{"product_id":"gasphase-pyrolytic-reactions-9781118057476","title":"GasPhase Pyrolytic Reactions","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eOffers a physical organic chemistry and mechanistic perspective of the chemistry of thermal processes in the gas phase\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eThe book looks at all aspects of the chemical processing technique called gas-phase pyrolysis, including its methodology and reactors, synthesis, reaction mechanisms, structure, kinetics, and applications. It discusses combinations of pyrolytic reactors with physiochemical techniques, routes for and reactions for the synthesis of organic compounds, and the control of reaction rates.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eGas-Phase Pyrolytic Reactions: Synthesis, Mechanisms, and Kinetics\u003c\/i\u003e starts with in-depth chapter coverage of static pyrolysis, dynamic flow pyrolysis, and analytical pyrolysis. It then examines synthesis and applications, including flash vacuum pyrolysis in organic synthesis, elimination of HX, elimination of CO and CO\u003csub\u003e2\u003c\/sub\u003e, pyrolysis of Meldrum's acid derivatives, and elimination of N\u003csub\u003e2\u003c\/sub\u003e. A chapter on reaction mechanism comes next and includes \u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003c\/p\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003eList of Abbreviations xiii\u003c\/p\u003e \u003cp\u003eAbout the Author xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Methodologies and Reactors \u003c\/b\u003e\u003cb\u003e1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Static Pyrolysis 1\u003c\/p\u003e \u003cp\u003e1.1.1 Sealed-Tube Reactor 2\u003c\/p\u003e \u003cp\u003e1.1.1.1 Pyrolyzer 2\u003c\/p\u003e \u003cp\u003e1.1.1.2 Reaction Tube 3\u003c\/p\u003e \u003cp\u003e1.1.1.3 Kinetic Studies 3\u003c\/p\u003e \u003cp\u003e1.1.1.4 Treatment of Kinetic Results 4\u003c\/p\u003e \u003cp\u003e1.1.2 Static Apparatus 5\u003c\/p\u003e \u003cp\u003e1.1.2.1 Reaction Chamber 6\u003c\/p\u003e \u003cp\u003e1.1.2.2 The Pyrolysis Method 7\u003c\/p\u003e \u003cp\u003e1.1.2.3 Treatment of the Results 7\u003c\/p\u003e \u003cp\u003e1.2 Dynamic Flow Pyrolysis 8\u003c\/p\u003e \u003cp\u003e1.2.1 Flash Vacuum Pyrolysis 8\u003c\/p\u003e \u003cp\u003e1.2.2 Synthetic Applications of FVP 10\u003c\/p\u003e \u003cp\u003e1.2.3 Gas-Flow Pyrolysis vs. STP 13\u003c\/p\u003e \u003cp\u003e1.2.4 Limitations of FVP 13\u003c\/p\u003e \u003cp\u003e1.2.5 Spray Pyrolysis 14\u003c\/p\u003e \u003cp\u003e1.2.6 Falling-Solid Pyrolysis 17\u003c\/p\u003e \u003cp\u003e1.3 Analytical Pyrolysis 19\u003c\/p\u003e \u003cp\u003e1.3.1 Pyrolysis Gas Chromatography (Py-GC) 19\u003c\/p\u003e \u003cp\u003e1.3.1.1 Online Py-GC 20\u003c\/p\u003e \u003cp\u003e1.3.2 Pyrolysis Mass Spectrometry 22\u003c\/p\u003e \u003cp\u003e1.3.2.1 Online Pyrolysis Gas Chromatography\/Mass Spectrometry (Py-GC\/MS) 22\u003c\/p\u003e \u003cp\u003e1.3.3 FVP with Spectroscopy 22\u003c\/p\u003e \u003cp\u003e1.3.4 Catalytic Gas-Phase Pyrolysis 24\u003c\/p\u003e \u003cp\u003eReferences 27\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Synthesis and Applications \u003c\/b\u003e\u003cb\u003e31\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Flash Vacuum Pyrolysis in Organic Synthesis 31\u003c\/p\u003e \u003cp\u003e2.2 Elimination of HX 34\u003c\/p\u003e \u003cp\u003e2.3 Elimination of CO and CO\u003csub\u003e2\u003c\/sub\u003e 38\u003c\/p\u003e \u003cp\u003e2.4 Pyrolysis of Meldrum’s Acid Derivatives 54\u003c\/p\u003e \u003cp\u003e2.5 Elimination of N\u003csub\u003e2 \u003c\/sub\u003e60\u003c\/p\u003e \u003cp\u003e2.5.1 Deazetization Reactions of Allylic Diazenes 63\u003c\/p\u003e \u003cp\u003e2.5.2 Pyrolysis of Benzotriazole Derivatives 65\u003c\/p\u003e \u003cp\u003e2.5.3 Pyrolysis of Triazine Derivatives 68\u003c\/p\u003e \u003cp\u003eReferences 72\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Reaction Mechanism \u003c\/b\u003e\u003cb\u003e79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Retro-ene Reactions 79\u003c\/p\u003e \u003cp\u003e3.1.1 Acetylenic Compounds 80\u003c\/p\u003e \u003cp\u003e3.1.2 Acyl Group Participation 82\u003c\/p\u003e \u003cp\u003e3.1.3 Cyanates and Isocyanates 82\u003c\/p\u003e \u003cp\u003e3.1.4 Esters 83\u003c\/p\u003e \u003cp\u003e3.1.5 Amides 88\u003c\/p\u003e \u003cp\u003e3.1.5.1 Acetamides and Thioacetamides 88\u003c\/p\u003e \u003cp\u003e3.1.5.2 Benzamides 92\u003c\/p\u003e \u003cp\u003e3.1.5.3 N-Substituted Amides 93\u003c\/p\u003e \u003cp\u003e3.2 Reactive Intermediates 94\u003c\/p\u003e \u003cp\u003e3.2.1 Radicals 94\u003c\/p\u003e \u003cp\u003e3.2.2 Diradicals 97\u003c\/p\u003e \u003cp\u003e3.2.3 Benzynes 98\u003c\/p\u003e \u003cp\u003e3.2.3.1 \u003ci\u003eo\u003c\/i\u003e-Benzynes 99\u003c\/p\u003e \u003cp\u003e3.2.3.2 \u003ci\u003em\u003c\/i\u003e- and \u003ci\u003ep\u003c\/i\u003e-Benzynes 101\u003c\/p\u003e \u003cp\u003e3.2.4 Carbenes 101\u003c\/p\u003e \u003cp\u003e3.2.5 Nitrenes 108\u003c\/p\u003e \u003cp\u003eReferences 120\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Structure\/Reactivity Correlation \u003c\/b\u003e\u003cb\u003e127\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Diketones 127\u003c\/p\u003e \u003cp\u003e4.2 Cyanoketones 133\u003c\/p\u003e \u003cp\u003e4.3 Ketoamides 135\u003c\/p\u003e \u003cp\u003e4.4 Benzotriazoles 136\u003c\/p\u003e \u003cp\u003e4.5 Hammett Correlation in Gas-Phase Pyrolysis 148\u003c\/p\u003e \u003cp\u003e4.6 Alkoxy versus Amino Group 153\u003c\/p\u003e \u003cp\u003e4.6.1 Neighboring Group Participation 155\u003c\/p\u003e \u003cp\u003e4.6.2 Amino Esters 158\u003c\/p\u003e \u003cp\u003eReferences 162\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Functional Group and Structural Frame Interconversions \u003c\/b\u003e\u003cb\u003e167\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Functional Group Interconversion 167\u003c\/p\u003e \u003cp\u003e5.1.1 Thermal Retro-Ene Reactions 167\u003c\/p\u003e \u003cp\u003e5.1.1.1 α-Substituted Carboxylic Acids 173\u003c\/p\u003e \u003cp\u003e5.1.1.2 2-Hydroxycarboxylic Acids 175\u003c\/p\u003e \u003cp\u003e5.1.1.3 2-Alkoxycarboxylic Acids 176\u003c\/p\u003e \u003cp\u003e5.1.1.4 2-Phenoxycarboxylic Acids 177\u003c\/p\u003e \u003cp\u003e5.1.1.5 2-Aminocarboxylic Acids 180\u003c\/p\u003e \u003cp\u003e5.1.1.6 2-Acetooxycarboxylic Acids 182\u003c\/p\u003e \u003cp\u003e5.1.1.7 2-Ketocarboxylic Acids 184\u003c\/p\u003e \u003cp\u003e5.1.1.8 α-Substituted Esters 186\u003c\/p\u003e \u003cp\u003e5.1.1.9 β-Substituted Carboxylic Acids 188\u003c\/p\u003e \u003cp\u003e5.2 Structural Frame Interconversion 191\u003c\/p\u003e \u003cp\u003e5.2.1 Alkyl Heterocycles 195\u003c\/p\u003e \u003cp\u003eReferences 197\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Gas-Phase Pyrolysis of Hydrazones \u003c\/b\u003e\u003cb\u003e201\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Substituted Phenylhydrazones 203\u003c\/p\u003e \u003cp\u003e6.2 N-Arylidineamino Heterocycles 213\u003c\/p\u003e \u003cp\u003e6.3 Arylidene Hydrazine Heterocycles 221\u003c\/p\u003e \u003cp\u003eReferences 231\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Gas-Phase Pyrolysis of Phosphorus Ylides \u003c\/b\u003e\u003cb\u003e235\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Synthetic Applications 235\u003c\/p\u003e \u003cp\u003e7.2 Haloalkynes 241\u003c\/p\u003e \u003cp\u003e7.3 Terminal Alkynes 244\u003c\/p\u003e \u003cp\u003e7.4 Diynes 247\u003c\/p\u003e \u003cp\u003e7.5 Enynes and Dienes 250\u003c\/p\u003e \u003cp\u003e7.6 Selective Elimination of Ph\u003csub\u003e3\u003c\/sub\u003ePO from Di- and Tri-oxo-stabilized Phosphorus Ylides 252\u003c\/p\u003e \u003cp\u003e7.7 Sulfonyl-Stabilized Phosphorus Ylides 257\u003c\/p\u003e \u003cp\u003e7.8 Sulfinyl-Stabilized Phosphorus Ylides 262\u003c\/p\u003e \u003cp\u003e7.9 Kinetic andThermal Reactivity of Carbonyl-Stabilized Phosphonium Ylides 266\u003c\/p\u003e \u003cp\u003eReferences 277\u003c\/p\u003e \u003cp\u003eIndex 281\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default 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