{"product_id":"handbook-of-free-radical-initiators-9780471207535","title":"Handbook of Free Radical Initiators","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eFree radical initiators-chemical molecules which easily decompose into free radicals-serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\"…the aim of the handbook, which was to give relevant information regarding free radical initiation, initiators, and reactions involving radicals was achieved…\" (\u003ci\u003ePolymer News\u003c\/i\u003e, 2004 Vol. 29)  \u003cp\u003e“...will be useful to all users of free-radical initiators...” (\u003ci\u003eAngewandte Chemie International Edition\u003c\/i\u003e, Vol. 43, 2004)\u003c\/p\u003e \u003cp\u003e\"...a valuable resource...\" (\u003ci\u003ePolymer News\u003c\/i\u003e)\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePreface \u003cp\u003eSymbols and Abbreviations.\u003c\/p\u003e \u003cp\u003ePART I: INITIATORS.\u003c\/p\u003e \u003cp\u003eChapter 1. Mechanism of Decomposition of Initiators.\u003c\/p\u003e \u003cp\u003e1.1 Introduction.\u003c\/p\u003e \u003cp\u003e1.2 Nonconcerted Unimolecular Decomposition.\u003c\/p\u003e \u003cp\u003e1.3 Concerted Fragmentation of Initiators.\u003c\/p\u003e \u003cp\u003e1.4 Anchimerically Assisted Decomposition of Peroxides.\u003c\/p\u003e \u003cp\u003e1.5 Decay of Initiators to Free Radicals and Molecular Products.\u003c\/p\u003e \u003cp\u003e1.6 Chain Decomposition of Initiators.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 2. Cage Effect.\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Experimental Evidence for the Cage Effect.\u003c\/p\u003e \u003cp\u003e2.3 Mechanistic Schemes of Cage Effect.\u003c\/p\u003e \u003cp\u003e2.4 Cage Effect in Solid Polymers.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 3. Methods of Study of Initiator Decomposition and Free Radical Generation.\u003c\/p\u003e \u003cp\u003e3.1 Kinetic Decay of Initiator (KDI).\u003c\/p\u003e \u003cp\u003e3.2 Kinetic Product Formation (KPF).\u003c\/p\u003e \u003cp\u003e3.3 Acceptors of Free Radicals (AFR).\u003c\/p\u003e \u003cp\u003e3.4 Kinetic Chain Initiated Reaction (KIR).\u003c\/p\u003e \u003cp\u003e3.5 Chemiluminescence (CL) Method.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 4. Dialkyl Peroxides and Hydroperoxides.\u003c\/p\u003e \u003cp\u003e4.1 Dialkyl Peroxides.\u003c\/p\u003e \u003cp\u003e4.2 Hydroperoxides and Peracids.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 5. Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides.\u003c\/p\u003e \u003cp\u003e5.1 Diacyl Peroxides.\u003c\/p\u003e \u003cp\u003e5.2 Peroxy Esters.\u003c\/p\u003e \u003cp\u003e5.3 Decomposition of Polyatomic Peroxides.\u003c\/p\u003e \u003cp\u003e5.4 Organometallic Peroxides.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 6. Organic Polyoxides.\u003c\/p\u003e \u003cp\u003e6.1 Dialkyl Trioxides.\u003c\/p\u003e \u003cp\u003e6.2 Hydrotrioxides.\u003c\/p\u003e \u003cp\u003e6.3 Tetroxides.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 7. Azo Compounds.\u003c\/p\u003e \u003cp\u003e7.1 Synthesis and Structure of Azo Compounds.\u003c\/p\u003e \u003cp\u003e7.2 Thermochemistry of Azo Compounds.\u003c\/p\u003e \u003cp\u003e7.3 Decomposition of Azo Compounds.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 8. Compounds with Weak C-C, N-N, C-N and N-O Bonds.\u003c\/p\u003e \u003cp\u003e8.1 Polyphenylhydrocarbons.\u003c\/p\u003e \u003cp\u003e8.2 Substituted Hydrazines.\u003c\/p\u003e \u003cp\u003e8.3 Alkoxyamines.\u003c\/p\u003e \u003cp\u003e8.4 Nitro Compounds.\u003c\/p\u003e \u003cp\u003e8.5 Nitrates and Nitrites.\u003c\/p\u003e \u003cp\u003e8.6 Disulfides and Polysulfides.\u003c\/p\u003e \u003cp\u003e8.7 Organometallic Compounds.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003ePART II: BIMOLECULAR REACTIONS OF FREE RADICAL GENERATION.\u003c\/p\u003e \u003cp\u003eChapter 9. Parabolic Model of Bimolecular Homolytic Reaction.\u003c\/p\u003e \u003cp\u003e9.1 Introduction.\u003c\/p\u003e \u003cp\u003e9.2 Principles for the Parabolic Model of Bimolecular Homolytic Reaction.\u003c\/p\u003e \u003cp\u003e9.3 Parameters of Bimolecular Homolytic Reaction in the Parabolic Model.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 10. Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen.\u003c\/p\u003e \u003cp\u003e10.1 Reaction of Dioxygen with C-H Bonds of Organic Compounds.\u003c\/p\u003e \u003cp\u003e10.2 Reaction of Dioxygen with the Double Bond of Olefins.\u003c\/p\u003e \u003cp\u003e10.3 Trimolecular Reaction of Radical Initiation by Dioxygen.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 11. Bimolecular Reactions of Free Radical Generation by Ozone.\u003c\/p\u003e \u003cp\u003e11.1 Initiation of Radicals by Ozone Reactions.\u003c\/p\u003e \u003cp\u003e11.2 Chain Reactions of Ozone Decomposition.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 12. Bimolecular Reactions of Hydroperoxides with Free Radical Generation.\u003c\/p\u003e \u003cp\u003e12.1 Bimolecular Decomposition of Hydroperoxides.\u003c\/p\u003e \u003cp\u003e12.2 Bimolecular Reactions of Hydroperoxides with a π-Bond to Olefins.\u003c\/p\u003e \u003cp\u003e12.3 Bimolecular Reactions of Hydroperoxides with C-H, N-H, and O-H Bonds of Organic Compounds.\u003c\/p\u003e \u003cp\u003e12.4 Acid Catalysis for Homolytic Reactions of Hydroperoxides.\u003c\/p\u003e \u003cp\u003e12.5 Reaction of Peroxides with Amines.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 13. Free Radical Generation by Olefins.\u003c\/p\u003e \u003cp\u003e13.1 Reactions of Retrodisproportionation.\u003c\/p\u003e \u003cp\u003e13.2 Chain Initiation in Thermal Radical Polymerization.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 14. Free Radicals Generation by Haloid Molecules and Nitrogen Dioxide.\u003c\/p\u003e \u003cp\u003e14.1 Reactions of Fluorine Compounds.\u003c\/p\u003e \u003cp\u003e14.2 Reactions of Dichlorine and Other Chlorine Compounds.\u003c\/p\u003e \u003cp\u003e14.3 Initiation by Nitrogen Dioxide.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 15. Free Radical Generation by Reactions of Ions with Molecules.\u003c\/p\u003e \u003cp\u003e15.1 Decomposition of Hydrogen Peroxide Catalyzed by Transition Metal Ions.\u003c\/p\u003e \u003cp\u003e15.2 Catalysis by Ions and Complexes of Transition Metals in Liquid-Phase Oxidation of Organic Compounds.\u003c\/p\u003e \u003cp\u003e15.3 Reactions of Free Radicals with Transition Metal Ions.\u003c\/p\u003e \u003cp\u003e15.4 Oxidation of Transition Metal Ions by Dioxygen.\u003c\/p\u003e \u003cp\u003e15.5 Oxidation of Organic Compounds by Transition Metal Ions.\u003c\/p\u003e \u003cp\u003e15.6 Reduction of Peroxides by Radical Anions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003ePART III: REACTIONS OF FREE RADICALS.\u003c\/p\u003e \u003cp\u003eChapter 16. Isomerization and Decomposition of Free Radicals.\u003c\/p\u003e \u003cp\u003e16.1 Intramolecular Abstraction of Hydrogen Atom.\u003c\/p\u003e \u003cp\u003e16.2 Cyclization of Free Radicals.\u003c\/p\u003e \u003cp\u003e16.3 Decyclization of Cyclic Radicals.\u003c\/p\u003e \u003cp\u003e16.4 Fragmentation of Free Radicals.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 17. Free Radical Abstraction Reactions.\u003c\/p\u003e \u003cp\u003e17.1 Classification of Radical Abstraction Reactions.\u003c\/p\u003e \u003cp\u003e17.2 Enthalpy of Reaction.\u003c\/p\u003e \u003cp\u003e17.3 Force Constants of Reacting Bonds.\u003c\/p\u003e \u003cp\u003e17.4 Triplet Repulsion.\u003c\/p\u003e \u003cp\u003e17.5 Electron Affinity of Atoms in Reaction Center.\u003c\/p\u003e \u003cp\u003e17.6 Repulsion of Atoms Forming the Reaction Center.\u003c\/p\u003e \u003cp\u003e17.7 Influence of π-Bonds in the Vicinity of the Reaction Center.\u003c\/p\u003e \u003cp\u003e17.8 Steric Effect.\u003c\/p\u003e \u003cp\u003e17.9 Polar Effect in Radical Reactions.\u003c\/p\u003e \u003cp\u003e17.10 Effect of Multidipole Interaction.\u003c\/p\u003e \u003cp\u003e17.11 Solvating Effect.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 18. Free Radical Reactions of Hydrogen Transfer and Substitution.\u003c\/p\u003e \u003cp\u003e18.1 Reactions of Hydrogen Atom Transfer from a Free Radical to a Molecule.\u003c\/p\u003e \u003cp\u003e18.2 Free Radical Substitution Reactions.\u003c\/p\u003e \u003cp\u003e18.3 Reaction of Peroxides with Ketyl Radicals.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 19. Free Radical Addition.\u003c\/p\u003e \u003cp\u003e19.1 Enthalpy and Entropy of Free Radical Addition.\u003c\/p\u003e \u003cp\u003e19.2 Empirical Correlation Equations.\u003c\/p\u003e \u003cp\u003e19.3 Quantum Chemical Calculations for the Activation Energy.\u003c\/p\u003e \u003cp\u003e19.4 Parabolic Model of Radical Addition.\u003c\/p\u003e \u003cp\u003e19.5 Contribution of Enthalpy for an Addition Reaction to Its Activation Energy.\u003c\/p\u003e \u003cp\u003e19.6 Force Constants of Reacting Bonds.\u003c\/p\u003e \u003cp\u003e19.7 Triplet Repulsion in the Transition State of Addition Reactions.\u003c\/p\u003e \u003cp\u003e19.8 Influence of Neighboring π-Bonds on the Activation Energy of Radical Addition.\u003c\/p\u003e \u003cp\u003e19.9 Role of the Radius of the Atom Bearing the Free Valence.\u003c\/p\u003e \u003cp\u003e19.10 Interaction of Two Polar Groups.\u003c\/p\u003e \u003cp\u003e19.11 Multidipole Interaction in Addition Reactions.\u003c\/p\u003e \u003cp\u003e19.12 Steric Hindrance.\u003c\/p\u003e \u003cp\u003e19.13 Addition of Alkyl Radicals to Dioxygen.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eChapter 20. Recombination and Disproportionation of Free Radicals.\u003c\/p\u003e \u003cp\u003e20.1 Alkyl Radicals.\u003c\/p\u003e \u003cp\u003e20.2 Macroradicals.\u003c\/p\u003e \u003cp\u003e20.3 Peroxyl Radicals.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003eIndex.\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49525401190743,"sku":"9780471207535","price":474.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780471207535.jpg?v=1731860373","url":"https:\/\/bookcurl.com\/products\/handbook-of-free-radical-initiators-9780471207535","provider":"Book Curl","version":"1.0","type":"link"}