{"product_id":"homogeneous-catalysts-activity-stability-deactivation-9783527323296","title":"Homogeneous Catalysts: Activity - Stability - Deactivation","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste.\u003cbr\u003e The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. \u003cbr\u003e The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with\/on organometallics.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e“The text is well-arranged thorough the monograph. The clear style makes it easy to read, further supported by the very informative formulas and figures. It is highly recommended for experts and novices and should serve as a primary source of valuable information not only for academics but also for industrial researchers. This very particular book should be an essential addition to any meaningful institutional library collection.”  (\u003ci\u003eCatal Lett\u003c\/i\u003e, 1 October 2013)\u003c\/p\u003e \u003cp\u003e\"This volume provides an up to date, well-informed appraisal of issues concerning activity and stability of homogeneous transition metal catalysts. It will prove to be a valuable source of information for researchers working in this field, from graduate students and academics to process chemists in industry.\" (Chemistry World, 2012)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eELEMENTARY STEPS\u003cbr\u003e Introduction\u003cbr\u003e Metal Deposition\u003cbr\u003e Ligand Decomposition by Oxidation\u003cbr\u003e Phosphines\u003cbr\u003e Phosphites\u003cbr\u003e Imines and Pyridines\u003cbr\u003e Carbenes\u003cbr\u003e Reactions of Metal-Carbon and Metal-Hydride Bonds\u003cbr\u003e Reactions Blocking the Active Sites\u003cbr\u003e EARLY TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION\u003cbr\u003e Ziegler-Natta Catalysts\u003cbr\u003e Metallocenes\u003cbr\u003e Other Single-Center Catalysts\u003cbr\u003e Vanadium-Based Catalysts\u003cbr\u003e Chromium-Based Catalysts\u003cbr\u003e Conclusions\u003cbr\u003e LATE TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION\u003cbr\u003e Nickel- and Palladium-Based Catalysts\u003cbr\u003e Iron- and Cobalt-Based Catalysts\u003cbr\u003e Conclusions\u003cbr\u003e EFFECTS OF IMMOBILIZATION OF CATALYSTS FOR OLEFIN POLYMERIZATION\u003cbr\u003e Introduction\u003cbr\u003e Metallocenes and Related Complexes\u003cbr\u003e Other Titanium and Zirconium Complexes\u003cbr\u003e Vanadium Complexes\u003cbr\u003e Chromium Complexes\u003cbr\u003e Nickel Complexes\u003cbr\u003e Iron Complexes\u003cbr\u003e Conclusions\u003cbr\u003e DORMANT SPECIES IN TRANSITION METAL-CATALYZED OLEFIN POLYMERIZATION\u003cbr\u003e Introduction\u003cbr\u003e Ziegler-Natta Catalysts\u003cbr\u003e Metallocenes and Related Early Transition Metal Catalysts\u003cbr\u003e Late Transition Metal Catalysts\u003cbr\u003e Reversible Chain Transfer in Olefin Polymerization\u003cbr\u003e Conclusions\u003cbr\u003e TRANSITION METAL CATALYZED OLEFIN OLIGOMERIZATION\u003cbr\u003e Introduction\u003cbr\u003e Zirconium Catalysts\u003cbr\u003e Titanium Catalysts\u003cbr\u003e Tantalum Catalysts\u003cbr\u003e Chromium Catalysts\u003cbr\u003e Nickel Catalysts\u003cbr\u003e Iron Catalysts\u003cbr\u003e Tandem Catalysis Involving Oligomerization and Polymerization\u003cbr\u003e Conclusions\u003cbr\u003e ASYMMETRIC HYDROGENATION\u003cbr\u003e Introduction\u003cbr\u003e Incubation by Dienes in Rhodium Diene Precursors\u003cbr\u003e Inhibition by Substrates, Solvents, Polar Additives, and Impurities\u003cbr\u003e Inhibition by Formation of Bridged Species\u003cbr\u003e Inhibition by Ligand Decomposition\u003cbr\u003e Inhibition by the Product\u003cbr\u003e Inhibition by Metal Formation;\u003cbr\u003e Heterogeneous Catalysis by Metals\u003cbr\u003e Selective Activation and Deactivation of Enantiomeric Catalysts\u003cbr\u003e Conclusions\u003cbr\u003e CARBONYLATION REACTIONS\u003cbr\u003e Introduction\u003cbr\u003e Cobalt-Catalyzed Hydroformylation\u003cbr\u003e Rhodium-Catalyzed Hydroformylation\u003cbr\u003e Palladium-Catalyzed Alkene-CO Reactions\u003cbr\u003e Methanol Carbonylation\u003cbr\u003e Conclusions\u003cbr\u003e METAL-CATALYZED CROSS-COUPLING REACTIONS\u003cbr\u003e Introduction: A Few Historic Notes\u003cbr\u003e On the Mechanism of Initiation and Precursors\u003cbr\u003e Transmetallation\u003cbr\u003e Reductive Elimination\u003cbr\u003e Phosphine Decomposition\u003cbr\u003e Metal Impurities\u003cbr\u003e Metal Nanoparticles and Supported Metal Catalysts\u003cbr\u003e Conclusions\u003cbr\u003e ALKENE METATHESIS\u003cbr\u003e Introduction\u003cbr\u003e Molybdenum and Tungsten Catalysts\u003cbr\u003e Rhenium Catalysts\u003cbr\u003e Ruthenium Catalysts\u003cbr\u003e Conclusions","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":53196946374999,"sku":"9783527323296","price":131.35,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/homogeneous-catalysts-activity-stability-deactivation-9783527323296","provider":"Book Curl","version":"1.0","type":"link"}