclopentadienyls 242\u003c\/p\u003e \u003cp\u003e12.3.1 Oxidation State (VI) 242\u003c\/p\u003e \u003cp\u003e12.3.2 Oxidation State (V) 242\u003c\/p\u003e \u003cp\u003e12.3.3 Oxidation State (IV) 242\u003c\/p\u003e \u003cp\u003e12.3.4 Oxidation State (III) 245\u003c\/p\u003e \u003cp\u003e12.4 Compounds of the Pentamethylcyclopentadienyl Ligand (C\u003csub\u003e5\u003c\/sub\u003eMe\u003csub\u003e5\u003c\/sub\u003e =Cp\u003csup\u003e∗\u003c\/sup\u003e) 246\u003c\/p\u003e \u003cp\u003e12.4.1 Oxidation State (IV) 246\u003c\/p\u003e \u003cp\u003e12.4.2 Cationic Species and Catalysts 247\u003c\/p\u003e \u003cp\u003e12.4.3 Hydrides 248\u003c\/p\u003e \u003cp\u003e12.4.4 Oxidation State (III) 249\u003c\/p\u003e \u003cp\u003e12.4.5 Oxidation State (II) 249\u003c\/p\u003e \u003cp\u003e12.4.6 Some Recent Chemistry of Neptunium and Plutonium 251\u003c\/p\u003e \u003cp\u003e12.5 Tris(pentamethylcyclopentadienyl) Systems 252\u003c\/p\u003e \u003cp\u003e12.6 Other Metallacycles 252\u003c\/p\u003e \u003cp\u003e12.7 Cyclooctatetraene Dianion Compounds 253\u003c\/p\u003e \u003cp\u003e12.8 Arene Complexes 254\u003c\/p\u003e \u003cp\u003e12.8.1 Simple Arene Derivatives 254\u003c\/p\u003e \u003cp\u003e12.8.2 Arene-Supported Triazacyclononane Derivatives 254\u003c\/p\u003e \u003cp\u003e12.9 Carbonyls 256\u003c\/p\u003e \u003cp\u003e12.10 Compounds with Actinide-metal Bonds 257\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Synthesis of the Transactinides and Their Chemistry 260\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 260\u003c\/p\u003e \u003cp\u003e13.2 Finding New Elements 261\u003c\/p\u003e \u003cp\u003e13.3 Synthesis of the Transactinides 261\u003c\/p\u003e \u003cp\u003e13.4 Naming the Transactinides 265\u003c\/p\u003e \u003cp\u003e13.5 Predicting Electronic Arrangements 266\u003c\/p\u003e \u003cp\u003e13.6 Identifying the Elements 266\u003c\/p\u003e \u003cp\u003e13.7 Predicting Chemistry of the Transactinides 272\u003c\/p\u003e \u003cp\u003e13.8 What Is Known about the Chemistry of the Transactinides 273\u003c\/p\u003e \u003cp\u003e13.8.1 Element 104 273\u003c\/p\u003e \u003cp\u003e13.8.2 Element 105 273\u003c\/p\u003e \u003cp\u003e13.8.3 Element 106 274\u003c\/p\u003e \u003cp\u003e13.8.4 Element 107 274\u003c\/p\u003e \u003cp\u003e13.8.5 Element 108 274\u003c\/p\u003e \u003cp\u003e13.8.6 Elements 112 and 114 276\u003c\/p\u003e \u003cp\u003e13.9 And the Future? 276\u003c\/p\u003e \u003cp\u003eReferences 278\u003c\/p\u003e \u003cp\u003eIndex 310\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49406938448215,"sku":"9781118873496","price":66.5,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781118873496.jpg?v=1730497622","url":"https:\/\/bookcurl.com\/products\/lanthanide-and-actinide-chemistry-9781118873496","provider":"Book Curl","version":"1.0","type":"link"}