{"product_id":"fundamentals-of-chemical-reactor-engineering-9781119755890","title":"Fundamentals of Chemical Reactor Engineering","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cb\u003eFUNDAMENTALS OF CHEMICAL REACTOR ENGINEERING\u003c\/b\u003e \u003cp\u003e\u003cb\u003eA comprehensive introduction to chemical reactor engineering from an industrial perspective\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eIn \u003ci\u003eFundamentals of Chemical Reactor Engineering: A Multi-Scale Approach\u003c\/i\u003e, a distinguished team of academics delivers a thorough introduction to foundational concepts in chemical reactor engineering. It offers readers the tools they need to develop a firm grasp of the kinetics and thermodynamics of reactions, hydrodynamics, transport processes, and heat and mass transfer resistances in a chemical reactor. \u003c\/p\u003e\u003cp\u003eThis textbook describes the interaction of reacting molecules on the molecular scale and uses real-world examples to illustrate the principles of chemical reactor analysis and heterogeneous catalysis at every scale. It includes a strong focus on new approaches to process intensification, the modeling of multifunctional reactors, structured reactor types, and the importance of hydrodynamics and transport processes in a chem\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003c\/p\u003e\u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003eForeword by \u003ci\u003eMarc-Olivier Coppens\u003c\/i\u003e xv\u003c\/p\u003e \u003cp\u003eForeword by \u003ci\u003eUmit S. Ozkan\u003c\/i\u003e xvii\u003c\/p\u003e \u003cp\u003eAbout the Authors and Acknowledgments xix\u003c\/p\u003e \u003cp\u003eList of Symbols xxi\u003c\/p\u003e \u003cp\u003eAbout the Companion Website xxvii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Rate Concept and Species Conservation Equations in Reactors \u003c\/b\u003e\u003cb\u003e1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Reaction Rates of Species in Chemical Conversions 1\u003c\/p\u003e \u003cp\u003e1.2 Rate of a Chemical Change 3\u003c\/p\u003e \u003cp\u003e1.3 Chemical Reactors and Conservation of Species 6\u003c\/p\u003e \u003cp\u003e1.4 Flow Reactors and the Reaction Rate Relations 8\u003c\/p\u003e \u003cp\u003e1.5 Comparison of Perfectly Mixed Flow and Batch Reactors 9\u003c\/p\u003e \u003cp\u003e1.6 Ideal Tubular Flow Reactor 10\u003c\/p\u003e \u003cp\u003e1.7 Stoichiometric Relations Between Reacting Species 13\u003c\/p\u003e \u003cp\u003e1.7.1 Batch Reactor Analysis 13\u003c\/p\u003e \u003cp\u003e1.7.2 Steady-Flow Analysis for a CSTR 13\u003c\/p\u003e \u003cp\u003e1.7.3 Unsteady Perfectly Mixed-Flow Reactor Analysis 14\u003c\/p\u003e \u003cp\u003eProblems and Questions 15\u003c\/p\u003e \u003cp\u003eReferences 18\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Reversible Reactions and Chemical Equilibrium \u003c\/b\u003e\u003cb\u003e19\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Equilibrium and Reaction Rate Relations 19\u003c\/p\u003e \u003cp\u003e2.2 Thermodynamics of Chemical Reactions 21\u003c\/p\u003e \u003cp\u003e2.3 Different Forms of Equilibrium Constant 23\u003c\/p\u003e \u003cp\u003e2.4 Temperature Dependence of Equilibrium Constant and Equilibrium Calculations 25\u003c\/p\u003e \u003cp\u003eProblems and Questions 33\u003c\/p\u003e \u003cp\u003eReferences 34\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Chemical Kinetics and Analysis of Batch Reactors \u003c\/b\u003e\u003cb\u003e35\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Kinetics and Mechanisms of Homogeneous Reactions 35\u003c\/p\u003e \u003cp\u003e3.2 Batch Reactor Data Analysis 39\u003c\/p\u003e \u003cp\u003e3.2.1 Integral Method of Analysis 41\u003c\/p\u003e \u003cp\u003e3.2.1.1 First-Order Reaction 41\u003c\/p\u003e \u003cp\u003e3.2.1.2 \u003ci\u003en\u003c\/i\u003eth-Order Reaction and Method of Half-Lives 43\u003c\/p\u003e \u003cp\u003e3.2.1.3 Overall Second-Order Reaction Between Reactants A and B 44\u003c\/p\u003e \u003cp\u003e3.2.1.4 Second-Order Autocatalytic Reactions 48\u003c\/p\u003e \u003cp\u003e3.2.1.5 Zeroth-Order Dependence of Reaction Rate on Concentrations 50\u003c\/p\u003e \u003cp\u003e3.2.1.6 Data Analysis for a Reversible Reaction 51\u003c\/p\u003e \u003cp\u003e3.2.2 Differential Method of Data Analysis 52\u003c\/p\u003e \u003cp\u003e3.3 Changes in Total Pressure or Volume in Gas-Phase Reactions 54\u003c\/p\u003e \u003cp\u003eProblems and Questions 56\u003c\/p\u003e \u003cp\u003eReferences 61\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Ideal-Flow Reactors: CSTR and Plug-Flow Reactor Models \u003c\/b\u003e\u003cb\u003e63\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 CSTR Model 63\u003c\/p\u003e \u003cp\u003e4.1.1 CSTR Data Analysis 67\u003c\/p\u003e \u003cp\u003e4.2 Analysis of Ideal Plug-Flow Reactor 69\u003c\/p\u003e \u003cp\u003e4.3 Comparison of Performances of CSTR and Ideal Plug-Flow Reactors 71\u003c\/p\u003e \u003cp\u003e4.4 Equilibrium and Rate Limitations in Ideal-Flow Reactors 72\u003c\/p\u003e \u003cp\u003e4.5 Unsteady Operation of Reactors 76\u003c\/p\u003e \u003cp\u003e4.5.1 Unsteady Operation of a Constant Volume Stirred-Tank Reactor 76\u003c\/p\u003e \u003cp\u003e4.5.2 Semi-batch Reactors 77\u003c\/p\u003e \u003cp\u003e4.6 Analysis of a CSTR with a Complex Rate Expression 79\u003c\/p\u003e \u003cp\u003eProblems and Questions 81\u003c\/p\u003e \u003cp\u003eReferences 85\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Multiple Reactor Systems \u003c\/b\u003e\u003cb\u003e87\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Multiple CSTRs Operating in Series 87\u003c\/p\u003e \u003cp\u003e5.1.1 Graphical Method for Multiple CSTRs 91\u003c\/p\u003e \u003cp\u003e5.2 Multiple Plug-Flow Reactors Operating in Series 93\u003c\/p\u003e \u003cp\u003e5.3 CSTR and Plug-Flow Reactor Combinations 94\u003c\/p\u003e \u003cp\u003eProblems and Questions 96\u003c\/p\u003e \u003cp\u003eReferences 98\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Multiple Reaction Systems \u003c\/b\u003e\u003cb\u003e99\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Selectivity and Yield Definitions 100\u003c\/p\u003e \u003cp\u003e6.2 Selectivity Relations for Ideal Flow Reactors 101\u003c\/p\u003e \u003cp\u003e6.3 Design of Ideal Reactors and Product Distributions for Multiple Reaction Systems 104\u003c\/p\u003e \u003cp\u003e6.3.1 Parallel Reactions 104\u003c\/p\u003e \u003cp\u003e6.3.2 Consecutive Reactions 110\u003c\/p\u003e \u003cp\u003eProblems and Questions 113\u003c\/p\u003e \u003cp\u003eReferences 116\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Heat Effects and Non-isothermal Reactor Design \u003c\/b\u003e\u003cb\u003e117\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Heat Effects in a Stirred-Tank Reactor 118\u003c\/p\u003e \u003cp\u003e7.2 Steady-State Multiplicity in a CSTR 121\u003c\/p\u003e \u003cp\u003e7.3 One-Dimensional Energy Balance for a Tubular Reactor 126\u003c\/p\u003e \u003cp\u003e7.4 Heat Effects in Multiple Reaction Systems 131\u003c\/p\u003e \u003cp\u003e7.4.1 Heat Effects in a CSTR with Parallel Reactions 131\u003c\/p\u003e \u003cp\u003e7.4.2 Heat Effects in a CSTR with Consecutive Reactions 132\u003c\/p\u003e \u003cp\u003e7.4.3 Energy Balance for a Plug-Flow Reactor with Multiple Reactions 133\u003c\/p\u003e \u003cp\u003e7.5 Heat Effects in Multiple Reactors and Reversible Reactions 133\u003c\/p\u003e \u003cp\u003e7.5.1 Temperature Selection and Multiple Reactor Combinations 133\u003c\/p\u003e \u003cp\u003e7.5.1.1 Endothermic-Reversible Reactions in a Multi-stage Reactor System 141\u003c\/p\u003e \u003cp\u003e7.5.2 Cold Injection Between Reactors 147\u003c\/p\u003e \u003cp\u003e7.5.3 Heat-Exchanger Reactors 149\u003c\/p\u003e \u003cp\u003eProblems and Questions 150\u003c\/p\u003e \u003cp\u003eCase Studies 154\u003c\/p\u003e \u003cp\u003eReferences 160\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Deviations from Ideal Reactor Performance \u003c\/b\u003e\u003cb\u003e161\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Residence Time Distributions in Flow Reactors 161\u003c\/p\u003e \u003cp\u003e8.2 General Species Conservation Equation in a Reactor 163\u003c\/p\u003e \u003cp\u003e8.3 Laminar Flow Reactor Model 166\u003c\/p\u003e \u003cp\u003e8.4 Dispersion Model for a Tubular Reactor 168\u003c\/p\u003e \u003cp\u003e8.5 Prediction of Axial Dispersion Coefficient 172\u003c\/p\u003e \u003cp\u003e8.6 Evaluation of Dispersion Coefficient by Moment Analysis 174\u003c\/p\u003e \u003cp\u003e8.7 Radial Temperature Variations in Tubular Reactors 175\u003c\/p\u003e \u003cp\u003e8.8 A Criterion for the Negligible Effect of Radial Temperature Variations on the Reaction Rate 177\u003c\/p\u003e \u003cp\u003e8.9 Effect of L\/d\u003csub\u003et\u003c\/sub\u003e Ratio on the Performance of a Tubular Reactor and Pressure Drop 179\u003c\/p\u003e \u003cp\u003eProblems and Questions 180\u003c\/p\u003e \u003cp\u003eExercises 181\u003c\/p\u003e \u003cp\u003eReferences 182\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Fixed-Bed Reactors and Interphase Transport Effects \u003c\/b\u003e\u003cb\u003e185\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Solid-Catalyzed Reactions and Transport Effects within Reactors 185\u003c\/p\u003e \u003cp\u003e9.2 Observed Reaction Rate and Fixed-Bed Reactors 187\u003c\/p\u003e \u003cp\u003e9.3 Significance of Film Mass Transfer Resistance in Catalytic Reactions 189\u003c\/p\u003e \u003cp\u003e9.4 Tubular Reactors with Catalytic Walls 191\u003c\/p\u003e \u003cp\u003e9.4.1 One-Dimensional Model 192\u003c\/p\u003e \u003cp\u003e9.4.2 Two-Dimensional Model 193\u003c\/p\u003e \u003cp\u003e9.5 Modeling of a Non-isothermal Fixed-Bed Reactor 194\u003c\/p\u003e \u003cp\u003e9.6 Steady-State Multiplicity on the Surface of a Catalyst Pellet 196\u003c\/p\u003e \u003cp\u003eExercises 197\u003c\/p\u003e \u003cp\u003eReferences 198\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Transport Effects and Effectiveness Factor for Reactions in Porous Catalysts \u003c\/b\u003e\u003cb\u003e199\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Effectiveness Factor Expressions in an Isothermal Catalyst Pellet 199\u003c\/p\u003e \u003cp\u003e10.2 Observed Activation Energy and Observed Reaction Order 205\u003c\/p\u003e \u003cp\u003e10.3 Effectiveness Factor in the Presence of Pore-Diffusion and Film Mass Transfer Resistances 208\u003c\/p\u003e \u003cp\u003e10.4 Thermal Effects in Porous Catalyst Pellets 210\u003c\/p\u003e \u003cp\u003e10.5 Interphase and Intrapellet Temperature Gradients for Catalyst Pellets 215\u003c\/p\u003e \u003cp\u003e10.6 Pore Structure Optimization and Effectiveness Factor Analysis for Catalysts with Bi-modal Pore-Size Distributions 217\u003c\/p\u003e \u003cp\u003e10.7 Criteria for Negligible Transport Effects in Catalytic Reactions 221\u003c\/p\u003e \u003cp\u003e10.7.1 Criteria for Negligible Diffusion and Heat Effects on the Observed Rate of Solid-Catalyzed Reactions 221\u003c\/p\u003e \u003cp\u003e10.7.2 Relative Importance of Concentration and Temperature Gradients in Catalyst Pellets 222\u003c\/p\u003e \u003cp\u003e10.7.3 Intrapellet and External Film Transport Limitations 225\u003c\/p\u003e \u003cp\u003e10.7.4 A Criterion for Negligible Diffusion Resistance in Bidisperse Catalyst Pellets 225\u003c\/p\u003e \u003cp\u003e10.8 Transport Effects on Product Selectivities in Catalytic Reactions 226\u003c\/p\u003e \u003cp\u003e10.8.1 Film Mass Transfer Effect 226\u003c\/p\u003e \u003cp\u003e10.8.2 Pore-Diffusion Effect 227\u003c\/p\u003e \u003cp\u003eProblems and Questions 228\u003c\/p\u003e \u003cp\u003eExercises 229\u003c\/p\u003e \u003cp\u003eReferences 233\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Introduction to Catalysis and Catalytic Reaction Mechanisms \u003c\/b\u003e\u003cb\u003e235\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Basic Concepts in Heterogeneous Catalysis 235\u003c\/p\u003e \u003cp\u003e11.2 Surface Reaction Mechanisms 237\u003c\/p\u003e \u003cp\u003e11.3 Adsorption Isotherms 241\u003c\/p\u003e \u003cp\u003e11.4 Deactivation of Solid Catalysts 244\u003c\/p\u003e \u003cp\u003eExercises 246\u003c\/p\u003e \u003cp\u003eReferences 246\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Diffusion in Porous Catalysts \u003c\/b\u003e\u003cb\u003e247\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Diffusion in a Capillary 247\u003c\/p\u003e \u003cp\u003e12.2 Effective Diffusivities in Porous Solids 251\u003c\/p\u003e \u003cp\u003e12.3 Surface Diffusion 252\u003c\/p\u003e \u003cp\u003e12.4 Models for the Prediction of Effective Diffusivities 253\u003c\/p\u003e \u003cp\u003e12.4.1 Random Pore Model 253\u003c\/p\u003e \u003cp\u003e12.4.2 Grain Model 254\u003c\/p\u003e \u003cp\u003e12.5 Diffusion and Flow in Porous Solids 254\u003c\/p\u003e \u003cp\u003e12.6 Experimental Methods for the Evaluation of Effective Diffusion Coefficients 255\u003c\/p\u003e \u003cp\u003e12.6.1 Steady-State Methods 255\u003c\/p\u003e \u003cp\u003e12.6.2 Dynamic Methods 256\u003c\/p\u003e \u003cp\u003e12.6.3 Single-Pellet Moment Method 257\u003c\/p\u003e \u003cp\u003eExercises 259\u003c\/p\u003e \u003cp\u003eReferences 259\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Process Intensification and Multifunctional Reactors \u003c\/b\u003e\u003cb\u003e261\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Membrane Reactors 262\u003c\/p\u003e \u003cp\u003e13.1.1 Modeling of a Membrane Reactor 263\u003c\/p\u003e \u003cp\u003e13.1.2 General Conservation Equations and Heat Effects in a Membrane Reactor 265\u003c\/p\u003e \u003cp\u003e13.2 Reactive Distillation 266\u003c\/p\u003e \u003cp\u003e13.2.1 Equilibrium-Stage Model 267\u003c\/p\u003e \u003cp\u003e13.2.2 A Rate-Based Model for a Continuous Reactive Distillation Column 269\u003c\/p\u003e \u003cp\u003e13.3 Sorption-Enhanced Reaction Process 270\u003c\/p\u003e \u003cp\u003e13.4 Monolithic and Microchannel Reactors 275\u003c\/p\u003e \u003cp\u003e13.4.1 Microchannel Reactors 278\u003c\/p\u003e \u003cp\u003e13.5 Chromatographic Reactors 279\u003c\/p\u003e \u003cp\u003e13.6 Alternative Energy Sources for Chemical Processing 279\u003c\/p\u003e \u003cp\u003e13.6.1 Microwave-Assisted Chemical Conversions 280\u003c\/p\u003e \u003cp\u003e13.6.2 Ultrasound Reactors 282\u003c\/p\u003e \u003cp\u003e13.6.3 Solar Energy for Chemical Conversion 282\u003c\/p\u003e \u003cp\u003eReferences 283\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Multiphase Reactors \u003c\/b\u003e\u003cb\u003e285\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Slurry Reactors 285\u003c\/p\u003e \u003cp\u003e14.2 Trickle-Bed Reactors 289\u003c\/p\u003e \u003cp\u003e14.3 Fluidized-Bed Reactors 290\u003c\/p\u003e \u003cp\u003eReferences 294\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Kinetics and Modeling of Non-catalytic Gas–Solid Reactions \u003c\/b\u003e\u003cb\u003e295\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Unreacted-Core Model 296\u003c\/p\u003e \u003cp\u003e15.2 Deactivation and Structural Models for Gas–Solid Reactions 299\u003c\/p\u003e \u003cp\u003e15.3 Chemical Vapor Deposition Reactors 302\u003c\/p\u003e \u003cp\u003eExercises 305\u003c\/p\u003e \u003cp\u003eReferences 307\u003c\/p\u003e \u003cp\u003eAppendix A Some Constants of Nature 309\u003c\/p\u003e \u003cp\u003eAppendix B Conversion Factors 311\u003c\/p\u003e \u003cp\u003eAppendix C Dimensionless Groups and Parameters 313\u003c\/p\u003e \u003cp\u003eIndex 315\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default 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