{"product_id":"handbook-of-aggregationinduced-emission-volume-2-9781119642985","title":"Handbook of AggregationInduced Emission Volume 2","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eThesecond volume of theultimate reference on the science and applications of aggregation-induced emission\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eTheHandbook of Aggregation-Induced Emission\u003c\/i\u003eexplores foundational and advanced topics in aggregation-induced emission, as well as cutting-edge developments in the field,celebratingtwenty years of progress and achievement in this important and interdisciplinary field.The three volumes combine to offer readers a comprehensive and insightful interpretation accessible to both new and experiencedresearchersworking on aggregation-induced emission.\u003c\/p\u003e \u003cp\u003eIn\u003ci\u003eVolume 2: TypicalAIEgensDesign\u003c\/i\u003e,the editorsaddress the design and synthesis of typicalAIEgensthat have made significant contributions toaggregation-induced emissionresearch.Recent advances in the development ofaggregation-induced emissionsystems are discussedand the bookcoversnovelaggregation-induced emissionsystems in small moleculeorganogels,polymersomes,metal-organic coordination complexes and metal nano\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003c\/p\u003e\u003cp\u003eList of Contributors xvii\u003c\/p\u003e \u003cp\u003ePreface to Handbook of Aggregation-Induced Emission xxiii\u003c\/p\u003e \u003cp\u003ePreface to Volume 2: Typical AIEgens Design xxv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Tetraphenylpyrazine-based AIEgens: Synthesis and Applications \u003c\/b\u003e\u003cb\u003e1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMing Chen, Anjun Qin, and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Synthesis of TPP-based AIEgens 3\u003c\/p\u003e \u003cp\u003e1.2.1 Cyclization Reaction 3\u003c\/p\u003e \u003cp\u003e1.2.2 Suzuki–Miyaura Reaction 7\u003c\/p\u003e \u003cp\u003e1.3 Functionalities of TPP-based AIEgens 8\u003c\/p\u003e \u003cp\u003e1.3.1 Organic Light-emitting Diodes 8\u003c\/p\u003e \u003cp\u003e1.3.2 Fluorescent Sensors 9\u003c\/p\u003e \u003cp\u003e1.3.3 Chiral Cage for Self-assembly to Achieve White-light Emission 13\u003c\/p\u003e \u003cp\u003e1.3.4 Metal–organic Framework 15\u003c\/p\u003e \u003cp\u003e1.4 Conclusion 17\u003c\/p\u003e \u003cp\u003eReferences 18\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 AIEgens Based on 9,10-Distyrylanthracene (DSA): From Small Molecules to Macromolecules 23\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLeijing Liu, Bin Xu, and Wenjing Tian\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 23\u003c\/p\u003e \u003cp\u003e2.2 Application of AIE Luminogens Based on 9,10-Distyrylanthracene 24\u003c\/p\u003e \u003cp\u003e2.2.1 Smart Materials with Stimulus Response 24\u003c\/p\u003e \u003cp\u003e2.2.1.1 Piezofluorochromic Materials 24\u003c\/p\u003e \u003cp\u003e2.2.1.2 Photochromic Materials 27\u003c\/p\u003e \u003cp\u003e2.2.1.3 Thermochromic Materials 27\u003c\/p\u003e \u003cp\u003e2.2.1.4 Acidichromic Materials 27\u003c\/p\u003e \u003cp\u003e2.2.1.5 Multistimuli-responsive Materials 30\u003c\/p\u003e \u003cp\u003e2.2.2 High Solid-state Luminescent Materials 30\u003c\/p\u003e \u003cp\u003e2.2.3 Fluorescent Materials for Bioimaging 35\u003c\/p\u003e \u003cp\u003e2.2.4 Fluorescent Probes for Chemical and Biological Sensing 41\u003c\/p\u003e \u003cp\u003e2.2.4.1 Fluorescent Probes for Chemical Sensing 41\u003c\/p\u003e \u003cp\u003e2.2.4.2 Fluorescent Probes for Biological Sensing 44\u003c\/p\u003e \u003cp\u003e2.3 Conclusions and Outlook 46\u003c\/p\u003e \u003cp\u003eAcknowledgments 47\u003c\/p\u003e \u003cp\u003eReferences 47\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Typical AIEgens Design: Salicylaldehyde Schiff Base 53\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYue Zheng and Aijun Tong\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 53\u003c\/p\u003e \u003cp\u003e3.1.1 AIE and ESIPT of Salicylaldehyde Schiff Base 53\u003c\/p\u003e \u003cp\u003e3.1.2 Universal Design of SSB-based AIEgens 55\u003c\/p\u003e \u003cp\u003e3.2 Fluorescent Probes 55\u003c\/p\u003e \u003cp\u003e3.2.1 Metal Ion Detection and Imaging 55\u003c\/p\u003e \u003cp\u003e3.2.2 Biologically and Environmentally Related Molecular Detection and Imaging 63\u003c\/p\u003e \u003cp\u003e3.2.3 Ratiometric pH Probes 76\u003c\/p\u003e \u003cp\u003e3.2.4 Bioimaging 76\u003c\/p\u003e \u003cp\u003e3.3 Fluorescent Materials 81\u003c\/p\u003e \u003cp\u003e3.3.1 Solid Fluorescence Emitting and Stimuli-Responsive Materials 81\u003c\/p\u003e \u003cp\u003e3.3.2 Nanoparticles 88\u003c\/p\u003e \u003cp\u003e3.4 Summary and Perspectives 91\u003c\/p\u003e \u003cp\u003eReferences 92\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Diaminodicyanoquinodimethanes: Fluorescence Emission Enhancement  in Aggregates and Solids 97\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eN. Senthilnathan and T. P. Radhakrishnan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 97\u003c\/p\u003e \u003cp\u003e4.1.1 Molecular Materials 97\u003c\/p\u003e \u003cp\u003e4.1.2 ‘Push–Pull’ Molecules 97\u003c\/p\u003e \u003cp\u003e4.1.3 Diaminodicyanoquinodimethanes 98\u003c\/p\u003e \u003cp\u003e4.2 Nonlinear Optical Materials based on DADQs 100\u003c\/p\u003e \u003cp\u003e4.2.1 Molecular Hyperpolarizability 100\u003c\/p\u003e \u003cp\u003e4.2.2 SHG Materials 100\u003c\/p\u003e \u003cp\u003e4.2.3 Structure–Property Correlations 101\u003c\/p\u003e \u003cp\u003e4.3 Enhanced Fluorescence in Aggregates and Solids Based on DADQs 102\u003c\/p\u003e \u003cp\u003e4.3.1 Remote Functionalized Systems 102\u003c\/p\u003e \u003cp\u003e4.3.2 Color Tuning, Nanocrystals, and Colloids 103\u003c\/p\u003e \u003cp\u003e4.3.3 Ultrathin Films 105\u003c\/p\u003e \u003cp\u003e4.3.4 New Directions 105\u003c\/p\u003e \u003cp\u003e4.4 Mechanistic Insights into the Enhanced Fluorescence 106\u003c\/p\u003e \u003cp\u003e4.4.1 Relevance of Intramolecular Effects 106\u003c\/p\u003e \u003cp\u003e4.4.2 Role of Intermolecular Effects 106\u003c\/p\u003e \u003cp\u003e4.5 Impact of Crystallinity on the Fluorescence Response 108\u003c\/p\u003e \u003cp\u003e4.5.1 Amorphous-to-Crystalline Transformation: Fluorescence Switching and Tuning 108\u003c\/p\u003e \u003cp\u003e4.5.2 Reversible Amorphous–Crystalline Transformations: Phase Change Materials 108\u003c\/p\u003e \u003cp\u003e4.5.3 Impact of External Stimuli 110\u003c\/p\u003e \u003cp\u003e4.6 Emergent and Potential Applications of DADQs 110\u003c\/p\u003e \u003cp\u003e4.6.1 Electroluminescence and Nonlinear Optics 110\u003c\/p\u003e \u003cp\u003e4.6.2 Bioimaging 110\u003c\/p\u003e \u003cp\u003e4.6.3 Photoelectrochemical and Photobioelectrochemical Applications 112\u003c\/p\u003e \u003cp\u003e4.6.4 Memory Devices 112\u003c\/p\u003e \u003cp\u003e4.7 Concluding\u003c\/p\u003e \u003cp\u003eRemarks 113\u003c\/p\u003e \u003cp\u003eAcknowledgements 114\u003c\/p\u003e \u003cp\u003eReferences 114\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Aggregation-induced Emission from the Sixth Main Group \u003c\/b\u003e\u003cb\u003e119\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJan Balszuweit, Bibhisan Roy, and Jens Voskuhl\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 119\u003c\/p\u003e \u003cp\u003e5.2 Oxygen 119\u003c\/p\u003e \u003cp\u003e5.2.1 Oxygen-Containing Heterocycles 120\u003c\/p\u003e \u003cp\u003e5.2.2 Oxo-ether Containing AIE-Active Luminogens 122\u003c\/p\u003e \u003cp\u003e5.3 Sulfur 126\u003c\/p\u003e \u003cp\u003e5.3.1 Luminogens Based on Thiophenes 126\u003c\/p\u003e \u003cp\u003e5.3.2 Thioethers with Aggregation-Induced Emission Properties 129\u003c\/p\u003e \u003cp\u003e5.3.3 Emissive Sulfones 131\u003c\/p\u003e \u003cp\u003e5.4 Selenium and Tellurium 132\u003c\/p\u003e \u003cp\u003e5.4.1 Selenium-Containing Luminophores 132\u003c\/p\u003e \u003cp\u003e5.4.2 Tellurium-Containing Luminophores 134\u003c\/p\u003e \u003cp\u003e5.5 Conclusion 138\u003c\/p\u003e \u003cp\u003eAcknowledgment 138\u003c\/p\u003e \u003cp\u003eReferences 138\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Fluorescence Detection of Dynamic Aggregation Processes Using AIEgens: Hexaphenylsilole and Cyanostilbene \u003c\/b\u003e\u003cb\u003e143\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eFuyuki Ito\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 143\u003c\/p\u003e \u003cp\u003e6.2 Selective Detection of Phase Transformation During Evaporative Crystallization of Hexaphenylsilole 145\u003c\/p\u003e \u003cp\u003e6.3 Observation of the Initial Stage of Organic Crystal Formation During Solvent Evaporation Using a Cyanostilbene Derivative 149\u003c\/p\u003e \u003cp\u003e6.4 Chemometrix Analysis of the Aggregated Structure of Cyanostilbene in a Reprecipitation Solution Using Fluorescence Excitation Spectroscopy 152\u003c\/p\u003e \u003cp\u003e6.5 UV-triggered Fluorescence Enhancement of a Dicyanostilbene Derivative Film Cast from an Ethanol Solution 158\u003c\/p\u003e \u003cp\u003e6.6 Concluding Remarks 162\u003c\/p\u003e \u003cp\u003eAcknowledgments 162\u003c\/p\u003e \u003cp\u003eReferences 162\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Cyclic Triimidazole Derivatives: An Intriguing Family of Multifaceted Emitters \u003c\/b\u003e\u003cb\u003e165\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eElena Cariati, Elena Lucenti, Andrea Previtali, and Alessandra Forni\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 165\u003c\/p\u003e \u003cp\u003e7.2 The Protoype: Cyclic Triimidazole 166\u003c\/p\u003e \u003cp\u003e7.3 Halogenated Derivatives of Cyclic Triimidazole 175\u003c\/p\u003e \u003cp\u003e7.3.1 Bromine Derivatives 176\u003c\/p\u003e \u003cp\u003e7.3.2 Iodine Derivatives 179\u003c\/p\u003e \u003cp\u003e7.4 Organic Derivatives 184\u003c\/p\u003e \u003cp\u003e7.4.1 2-Fluoropyridine Derivative 185\u003c\/p\u003e \u003cp\u003e7.4.2 Tribenzoimidazole Derivative 186\u003c\/p\u003e \u003cp\u003e7.5 Hybrid Inorganic\/Organic Derivatives 188\u003c\/p\u003e \u003cp\u003e7.6 Conclusions 191\u003c\/p\u003e \u003cp\u003eAcknowledgments 191\u003c\/p\u003e \u003cp\u003eReferences 191\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Synthesis of Multi-phenyl-substituted Pyrrole (MPP)-based AIE Materials and Their Applications \u003c\/b\u003e\u003cb\u003e195\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eZhengxu Cai, Yunxiang Lei, and Yuping Dong\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 195\u003c\/p\u003e \u003cp\u003e8.2 Modular Approach: Systematic Synthesis of MPPs 196\u003c\/p\u003e \u003cp\u003e8.3 Structures and Photophysical Properties 198\u003c\/p\u003e \u003cp\u003e8.4 Applications of MPP-based Materials 204\u003c\/p\u003e \u003cp\u003e8.4.1 Chemical\/Biological Sensing 204\u003c\/p\u003e \u003cp\u003e8.4.2 Multi-stimulus Response Materials 208\u003c\/p\u003e \u003cp\u003e8.4.3 Optoelectronic Systems 210\u003c\/p\u003e \u003cp\u003e8.4.4 Biological Application 213\u003c\/p\u003e \u003cp\u003e8.5 Conclusion and Outlook 216\u003c\/p\u003e \u003cp\u003eReferences 216\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Development of a New Class of AIEgens: Tetraarylpyrrolo [3,2-\u003ci\u003eb\u003c\/i\u003e] Pyrroles (TAPPs) \u003c\/b\u003e\u003cb\u003e221\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eVishal G. More, Ratan W. Jadhav, Mohammad Al Kobaisi, Lathe A. Jones, and Sheshanath V. Bhosale\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 221\u003c\/p\u003e \u003cp\u003e9.2 The Accidental Discovery of TAPP 223\u003c\/p\u003e \u003cp\u003e9.3 Synthesis of TAPP 223\u003c\/p\u003e \u003cp\u003e9.4 Possible Mechanism of TAPP Synthesis 227\u003c\/p\u003e \u003cp\u003e9.5 Reactivity of TAPP 228\u003c\/p\u003e \u003cp\u003e9.6 π-Expansion of TAPP 229\u003c\/p\u003e \u003cp\u003e9.7 π-Expanded 1,4-dihydropyrrolo[3,2-\u003ci\u003eb\u003c\/i\u003e] pyrrole 231\u003c\/p\u003e \u003cp\u003e9.8 Photophysical Optical Properties of TAPP 239\u003c\/p\u003e \u003cp\u003e9.9 Conclusion and Outlook 245\u003c\/p\u003e \u003cp\u003eAcknowledgments 247\u003c\/p\u003e \u003cp\u003eReferences 247\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Small Molecule Organogels from AIE Active α-Cyanostilbenes \u003c\/b\u003e\u003cb\u003e255\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJagadish Katla, Beena Kumari, and Sriram Kanvah\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 255\u003c\/p\u003e \u003cp\u003e10.2 Organogels with Trifluoromethyl Substitution 256\u003c\/p\u003e \u003cp\u003e10.3 Organogels with Chiral Units\/Chiral Hosts 260\u003c\/p\u003e \u003cp\u003e10.4 Stimuli–Responsive Organogels 262\u003c\/p\u003e \u003cp\u003e10.5 Organogels with Sensing Applications 266\u003c\/p\u003e \u003cp\u003e10.6 Concluding Remarks 271\u003c\/p\u003e \u003cp\u003eAcknowledgments 271\u003c\/p\u003e \u003cp\u003eReferences 271\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Stimuli-responsive Pure Organic Luminescent Supramolecules \u003c\/b\u003e\u003cb\u003e277\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSiyu Sun and Xiang Ma\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 277\u003c\/p\u003e \u003cp\u003e11.2 Pure Organic Fluorescent Supramolecules 280\u003c\/p\u003e \u003cp\u003e11.2.1 Pure Organic Fluorescent Supramolecules Containing Macrocycles 280\u003c\/p\u003e \u003cp\u003e11.2.1.1 Pure Organic Fluorescent Supramolecules Containing Cyclodextrins 280\u003c\/p\u003e \u003cp\u003e11.2.1.2 Pure Organic Fluorescent Supramolecules Containing Calixarenes 284\u003c\/p\u003e \u003cp\u003e11.2.1.3 Pure Organic Fluorescent Supramolecules Containing Cucurbiturils 284\u003c\/p\u003e \u003cp\u003e11.2.1.4 Pure Organic Fluorescent Supramolecules Containing Pillararene 288\u003c\/p\u003e \u003cp\u003e11.2.1.5 Pure Organic Fluorescent Supramolecules Containing Crown Ether 290\u003c\/p\u003e \u003cp\u003e11.2.2 Pure Organic Fluorescent Supramolecules Without Macrocycles 291\u003c\/p\u003e \u003cp\u003e11.3 Pure Organic Phosphorescent Supramolecules 293\u003c\/p\u003e \u003cp\u003e11.3.1 Pure Organic Phosphorescent Supramolecules Based on Macrocyclic Molecules 293\u003c\/p\u003e \u003cp\u003e11.3.1.1 Pure Organic Phosphorescent Supramolecules Containing Cyclodextrin 293\u003c\/p\u003e \u003cp\u003e11.3.1.2 Pure Organic Phosphorescent Supramolecules Containing Cucurbiturils 297\u003c\/p\u003e \u003cp\u003e11.3.1.3 Pure Organic Phosphorescent Supramolecules Containing Calixarenes 297\u003c\/p\u003e \u003cp\u003e11.3.1.4 Pure Organic Phosphorescent Supramolecules Containing Crown Ether 297\u003c\/p\u003e \u003cp\u003e11.3.2 Pure Organic Phosphorescent Supramolecules Without Macrocyclic Molecules 299\u003c\/p\u003e \u003cp\u003e11.3.2.1 Pure Organic Supramolecular Phosphorescence System With Doping-Based Host–Guest Interaction 299\u003c\/p\u003e \u003cp\u003e11.3.2.2 Other Pure Organic Phosphorescent Supramolecules 301\u003c\/p\u003e \u003cp\u003e11.4 Conclusions 306\u003c\/p\u003e \u003cp\u003eAcknowledgments 306\u003c\/p\u003e \u003cp\u003eReferences 307\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 AIE Fluorescent Polymersomes \u003c\/b\u003e\u003cb\u003e311\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHui Chen and Min-Hui Li\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 311\u003c\/p\u003e \u003cp\u003e12.2 Structural Consideration of Block Copolymers for Polymersome Formation 314\u003c\/p\u003e \u003cp\u003e12.3 Methods of Polymersome Preparation 315\u003c\/p\u003e \u003cp\u003e12.4 Techniques of Polymersome Characterization 317\u003c\/p\u003e \u003cp\u003e12.5 AIE Polymersomes Based on PEG-\u003ci\u003eb\u003c\/i\u003e-POSS 317\u003c\/p\u003e \u003cp\u003e12.6 AIE Polymersomes Based on Amphiphilic Polypeptoids 319\u003c\/p\u003e \u003cp\u003e12.7 AIE Polymersomes Based on PEG-\u003ci\u003eb\u003c\/i\u003e-Polycarbonate 321\u003c\/p\u003e \u003cp\u003e12.8 AIE Polymersomes Based on Amphiphilic Polynorbornene 323\u003c\/p\u003e \u003cp\u003e12.9 AIE Polymersomes Based on Amphiphilic Block Copolymers by RAFT Polymerization 326\u003c\/p\u003e \u003cp\u003e12.10 Summary and Perspectives 330\u003c\/p\u003e \u003cp\u003eReferences 334\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Designs for AIE Molecules and Functional Luminescent Materials Based on Boron-containing Element-blocks \u003c\/b\u003e\u003cb\u003e341\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKazuo Tanaka, Masayuki Gon, Shunichiro Ito, and Yoshiki Chujo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 341\u003c\/p\u003e \u003cp\u003e13.1.1 Generals of Commodity Luminescent Boron Complexes 341\u003c\/p\u003e \u003cp\u003e13.1.2 Trends in the Development of Advanced Organic Electronic Devices 342\u003c\/p\u003e \u003cp\u003e13.1.3 Strategies for Obtaining Solid-state Luminescence and Stimuli-responsiveness 343\u003c\/p\u003e \u003cp\u003e13.1.4 New Ideas for Material Design Based on “Element-blocks” 343\u003c\/p\u003e \u003cp\u003e13.2 Solid-state Luminescence and Luminochromism of \u003ci\u003eo\u003c\/i\u003e-Carboranes 344\u003c\/p\u003e \u003cp\u003e13.2.1 Emission Mechanism of Aryl-modified \u003ci\u003eo\u003c\/i\u003e-Carboranes 344\u003c\/p\u003e \u003cp\u003e13.2.2 AIE Behavior of \u003ci\u003eo\u003c\/i\u003e-Carborane Materials 344\u003c\/p\u003e \u003cp\u003e13.2.3 Formation of Twisted Intramolecular Charge Transfer (TICT) State in the Crystalline State of \u003ci\u003eo\u003c\/i\u003e-Carboranes 346\u003c\/p\u003e \u003cp\u003e13.2.4 Thermochromic Luminescence of \u003ci\u003eo\u003c\/i\u003e-Carboranes 346\u003c\/p\u003e \u003cp\u003e13.2.5 Intense Solid-state Luminescent Molecules 347\u003c\/p\u003e \u003cp\u003e13.2.6 Solid-state Excimer Emission 348\u003c\/p\u003e \u003cp\u003e13.3 Boron Complexes with β-Ketimine and β-Diketimine Ligands 349\u003c\/p\u003e \u003cp\u003e13.3.1 Generals of Boron Ketiminates and Diketiminates 349\u003c\/p\u003e \u003cp\u003e13.3.2 Unique Solid-state Luminescent Properties of Conjugated Boron Complexes 350\u003c\/p\u003e \u003cp\u003e13.3.3 Thermally Stable Mechanochromic Luminescent Hybrid with the Siloxane Unit 350\u003c\/p\u003e \u003cp\u003e13.3.4 Luminescent Properties of β-Diketiminate Complexes 352\u003c\/p\u003e \u003cp\u003e13.3.5 AIE-active Conjugated Polymers 352\u003c\/p\u003e \u003cp\u003e13.3.6 Design for Film-type Sensors 353\u003c\/p\u003e \u003cp\u003e13.3.7 Sensitive Luminochromic Sensors with Gallium Complexes 354\u003c\/p\u003e \u003cp\u003e13.4 Rational Design for AIE-active Molecules Based on “Flexible” Boron Complexes 355\u003c\/p\u003e \u003cp\u003e13.4.1 Concept for Rational Design 355\u003c\/p\u003e \u003cp\u003e13.4.2 Ring-fused or Nonring-fused Molecules 355\u003c\/p\u003e \u003cp\u003e13.4.3 Thermosalient-active Molecules 357\u003c\/p\u003e \u003cp\u003e13.4.4 Solid-state Luminescent π-Conjugated Polymer 358\u003c\/p\u003e \u003cp\u003e13.5 Conclusion 359\u003c\/p\u003e \u003cp\u003eReferences 359\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Aggregation-induced Emission (AIE) Active Metal–Organic Coordination Complexes \u003c\/b\u003e\u003cb\u003e367\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eXueliang Shi, Xuzhou Yan, and Hai-Bo Yang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 367\u003c\/p\u003e \u003cp\u003e14.2 Conception and Design Strategy 368\u003c\/p\u003e \u003cp\u003e14.3 AIE Active Metallacycles 371\u003c\/p\u003e \u003cp\u003e14.3.1 AIE Active Simple Metallacycles 371\u003c\/p\u003e \u003cp\u003e14.3.2 AIE Active Fused Metallacycles 378\u003c\/p\u003e \u003cp\u003e14.3.3 AIE Active Metallacycle Polymers 382\u003c\/p\u003e \u003cp\u003e14.4 AIE Active Metallacages 389\u003c\/p\u003e \u003cp\u003e14.5 AIE Active Metal–organic Frameworks (MOFs) 397\u003c\/p\u003e \u003cp\u003e14.6 Summary and Outlook 405\u003c\/p\u003e \u003cp\u003eAcknowledgments 406\u003c\/p\u003e \u003cp\u003eReferences 406\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 AIE-type Luminescent Metal Nanoclusters \u003c\/b\u003e\u003cb\u003e411\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eZhennan Wu, Qiaofeng Yao, and Jianping Xie\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 411\u003c\/p\u003e \u003cp\u003e15.2 In the “Single-cluster” Scenario 412\u003c\/p\u003e \u003cp\u003e15.2.1 AIE-type Luminescent Metal NCs 412\u003c\/p\u003e \u003cp\u003e15.2.2 Atomically Precise AIE-type Luminescent Metal NCs 416\u003c\/p\u003e \u003cp\u003e15.2.3 Approaches to Luminescence Enhancement of Metal NCs in the Scheme of AIE 418\u003c\/p\u003e \u003cp\u003e15.2.3.1 Surface Engineering 418\u003c\/p\u003e \u003cp\u003e15.2.3.2 Roles of the Core 422\u003c\/p\u003e \u003cp\u003e15.3 Beyond the “Single-cluster” Scenario 423\u003c\/p\u003e \u003cp\u003e15.3.1 Poor-solvent-induced AIE of Metal NCs 423\u003c\/p\u003e \u003cp\u003e15.3.2 Ion-induced AIE of Metal NCs 423\u003c\/p\u003e \u003cp\u003e15.3.3 Supramolecular Interactions Induced AIE of Metal NCs 426\u003c\/p\u003e \u003cp\u003e15.3.4 Spatial Confinement-induced AIE of Metal NCs 429\u003c\/p\u003e \u003cp\u003e15.4 Application of the AIE-type Luminescent Metal NCs 433\u003c\/p\u003e \u003cp\u003e15.4.1 Chemical Sensing 433\u003c\/p\u003e \u003cp\u003e15.4.2 Biological Applications 434\u003c\/p\u003e \u003cp\u003e15.4.3 Photosensitizer 434\u003c\/p\u003e \u003cp\u003e15.4.4 Light-emitting Diodes (LEDs) 434\u003c\/p\u003e \u003cp\u003e15.5 Conclusion and Outlook 436\u003c\/p\u003e \u003cp\u003eReferences 437\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Aggregation-induced Emission in Coinage Metal Clusters \u003c\/b\u003e\u003cb\u003e443\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eShuang-Quan Zang and Kai Li\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 443\u003c\/p\u003e \u003cp\u003e16.2 AIE-active Gold Cluster 444\u003c\/p\u003e \u003cp\u003e16.3 AIE-active Silver Cluster 450\u003c\/p\u003e \u003cp\u003e16.4 AIE-active Copper Cluster 454\u003c\/p\u003e \u003cp\u003e16.5 AIE-active Bimetallic Cluster 462\u003c\/p\u003e \u003cp\u003e16.6 Conclusions 465\u003c\/p\u003e \u003cp\u003eReferences 466\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Activated Alkynes in Metal-free Bioconjugation \u003c\/b\u003e\u003cb\u003e471\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eXianglong Hu and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 471\u003c\/p\u003e \u003cp\u003e17.2 Alkyne–Azide-based Bioconjugation 472\u003c\/p\u003e \u003cp\u003e17.3 Activated Alkyne–Amine-based Bioconjugation 473\u003c\/p\u003e \u003cp\u003e17.4 Activated Alkyne–Thiol-based Bioconjugation 480\u003c\/p\u003e \u003cp\u003e17.5 Activated Alkyne–Hydroxyl-based Bioconjugation 483\u003c\/p\u003e \u003cp\u003e17.6 Activated Alkyne-based Bioconjugation and Polymerization in Living Cells and Pathogens 484\u003c\/p\u003e \u003cp\u003e17.7 Conclusion 488\u003c\/p\u003e \u003cp\u003eReferences 488\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 AIE-active BODIPY Derivatives \u003c\/b\u003e\u003cb\u003e493\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYali Liu, Yuzhang Huang, Rongrong Hu, and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 493\u003c\/p\u003e \u003cp\u003e18.2 Structures of BODIPY Derivatives 495\u003c\/p\u003e \u003cp\u003e18.2.1 BODIPY Derivatives Without Other Chromophore 495\u003c\/p\u003e \u003cp\u003e18.2.2 TPE-containing BODIPYs 496\u003c\/p\u003e \u003cp\u003e18.2.3 TPA-containing BODIPYs 498\u003c\/p\u003e \u003cp\u003e18.2.4 Benzodithiophene-containing BODIPYs 499\u003c\/p\u003e \u003cp\u003e18.2.5 Chiral BODIPYs 500\u003c\/p\u003e \u003cp\u003e18.2.6 Metal-containing BODIPYs 502\u003c\/p\u003e \u003cp\u003e18.2.7 BODIPY-containing Polymers 503\u003c\/p\u003e \u003cp\u003e18.2.8 Other BODIPY Derivatives 504\u003c\/p\u003e \u003cp\u003e18.3 Structural–property Relationship 508\u003c\/p\u003e \u003cp\u003e18.3.1 Conjugation Effect 508\u003c\/p\u003e \u003cp\u003e18.3.2 Number and Position of Substitutes 508\u003c\/p\u003e \u003cp\u003e18.3.3 Substitution Group 513\u003c\/p\u003e \u003cp\u003e18.3.4 Alkyl Substitutes on BODIPY Core 516\u003c\/p\u003e \u003cp\u003e18.3.5 AIEgens Attached Through Nonconjugated Spacers 518\u003c\/p\u003e \u003cp\u003e18.3.6 Other Substitution Structures 519\u003c\/p\u003e \u003cp\u003e18.4 Application 522\u003c\/p\u003e \u003cp\u003e18.4.1 Chemosensor 522\u003c\/p\u003e \u003cp\u003e18.4.2 Bioimaging 526\u003c\/p\u003e \u003cp\u003e18.5 Conclusion 532\u003c\/p\u003e \u003cp\u003eReferences 532\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Photochemistry-regulated AIEgens and Their Applications \u003c\/b\u003e\u003cb\u003e537\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eXia Ling and Meng Gao\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 537\u003c\/p\u003e \u003cp\u003e19.2 Photocleavage Reaction 537\u003c\/p\u003e \u003cp\u003e19.3 Photoreduction Reaction 539\u003c\/p\u003e \u003cp\u003e19.4 Photocyclodehydrogenation Reaction 540\u003c\/p\u003e \u003cp\u003e19.5 Photooxidative Dehydrogenation Reaction 543\u003c\/p\u003e \u003cp\u003e19.6 Spiropyran-merocyanine Reversible Conversion 544\u003c\/p\u003e \u003cp\u003e19.7 Dithienylethene-based Ring-open\/-closing Reaction 545\u003c\/p\u003e \u003cp\u003e19.8 Enol–Keto Isomerization Reaction 550\u003c\/p\u003e \u003cp\u003e19.9 \u003ci\u003eE\/Z \u003c\/i\u003eIsomerization Reaction 552\u003c\/p\u003e \u003cp\u003e19.10 Photo-induced [2 + 2] Cycloaddition 554\u003c\/p\u003e \u003cp\u003e19.11 Combinational Photoreactions 554\u003c\/p\u003e \u003cp\u003e19.12 Conclusion and Outlook 556\u003c\/p\u003e \u003cp\u003eReferences 556\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Design and Development of Naphthalimide Luminogens \u003c\/b\u003e\u003cb\u003e559\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eNiranjan Meher and Parameswar Krishnan Iyer\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 559\u003c\/p\u003e \u003cp\u003e20.2 Naphthalimides with N-Functionalization (I) 564\u003c\/p\u003e \u003cp\u003e20.3 Naphthalimides Substituted at the 4th Position with Oxygen Atom (II) 567\u003c\/p\u003e \u003cp\u003e20.4 Naphthalimides Substituted at the 4th Position with Nitrogen Atom (III) 570\u003c\/p\u003e \u003cp\u003e20.5 Naphthalimides with C−C Aromatic Substitution (IV) 571\u003c\/p\u003e \u003cp\u003e20.6 Naphthalimides with C−C Double-and Triple-Bond Substitutions (V and VI) 574\u003c\/p\u003e \u003cp\u003e20.7 Naphthalimides with the Significant Role of Multifunctionalization (VII) 576\u003c\/p\u003e \u003cp\u003e20.8 Conclusion and Outlooks 580\u003c\/p\u003e \u003cp\u003eReferences 581\u003c\/p\u003e \u003cp\u003eIndex 587\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49407107432791,"sku":"9781119642985","price":178.16,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119642985.jpg?v=1730498201","url":"https:\/\/bookcurl.com\/products\/handbook-of-aggregationinduced-emission-volume-2-9781119642985","provider":"Book Curl","version":"1.0","type":"link"}