{"product_id":"cyclopropanes-in-organic-synthesis-9781118057438","title":"Cyclopropanes in Organic Synthesis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis is a practical guidebook about cyclopropanes that thoroughly surveys derivatives and transformations, synthetic methods, and experimental efficiency as a gateway for further research and development in the field.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface ix\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart I Reactivity and availability 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eIntroduction, 1\u003c\/p\u003e \u003cp\u003eReference, 2\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Structure and Reactivity of the Cyclopropane Species 3\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Geometry and Bonding, 3\u003c\/p\u003e \u003cp\u003e1.2 Energy, 4\u003c\/p\u003e \u003cp\u003e1.3 Spectra, 5\u003c\/p\u003e \u003cp\u003e1.4 Cyclopropyl Cations, 5\u003c\/p\u003e \u003cp\u003e1.5 Cyclopropyl Anions, 6\u003c\/p\u003e \u003cp\u003e1.6 Cyclopropyl Radicals, 7\u003c\/p\u003e \u003cp\u003e1.7 Cyclopropylidenes, 7\u003c\/p\u003e \u003cp\u003e1.8 Cyclopropylcarbinyl Cations, 8\u003c\/p\u003e \u003cp\u003e1.9 Cyclopropylcarbinyl Anions, 8\u003c\/p\u003e \u003cp\u003e1.10 Cyclopropylcarbinyl Radicals, 10\u003c\/p\u003e \u003cp\u003e1.11 Cyclopropylcarbenes, 10\u003c\/p\u003e \u003cp\u003e1.12 Conclusion, 11\u003c\/p\u003e \u003cp\u003eReferences, 13\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Ring Cleavage Reactions 15\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Cyclopropyl Activation, 16\u003c\/p\u003e \u003cp\u003e2.1.1 Halogen, Oxy, and Sulfur Substituted Cyclopropanes, 16\u003c\/p\u003e \u003cp\u003e2.1.2 Alkylidenecyclopropanes, 19\u003c\/p\u003e \u003cp\u003e2.2 Cyclopropylcarbinyl Activation, 23\u003c\/p\u003e \u003cp\u003e2.2.1 Halogeno, Oxy, Acyl and Metallomethyl Cyclopropanes, 23\u003c\/p\u003e \u003cp\u003e2.2.2 Alkylidenecyclopropanes, 27\u003c\/p\u003e \u003cp\u003e2.2.3 Vinyl and Ethynyl Cyclopropanes, 29\u003c\/p\u003e \u003cp\u003e2.2.4 1,2]Divinylcyclopropanes, 33\u003c\/p\u003e \u003cp\u003e2.2.5 Acceptor Cyclopropanes, 35\u003c\/p\u003e \u003cp\u003e2.2.6 Donor Cyclopropanes, 38\u003c\/p\u003e \u003cp\u003e2.2.7 Donor–Acceptor Cyclopropanes, 43\u003c\/p\u003e \u003cp\u003e2.3 Conclusion, 48\u003c\/p\u003e \u003cp\u003eReferences, 49\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Synthesis of Cyclopropanes 57\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 1,3]Cyclization Reactions, 57\u003c\/p\u003e \u003cp\u003e3.1.1 Cyclizations with Cleavage of Two Single Bonds, 58\u003c\/p\u003e \u003cp\u003e3.1.2 Cyclizations with Cleavage of One Double Bond and One Single Bond, 59\u003c\/p\u003e \u003cp\u003e3.1.3 Cyclizations with Cleavage of Two Double Bonds, 62\u003c\/p\u003e \u003cp\u003e3.2 [2 + 1] Cyclization Reactions, 65\u003c\/p\u003e \u003cp\u003e3.2.1 Cycloaddition of Carbene Equivalents to Olefins, 66\u003c\/p\u003e \u003cp\u003e3.2.2 Coupling of 1,1]Carbodianion and 1,2]Carbodication Equivalents, 79\u003c\/p\u003e \u003cp\u003e3.2.3 Coupling of 1,1]Carbodication and 1,2]Carbodianion Equivalents, 83\u003c\/p\u003e \u003cp\u003e3.3 Addition Reactions to the Double Bond of Cyclopropenes, 88\u003c\/p\u003e \u003cp\u003e3.4 Interconversion of Cyclopropanes, 90\u003c\/p\u003e \u003cp\u003e3.5 Conclusion, 90\u003c\/p\u003e \u003cp\u003eReferences, 90\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart Ii Synthetic Application 99\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eIntroduction, 99\u003c\/p\u003e \u003cp\u003eReferences, 100\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Triangulation Retrosynthetic Analysis 103\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Retrosynthetic Triangulation, 103\u003c\/p\u003e \u003cp\u003e4.2 Conclusion, 108\u003c\/p\u003e \u003cp\u003eReferences, 108\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Acyclic Compounds 109\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Formation of Carbon Substituents, 109\u003c\/p\u003e \u003cp\u003e5.1.1 Nonactivated Cyclopropane Precursors, 109\u003c\/p\u003e \u003cp\u003e5.1.2 Cyclopropylcarbinyl Activated Precursors, 112\u003c\/p\u003e \u003cp\u003e5.1.3 Cooperatively Activated Precursors, 138\u003c\/p\u003e \u003cp\u003e5.2 Formation of Olefin Groups, 139\u003c\/p\u003e \u003cp\u003e5.2.1 Cyclopropylcarbinyl Activated Precursors, 139\u003c\/p\u003e \u003cp\u003e5.2.2 Cyclopropyl Activated Precursors, 142\u003c\/p\u003e \u003cp\u003e5.2.3 Fragmentation of the Cyclopropane Precursors, 146\u003c\/p\u003e \u003cp\u003e5.2.4 Cooperatively Activated Cyclopropane Precursors, 147\u003c\/p\u003e \u003cp\u003e5.3 Formation of Carbonyl Groups, 151\u003c\/p\u003e \u003cp\u003e5.3.1 Cyclopropylcarbinyl Precursors, 151\u003c\/p\u003e \u003cp\u003e5.3.2 Cooperatively Activated Precursors, 156\u003c\/p\u003e \u003cp\u003e5.4 Retrosynthetic Account, 162\u003c\/p\u003e \u003cp\u003eReferences, 163\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Cyclobutane Derivatives 167\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Grandisol Syntheses, 167\u003c\/p\u003e \u003cp\u003e6.2 Cyclobutane Synthetic Intermediates, 169\u003c\/p\u003e \u003cp\u003e6.3 Retrosynthetic Account, 183\u003c\/p\u003e \u003cp\u003eReferences, 184\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Cyclopentanes 187\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Vinylcyclopropane–Cyclopentene Rearrangement, 187\u003c\/p\u003e \u003cp\u003e7.1.1 Cyclopropylcarbinyl Activated Precursors, 187\u003c\/p\u003e \u003cp\u003e7.1.2 Cooperatively Activated Precursors, 188\u003c\/p\u003e \u003cp\u003e7.2 Cycloaddition Reactions, 221\u003c\/p\u003e \u003cp\u003e7.2.1 Cyclopropylcarbinyl Activated Precursors, 221\u003c\/p\u003e \u003cp\u003e7.2.2 Cooperatively Activated Precursors, 221\u003c\/p\u003e \u003cp\u003e7.3 Modification of Substituents, 223\u003c\/p\u003e \u003cp\u003e7.3.1 N onactivated Cyclopropane Precursors, 223\u003c\/p\u003e \u003cp\u003e7.3.2 Cyclopropylcarbinyl Activated Precursors, 224\u003c\/p\u003e \u003cp\u003e7.3.3 Cooperatively Activated Precursors, 231\u003c\/p\u003e \u003cp\u003e7.3.4 Fragmentation Reactions, 245\u003c\/p\u003e \u003cp\u003e7.4 Retrosynthetic Account, 246\u003c\/p\u003e \u003cp\u003eReferences, 246\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Cyclohexanes 251\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Intramolecular Cyclization Reactions, 251\u003c\/p\u003e \u003cp\u003e8.2 Cycloaddition Reactions, 255\u003c\/p\u003e \u003cp\u003e8.3 Modification of Substituents, 269\u003c\/p\u003e \u003cp\u003e8.3.1 Cyclopropylcarbinyl Activated Precursors, 269\u003c\/p\u003e \u003cp\u003e8.3.2 Cyclopropyl Activated Precursors, 275\u003c\/p\u003e \u003cp\u003e8.3.3 Cooperatively Activated Precursors, 277\u003c\/p\u003e \u003cp\u003e8.4 Retrosynthetic Account, 282\u003c\/p\u003e \u003cp\u003eReferences, 283\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Cycloheptanes 285\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Divinylcyclopropane–Cycloheptadiene Rearrangement, 285\u003c\/p\u003e \u003cp\u003e9.2 Cycloaddition Reactions, 315\u003c\/p\u003e \u003cp\u003e9.3 Modification of Substituents, 318\u003c\/p\u003e \u003cp\u003e9.3.1 Nonactivated Cyclopropane Precursors, 318\u003c\/p\u003e \u003cp\u003e9.3.2 Cyclopropylcarbinyl Activated Precursors, 318\u003c\/p\u003e \u003cp\u003e9.3.3 Cyclopropyl Activated Precursors, 323\u003c\/p\u003e \u003cp\u003e9.3.4 Cooperatively Activated Precursors, 325\u003c\/p\u003e \u003cp\u003e9.4 Retrosynthetic Account, 329\u003c\/p\u003e \u003cp\u003eReferences, 330\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Cyclooctanes and Larger Carbocycles 333\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Cycloaddition Reactions, 333\u003c\/p\u003e \u003cp\u003e10.2 Modification of Substituents, 334\u003c\/p\u003e \u003cp\u003e10.2.1 Cyclopropylcarbinyl Activated Precursors, 334\u003c\/p\u003e \u003cp\u003e10.2.2 Cyclopropyl Activated Precursors, 338\u003c\/p\u003e \u003cp\u003e10.3 Retrosynthetic Account, 340\u003c\/p\u003e \u003cp\u003eReferences, 340\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Heterocyclic Compounds 341\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Intramolecular Cyclization Reactions, 341\u003c\/p\u003e \u003cp\u003e11.1.1 Nonactivated Cyclopropane Precursors, 341\u003c\/p\u003e \u003cp\u003e11.1.2 Cyclopropylcarbinyl Activated Precursors, 342\u003c\/p\u003e \u003cp\u003e11.1.3 Cyclopropyl Activated Precursors, 378\u003c\/p\u003e \u003cp\u003e11.1.4 Cooperatively Activated Precursors, 380\u003c\/p\u003e \u003cp\u003e11.2 Cycloaddition Reactions, 387\u003c\/p\u003e \u003cp\u003e11.2.1 Cyclopropylcarbinyl Activated Precursors, 387\u003c\/p\u003e \u003cp\u003e11.2.2 Cooperatively Activated Precursors, 390\u003c\/p\u003e \u003cp\u003e11.3 Modification of Substituents, 400\u003c\/p\u003e \u003cp\u003e11.3.1 Cyclopropylcarbinyl Activated Substrates, 400\u003c\/p\u003e \u003cp\u003e11.3.2 Cyclopropyl Activated Substrates, 402\u003c\/p\u003e \u003cp\u003e11.3.3 Cooperatively Activated Substrates, 402\u003c\/p\u003e \u003cp\u003e11.4 Retrosynthetic Account, 409\u003c\/p\u003e \u003cp\u003eReferences, 410\u003c\/p\u003e \u003cp\u003eCONCLUSION 415\u003c\/p\u003e \u003cp\u003eAUTHOR Index 417\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49406824350039,"sku":"9781118057438","price":136.76,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781118057438.jpg?v=1730497241","url":"https:\/\/bookcurl.com\/products\/cyclopropanes-in-organic-synthesis-9781118057438","provider":"Book Curl","version":"1.0","type":"link"}