{"product_id":"chirality-in-supramolecular-assemblies-9781118867341","title":"Chirality in Supramolecular Assemblies","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eSupramolecular chemistry deals with the organisation of molecules into defined assemblies using non-covalent interactions, including weaker and reversible interactions such as hydrogen bonds, and metal-ligand interactions. The aspect of stereochemistry within such chemical architectures, and in particular chirality, is of special interest as it impacts on considerations of molecular recognition, the development of functional materials, the vexed question of homochirality, nanoscale effects of interactions at interfaces, biocatalysis and enzymatic catalysis, and applications in organic synthesis.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eChirality in Supramolecular Assemblies\u003c\/i\u003e addresses many of these aspects, presenting a broad overview of this important and rapidly developing interdisciplinary field. Topics covered include:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eOrigins of molecular and topological chirality\u003c\/li\u003e \u003cli\u003eHomochirogenesis\u003c\/li\u003e \u003cli\u003eChirality in crystallinity\u003c\/li\u003e \u003cli\u003eHost-guest behavior\u003c\/li\u003e \u003cli\u003eChiral influences in functiona\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eList of Contributors xi \u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Principles of Molecular Chirality 1\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJean]Claude Chambron and F. Richard Keene\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 General Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Geometrical Chirality 2\u003c\/p\u003e \u003cp\u003e1.3 Topological Chirality 25\u003c\/p\u003e \u003cp\u003e1.4 Conclusion 39\u003c\/p\u003e \u003cp\u003eReferences 39\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Homochirogenesis and the Emergence of Lifelike Structures 44\u003c\/b\u003e\u003cbr\u003e\u003ci\u003ePedro Cintas\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction and Scope 44\u003c\/p\u003e \u003cp\u003e2.2 The Racemic State: Mirror Symmetry Breaking 45\u003c\/p\u003e \u003cp\u003e2.3 Asymmetric Oligomerization 49\u003c\/p\u003e \u003cp\u003e2.4 Biochirality in Active Sites 58\u003c\/p\u003e \u003cp\u003e2.5 Conclusions 61\u003c\/p\u003e \u003cp\u003eAcknowledgements 61\u003c\/p\u003e \u003cp\u003eReferences 61\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Aspects of Crystallization and Chirality 65\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eRoger Bishop\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 65\u003c\/p\u003e \u003cp\u003e3.2 Crystal Space Groups 65\u003c\/p\u003e \u003cp\u003e3.3 Fundamentals of Crystallization for a Racemic Mixture 69\u003c\/p\u003e \u003cp\u003e3.4 More Complex Crystallization Behavior 71\u003c\/p\u003e \u003cp\u003e3.5 Multiple Crystal Forms 74\u003c\/p\u003e \u003cp\u003e3.6 Conglomerates Revisited 85\u003c\/p\u003e \u003cp\u003eReferences 90\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Complexity of Supramolecular Assemblies 94\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJonathan A. Kitchen and Philip A. Gale\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 94\u003c\/p\u003e \u003cp\u003e4.2 Generating Supramolecular Chirality through Assembly of Achiral Components 96\u003c\/p\u003e \u003cp\u003e4.3 Enantioselective Supramolecular Assemblies 121\u003c\/p\u003e \u003cp\u003e4.4 Conclusions and Future Outlook 134\u003c\/p\u003e \u003cp\u003eReferences 134\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Chirality in the Host]Guest Behaviour of Supramolecular Systems 142\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eNicholas H. Evans and Paul D. Beer\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 An Introduction to Chiral Recognition and its Importance 142\u003c\/p\u003e \u003cp\u003e5.2 Chiral Hosts for Chiral Guests 143\u003c\/p\u003e \u003cp\u003e5.3 Conclusions: Summary and Future Directions 155\u003c\/p\u003e \u003cp\u003eReferences 156\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Chiral Influences in Functional Molecular Materials 159\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eDavid B. Amabilino\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 159\u003c\/p\u003e \u003cp\u003e6.2 Functional Molecular Materials in Different States 161\u003c\/p\u003e \u003cp\u003e6.3 Switching 168\u003c\/p\u003e \u003cp\u003e6.4 Conducting Materials 171\u003c\/p\u003e \u003cp\u003e6.5 Magnetic Materials 173\u003c\/p\u003e \u003cp\u003e6.6 Sensors 177\u003c\/p\u003e \u003cp\u003e6.7 Conclusions and Outlook 180\u003c\/p\u003e \u003cp\u003eAcknowledgements 181\u003c\/p\u003e \u003cp\u003eReferences 181\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Chirality in Network Solids 190\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eDavid R. Turner\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 190\u003c\/p\u003e \u003cp\u003e7.2 Chirality in Inorganic Network Solids 191\u003c\/p\u003e \u003cp\u003e7.3 Synthesis of Chiral Coordination Polymers 192\u003c\/p\u003e \u003cp\u003e7.4 Applications of Chiral Coordination Polymers 207\u003c\/p\u003e \u003cp\u003e7.5 Summary and Outlook 209\u003c\/p\u003e \u003cp\u003eReferences 210\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Chiral Metallosupramolecular Polyhedra 218\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJack K. Clegg and John C. McMurtrie\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 218\u003c\/p\u003e \u003cp\u003e8.2 Basic Design Principles 219\u003c\/p\u003e \u003cp\u003e8.3 Chiral Polyhedra from Achiral Components 221\u003c\/p\u003e \u003cp\u003e8.4 Stereochemical Communication 231\u003c\/p\u003e \u003cp\u003e8.5 Resolution of Racemic Metallo]Supramolecular Polyhedra 236\u003c\/p\u003e \u003cp\u003e8.6 Chiral Polyhedra from Chiral Molecular Components 239\u003c\/p\u003e \u003cp\u003e8.7 Conclusions and Outlook 250\u003c\/p\u003e \u003cp\u003eReferences 251\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Chirality at the Solution\/Solid]State Interface 257\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eIris Destoop and Steven De Feyter\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Self]Assembly at the Solution \/ Solid]State Interface 257\u003c\/p\u003e \u003cp\u003e9.2 Chirality Expression at the Solution \/ Solid]State Interface 258\u003c\/p\u003e \u003cp\u003e9.3 Chiral Induction \/ Amplification at the Solution \/ Solid]State Interface 266\u003c\/p\u003e \u003cp\u003e9.4 Towards Applications 278\u003c\/p\u003e \u003cp\u003e9.5 Conclusions 282\u003c\/p\u003e \u003cp\u003eReferences 282\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Nanoscale Aspects of Chiral Nucleation and Propagation 285\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eEdward G. Latter and Rasmita Raval\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 285\u003c\/p\u003e \u003cp\u003e10.2 Systems of Discussion 288\u003c\/p\u003e \u003cp\u003e10.3 Conclusions 303\u003c\/p\u003e \u003cp\u003eReferences 304\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Chirality in Organic Hosts 307\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eDaniel Fankhauser and Christopher J. Easton\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 307\u003c\/p\u003e \u003cp\u003e11.2 Chiral Hosts in Analytical Applications 307\u003c\/p\u003e \u003cp\u003e11.3 Chiral Hosts in Asymmetric Reactions 313\u003c\/p\u003e \u003cp\u003e11.4 Conclusion 337\u003c\/p\u003e \u003cp\u003eAcknowledgements 338\u003c\/p\u003e \u003cp\u003eReferences 338\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Chirality Related to Biocatalysis and Enzymes in Organic Synthesis 343\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eDeclan P. Gavin and Anita R. Maguire\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 343\u003c\/p\u003e \u003cp\u003e12.2 Biocatalysis 344\u003c\/p\u003e \u003cp\u003e12.3 Biocatalytic Methodologies: Kinetic\/Dynamic Kinetic Resolution and Asymmetric Transformations\/Chemoselective Desymmetrizations 348\u003c\/p\u003e \u003cp\u003e12.4 Optimization of Biocatalyst Performance 351\u003c\/p\u003e \u003cp\u003e12.5 Protein Engineering 352\u003c\/p\u003e \u003cp\u003e12.6 Hydrolysis\/Reverse Hydrolysis 356\u003c\/p\u003e \u003cp\u003e12.7 Redox Reactions 366\u003c\/p\u003e \u003cp\u003e12.8 C]C and Other C]X Bond Formation 380\u003c\/p\u003e \u003cp\u003e12.9 Future and Outlook 385\u003c\/p\u003e \u003cp\u003eReferences 385\u003c\/p\u003e \u003cp\u003eIndex 407\u003c\/p\u003e\n\u003c\/li\u003e\n\u003c\/ul\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49528839373143,"sku":"9781118867341","price":117.85,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781118867341.jpg?v=1731873224","url":"https:\/\/bookcurl.com\/products\/chirality-in-supramolecular-assemblies-9781118867341","provider":"Book Curl","version":"1.0","type":"link"}