{"product_id":"keynotes-in-organic-chemistry-9781119999140","title":"Keynotes in Organic Chemistry","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis concise and accessible book provides organic chemistry notes for students studying chemistry and related courses at undergraduate level, covering core organic chemistry in a format ideal for learning and rapid revision.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e“I recommend instructors delivering undergraduate organic chemistry consider promoting this textbook to their students as a keynote revision guide.”  (\u003ci\u003eAppl. Organometal. Chem\u003c\/i\u003e, 17 November 2014)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Structure and bonding 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Ionic versus covalent bonds 1\u003c\/p\u003e \u003cp\u003e1.2 The octet rule 2\u003c\/p\u003e \u003cp\u003e1.3 Formal charge 2\u003c\/p\u003e \u003cp\u003e1.4 Sigma and pi bonds 3\u003c\/p\u003e \u003cp\u003e1.5 Hybridisation 4\u003c\/p\u003e \u003cp\u003e1.6 Inductive effects, hyperconjugation and mesomeric effects 6\u003c\/p\u003e \u003cp\u003e1.7 Acidity and basicity 9\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Functional groups, nomenclature and drawing organic compounds 21\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Functional groups 21\u003c\/p\u003e \u003cp\u003e2.2 Alkyl and aryl groups 22\u003c\/p\u003e \u003cp\u003e2.3 Alkyl substitution 23\u003c\/p\u003e \u003cp\u003e2.4 Naming carbon chains 23\u003c\/p\u003e \u003cp\u003e2.5 Drawing organic structures 27\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Stereochemistry 31\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Isomerism 31\u003c\/p\u003e \u003cp\u003e3.2 Conformational isomers 32\u003c\/p\u003e \u003cp\u003e3.3 Configurational isomers 37\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Reactivity and mechanism 49\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Reactive intermediates: ions versus radicals 49\u003c\/p\u003e \u003cp\u003e4.2 Nucleophiles and electrophiles 51\u003c\/p\u003e \u003cp\u003e4.3 Carbocations, carbanions and carbon radicals 53\u003c\/p\u003e \u003cp\u003e4.4 Steric effects 55\u003c\/p\u003e \u003cp\u003e4.5 Oxidation levels 55\u003c\/p\u003e \u003cp\u003e4.6 General types of reaction 56\u003c\/p\u003e \u003cp\u003e4.7 Ions versus radicals 59\u003c\/p\u003e \u003cp\u003e4.8 Reaction selectivity 60\u003c\/p\u003e \u003cp\u003e4.9 Reaction thermodynamics and kinetics 60\u003c\/p\u003e \u003cp\u003e4.10 Orbital overlap and energy 65\u003c\/p\u003e \u003cp\u003e4.11 Guidelines for drawing reaction mechanisms 67\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Halogenoalkanes 73\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Structure 73\u003c\/p\u003e \u003cp\u003e5.2 Preparation 74\u003c\/p\u003e \u003cp\u003e5.3 Reactions 78\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Alkenes and alkynes 95\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Structure 95\u003c\/p\u003e \u003cp\u003e6.2 Alkenes 97\u003c\/p\u003e \u003cp\u003e6.3 Alkynes 110\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Benzenes 117\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Structure 117\u003c\/p\u003e \u003cp\u003e7.2 Reactions 119\u003c\/p\u003e \u003cp\u003e7.3 Reactivity of substituted benzenes 123\u003c\/p\u003e \u003cp\u003e7.4 Nucleophilic aromatic substitution (the SNAr mechanism) 127\u003c\/p\u003e \u003cp\u003e7.5 The formation of benzyne 128\u003c\/p\u003e \u003cp\u003e7.6 Transformation of side chains 129\u003c\/p\u003e \u003cp\u003e7.7 Reduction of the benzene ring 132\u003c\/p\u003e \u003cp\u003e7.8 The synthesis of substituted benzenes 132\u003c\/p\u003e \u003cp\u003e7.9 Electrophilic substitution of naphthalene 135\u003c\/p\u003e \u003cp\u003e7.10 Electrophilic substitution of pyridine 135\u003c\/p\u003e \u003cp\u003e7.11 Electrophilic substitution of pyrrole, furan and thiophene 136\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Carbonyl compounds: aldehydes and ketones 139\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Structure 139\u003c\/p\u003e \u003cp\u003e8.2 Reactivity 140\u003c\/p\u003e \u003cp\u003e8.3 Nucleophilic addition reactions 142\u003c\/p\u003e \u003cp\u003e8.4 a-Substitution reactions 156\u003c\/p\u003e \u003cp\u003e8.5 Carbonyl-carbonyl condensation reactions 160\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Carbonyl compounds: carboxylic acids and derivatives 167\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Structure 167\u003c\/p\u003e \u003cp\u003e9.2 Reactivity 168\u003c\/p\u003e \u003cp\u003e9.3 Nucleophilic acyl substitution reactions 168\u003c\/p\u003e \u003cp\u003e9.4 Nucleophilic substitution reactions of carboxylic acids 170\u003c\/p\u003e \u003cp\u003e9.5 Nucleophilic substitution reactions of acid chlorides 171\u003c\/p\u003e \u003cp\u003e9.6 Nucleophilic substitution reactions of acid anhydrides 172\u003c\/p\u003e \u003cp\u003e9.7 Nucleophilic substitution reactions of esters 173\u003c\/p\u003e \u003cp\u003e9.8 Nucleophilic substitution and reduction reactions of amides 175\u003c\/p\u003e \u003cp\u003e9.9 Nucleophilic addition reactions of nitriles 176\u003c\/p\u003e \u003cp\u003e9.10 a-Substitution reactions of carboxylic acids 178\u003c\/p\u003e \u003cp\u003e9.11 Carbonyl-carbonyl condensation reactions 178\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Spectroscopy 185\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Mass spectrometry (MS) 185\u003c\/p\u003e \u003cp\u003e10.2 The electromagnetic spectrum 189\u003c\/p\u003e \u003cp\u003e10.3 Ultraviolet (UV) spectroscopy 190\u003c\/p\u003e \u003cp\u003e10.4 Infrared (IR) spectroscopy 192\u003c\/p\u003e \u003cp\u003e10.5 Nuclear magnetic resonance (NMR) spectroscopy 194\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Natural products and synthetic polymers 207\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Carbohydrates 207\u003c\/p\u003e \u003cp\u003e11.2 Lipids 209\u003c\/p\u003e \u003cp\u003e11.3 Amino acids, peptides and proteins 211\u003c\/p\u003e \u003cp\u003e11.4 Nucleic acids 213\u003c\/p\u003e \u003cp\u003e11.5 Synthetic polymers 214\u003c\/p\u003e \u003cp\u003eWorked example 218\u003c\/p\u003e \u003cp\u003eProblems 219\u003c\/p\u003e \u003cp\u003eAppendix 1: Bond dissociation enthalpies 221\u003c\/p\u003e \u003cp\u003eAppendix 2: Bond lengths 223\u003c\/p\u003e \u003cp\u003eAppendix 3: Approximate pKa values (relative to water) 225\u003c\/p\u003e \u003cp\u003eAppendix 4: Useful abbreviations 227\u003c\/p\u003e \u003cp\u003eAppendix 5: Infrared absorptions 229\u003c\/p\u003e \u003cp\u003eAppendix 6: Approximate NMR chemical shifts 231\u003c\/p\u003e \u003cp\u003eAppendix 7: Reaction summaries 235\u003c\/p\u003e \u003cp\u003eAppendix 8: Glossary 241\u003c\/p\u003e \u003cp\u003eFurther reading 249\u003c\/p\u003e \u003cp\u003eOutline answers 251\u003c\/p\u003e \u003cp\u003eIndex 277\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49407201968471,"sku":"9781119999140","price":29.4,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119999140.jpg?v=1730498547","url":"https:\/\/bookcurl.com\/products\/keynotes-in-organic-chemistry-9781119999140","provider":"Book Curl","version":"1.0","type":"link"}