{"product_id":"co2-as-a-building-block-in-organic-synthesis-9783527346134","title":"CO2 as a Building Block in Organic Synthesis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eA guide to the fascinating application of CO\u003csub\u003e2\u003c\/sub\u003e as a building block in organic synthesis\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eThis important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO\u003csub\u003e2\u003c\/sub\u003eas an attractive C1 building block. With contributions from an international panel of experts, \u003ci\u003eCO\u003csub\u003e2\u003c\/sub\u003e as a Building Block in Organic Synthesis\u003c\/i\u003e offers a review of the most important reactions which use CO\u003csub\u003e2\u003c\/sub\u003e as a building block in organic synthesis.\u003c\/p\u003e \u003cp\u003eThe contributors examine a wide-range of CO\u003csub\u003e2\u003c\/sub\u003e reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also:\u003c\/p\u003e \u003cul\u003e\n\u003cli\u003ePresents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more\u003c\/li\u003e\n\u003cli\u003eContains contributions from an international panel of experts\u003c\/li\u003e\n\u003cli\u003eOffers a comprehensive resource for academics and professionals in the field\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003eWritten for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, \u003ci\u003eCO\u003csub\u003e2\u003c\/sub\u003e as Building Block in Organic Synthesis\u003c\/i\u003e contains an analysis of the most important reactions which use CO\u003csub\u003e2\u003c\/sub\u003e as an effective building block in organic synthesis.\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003e1 Photochemical and Substrate‐Driven CO\u003csub\u003e2\u003c\/sub\u003e Conversion 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eBart Limburg, Cristina Maquilon, and Arjan W. Kleij\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Iodine Activation of (Homo)Allylic Substrates 3\u003c\/p\u003e \u003cp\u003e1.3 Substrate Activation Via Radical Addition\/Photochemical Oxidation Processes 9\u003c\/p\u003e \u003cp\u003e1.4 Substrate‐Induced Activation of Oxiranes 12\u003c\/p\u003e \u003cp\u003e1.5 Substrate‐Involved Activation of Oxetanes and Azetidines 21\u003c\/p\u003e \u003cp\u003e1.6 Concluding Remarks 21\u003c\/p\u003e \u003cp\u003eReferences 22\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 C–H Carboxylations with CO\u003csub\u003e2\u003c\/sub\u003e 29\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eUttam Dhawa, Isaac Choi, and Lutz Ackermann\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 29\u003c\/p\u003e \u003cp\u003e2.2 Transition‐Metal‐Catalyzed C–H Carboxylation 30\u003c\/p\u003e \u003cp\u003e2.2.1 Copper‐Catalyzed C–H Carboxylation 30\u003c\/p\u003e \u003cp\u003e2.2.2 Cobalt‐Catalyzed C–H Carboxylation 36\u003c\/p\u003e \u003cp\u003e2.2.3 Nickel‐Catalyzed C–H Carboxylation 36\u003c\/p\u003e \u003cp\u003e2.2.4 Molybdenum‐Catalyzed C–H Carboxylation 38\u003c\/p\u003e \u003cp\u003e2.2.5 Ruthenium‐Catalyzed C–H Carboxylation 38\u003c\/p\u003e \u003cp\u003e2.2.6 Rhodium‐Catalyzed C–H Carboxylation 39\u003c\/p\u003e \u003cp\u003e2.2.7 Palladium‐Catalyzed C–H Carboxylation 41\u003c\/p\u003e \u003cp\u003e2.2.8 Silver‐Catalyzed C–H Carboxylation 42\u003c\/p\u003e \u003cp\u003e2.2.9 Iridium‐Catalyzed C–H Carboxylation 45\u003c\/p\u003e \u003cp\u003e2.2.10 Gold‐Catalyzed C–H Carboxylation 45\u003c\/p\u003e \u003cp\u003e2.2.11 Neodymium‐Catalyzed C–H Carboxylation 45\u003c\/p\u003e \u003cp\u003e2.3 Metal‐Free C–H Carboxylation 46\u003c\/p\u003e \u003cp\u003e2.3.1 Base‐Mediated C–H Carboxylation 46\u003c\/p\u003e \u003cp\u003e2.3.2 Electro‐Catalyzed C–H Carboxylation 49\u003c\/p\u003e \u003cp\u003e2.3.3 Lewis Acid‐Mediated Carboxylation 49\u003c\/p\u003e \u003cp\u003e2.3.4 Light‐Driven Carboxylation 50\u003c\/p\u003e \u003cp\u003e2.4 CO\u003csub\u003e2\u003c\/sub\u003e Carboxylation Promoted by Transition Metal Complexes 52\u003c\/p\u003e \u003cp\u003e2.5 Conclusions 53\u003c\/p\u003e \u003cp\u003eReferences 53\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Transition‐Metal‐Catalyzed C–H Carboxylation 59\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJoaquim Caner and Nobuharu Iwasawa\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 59\u003c\/p\u003e \u003cp\u003e3.2 Direct C–H Carboxylation of Electron‐Deficient Arenes and (Hetero) Arenes Catalyzed by Basic Complexes 59\u003c\/p\u003e \u003cp\u003e3.3 Direct Carboxylation of Inert Csp2─H Bonds 66\u003c\/p\u003e \u003cp\u003e3.3.1 Rhodium‐Catalyzed C–H Carboxylation Reactions 66\u003c\/p\u003e \u003cp\u003e3.3.2 Palladium‐Catalyzed C–H Carboxylation Reactions 76\u003c\/p\u003e \u003cp\u003e3.4 Direct Carboxylation of Csp3─H Bonds 85\u003c\/p\u003e \u003cp\u003e3.5 Summary and Outlook 89\u003c\/p\u003e \u003cp\u003eReferences 90\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Fixation of CO\u003csub\u003e2\u003c\/sub\u003e in Organic Molecules with Heterogeneous Catalysts 95\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eDongcheng He, Hongli Wang, and Feng Shi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 95\u003c\/p\u003e \u003cp\u003e4.2 CO\u003csub\u003e2\u003c\/sub\u003e Cycloaddition to Epoxide 96\u003c\/p\u003e \u003cp\u003e4.2.1 Oxides 96\u003c\/p\u003e \u003cp\u003e4.2.2 Zeolite Catalysts 97\u003c\/p\u003e \u003cp\u003e4.2.3 Supported Nanoparticle and Lewis Acid Catalysts 98\u003c\/p\u003e \u003cp\u003e4.2.4 Carbon and Its Derivatives 99\u003c\/p\u003e \u003cp\u003e4.2.5 Salen, Porphyrin, and Phthalocyanine Catalyst 101\u003c\/p\u003e \u003cp\u003e4.2.6 Ionic Liquid Catalyst 103\u003c\/p\u003e \u003cp\u003e4.2.7 Metal−Organic Framework (MOF) Catalyst 108\u003c\/p\u003e \u003cp\u003e4.2.8 Bifunctional Catalyst 112\u003c\/p\u003e \u003cp\u003e4.2.9 Other Catalysts 120\u003c\/p\u003e \u003cp\u003e4.3 Reactions of Aziridines and CO\u003csub\u003e2\u003c\/sub\u003e 120\u003c\/p\u003e \u003cp\u003e4.4 Reactions of Polyalcohols\/Olefins and CO\u003csub\u003e2\u003c\/sub\u003e 121\u003c\/p\u003e \u003cp\u003e4.5 Reaction of Propargyl Alcohols\/Propargyl Amines and CO\u003csub\u003e2\u003c\/sub\u003e 124\u003c\/p\u003e \u003cp\u003e4.6 Reactions of Terminal Alkynes and CO\u003csub\u003e2\u003c\/sub\u003e 125\u003c\/p\u003e \u003cp\u003e4.7 Formylation of Amines and CO\u003csub\u003e2\u003c\/sub\u003e 127\u003c\/p\u003e \u003cp\u003e4.8 Methylation of Amines and CO\u003csub\u003e2\u003c\/sub\u003e 130\u003c\/p\u003e \u003cp\u003e4.9 Other Reactions of Amines and CO\u003csub\u003e2\u003c\/sub\u003e131\u003c\/p\u003e \u003cp\u003e4.10 Hydroformylation of CO\u003csub\u003e2\u003c\/sub\u003e and Olefins into Alcohols 133\u003c\/p\u003e \u003cp\u003e4.11 Reactions of Aromatic Halides and CO\u003csub\u003e2\u003c\/sub\u003e 134\u003c\/p\u003e \u003cp\u003e4.12 Reactions of 2‐Aminobenzonitriles and CO\u003csub\u003e2\u003c\/sub\u003e 136\u003c\/p\u003e \u003cp\u003e4.13 Conclusions 137\u003c\/p\u003e \u003cp\u003eReferences 138\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 CO\u003csub\u003e2\u003c\/sub\u003e Fixation into Organic Molecules via Carbon–Heteroatom Bond Formation 155\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYu‐Nong Li, Hong‐Ru Li and Liang‐Nian He\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 155\u003c\/p\u003e \u003cp\u003e5.2 CO2 Conversion with C\u003cb\u003e─\u003c\/b\u003eN Bond Formation 157\u003c\/p\u003e \u003cp\u003e5.2.1 Synthesis of Oxazolidinones 157\u003c\/p\u003e \u003cp\u003e5.2.1.1 Oxazolidinone Synthesis from Aziridine and CO\u003csub\u003e2\u003c\/sub\u003e 158\u003c\/p\u003e \u003cp\u003e5.2.1.2 Oxazolidinone Synthesis from Olefin, a Nitrogen Source, and CO\u003csub\u003e2\u003c\/sub\u003e 163\u003c\/p\u003e \u003cp\u003e5.2.1.3 Oxazolidinone Synthesis from Amino Alcohols and CO\u003csub\u003e2\u003c\/sub\u003e 164\u003c\/p\u003e \u003cp\u003e5.2.1.4 Oxazolidinone Synthesis from Carboxylative Cyclization of Propargyl Amines with CO\u003csub\u003e2\u003c\/sub\u003e 165\u003c\/p\u003e \u003cp\u003e5.2.1.5 Oxazolidinone Synthesis from Propargyl Alcohol, Aliphatic Amines\/2‐Aminoethanols, and CO\u003csub\u003e2\u003c\/sub\u003e 167\u003c\/p\u003e \u003cp\u003e5.2.1.6 Photoinduced Radical‐Initiated Carboxylative Cyclization of Allyl Amines with CO\u003csub\u003e2\u003c\/sub\u003e 170\u003c\/p\u003e \u003cp\u003e5.2.2 Synthesis of Isocyanates and Linear Carbamates 172\u003c\/p\u003e \u003cp\u003e5.2.3 Synthesis of Urea Derivatives 174\u003c\/p\u003e \u003cp\u003e5.2.4 Synthesis of Quinazolines 175\u003c\/p\u003e \u003cp\u003e5.3 CO\u003csub\u003e2\u003c\/sub\u003e Conversion with C─O Bond Formation 178\u003c\/p\u003e \u003cp\u003e5.3.1 Synthesis of Cyclic Carbonates 178\u003c\/p\u003e \u003cp\u003e5.3.1.1 Cyclic Carbonate Synthesis from Epoxide and CO\u003csub\u003e2\u003c\/sub\u003e 178\u003c\/p\u003e \u003cp\u003e5.3.1.2 α‐Alkylidene Cyclic Carbonate Synthesis from Carboxylative Cyclization of Propargyl Alcohols with CO\u003csub\u003e2\u003c\/sub\u003e 181\u003c\/p\u003e \u003cp\u003e5.3.1.3 Cyclic Carbonate Synthesis from Carboxylative Cyclization of 1,2‐Diols with CO\u003csub\u003e2\u003c\/sub\u003e 182\u003c\/p\u003e \u003cp\u003e5.3.1.4 One‐Pot Stepwise Synthesis of Cyclic Carbonates Directly from Olefins or Vicinal Halohydrins with CO\u003csub\u003e2\u003c\/sub\u003e 183\u003c\/p\u003e \u003cp\u003e5.3.2 Synthesis of Linear Carbonates 185\u003c\/p\u003e \u003cp\u003e5.4 CO\u003csub\u003e2\u003c\/sub\u003e Conversion with C─S Bond Formation 187\u003c\/p\u003e \u003cp\u003e5.4.1 Synthesis of Dithioacetals 187\u003c\/p\u003e \u003cp\u003e5.4.2 Synthesis of Benzothiazolones 188\u003c\/p\u003e \u003cp\u003e5.4.3 Synthesis of Benzothiazoles 189\u003c\/p\u003e \u003cp\u003e5.5 Carbon–Heteroatom Bond Formation from the Captured CO\u003csub\u003e2\u003c\/sub\u003e or CO\u003csub\u003e2 \u003c\/sub\u003eDerivatives 190\u003c\/p\u003e \u003cp\u003e5.6 Conclusions 191\u003c\/p\u003e \u003cp\u003eAbbreviations 192\u003c\/p\u003e \u003cp\u003eReferences 193\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Carbonyl‐Ene Reactions of Alkenes with Carbon Dioxide 199\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYasuyuki Mori and Masanari Kimura\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 199\u003c\/p\u003e \u003cp\u003e6.2 Carbonyl‐Ene Reactions of Alkenes with CO\u003csub\u003e2\u003c\/sub\u003e 199\u003c\/p\u003e \u003cp\u003e6.2.1 Organoaluminum and Pyridine Derivative‐Mediated Coupling Reaction 199\u003c\/p\u003e \u003cp\u003e6.2.2 Light‐Induced Copper‐Catalyzed Carboxylation of Allylic C─H Bonds 204\u003c\/p\u003e \u003cp\u003e6.2.3 Copper and Aluminum Ate Compound System for Carboxylation of Allylic C─H Bond of Alkenes 208\u003c\/p\u003e \u003cp\u003e6.2.4 Cobalt‐Catalyzed Carboxylation of Allylic C─H Bond of Terminal Alkenes 212\u003c\/p\u003e \u003cp\u003e6.2.5 Nickel‐Catalyzed Carbonyl‐ene‐Type Reaction of Terminal Alkenes with CO\u003csub\u003e2\u003c\/sub\u003e 217\u003c\/p\u003e \u003cp\u003eReferences 223\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Recent Advances in Electrochemical Carboxylation of Organic Compounds for CO\u003csub\u003e2\u003c\/sub\u003e Valorization 225\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLuca Dell’Amico, Marcella Bonchio, and Xavier Companyo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 225\u003c\/p\u003e \u003cp\u003e7.2 Electrochemical Carboxylation of Unsaturated Compounds 228\u003c\/p\u003e \u003cp\u003e7.3 Electrochemical Carboxylation of Organic Halides 236\u003c\/p\u003e \u003cp\u003e7.4 Stereoselective Electrochemical Carboxylations 245\u003c\/p\u003e \u003cp\u003e7.5 Conclusions 249\u003c\/p\u003e \u003cp\u003eReferences 250\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Photocatalysis as a Powerful Tool for the Utilization of CO\u003csub\u003e2\u003c\/sub\u003e in Organic Synthesis 253\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eDaniel Riemer and Shoubhik Das\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Key Intermediate Involving Substrate with Late‐Stage CO\u003csub\u003e2\u003c\/sub\u003e Addition\/Insertion 254\u003c\/p\u003e \u003cp\u003e8.1.1 Unsaturated Substrates 254\u003c\/p\u003e \u003cp\u003e8.1.2 Aryl Halides 264\u003c\/p\u003e \u003cp\u003e8.1.3 Benzylic C─H Bonds 267\u003c\/p\u003e \u003cp\u003e8.2 CO2 Substrate Adduct as the Key Intermediate 269\u003c\/p\u003e \u003cp\u003e8.3 CO2 Radical Anion as a Key Intermediate 276\u003c\/p\u003e \u003cp\u003e8.4 Hydroxycarbonyl Radical as a Key Intermediate 282\u003c\/p\u003e \u003cp\u003e8.5 Conclusion and Outlook 284\u003c\/p\u003e \u003cp\u003eReferences 285\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Direct Carboxylation of Alkenes and Alkynes 291\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMartin Pichette Drapeau, Johannes Schranck, and Anis Tlili\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 291\u003c\/p\u003e \u003cp\u003e9.2 Carboxylation of Alkenes 291\u003c\/p\u003e \u003cp\u003e9.2.1 Stoichiometric Carboxylation of Alkenes 291\u003c\/p\u003e \u003cp\u003e9.2.2 Catalytic Hydrocarboxylation of Alkenes 295\u003c\/p\u003e \u003cp\u003e9.2.3 Photoinduced Hydrocarboxylation of Alkenes 300\u003c\/p\u003e \u003cp\u003e9.2.4 Difunctionalization of Alkenes with Carbon Dioxide 304\u003c\/p\u003e \u003cp\u003e9.3 Carboxylation of Alkynes 305\u003c\/p\u003e \u003cp\u003e9.3.1 Carboxylation of Terminal Alkynes 305\u003c\/p\u003e \u003cp\u003e9.3.1.1 Synthesis of Propiolic Esters 305\u003c\/p\u003e \u003cp\u003e9.3.1.2 Synthesis of Propiolic Acids 308\u003c\/p\u003e \u003cp\u003e9.3.2 Synthesis of Acrylic Acid Derivatives 316\u003c\/p\u003e \u003cp\u003e9.3.2.1 Hydrocarboxylation 316\u003c\/p\u003e \u003cp\u003e9.3.2.2 Alkyl‐ and Arylcarboxylations 321\u003c\/p\u003e \u003cp\u003e9.3.2.3 Sila‐ and Boracarboxylations 323\u003c\/p\u003e \u003cp\u003e9.3.3 Carboxylation Leading to Cyclization Products 324\u003c\/p\u003e \u003cp\u003e9.4 Conclusions 326\u003c\/p\u003e \u003cp\u003eReferences 327\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Homogeneous Iron Catalysts for the Synthesis of Useful Molecules from CO\u003csub\u003e2 \u003c\/sub\u003e331\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eFrancesco Della Monica and Carmine Capacchione\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 331\u003c\/p\u003e \u003cp\u003e10.2 Reductive Processes 332\u003c\/p\u003e \u003cp\u003e10.2.1 Hydrogenation 332\u003c\/p\u003e \u003cp\u003e10.2.2 Hydrosilylation and Hydroboration 335\u003c\/p\u003e \u003cp\u003e10.2.3 Mechanistic Details 336\u003c\/p\u003e \u003cp\u003e10.3 Nonreductive Processes 337\u003c\/p\u003e \u003cp\u003e10.3.1 Cyclic Organic Carbonates and Aliphatic Polycarbonates from CO\u003csub\u003e2 \u003c\/sub\u003eand Epoxides 337\u003c\/p\u003e \u003cp\u003e10.3.2 Mechanistic Details 346\u003c\/p\u003e \u003cp\u003e10.3.3 Stereochemistry of Cyclic Organic Carbonates 354\u003c\/p\u003e \u003cp\u003e10.3.4 Oxazolidinones 358\u003c\/p\u003e \u003cp\u003e10.4 Conclusions 360\u003c\/p\u003e \u003cp\u003eReferences 360\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 NHC‐catalyzed CO\u003csub\u003e2\u003c\/sub\u003e Fixations in Organic Synthesis 367\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eVishakha Goyal, Naina Sarki, Anand Narani, and Kishore Natte\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 367\u003c\/p\u003e \u003cp\u003e11.2 Direct C–H Activation with CO\u003csub\u003e2\u003c\/sub\u003e 369\u003c\/p\u003e \u003cp\u003e11.2.1 C–H Activation of Terminal Alkynes 369\u003c\/p\u003e \u003cp\u003e11.2.2 Carboxylation of Arenes and Heteroarenes 373\u003c\/p\u003e \u003cp\u003e11.2.3 Carboxylation of Alkenes and Organoboronic Esters 376\u003c\/p\u003e \u003cp\u003e11.3 Oxidation of Aldehydes with CO\u003csub\u003e2 \u003c\/sub\u003e376\u003c\/p\u003e \u003cp\u003e11.4 Cyclization Reactions with CO\u003csub\u003e2\u003c\/sub\u003e 379\u003c\/p\u003e \u003cp\u003e11.4.1 Synthesis of Cyclic Carbonates from CO\u003csub\u003e2\u003c\/sub\u003e and Epoxides 379\u003c\/p\u003e \u003cp\u003e11.4.2 Cyclization of CO\u003csub\u003e2\u003c\/sub\u003e in Presence of NHC–CO\u003csub\u003e2\u003c\/sub\u003e Adducts 380\u003c\/p\u003e \u003cp\u003e11.4.3 Cyclization of CO\u003csub\u003e2\u003c\/sub\u003e in Presence of Metal NHCs Complexes 382\u003c\/p\u003e \u003cp\u003e11.4.4 Cyclization of Propargylic Amines 385\u003c\/p\u003e \u003cp\u003e11.5 Alkylation with CO\u003csub\u003e2\u003c\/sub\u003e 387\u003c\/p\u003e \u003cp\u003e11.5.1 N‐methylation 387\u003c\/p\u003e \u003cp\u003e11.5.2 N‐formylation 388\u003c\/p\u003e \u003cp\u003e11.6 Miscellaneous 390\u003c\/p\u003e \u003cp\u003e11.7 Summary 393\u003c\/p\u003e \u003cp\u003eReferences 393\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Silver‐Catalyzed CO\u003csub\u003e2\u003c\/sub\u003e Fixation 397\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKodai Saito and Tohru Yamada\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 397\u003c\/p\u003e \u003cp\u003e12.2 Historical Background of Carbon Dioxide Fixation into Organosilver Complexes 398\u003c\/p\u003e \u003cp\u003e12.3 Carboxylation of Terminal Alkynes 399\u003c\/p\u003e \u003cp\u003e12.4 Cascade Carboxylative Cyclization 404\u003c\/p\u003e \u003cp\u003e12.5 Silver‐Catalyzed Sequential Carboxylative Cyclization of Propargyl Alcohols 405\u003c\/p\u003e \u003cp\u003e12.6 Synthesis of Cyclic Carbonate 405\u003c\/p\u003e \u003cp\u003e12.7 Catalytic Asymmetric Synthesis of Cyclic Carbonate 411\u003c\/p\u003e \u003cp\u003e12.8 Three‐Component Reaction of Propargyl Alcohols, Carbon Dioxide, and Nucleophiles 411\u003c\/p\u003e \u003cp\u003e12.9 CO\u003csub\u003e2\u003c\/sub\u003e‐Mediated Transformation of Propargyl Alcohols 412\u003c\/p\u003e \u003cp\u003e12.10 Transformation of Amine Derivatives 417\u003c\/p\u003e \u003cp\u003e12.11 Cascade Carboxylation and Cyclization of Unsaturated Amine Derivatives 417\u003c\/p\u003e \u003cp\u003e12.11.1 Benzoxazine‐2‐one from \u003ci\u003eo\u003c\/i\u003e‐Alkynylaniline and Carbon Dioxide 418\u003c\/p\u003e \u003cp\u003e12.11.2 Cascade Carboxylation – Addition to Allenes 418\u003c\/p\u003e \u003cp\u003e12.11.3 Three‐Component Reaction of Carbon Dioxide, Amines, and Aryloxyallens 419\u003c\/p\u003e \u003cp\u003e12.12 Domino Carboxylation – Cyclization – Migration of Unsaturated Amines 421\u003c\/p\u003e \u003cp\u003e12.12.1 Carboxylation Involving C-C Bond Formation – Sequential Cyclization 423\u003c\/p\u003e \u003cp\u003e12.12.2 Carboxylation of Enolate – Sequential Cyclization 423\u003c\/p\u003e \u003cp\u003e12.12.3 Carbon Dioxide Incorporation Reaction Using Other Carbanions 427\u003c\/p\u003e \u003cp\u003e12.13 Carboxylation of Arylboronic Esters 428\u003c\/p\u003e \u003cp\u003e12.13.1 Functionalization of Terminal Epoxides 431\u003c\/p\u003e \u003cp\u003e12.14 Conclusion 432\u003c\/p\u003e \u003cp\u003eReferences 433\u003c\/p\u003e \u003cp\u003eIndex 437\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":49419451400535,"sku":"9783527346134","price":118.76,"currency_code":"GBP","in_stock":false}],"url":"https:\/\/bookcurl.com\/products\/co2-as-a-building-block-in-organic-synthesis-9783527346134","provider":"Book Curl","version":"1.0","type":"link"}