{"product_id":"electronic-structure-and-properties-of-transition-metal-compounds-9780470180235","title":"Electronic Structure and Properties of Transition","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eWith more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003eApplied Organometallic Chemistry\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePreface.  \u003cp\u003eForeword to the First Edition.\u003c\/p\u003e \u003cp\u003eMathematical Symbols.\u003c\/p\u003e \u003cp\u003eAbbreviations.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction: Subject and Methods.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Objectives.\u003c\/p\u003e \u003cp\u003e1.2 Definitions of Chemical Bonding and Transition Metal Coordination System.\u003c\/p\u003e \u003cp\u003e1.3 The Schrödinger Equation.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Atomic States.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 One-Electron States.\u003c\/p\u003e \u003cp\u003e2.2 Multielectron States: Energy Terms.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eQuestions.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Symmetry Ideas and Group-Theoretical Description.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Symmetry Transformations and Matrices.\u003c\/p\u003e \u003cp\u003e3.2 Groups of Symmetry Transformations.\u003c\/p\u003e \u003cp\u003e3.3 Representations of Groups and Matrices of Representations.\u003c\/p\u003e \u003cp\u003e3.4 Classification of Molecular Terms and Vibrations, Selection Rules, and Wigner-Eckart Theorem.\u003c\/p\u003e \u003cp\u003e3.5 Construction of Symmetrized Molecular Orbitals and Normal Vibrations.\u003c\/p\u003e \u003cp\u003e3.6 The Notion of Double Groups.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Crystal Field Theory.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction.\u003c\/p\u003e \u003cp\u003e4.2 Splitting of the Energy Levels of One \u003ci\u003ed\u003c\/i\u003e Electron in Ligand Fields.\u003c\/p\u003e \u003cp\u003e4.3 Several \u003ci\u003ed\u003c\/i\u003e Electrons.\u003c\/p\u003e \u003cp\u003e4.4 \u003ci\u003ef\u003c\/i\u003e -Electron Term Splitting.\u003c\/p\u003e \u003cp\u003e4.5 Crystal Field Parameters and Extrastabilization Energy.\u003c\/p\u003e \u003cp\u003e4.6 Limits of Applicability of Crystal Field Theory.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eQuestions.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Method of Molecular Orbitals and Related Approaches.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Basic Ideas of the MO LCAO Method.\u003c\/p\u003e \u003cp\u003e5.2 Charge Distribution and Bonding in the MO LCAO Method and the Case of Weak Covalency.\u003c\/p\u003e \u003cp\u003e5.3 Methods of Calculation of MO Energies and LCAO Coefficients.\u003c\/p\u003e \u003cp\u003e5.4 Semiquantitative Approaches.\u003c\/p\u003e \u003cp\u003e5.5 Semiempirical Methods.\u003c\/p\u003e \u003cp\u003e5.6 Fragmentary Calculations, Molecular Mechanics, and Combined Quantum\/Classical (QM\/MM) Modeling.\u003c\/p\u003e \u003cp\u003e5.7 General Comparison of Methods.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Electronic Structure and Chemical Bonding.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Classification of Chemical Bonds by Electronic Structure and Role of \u003ci\u003ed\u003c\/i\u003e and \u003ci\u003ef\u003c\/i\u003e Electrons in Coordination Bonding.\u003c\/p\u003e \u003cp\u003e6.2 Qualitative Aspects and Electronic Configurations.\u003c\/p\u003e \u003cp\u003e6.3 Ligand Bonding.\u003c\/p\u003e \u003cp\u003e6.4 Energies, Geometries, and Charge Distributions.\u003c\/p\u003e \u003cp\u003e6.5 Relativistic Effects.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Electronic Control of Molecular Shapes and Transformations via Vibronic Coupling.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Molecular Vibrations.\u003c\/p\u003e \u003cp\u003e7.2 Vibronic Coupling.\u003c\/p\u003e \u003cp\u003e7.3 The Jahn-Teller Effect.\u003c\/p\u003e \u003cp\u003e7.4 Pseudo-Jahn-Teller Effect and the Two-Level Paradigm.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Electronic Structure Investigated by Physical Methods.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Band Shapes of Electronic Spectra.\u003c\/p\u003e \u003cp\u003e8.2 \u003ci\u003ed\u003c\/i\u003e –\u003ci\u003ed\u003c\/i\u003e, Charge Transfer, Infrared, and Raman Spectra.\u003c\/p\u003e \u003cp\u003e8.3 X-Ray and Ultraviolet Photoelectron Spectra; EXAFS.\u003c\/p\u003e \u003cp\u003e8.4 Magnetic Properties.\u003c\/p\u003e \u003cp\u003e8.5 Gamma-Resonance Spectroscopy.\u003c\/p\u003e \u003cp\u003e8.6 Electron Charge and Spin Density Distribution in Diffraction Methods.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Stereochemistry and Crystal Chemistry.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Definitions. Semiclassical Approaches.\u003c\/p\u003e \u003cp\u003e9.2 Vibronic Effects in Stereochemistry.\u003c\/p\u003e \u003cp\u003e9.3 Mutual Influence of Ligands.\u003c\/p\u003e \u003cp\u003e9.4 Crystal Stereochemistry.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Electron Transfer, Redox Properties, and Electron-Conformational Effects.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Electron Transfer and Charge Transfer by Coordination.\u003c\/p\u003e \u003cp\u003e10.2 Electron Transfer in Mixed-Valence Compounds.\u003c\/p\u003e \u003cp\u003e10.3 Electron-Conformational Effects in Biological Systems.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eExercises and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Reactivity and Catalytic Action.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Electronic Factors in Reactivity.\u003c\/p\u003e \u003cp\u003e11.2 Electronic Control of Chemical Activation via Vibronic Coupling.\u003c\/p\u003e \u003cp\u003e11.3 Direct Computation of Energy Barriers of Chemical Reactions.\u003c\/p\u003e \u003cp\u003eSummary Notes.\u003c\/p\u003e \u003cp\u003eQuestions and Problems.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eAppendixes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eAnswers and Solutions.\u003c\/p\u003e \u003cp\u003eSubject Index.\u003c\/p\u003e \u003cp\u003eFormula Index.\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49402300793175,"sku":"9780470180235","price":148.45,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/electronic-structure-and-properties-of-transition-metal-compounds-9780470180235","provider":"Book Curl","version":"1.0","type":"link"}