{"product_id":"green-energetic-materials-9781119941293","title":"Green Energetic Materials","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis comprehensive book presents a detailed account of research and recent developments in the field of green energetic materials, including pyrotechnics, explosives and propellants.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eList of Contributors ix  \u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction to Green Energetic Materials 1\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eTore Brinck\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Green Chemistry and Energetic Materials 2\u003c\/p\u003e \u003cp\u003e1.3 Green Propellants in Civil Space Travel 5\u003c\/p\u003e \u003cp\u003e1.3.1 Green Oxidizers to Replace Ammonium Perchlorate 6\u003c\/p\u003e \u003cp\u003e1.3.2 Green Liquid Propellants to Replace Hydrazine 8\u003c\/p\u003e \u003cp\u003e1.3.3 Electric Propulsion 10\u003c\/p\u003e \u003cp\u003e1.4 Conclusions 10\u003c\/p\u003e \u003cp\u003eReferences 11\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Theoretical Design of Green Energetic Materials: Predicting Stability, Detection, and Synthesis and Performance 15\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eTore Brinck and Martin Rahm\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 15\u003c\/p\u003e \u003cp\u003e2.2 Computational Methods 17\u003c\/p\u003e \u003cp\u003e2.3 Green Propellant Components 20\u003c\/p\u003e \u003cp\u003e2.3.1 Trinitramide 20\u003c\/p\u003e \u003cp\u003e2.3.2 Energetic Anions Rich in Oxygen and Nitrogen 24\u003c\/p\u003e \u003cp\u003e2.3.3 The Pentazolate Anion and its Oxy-Derivatives 27\u003c\/p\u003e \u003cp\u003e2.3.4 Tetrahedral N4 33\u003c\/p\u003e \u003cp\u003e2.4 Conclusions 38\u003c\/p\u003e \u003cp\u003eReferences 39\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Some Perspectives on Sensitivity to Initiation of Detonation 45\u003c\/b\u003e\u003cbr\u003e \u003ci\u003ePeter Politzer and Jane S. Murray\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Energetic Materials and Green Chemistry 45\u003c\/p\u003e \u003cp\u003e3.2 Sensitivity: Some Background 46\u003c\/p\u003e \u003cp\u003e3.3 Sensitivity Relationships 47\u003c\/p\u003e \u003cp\u003e3.4 Sensitivity: Some Relevant Factors 48\u003c\/p\u003e \u003cp\u003e3.4.1 Amino Substituents 48\u003c\/p\u003e \u003cp\u003e3.4.2 Layered (Graphite-Like) Crystal Lattice 49\u003c\/p\u003e \u003cp\u003e3.4.3 Free Space in the Crystal Lattice 50\u003c\/p\u003e \u003cp\u003e3.4.4 Weak Trigger Bonds 50\u003c\/p\u003e \u003cp\u003e3.4.5 Molecular Electrostatic Potentials 51\u003c\/p\u003e \u003cp\u003e3.5 Summary 56\u003c\/p\u003e \u003cp\u003eAcknowledgments 56\u003c\/p\u003e \u003cp\u003eReferences 57\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Advances Toward the Development of “Green” Pyrotechnics\u003c\/b\u003e 63\u003cbr\u003e \u003ci\u003eJesse J. Sabatini\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 63\u003c\/p\u003e \u003cp\u003e4.2 The Foundation of “Green” Pyrotechnics 65\u003c\/p\u003e \u003cp\u003e4.3 Development of Perchlorate-Free Pyrotechnics 67\u003c\/p\u003e \u003cp\u003e4.3.1 Perchlorate-Free Illuminating Pyrotechnics 67\u003c\/p\u003e \u003cp\u003e4.3.2 Perchlorate-Free Simulators 72\u003c\/p\u003e \u003cp\u003e4.4 Removal of Heavy Metals from Pyrotechnic Formulations 75\u003c\/p\u003e \u003cp\u003e4.4.1 Barium-Free Green-Light Emitting Illuminants 76\u003c\/p\u003e \u003cp\u003e4.4.2 Barium-Free Incendiary Compositions 78\u003c\/p\u003e \u003cp\u003e4.4.3 Lead-Free Pyrotechnic Compositions 80\u003c\/p\u003e \u003cp\u003e4.4.4 Chromium-Free Pyrotechnic Compositions 82\u003c\/p\u003e \u003cp\u003e4.5 Removal of Chlorinated Organic Compounds from Pyrotechnic Formulations 83\u003c\/p\u003e \u003cp\u003e4.5.1 Chlorine-Free Illuminating Compositions 83\u003c\/p\u003e \u003cp\u003e4.6 Environmentally Friendly Smoke Compositions 84\u003c\/p\u003e \u003cp\u003e4.6.1 Environmentally Friendly Colored Smoke Compositions 84\u003c\/p\u003e \u003cp\u003e4.6.2 Environmentally Friendly White Smoke Compositions 88\u003c\/p\u003e \u003cp\u003e4.7 Conclusions 93\u003c\/p\u003e \u003cp\u003eAcknowledgments 94\u003c\/p\u003e \u003cp\u003eAbbreviations 95\u003c\/p\u003e \u003cp\u003eReferences 97\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Green Primary Explosives 103\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eKarl D. Oyler\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 103\u003c\/p\u003e \u003cp\u003e5.1.1 What is a Primary Explosive? 104\u003c\/p\u003e \u003cp\u003e5.1.2 The Case for Green Primary Explosives 107\u003c\/p\u003e \u003cp\u003e5.1.3 Legacy Primary Explosives 108\u003c\/p\u003e \u003cp\u003e5.2 Green Primary Explosive Candidates 110\u003c\/p\u003e \u003cp\u003e5.2.1 Inorganic Compounds 111\u003c\/p\u003e \u003cp\u003e5.2.2 Organic-Based Compounds 116\u003c\/p\u003e \u003cp\u003e5.3 Conclusions 125\u003c\/p\u003e \u003cp\u003eAcknowledgments 126\u003c\/p\u003e \u003cp\u003eReferences 126\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Energetic Tetrazole N-oxides 133\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eThomas M. Klap€otke and J€org Stierstorfer\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 133\u003c\/p\u003e \u003cp\u003e6.2 Rationale for the Investigation of Tetrazole N-oxides 133\u003c\/p\u003e \u003cp\u003e6.3 Synthetic Strategies for the Formation of Tetrazole N-oxides 136\u003c\/p\u003e \u003cp\u003e6.3.1 HOF CH3CN 136\u003c\/p\u003e \u003cp\u003e6.3.2 Oxone1 137\u003c\/p\u003e \u003cp\u003e6.3.3 CF3COOH\/H2O2 138\u003c\/p\u003e \u003cp\u003e6.3.4 Cyclization of Azido-Oximes 139\u003c\/p\u003e \u003cp\u003e6.4 Recent Examples of Energetic Tetrazole N-oxides 139\u003c\/p\u003e \u003cp\u003e6.4.1 Tetrazole N-oxides 140\u003c\/p\u003e \u003cp\u003e6.4.2 Bis(tetrazole-N-oxides) 150\u003c\/p\u003e \u003cp\u003e6.4.3 5,50-Azoxytetrazolates 164\u003c\/p\u003e \u003cp\u003e6.4.4 Bis(tetrazole)dihydrotetrazine and bis(tetrazole)tetrazine N-oxides 170\u003c\/p\u003e \u003cp\u003e6.5 Conclusion 173\u003c\/p\u003e \u003cp\u003eAcknowledgments 174\u003c\/p\u003e \u003cp\u003eReferences 174\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Green Propellants Based on Dinitramide Salts: Mastering Stability and Chemical Compatibility Issues 179\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMartin Rahm and Tore Brinck\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 The Promises and Problems of Dinitramide Salts 179\u003c\/p\u003e \u003cp\u003e7.2 Understanding Dinitramide Decomposition 181\u003c\/p\u003e \u003cp\u003e7.2.1 The Dinitramide Anion 182\u003c\/p\u003e \u003cp\u003e7.2.2 Dinitraminic Acid 184\u003c\/p\u003e \u003cp\u003e7.2.3 Dinitramide Salts 185\u003c\/p\u003e \u003cp\u003e7.3 Vibrational Sum-Frequency Spectroscopy of ADN and KDN 189\u003c\/p\u003e \u003cp\u003e7.4 Anomalous Solid-State Decomposition 192\u003c\/p\u003e \u003cp\u003e7.5 Dinitramide Chemistry 194\u003c\/p\u003e \u003cp\u003e7.5.1 Compatibility and Reactivity of ADN 194\u003c\/p\u003e \u003cp\u003e7.5.2 Dinitramides in Synthesis 196\u003c\/p\u003e \u003cp\u003e7.6 Dinitramide Stabilization 198\u003c\/p\u003e \u003cp\u003e7.7 Conclusions 200\u003c\/p\u003e \u003cp\u003eReferences 201\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Binder Materials for Green Propellants 205\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eCarina Elds€ater and Eva Malmstr€om\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Binder Properties 209\u003c\/p\u003e \u003cp\u003e8.2 Inert Polymers for Binders 210\u003c\/p\u003e \u003cp\u003e8.2.1 Polybutadiene 210\u003c\/p\u003e \u003cp\u003e8.2.2 Polyethers 212\u003c\/p\u003e \u003cp\u003e8.2.3 Polyesters and Polycarbonates 213\u003c\/p\u003e \u003cp\u003e8.3 Energetic Polymers 215\u003c\/p\u003e \u003cp\u003e8.3.1 Nitrocellulose 215\u003c\/p\u003e \u003cp\u003e8.3.2 Poly(glycidyl azide) 216\u003c\/p\u003e \u003cp\u003e8.3.3 Poly(3-nitratomethyl-3-methyloxetane) 220\u003c\/p\u003e \u003cp\u003e8.3.4 Poly(glycidyl nitrate) 221\u003c\/p\u003e \u003cp\u003e8.3.5 Poly[3,3-bis(azidomethyl)oxetane] 222\u003c\/p\u003e \u003cp\u003e8.4 Energetic Plasticisers 223\u003c\/p\u003e \u003cp\u003e8.5 Outlook for Design of New Green Binder Systems 223\u003c\/p\u003e \u003cp\u003e8.5.1 Architecture of the Binder Polymer 224\u003c\/p\u003e \u003cp\u003e8.5.2 Chemical Composition and Crosslinking Chemistries 225\u003c\/p\u003e \u003cp\u003eReferences 226\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 The Development of Environmentally Sustainable Manufacturing Technologies for Energetic Materials 235\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eDavid E. Chavez\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 235\u003c\/p\u003e \u003cp\u003e9.2 Explosives 236\u003c\/p\u003e \u003cp\u003e9.2.1 Sustainable Manufacturing of Explosives 236\u003c\/p\u003e \u003cp\u003e9.2.2 Environmentally Friendly Materials for Initiation 240\u003c\/p\u003e \u003cp\u003e9.2.3 Synthesis of Explosive Precursors 244\u003c\/p\u003e \u003cp\u003e9.3 Pyrotechnics 246\u003c\/p\u003e \u003cp\u003e9.3.1 Commercial Pyrotechnics Manufacturing 246\u003c\/p\u003e \u003cp\u003e9.3.2 Military Pyrotechnics 248\u003c\/p\u003e \u003cp\u003e9.4 Propellants 249\u003c\/p\u003e \u003cp\u003e9.4.1 The “Green Missile” Program 249\u003c\/p\u003e \u003cp\u003e9.4.2 Other Rocket Propellant Efforts 250\u003c\/p\u003e \u003cp\u003e9.4.3 Gun Propellants 251\u003c\/p\u003e \u003cp\u003e9.5 Formulation 253\u003c\/p\u003e \u003cp\u003e9.6 Conclusions 254\u003c\/p\u003e \u003cp\u003eAcknowledgments 254\u003c\/p\u003e \u003cp\u003eAbbreviations and Acronyms 255\u003c\/p\u003e \u003cp\u003eReferences 256\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Electrochemical Methods for Synthesis of Energetic Materials and Remediation of Waste Water 259\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eLynne Wallace\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 259\u003c\/p\u003e \u003cp\u003e10.2 Practical Aspects 260\u003c\/p\u003e \u003cp\u003e10.3 Electrosynthesis 262\u003c\/p\u003e \u003cp\u003e10.3.1 Electrosynthesis of EM and EM Precursors 262\u003c\/p\u003e \u003cp\u003e10.3.2 Electrosynthesis of Useful Reagents 265\u003c\/p\u003e \u003cp\u003e10.4 Electrochemical Remediation 266\u003c\/p\u003e \u003cp\u003e10.4.1 Direct Electrolysis 267\u003c\/p\u003e \u003cp\u003e10.4.2 Indirect Electrolytic Methods 269\u003c\/p\u003e \u003cp\u003e10.4.3 Electrokinetic Remediation of Soils 272\u003c\/p\u003e \u003cp\u003e10.4.4 Electrodialysis 273\u003c\/p\u003e \u003cp\u003e10.5 Current Developments and Future Directions 273\u003c\/p\u003e \u003cp\u003eReferences 275\u003c\/p\u003e \u003cp\u003eIndex 281\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49407191253335,"sku":"9781119941293","price":108.86,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781119941293.jpg?v=1730498498","url":"https:\/\/bookcurl.com\/products\/green-energetic-materials-9781119941293","provider":"Book Curl","version":"1.0","type":"link"}